24CALSULPH_TDS.pdf

PERFORMANCE MINERALS CORP.
10220 Wicker Ave Ste 4
Saint John, Indiana 46373

PRODUCT BULLETIN

PMC SP

PMC dihydrous calcium sulfates are ground fillers/extenders. Particle sizing is computer
controlled with air classifiers, thereby increasing the uniformity of the particulate. Our
unique processing technique e nsures that no oversize particles enter the product stream.
This allows for higher filler loading and/or lower working viscosities. Consistent product
uniformity, low moisture content, and economical pricing are inherent to all of PMC s
products.

APPLICATIONS TYPICAL PHYSICAL PROPERTIES

PMC products find extensive use in Bound Water 19.12%
fiberglass, adhesives, caulks, putties,
coatings, floor tile, joint cement and Hardness (Mohs) 2
plastics.
Specific Gravity 2.32

TYPICAL CHEMICAL COMPOSITION PH 7.8

CaSO
4 2H2O 91-92 Color White

MgCO
3 1 2% Average Bulk Density lb/ft3 50-55

CaCO
3 Less Than 1% Average Particle Size, Microns Proprietary

FE2O3 Less Than .05% Screen Analysis (US Standard):
% Retained 100 mesh Trace
AI
2O3 Less Than .2% % Retained 200 mesh 5-8
% Retained 325 mesh 25-28

24BJO0930Q_TDS.pdf

BJO-0930

mac@mac-resins.com

PHENOSET

MICROSPHERES

BJO-0930 hollow microspheres are reddish-brown in colour and primarily used as a hollow
filler. The density and maximum working pressure allows the formulator to choose the
minimum density product that will survive formulation, pumping and use.

TYPICAL PROPERTIES

Average Hydrostatic Compressive Strength 350 psi

Liquid Density (Liquid Displacement) 0.21 to 0.25 g/mL

Average Bulk Density 0.104g/cc max

Moisture Content < 4 wt % Floatation in Toluene Dupanol solution > 90 %

Mean Particle Size 90 microns by sieve method
65 microns by laser diffraction

PACKAGING

Polyethylene-lined cardboard boxes
Phenoset

BJO-0930 :12.0 kgs / 26.4 lbs

STORAGE AND HANDLING

Store Phenoset

microspheres in a cool, well-ventilated area
Keep away from sunlight

For further information on storage and handling, please refer to the Material Safety Data
Sheets.

PRODUCT SAFETY

When considering the use of MAC products in a particular application, kindly review our
latest Material Safety Data Sheets and ensure that the use you intend can be
accomplished safely. For Material Safety Data Sheets and other product safety information,
contact Malayan Adhesives & Chemicals Sales / Distributor s Office nearest to you.

Date of issue : April 1, 2008

IMPORTANT : This information is not to be taken as a warranty or representation for which we assume legal responsibility nor
as permission or recommendation to practice any patented invention without license. It is offered solely for your consideration
and investigation. Since your specific application and conditions of use are beyond the control of Malayan Adhesives &
Chemicals Sdn Bhd, you must determine the suitability of the products and the suggestions mentioned herewith for your
specific application.

243MK-1_TDS.pdf

3
Introduction
3M
Glass Bubbles are engineered hollow glass microspheres
that are alternatives to conventional fillers and additives such as
silicas, calcium carbonate, talc, clay, etc., for many demanding
applications. These low-density particles are used in a wide range
of industries to reduce part weight, lower costs and enhance
product properties.
The unique spherical shape of 3M glass bubbles offers a number
of important benefits, including: higher filler loading, lower
viscosity/improved flow and reduced shrinkage and warpage. It
also helps the 3M glass bubbles blend readily into compounds
and makes them adaptable to a variety of production processes
including spraying, casting and molding.
The chemically stable soda-lime-borosilicate glass composition
of 3M glass bubbles provides excellent water resistance to create
more stable emulsions. They are also non-combustible and non-
porous, so they do not absorb resin. And, their low alkalinity gives
3M glass bubbles compatibility with most resins, stable viscosity
and long shelf life.
3M Glass Bubbles K Series, S Series and iM Series are specially
formulated for a high strength-to-weight ratio. This allows greater
survivability under many demanding processing conditions, such
as injection molding. They also produce stable voids, which results
in low thermal conductivity and a low dielectric constant. 3M glass
bubbles are available in a variety of sizes and grades to help you
meet your product and processing requirements.
3M

Glass Bubbles
K Series, S Series and iM Series
Product Information
Product
Test Pressure
(psi)
Target Fractional
Survival
Minimum
Fractional
Survival
K Series
K1 250 90% 80%
K15 300 90% 80%
K20 500 90% 80%
K25 750 90% 80%
K37 3,000 90% 80%
K46 6,000 90% 80%
S Series
S15 300 90% 80%
S22 400 90% 80%
S32 2,000 90% 80%
S35 3,000 90% 80%
S38 4,000 90% 80%
S38HS 5,500 90% 80%
S60 10,000 90% 80%
S60HS 18,000 90% 90%
iM Series
iM16K 16,000 90% 90%
iM30K 28,000 90% 90%
Isostatic Crush Strength
True Density (g/cc)
Product Typical Minimum Maximum
K Series
K1 0.125 0.10 0.14
K15 0.15 0.13 0.17
K20 0.20 0.18 0.22
K25 0.25 0.23 0.27
K37 0.37 0.34 0.40
K46 0.46 0.43 0.49
S Series
S15 0.15 0.13 0.17
S22 0.22 0.19 0.25
S32 0.32 0.29 0.35
S35 0.35 0.32 0.38
S38 0.38 0.35 0.41
S38HS 0.38 0.35 0.41
S60 0.60 0.57 0.63
S60HS 0.60 0.57 0.63
iM Series
iM16K 0.46 0.43 0.49
iM30K 0.60 0.57 0.63
True Density
Typical Properties
Not for specification purposes

Typical Properties
Chemical Resistance
In general, the chemical properties of 3M
Glass Bubbles
resemble those of a soda-lime-borosilicate glass.
Thermal Conductivity
Product
Calculated Thermal Conductivity
(W m-1 K-1) at 70 F (21 C)
K Series
K1 0.047
K15 0.055
K20 0.070
K25 0.085
K37 0.124
K46 0.153
S Series
S15 0.055
S22 0.076
S32 0.108
S35 0.117
S38 0.127
S38HS 0.127
S60 0.200
S60HS 0.200
iM Series
iM16K 0.153
iM30K 0.200
Conductivity increases with temperature and product density. The
thermal conductivity of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Thermal Stability
Appreciable changes in bubble properties may occur above 1112 F
(600 C) depending on temperature and duration of exposure.
Flotation
Floaters (% by bulk volume)
Product Typical Minimum
K Series
K1 96% 90%
K15 96% 90%
K20 96% 90%
K25 96% 90%
K37 94% 90%
K46 92% 90%
S Series
S15 96% 90%
S22 96% 90%
S32 94% 90%
S35 96% 90%
S38 94% 90%
S38HS 96% 90%
S60 92% 90%
S60HS 92% 90%
iM Series
iM16K 96% 90%
iM30K 92% 90%
Packing Factor (Ratio of bulk density to true particle density)
Averages about 60%.
Oil Absorption
0.2 0.6 g oil/cc of 3M glass bubbles, per ASTM D281-84.
Volatile Content
Maximum of 0.5 percent by weight.
Alkalinity
Maximum of 0.5 milliequivalents per gram
pH
Because 3M glass bubbles are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.
Dielectric Constant
K Series: 1.2 to 1.7 @ 100 MHz, based on theoretical calculations.
S Series: 1.2 to 2.0 @ 100 MHz, based on theoretical calculations.
iM Series: 1.2 to 1.7 @ 100 MHz, based on theoretical
calculations
The dielectric constant of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Particle Size
Particle Size (microns, by volume) 3M QCM 193.0
Product Distribution
Effective
Top Size10th% 50th% 90th%
K Series
K1 30 65 115 120
K15 30 60 105 115
K20 30 60 90 105
K25 25 55 90 105
K37 20 45 80 85
K46 15 40 70 80
S Series
S15 25 55 90 95
S22 20 35 65 75
S32 20 40 70 80
S35 20 40 65 80
S38 15 40 75 85
S38HS 19 44 70 85
S60 15 30 55 65
S60HS 12 29 48 60
iM Series
iM16K 12 20 30 40
iM30K 8.6 15.3 23.6 26.7
3M

Glass Bubbles K, S and iM Series

Minimum storage conditions should be unopened cartons in an
unheated warehouse.
Under high humidity conditions with an ambient temperature
cycling over a wide range, moisture can be drawn into the bag
as the temperature drops and the air contracts. The result may
be moisture condensation within the bag. Extended exposure to
these conditions may result in caking of the 3M glass bubbles
to various degrees. To minimize the potential for caking and
prolong the storage life, the following suggestions are made:
1. Carefully re-tie open bags after use.
2. If the polyethylene bag is punctured during shipping or
handling, use this bag as soon as possible, patch the hole,
or insert the contents into an undamaged bag.
3. During humid summer months, store in the driest, coolest
space available.
4. If good storage conditions are unavailable, carry a
minimum inventory, and process on a first in/first

out basis.
Dusting problems that may occur while handling and processing
can be minimized by the following procedures:
1. For eye protection wear chemical safety goggles. For
respiratory system protection wear an appropriate NIOSH/
MSHA approved respirator. (For additional information
about personal protective equipment, refer to Material
Safety Data Sheet.)
2. Use appropriate ventilation in the work area.
3. Pneumatic conveyor systems have been used successfully
to transport 3M glass bubbles without dusting from
shipping containers to batch mixing equipment. Static
eliminators should be used to help prevent static charges.
Diaphragm pumps have been used to successfully convey
3M glass bubbles. Vendors should be consulted for
specific recommendations.
3M glass bubble breakage may occur if the product is improperly
processed. To minimize breakage, avoid high shear processes such
as high speed Cowles Dissolvers, point contact shear such as gear
pumps or 3-roll mills, and processing pressures above the strength
test pressure for each product.
Health and Safety Information
For product Health and Safety Information, refer to product label
and Material Safety Data Sheet (MSDS) before using product.
Particle Size (continued)
Hard Particles (3M QCM 93.4.3)

No hard particles (e.g. glass slag, flow agent, etc.) greater than
U.S. number 40 (420 microns) standard sieve will exist.
Oversize Particles (3M QCM 93.4.4)

For K1, K15, K20 and K25 glass bubbles:
Using a 10 gram sample on a U.S. number 80 standard sieve
(177 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
For K37 and K46 glass bubbles:

Using a 10 gram sample on U.S. number 100 standard sieve
(149 microns), a maximum of one (1) percent by weight glass
bubbles will be retained on the sieve.
For S15, S32, S35, S38, S38HS, S60, S60HS, iM16K and iM30K
glass bubbles:

Using a 10 gram sample on a U.S. number 140 standard sieve
(105 microns), a maximum of three (3) percent by weight glass
bubbles will be retained on the sieve.
For S22 glass bubbles:

Using a 10 gram sample on a U.S. number 200 standard sieve
(74 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
Appearance (3M QCM 22.85)
White to the unaided eye.
Flow (3M QCM 22.83)
3M

Glass Bubbles remain free flowing for at least one year from
the date of shipment if stored in the original, unopened container
in the minimum storage conditions of an unheated warehouse.
Labeling
3M glass bubbles will be packaged in suitable containers to help
prevent damage during normal handling and shipping. Each
container will be labeled with:
1. Name of manufacturer
2. Type of 3M glass bubbles
3. Lot number
4. Quantity in pounds
Storage and Handling
To help ensure ease of storage and handling while maintaining
free flowing properties, 3M

Glass Bubbles have been made
from a chemically stable glass and are packaged in a heavy-duty
polyethylene bag within a cardboard container.

Packaging Information
Small Box (10 Cubic ft.)
A single corrugated box with a plastic liner. All boxes are
banded together and to the wooden pallet. 4 boxes per pallet.
Each box inside diameter is 22 in. 19 in. 39 in.

Pallet size is 42 in. 48 in.
Large Box (50 Cubic ft.)*
A single corrugated box with a plastic liner. Top enclosed
with interlocking double cover banded. Bottom is normal box
closure, entire box banded to wooden pallet.
Each box inside diameter is 48 in. 42 in. 44 in. Overall
load size is 48
3
/4 in. 42
3
/4 in. 50 in. including pallet.
Pallet size is 42 in. 48 in.
*S60 and S60HS large boxes are 38 cubic ft.
Product
Small
Box
Large
Box*
Truckload Large Box*
44 Pallets
K Series
K1 40 lb. 210 lb. 9,240 lb.
K15 50 lb. 265 lb. 11,660 lb.
K20 60 lb. 350 lb. 15,400 lb.
K25 80 lb. 430 lb. 18,920 lb.
K37 100 lb.660 lb. 29,040 lb.
K46 125 lb.815 lb. 35,860 lb.
S Series
S15 50 lb. 265 lb. 11,660 lb.
S22 60 lb. 385 lb. 16,940 lb.
S32 100 lb.525 lb. 23,100 lb.
S35 100 lb.630 lb. 27,720 lb.
S38 100 lb.680 lb. 29,920 lb.
S38HS 100 lb.680 lb. 29,920 lb.
S60 125 lb.850 lb. 37,400 lb.
S60HS 125 lb.850 lb. 37,400 lb.
iM Series
iM16K 99 lb. 800 lb.
iM30K 125 lb.850 lb. 37,400 lb.
Box Weights
*Box weights may vary due to manufacturing tolerances on each product.
Resources
3M
Glass Bubbles are supported by global sales, technical and
customer service resources, with fully-staffed technical service
laboratories in the U.S., Europe, Japan, Latin America and
Southeast Asia. Users benefit from 3M s broad technology base

and continuing attention to product development, performance,
safety and environmental issues.
For additional technical information on 3M glass bubbles in the
United States, call 3M Advanced Materials Division, 800-367-8905 .
For other 3M global offices, and information on additional 3M
products, visit our website at: www.3M.com/engineeredadditives .
3M

Glass Bubbles K, S and iM Series
Please recycle. Printed in USA.
3M 2013. All rights reserved.
Issued: 3/13 9049HB
98-0212-3859-1
3M is a trademark of 3M. Used under license
by 3M subsidiaries and affiliates.
3M Center
St. Paul, MN 55144-1000

1-800-367-8905
www.3M.com/engineeredadditives
3
Warranty, Limited Remedy, and Disclaimer: Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product
in a particular application. User is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application.
Unless a different warranty is specifically stated in the applicable product literature or packaging insert, 3M warrants that each 3M product meets the applicable 3M product specification at
the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M
product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price.
Limitation of Liability: Except where prohibited by law, 3M will not be liable for any loss or damages arising from the 3M product, whether direct, indirect, special, incidental or
consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability.
Technical Information: Technical information, recommendations, and other statements contained in this document or provided by 3M personnel are based on tests or experience that 3M
believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to
assess and apply their own informed judgment to the information. No license under any 3M or third party intellectual property rights is granted or implied with this information.

243MK-15_TDS.pdf

3
Introduction
3M
Glass Bubbles are engineered hollow glass microspheres
that are alternatives to conventional fillers and additives such as
silicas, calcium carbonate, talc, clay, etc., for many demanding
applications. These low-density particles are used in a wide range
of industries to reduce part weight, lower costs and enhance
product properties.
The unique spherical shape of 3M glass bubbles offers a number
of important benefits, including: higher filler loading, lower
viscosity/improved flow and reduced shrinkage and warpage. It
also helps the 3M glass bubbles blend readily into compounds
and makes them adaptable to a variety of production processes
including spraying, casting and molding.
The chemically stable soda-lime-borosilicate glass composition
of 3M glass bubbles provides excellent water resistance to create
more stable emulsions. They are also non-combustible and non-
porous, so they do not absorb resin. And, their low alkalinity gives
3M glass bubbles compatibility with most resins, stable viscosity
and long shelf life.
3M Glass Bubbles K Series, S Series and iM Series are specially
formulated for a high strength-to-weight ratio. This allows greater
survivability under many demanding processing conditions, such
as injection molding. They also produce stable voids, which results
in low thermal conductivity and a low dielectric constant. 3M glass
bubbles are available in a variety of sizes and grades to help you
meet your product and processing requirements.
3M

Glass Bubbles
K Series, S Series and iM Series
Product Information
Product
Test Pressure
(psi)
Target Fractional
Survival
Minimum
Fractional
Survival
K Series
K1 250 90% 80%
K15 300 90% 80%
K20 500 90% 80%
K25 750 90% 80%
K37 3,000 90% 80%
K46 6,000 90% 80%
S Series
S15 300 90% 80%
S22 400 90% 80%
S32 2,000 90% 80%
S35 3,000 90% 80%
S38 4,000 90% 80%
S38HS 5,500 90% 80%
S60 10,000 90% 80%
S60HS 18,000 90% 90%
iM Series
iM16K 16,000 90% 90%
iM30K 28,000 90% 90%
Isostatic Crush Strength
True Density (g/cc)
Product Typical Minimum Maximum
K Series
K1 0.125 0.10 0.14
K15 0.15 0.13 0.17
K20 0.20 0.18 0.22
K25 0.25 0.23 0.27
K37 0.37 0.34 0.40
K46 0.46 0.43 0.49
S Series
S15 0.15 0.13 0.17
S22 0.22 0.19 0.25
S32 0.32 0.29 0.35
S35 0.35 0.32 0.38
S38 0.38 0.35 0.41
S38HS 0.38 0.35 0.41
S60 0.60 0.57 0.63
S60HS 0.60 0.57 0.63
iM Series
iM16K 0.46 0.43 0.49
iM30K 0.60 0.57 0.63
True Density
Typical Properties
Not for specification purposes

Typical Properties
Chemical Resistance
In general, the chemical properties of 3M
Glass Bubbles
resemble those of a soda-lime-borosilicate glass.
Thermal Conductivity
Product
Calculated Thermal Conductivity
(W m-1 K-1) at 70 F (21 C)
K Series
K1 0.047
K15 0.055
K20 0.070
K25 0.085
K37 0.124
K46 0.153
S Series
S15 0.055
S22 0.076
S32 0.108
S35 0.117
S38 0.127
S38HS 0.127
S60 0.200
S60HS 0.200
iM Series
iM16K 0.153
iM30K 0.200
Conductivity increases with temperature and product density. The
thermal conductivity of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Thermal Stability
Appreciable changes in bubble properties may occur above 1112 F
(600 C) depending on temperature and duration of exposure.
Flotation
Floaters (% by bulk volume)
Product Typical Minimum
K Series
K1 96% 90%
K15 96% 90%
K20 96% 90%
K25 96% 90%
K37 94% 90%
K46 92% 90%
S Series
S15 96% 90%
S22 96% 90%
S32 94% 90%
S35 96% 90%
S38 94% 90%
S38HS 96% 90%
S60 92% 90%
S60HS 92% 90%
iM Series
iM16K 96% 90%
iM30K 92% 90%
Packing Factor (Ratio of bulk density to true particle density)
Averages about 60%.
Oil Absorption
0.2 0.6 g oil/cc of 3M glass bubbles, per ASTM D281-84.
Volatile Content
Maximum of 0.5 percent by weight.
Alkalinity
Maximum of 0.5 milliequivalents per gram
pH
Because 3M glass bubbles are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.
Dielectric Constant
K Series: 1.2 to 1.7 @ 100 MHz, based on theoretical calculations.
S Series: 1.2 to 2.0 @ 100 MHz, based on theoretical calculations.
iM Series: 1.2 to 1.7 @ 100 MHz, based on theoretical
calculations
The dielectric constant of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Particle Size
Particle Size (microns, by volume) 3M QCM 193.0
Product Distribution
Effective
Top Size10th% 50th% 90th%
K Series
K1 30 65 115 120
K15 30 60 105 115
K20 30 60 90 105
K25 25 55 90 105
K37 20 45 80 85
K46 15 40 70 80
S Series
S15 25 55 90 95
S22 20 35 65 75
S32 20 40 70 80
S35 20 40 65 80
S38 15 40 75 85
S38HS 19 44 70 85
S60 15 30 55 65
S60HS 12 29 48 60
iM Series
iM16K 12 20 30 40
iM30K 8.6 15.3 23.6 26.7
3M

Glass Bubbles K, S and iM Series

Minimum storage conditions should be unopened cartons in an
unheated warehouse.
Under high humidity conditions with an ambient temperature
cycling over a wide range, moisture can be drawn into the bag
as the temperature drops and the air contracts. The result may
be moisture condensation within the bag. Extended exposure to
these conditions may result in caking of the 3M glass bubbles
to various degrees. To minimize the potential for caking and
prolong the storage life, the following suggestions are made:
1. Carefully re-tie open bags after use.
2. If the polyethylene bag is punctured during shipping or
handling, use this bag as soon as possible, patch the hole,
or insert the contents into an undamaged bag.
3. During humid summer months, store in the driest, coolest
space available.
4. If good storage conditions are unavailable, carry a
minimum inventory, and process on a first in/first

out basis.
Dusting problems that may occur while handling and processing
can be minimized by the following procedures:
1. For eye protection wear chemical safety goggles. For
respiratory system protection wear an appropriate NIOSH/
MSHA approved respirator. (For additional information
about personal protective equipment, refer to Material
Safety Data Sheet.)
2. Use appropriate ventilation in the work area.
3. Pneumatic conveyor systems have been used successfully
to transport 3M glass bubbles without dusting from
shipping containers to batch mixing equipment. Static
eliminators should be used to help prevent static charges.
Diaphragm pumps have been used to successfully convey
3M glass bubbles. Vendors should be consulted for
specific recommendations.
3M glass bubble breakage may occur if the product is improperly
processed. To minimize breakage, avoid high shear processes such
as high speed Cowles Dissolvers, point contact shear such as gear
pumps or 3-roll mills, and processing pressures above the strength
test pressure for each product.
Health and Safety Information
For product Health and Safety Information, refer to product label
and Material Safety Data Sheet (MSDS) before using product.
Particle Size (continued)
Hard Particles (3M QCM 93.4.3)

No hard particles (e.g. glass slag, flow agent, etc.) greater than
U.S. number 40 (420 microns) standard sieve will exist.
Oversize Particles (3M QCM 93.4.4)

For K1, K15, K20 and K25 glass bubbles:
Using a 10 gram sample on a U.S. number 80 standard sieve
(177 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
For K37 and K46 glass bubbles:

Using a 10 gram sample on U.S. number 100 standard sieve
(149 microns), a maximum of one (1) percent by weight glass
bubbles will be retained on the sieve.
For S15, S32, S35, S38, S38HS, S60, S60HS, iM16K and iM30K
glass bubbles:

Using a 10 gram sample on a U.S. number 140 standard sieve
(105 microns), a maximum of three (3) percent by weight glass
bubbles will be retained on the sieve.
For S22 glass bubbles:

Using a 10 gram sample on a U.S. number 200 standard sieve
(74 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
Appearance (3M QCM 22.85)
White to the unaided eye.
Flow (3M QCM 22.83)
3M

Glass Bubbles remain free flowing for at least one year from
the date of shipment if stored in the original, unopened container
in the minimum storage conditions of an unheated warehouse.
Labeling
3M glass bubbles will be packaged in suitable containers to help
prevent damage during normal handling and shipping. Each
container will be labeled with:
1. Name of manufacturer
2. Type of 3M glass bubbles
3. Lot number
4. Quantity in pounds
Storage and Handling
To help ensure ease of storage and handling while maintaining
free flowing properties, 3M

Glass Bubbles have been made
from a chemically stable glass and are packaged in a heavy-duty
polyethylene bag within a cardboard container.

Packaging Information
Small Box (10 Cubic ft.)
A single corrugated box with a plastic liner. All boxes are
banded together and to the wooden pallet. 4 boxes per pallet.
Each box inside diameter is 22 in. 19 in. 39 in.

Pallet size is 42 in. 48 in.
Large Box (50 Cubic ft.)*
A single corrugated box with a plastic liner. Top enclosed
with interlocking double cover banded. Bottom is normal box
closure, entire box banded to wooden pallet.
Each box inside diameter is 48 in. 42 in. 44 in. Overall
load size is 48
3
/4 in. 42
3
/4 in. 50 in. including pallet.
Pallet size is 42 in. 48 in.
*S60 and S60HS large boxes are 38 cubic ft.
Product
Small
Box
Large
Box*
Truckload Large Box*
44 Pallets
K Series
K1 40 lb. 210 lb. 9,240 lb.
K15 50 lb. 265 lb. 11,660 lb.
K20 60 lb. 350 lb. 15,400 lb.
K25 80 lb. 430 lb. 18,920 lb.
K37 100 lb.660 lb. 29,040 lb.
K46 125 lb.815 lb. 35,860 lb.
S Series
S15 50 lb. 265 lb. 11,660 lb.
S22 60 lb. 385 lb. 16,940 lb.
S32 100 lb.525 lb. 23,100 lb.
S35 100 lb.630 lb. 27,720 lb.
S38 100 lb.680 lb. 29,920 lb.
S38HS 100 lb.680 lb. 29,920 lb.
S60 125 lb.850 lb. 37,400 lb.
S60HS 125 lb.850 lb. 37,400 lb.
iM Series
iM16K 99 lb. 800 lb.
iM30K 125 lb.850 lb. 37,400 lb.
Box Weights
*Box weights may vary due to manufacturing tolerances on each product.
Resources
3M
Glass Bubbles are supported by global sales, technical and
customer service resources, with fully-staffed technical service
laboratories in the U.S., Europe, Japan, Latin America and
Southeast Asia. Users benefit from 3M s broad technology base

and continuing attention to product development, performance,
safety and environmental issues.
For additional technical information on 3M glass bubbles in the
United States, call 3M Advanced Materials Division, 800-367-8905 .
For other 3M global offices, and information on additional 3M
products, visit our website at: www.3M.com/engineeredadditives .
3M

Glass Bubbles K, S and iM Series
Please recycle. Printed in USA.
3M 2013. All rights reserved.
Issued: 3/13 9049HB
98-0212-3859-1
3M is a trademark of 3M. Used under license
by 3M subsidiaries and affiliates.
3M Center
St. Paul, MN 55144-1000

1-800-367-8905
www.3M.com/engineeredadditives
3
Warranty, Limited Remedy, and Disclaimer: Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product
in a particular application. User is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application.
Unless a different warranty is specifically stated in the applicable product literature or packaging insert, 3M warrants that each 3M product meets the applicable 3M product specification at
the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M
product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price.
Limitation of Liability: Except where prohibited by law, 3M will not be liable for any loss or damages arising from the 3M product, whether direct, indirect, special, incidental or
consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability.
Technical Information: Technical information, recommendations, and other statements contained in this document or provided by 3M personnel are based on tests or experience that 3M
believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to
assess and apply their own informed judgment to the information. No license under any 3M or third party intellectual property rights is granted or implied with this information.

243M-K25_TDS.pdf

3
Introduction
3M
Glass Bubbles are engineered hollow glass microspheres
that are alternatives to conventional fillers and additives such as
silicas, calcium carbonate, talc, clay, etc., for many demanding
applications. These low-density particles are used in a wide range
of industries to reduce part weight, lower costs and enhance
product properties.
The unique spherical shape of 3M glass bubbles offers a number
of important benefits, including: higher filler loading, lower
viscosity/improved flow and reduced shrinkage and warpage. It
also helps the 3M glass bubbles blend readily into compounds
and makes them adaptable to a variety of production processes
including spraying, casting and molding.
The chemically stable soda-lime-borosilicate glass composition
of 3M glass bubbles provides excellent water resistance to create
more stable emulsions. They are also non-combustible and non-
porous, so they do not absorb resin. And, their low alkalinity gives
3M glass bubbles compatibility with most resins, stable viscosity
and long shelf life.
3M Glass Bubbles K Series, S Series and iM Series are specially
formulated for a high strength-to-weight ratio. This allows greater
survivability under many demanding processing conditions, such
as injection molding. They also produce stable voids, which results
in low thermal conductivity and a low dielectric constant. 3M glass
bubbles are available in a variety of sizes and grades to help you
meet your product and processing requirements.
3M

Glass Bubbles
K Series, S Series and iM Series
Product Information
Product
Test Pressure
(psi)
Target Fractional
Survival
Minimum
Fractional
Survival
K Series
K1 250 90% 80%
K15 300 90% 80%
K20 500 90% 80%
K25 750 90% 80%
K37 3,000 90% 80%
K46 6,000 90% 80%
S Series
S15 300 90% 80%
S22 400 90% 80%
S32 2,000 90% 80%
S35 3,000 90% 80%
S38 4,000 90% 80%
S38HS 5,500 90% 80%
S60 10,000 90% 80%
S60HS 18,000 90% 90%
iM Series
iM16K 16,000 90% 90%
iM30K 28,000 90% 90%
Isostatic Crush Strength
True Density (g/cc)
Product Typical Minimum Maximum
K Series
K1 0.125 0.10 0.14
K15 0.15 0.13 0.17
K20 0.20 0.18 0.22
K25 0.25 0.23 0.27
K37 0.37 0.34 0.40
K46 0.46 0.43 0.49
S Series
S15 0.15 0.13 0.17
S22 0.22 0.19 0.25
S32 0.32 0.29 0.35
S35 0.35 0.32 0.38
S38 0.38 0.35 0.41
S38HS 0.38 0.35 0.41
S60 0.60 0.57 0.63
S60HS 0.60 0.57 0.63
iM Series
iM16K 0.46 0.43 0.49
iM30K 0.60 0.57 0.63
True Density
Typical Properties
Not for specification purposes

Typical Properties
Chemical Resistance
In general, the chemical properties of 3M
Glass Bubbles
resemble those of a soda-lime-borosilicate glass.
Thermal Conductivity
Product
Calculated Thermal Conductivity
(W m-1 K-1) at 70 F (21 C)
K Series
K1 0.047
K15 0.055
K20 0.070
K25 0.085
K37 0.124
K46 0.153
S Series
S15 0.055
S22 0.076
S32 0.108
S35 0.117
S38 0.127
S38HS 0.127
S60 0.200
S60HS 0.200
iM Series
iM16K 0.153
iM30K 0.200
Conductivity increases with temperature and product density. The
thermal conductivity of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Thermal Stability
Appreciable changes in bubble properties may occur above 1112 F
(600 C) depending on temperature and duration of exposure.
Flotation
Floaters (% by bulk volume)
Product Typical Minimum
K Series
K1 96% 90%
K15 96% 90%
K20 96% 90%
K25 96% 90%
K37 94% 90%
K46 92% 90%
S Series
S15 96% 90%
S22 96% 90%
S32 94% 90%
S35 96% 90%
S38 94% 90%
S38HS 96% 90%
S60 92% 90%
S60HS 92% 90%
iM Series
iM16K 96% 90%
iM30K 92% 90%
Packing Factor (Ratio of bulk density to true particle density)
Averages about 60%.
Oil Absorption
0.2 0.6 g oil/cc of 3M glass bubbles, per ASTM D281-84.
Volatile Content
Maximum of 0.5 percent by weight.
Alkalinity
Maximum of 0.5 milliequivalents per gram
pH
Because 3M glass bubbles are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.
Dielectric Constant
K Series: 1.2 to 1.7 @ 100 MHz, based on theoretical calculations.
S Series: 1.2 to 2.0 @ 100 MHz, based on theoretical calculations.
iM Series: 1.2 to 1.7 @ 100 MHz, based on theoretical
calculations
The dielectric constant of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Particle Size
Particle Size (microns, by volume) 3M QCM 193.0
Product Distribution
Effective
Top Size10th% 50th% 90th%
K Series
K1 30 65 115 120
K15 30 60 105 115
K20 30 60 90 105
K25 25 55 90 105
K37 20 45 80 85
K46 15 40 70 80
S Series
S15 25 55 90 95
S22 20 35 65 75
S32 20 40 70 80
S35 20 40 65 80
S38 15 40 75 85
S38HS 19 44 70 85
S60 15 30 55 65
S60HS 12 29 48 60
iM Series
iM16K 12 20 30 40
iM30K 8.6 15.3 23.6 26.7
3M

Glass Bubbles K, S and iM Series

Minimum storage conditions should be unopened cartons in an
unheated warehouse.
Under high humidity conditions with an ambient temperature
cycling over a wide range, moisture can be drawn into the bag
as the temperature drops and the air contracts. The result may
be moisture condensation within the bag. Extended exposure to
these conditions may result in caking of the 3M glass bubbles
to various degrees. To minimize the potential for caking and
prolong the storage life, the following suggestions are made:
1. Carefully re-tie open bags after use.
2. If the polyethylene bag is punctured during shipping or
handling, use this bag as soon as possible, patch the hole,
or insert the contents into an undamaged bag.
3. During humid summer months, store in the driest, coolest
space available.
4. If good storage conditions are unavailable, carry a
minimum inventory, and process on a first in/first

out basis.
Dusting problems that may occur while handling and processing
can be minimized by the following procedures:
1. For eye protection wear chemical safety goggles. For
respiratory system protection wear an appropriate NIOSH/
MSHA approved respirator. (For additional information
about personal protective equipment, refer to Material
Safety Data Sheet.)
2. Use appropriate ventilation in the work area.
3. Pneumatic conveyor systems have been used successfully
to transport 3M glass bubbles without dusting from
shipping containers to batch mixing equipment. Static
eliminators should be used to help prevent static charges.
Diaphragm pumps have been used to successfully convey
3M glass bubbles. Vendors should be consulted for
specific recommendations.
3M glass bubble breakage may occur if the product is improperly
processed. To minimize breakage, avoid high shear processes such
as high speed Cowles Dissolvers, point contact shear such as gear
pumps or 3-roll mills, and processing pressures above the strength
test pressure for each product.
Health and Safety Information
For product Health and Safety Information, refer to product label
and Material Safety Data Sheet (MSDS) before using product.
Particle Size (continued)
Hard Particles (3M QCM 93.4.3)

No hard particles (e.g. glass slag, flow agent, etc.) greater than
U.S. number 40 (420 microns) standard sieve will exist.
Oversize Particles (3M QCM 93.4.4)

For K1, K15, K20 and K25 glass bubbles:
Using a 10 gram sample on a U.S. number 80 standard sieve
(177 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
For K37 and K46 glass bubbles:

Using a 10 gram sample on U.S. number 100 standard sieve
(149 microns), a maximum of one (1) percent by weight glass
bubbles will be retained on the sieve.
For S15, S32, S35, S38, S38HS, S60, S60HS, iM16K and iM30K
glass bubbles:

Using a 10 gram sample on a U.S. number 140 standard sieve
(105 microns), a maximum of three (3) percent by weight glass
bubbles will be retained on the sieve.
For S22 glass bubbles:

Using a 10 gram sample on a U.S. number 200 standard sieve
(74 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
Appearance (3M QCM 22.85)
White to the unaided eye.
Flow (3M QCM 22.83)
3M

Glass Bubbles remain free flowing for at least one year from
the date of shipment if stored in the original, unopened container
in the minimum storage conditions of an unheated warehouse.
Labeling
3M glass bubbles will be packaged in suitable containers to help
prevent damage during normal handling and shipping. Each
container will be labeled with:
1. Name of manufacturer
2. Type of 3M glass bubbles
3. Lot number
4. Quantity in pounds
Storage and Handling
To help ensure ease of storage and handling while maintaining
free flowing properties, 3M

Glass Bubbles have been made
from a chemically stable glass and are packaged in a heavy-duty
polyethylene bag within a cardboard container.

Packaging Information
Small Box (10 Cubic ft.)
A single corrugated box with a plastic liner. All boxes are
banded together and to the wooden pallet. 4 boxes per pallet.
Each box inside diameter is 22 in. 19 in. 39 in.

Pallet size is 42 in. 48 in.
Large Box (50 Cubic ft.)*
A single corrugated box with a plastic liner. Top enclosed
with interlocking double cover banded. Bottom is normal box
closure, entire box banded to wooden pallet.
Each box inside diameter is 48 in. 42 in. 44 in. Overall
load size is 48
3
/4 in. 42
3
/4 in. 50 in. including pallet.
Pallet size is 42 in. 48 in.
*S60 and S60HS large boxes are 38 cubic ft.
Product
Small
Box
Large
Box*
Truckload Large Box*
44 Pallets
K Series
K1 40 lb. 210 lb. 9,240 lb.
K15 50 lb. 265 lb. 11,660 lb.
K20 60 lb. 350 lb. 15,400 lb.
K25 80 lb. 430 lb. 18,920 lb.
K37 100 lb.660 lb. 29,040 lb.
K46 125 lb.815 lb. 35,860 lb.
S Series
S15 50 lb. 265 lb. 11,660 lb.
S22 60 lb. 385 lb. 16,940 lb.
S32 100 lb.525 lb. 23,100 lb.
S35 100 lb.630 lb. 27,720 lb.
S38 100 lb.680 lb. 29,920 lb.
S38HS 100 lb.680 lb. 29,920 lb.
S60 125 lb.850 lb. 37,400 lb.
S60HS 125 lb.850 lb. 37,400 lb.
iM Series
iM16K 99 lb. 800 lb.
iM30K 125 lb.850 lb. 37,400 lb.
Box Weights
*Box weights may vary due to manufacturing tolerances on each product.
Resources
3M
Glass Bubbles are supported by global sales, technical and
customer service resources, with fully-staffed technical service
laboratories in the U.S., Europe, Japan, Latin America and
Southeast Asia. Users benefit from 3M s broad technology base

and continuing attention to product development, performance,
safety and environmental issues.
For additional technical information on 3M glass bubbles in the
United States, call 3M Advanced Materials Division, 800-367-8905 .
For other 3M global offices, and information on additional 3M
products, visit our website at: www.3M.com/engineeredadditives .
3M

Glass Bubbles K, S and iM Series
Please recycle. Printed in USA.
3M 2013. All rights reserved.
Issued: 3/13 9049HB
98-0212-3859-1
3M is a trademark of 3M. Used under license
by 3M subsidiaries and affiliates.
3M Center
St. Paul, MN 55144-1000

1-800-367-8905
www.3M.com/engineeredadditives
3
Warranty, Limited Remedy, and Disclaimer: Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product
in a particular application. User is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application.
Unless a different warranty is specifically stated in the applicable product literature or packaging insert, 3M warrants that each 3M product meets the applicable 3M product specification at
the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M
product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price.
Limitation of Liability: Except where prohibited by law, 3M will not be liable for any loss or damages arising from the 3M product, whether direct, indirect, special, incidental or
consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability.
Technical Information: Technical information, recommendations, and other statements contained in this document or provided by 3M personnel are based on tests or experience that 3M
believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to
assess and apply their own informed judgment to the information. No license under any 3M or third party intellectual property rights is granted or implied with this information.

243M-K20_TDS.pdf

3
Introduction
3M
Glass Bubbles are engineered hollow glass microspheres
that are alternatives to conventional fillers and additives such as
silicas, calcium carbonate, talc, clay, etc., for many demanding
applications. These low-density particles are used in a wide range
of industries to reduce part weight, lower costs and enhance
product properties.
The unique spherical shape of 3M glass bubbles offers a number
of important benefits, including: higher filler loading, lower
viscosity/improved flow and reduced shrinkage and warpage. It
also helps the 3M glass bubbles blend readily into compounds
and makes them adaptable to a variety of production processes
including spraying, casting and molding.
The chemically stable soda-lime-borosilicate glass composition
of 3M glass bubbles provides excellent water resistance to create
more stable emulsions. They are also non-combustible and non-
porous, so they do not absorb resin. And, their low alkalinity gives
3M glass bubbles compatibility with most resins, stable viscosity
and long shelf life.
3M Glass Bubbles K Series, S Series and iM Series are specially
formulated for a high strength-to-weight ratio. This allows greater
survivability under many demanding processing conditions, such
as injection molding. They also produce stable voids, which results
in low thermal conductivity and a low dielectric constant. 3M glass
bubbles are available in a variety of sizes and grades to help you
meet your product and processing requirements.
3M

Glass Bubbles
K Series, S Series and iM Series
Product Information
Product
Test Pressure
(psi)
Target Fractional
Survival
Minimum
Fractional
Survival
K Series
K1 250 90% 80%
K15 300 90% 80%
K20 500 90% 80%
K25 750 90% 80%
K37 3,000 90% 80%
K46 6,000 90% 80%
S Series
S15 300 90% 80%
S22 400 90% 80%
S32 2,000 90% 80%
S35 3,000 90% 80%
S38 4,000 90% 80%
S38HS 5,500 90% 80%
S60 10,000 90% 80%
S60HS 18,000 90% 90%
iM Series
iM16K 16,000 90% 90%
iM30K 28,000 90% 90%
Isostatic Crush Strength
True Density (g/cc)
Product Typical Minimum Maximum
K Series
K1 0.125 0.10 0.14
K15 0.15 0.13 0.17
K20 0.20 0.18 0.22
K25 0.25 0.23 0.27
K37 0.37 0.34 0.40
K46 0.46 0.43 0.49
S Series
S15 0.15 0.13 0.17
S22 0.22 0.19 0.25
S32 0.32 0.29 0.35
S35 0.35 0.32 0.38
S38 0.38 0.35 0.41
S38HS 0.38 0.35 0.41
S60 0.60 0.57 0.63
S60HS 0.60 0.57 0.63
iM Series
iM16K 0.46 0.43 0.49
iM30K 0.60 0.57 0.63
True Density
Typical Properties
Not for specification purposes

Typical Properties
Chemical Resistance
In general, the chemical properties of 3M
Glass Bubbles
resemble those of a soda-lime-borosilicate glass.
Thermal Conductivity
Product
Calculated Thermal Conductivity
(W m-1 K-1) at 70 F (21 C)
K Series
K1 0.047
K15 0.055
K20 0.070
K25 0.085
K37 0.124
K46 0.153
S Series
S15 0.055
S22 0.076
S32 0.108
S35 0.117
S38 0.127
S38HS 0.127
S60 0.200
S60HS 0.200
iM Series
iM16K 0.153
iM30K 0.200
Conductivity increases with temperature and product density. The
thermal conductivity of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Thermal Stability
Appreciable changes in bubble properties may occur above 1112 F
(600 C) depending on temperature and duration of exposure.
Flotation
Floaters (% by bulk volume)
Product Typical Minimum
K Series
K1 96% 90%
K15 96% 90%
K20 96% 90%
K25 96% 90%
K37 94% 90%
K46 92% 90%
S Series
S15 96% 90%
S22 96% 90%
S32 94% 90%
S35 96% 90%
S38 94% 90%
S38HS 96% 90%
S60 92% 90%
S60HS 92% 90%
iM Series
iM16K 96% 90%
iM30K 92% 90%
Packing Factor (Ratio of bulk density to true particle density)
Averages about 60%.
Oil Absorption
0.2 0.6 g oil/cc of 3M glass bubbles, per ASTM D281-84.
Volatile Content
Maximum of 0.5 percent by weight.
Alkalinity
Maximum of 0.5 milliequivalents per gram
pH
Because 3M glass bubbles are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.
Dielectric Constant
K Series: 1.2 to 1.7 @ 100 MHz, based on theoretical calculations.
S Series: 1.2 to 2.0 @ 100 MHz, based on theoretical calculations.
iM Series: 1.2 to 1.7 @ 100 MHz, based on theoretical
calculations
The dielectric constant of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Particle Size
Particle Size (microns, by volume) 3M QCM 193.0
Product Distribution
Effective
Top Size10th% 50th% 90th%
K Series
K1 30 65 115 120
K15 30 60 105 115
K20 30 60 90 105
K25 25 55 90 105
K37 20 45 80 85
K46 15 40 70 80
S Series
S15 25 55 90 95
S22 20 35 65 75
S32 20 40 70 80
S35 20 40 65 80
S38 15 40 75 85
S38HS 19 44 70 85
S60 15 30 55 65
S60HS 12 29 48 60
iM Series
iM16K 12 20 30 40
iM30K 8.6 15.3 23.6 26.7
3M

Glass Bubbles K, S and iM Series

Minimum storage conditions should be unopened cartons in an
unheated warehouse.
Under high humidity conditions with an ambient temperature
cycling over a wide range, moisture can be drawn into the bag
as the temperature drops and the air contracts. The result may
be moisture condensation within the bag. Extended exposure to
these conditions may result in caking of the 3M glass bubbles
to various degrees. To minimize the potential for caking and
prolong the storage life, the following suggestions are made:
1. Carefully re-tie open bags after use.
2. If the polyethylene bag is punctured during shipping or
handling, use this bag as soon as possible, patch the hole,
or insert the contents into an undamaged bag.
3. During humid summer months, store in the driest, coolest
space available.
4. If good storage conditions are unavailable, carry a
minimum inventory, and process on a first in/first

out basis.
Dusting problems that may occur while handling and processing
can be minimized by the following procedures:
1. For eye protection wear chemical safety goggles. For
respiratory system protection wear an appropriate NIOSH/
MSHA approved respirator. (For additional information
about personal protective equipment, refer to Material
Safety Data Sheet.)
2. Use appropriate ventilation in the work area.
3. Pneumatic conveyor systems have been used successfully
to transport 3M glass bubbles without dusting from
shipping containers to batch mixing equipment. Static
eliminators should be used to help prevent static charges.
Diaphragm pumps have been used to successfully convey
3M glass bubbles. Vendors should be consulted for
specific recommendations.
3M glass bubble breakage may occur if the product is improperly
processed. To minimize breakage, avoid high shear processes such
as high speed Cowles Dissolvers, point contact shear such as gear
pumps or 3-roll mills, and processing pressures above the strength
test pressure for each product.
Health and Safety Information
For product Health and Safety Information, refer to product label
and Material Safety Data Sheet (MSDS) before using product.
Particle Size (continued)
Hard Particles (3M QCM 93.4.3)

No hard particles (e.g. glass slag, flow agent, etc.) greater than
U.S. number 40 (420 microns) standard sieve will exist.
Oversize Particles (3M QCM 93.4.4)

For K1, K15, K20 and K25 glass bubbles:
Using a 10 gram sample on a U.S. number 80 standard sieve
(177 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
For K37 and K46 glass bubbles:

Using a 10 gram sample on U.S. number 100 standard sieve
(149 microns), a maximum of one (1) percent by weight glass
bubbles will be retained on the sieve.
For S15, S32, S35, S38, S38HS, S60, S60HS, iM16K and iM30K
glass bubbles:

Using a 10 gram sample on a U.S. number 140 standard sieve
(105 microns), a maximum of three (3) percent by weight glass
bubbles will be retained on the sieve.
For S22 glass bubbles:

Using a 10 gram sample on a U.S. number 200 standard sieve
(74 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
Appearance (3M QCM 22.85)
White to the unaided eye.
Flow (3M QCM 22.83)
3M

Glass Bubbles remain free flowing for at least one year from
the date of shipment if stored in the original, unopened container
in the minimum storage conditions of an unheated warehouse.
Labeling
3M glass bubbles will be packaged in suitable containers to help
prevent damage during normal handling and shipping. Each
container will be labeled with:
1. Name of manufacturer
2. Type of 3M glass bubbles
3. Lot number
4. Quantity in pounds
Storage and Handling
To help ensure ease of storage and handling while maintaining
free flowing properties, 3M

Glass Bubbles have been made
from a chemically stable glass and are packaged in a heavy-duty
polyethylene bag within a cardboard container.

Packaging Information
Small Box (10 Cubic ft.)
A single corrugated box with a plastic liner. All boxes are
banded together and to the wooden pallet. 4 boxes per pallet.
Each box inside diameter is 22 in. 19 in. 39 in.

Pallet size is 42 in. 48 in.
Large Box (50 Cubic ft.)*
A single corrugated box with a plastic liner. Top enclosed
with interlocking double cover banded. Bottom is normal box
closure, entire box banded to wooden pallet.
Each box inside diameter is 48 in. 42 in. 44 in. Overall
load size is 48
3
/4 in. 42
3
/4 in. 50 in. including pallet.
Pallet size is 42 in. 48 in.
*S60 and S60HS large boxes are 38 cubic ft.
Product
Small
Box
Large
Box*
Truckload Large Box*
44 Pallets
K Series
K1 40 lb. 210 lb. 9,240 lb.
K15 50 lb. 265 lb. 11,660 lb.
K20 60 lb. 350 lb. 15,400 lb.
K25 80 lb. 430 lb. 18,920 lb.
K37 100 lb.660 lb. 29,040 lb.
K46 125 lb.815 lb. 35,860 lb.
S Series
S15 50 lb. 265 lb. 11,660 lb.
S22 60 lb. 385 lb. 16,940 lb.
S32 100 lb.525 lb. 23,100 lb.
S35 100 lb.630 lb. 27,720 lb.
S38 100 lb.680 lb. 29,920 lb.
S38HS 100 lb.680 lb. 29,920 lb.
S60 125 lb.850 lb. 37,400 lb.
S60HS 125 lb.850 lb. 37,400 lb.
iM Series
iM16K 99 lb. 800 lb.
iM30K 125 lb.850 lb. 37,400 lb.
Box Weights
*Box weights may vary due to manufacturing tolerances on each product.
Resources
3M
Glass Bubbles are supported by global sales, technical and
customer service resources, with fully-staffed technical service
laboratories in the U.S., Europe, Japan, Latin America and
Southeast Asia. Users benefit from 3M s broad technology base

and continuing attention to product development, performance,
safety and environmental issues.
For additional technical information on 3M glass bubbles in the
United States, call 3M Advanced Materials Division, 800-367-8905 .
For other 3M global offices, and information on additional 3M
products, visit our website at: www.3M.com/engineeredadditives .
3M

Glass Bubbles K, S and iM Series
Please recycle. Printed in USA.
3M 2013. All rights reserved.
Issued: 3/13 9049HB
98-0212-3859-1
3M is a trademark of 3M. Used under license
by 3M subsidiaries and affiliates.
3M Center
St. Paul, MN 55144-1000

1-800-367-8905
www.3M.com/engineeredadditives
3
Warranty, Limited Remedy, and Disclaimer: Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product
in a particular application. User is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application.
Unless a different warranty is specifically stated in the applicable product literature or packaging insert, 3M warrants that each 3M product meets the applicable 3M product specification at
the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M
product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price.
Limitation of Liability: Except where prohibited by law, 3M will not be liable for any loss or damages arising from the 3M product, whether direct, indirect, special, incidental or
consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability.
Technical Information: Technical information, recommendations, and other statements contained in this document or provided by 3M personnel are based on tests or experience that 3M
believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to
assess and apply their own informed judgment to the information. No license under any 3M or third party intellectual property rights is granted or implied with this information.

243M-K1_TDS.pdf

3
Introduction
3M
Glass Bubbles are engineered hollow glass microspheres
that are alternatives to conventional fillers and additives such as
silicas, calcium carbonate, talc, clay, etc., for many demanding
applications. These low-density particles are used in a wide range
of industries to reduce part weight, lower costs and enhance
product properties.
The unique spherical shape of 3M glass bubbles offers a number
of important benefits, including: higher filler loading, lower
viscosity/improved flow and reduced shrinkage and warpage. It
also helps the 3M glass bubbles blend readily into compounds
and makes them adaptable to a variety of production processes
including spraying, casting and molding.
The chemically stable soda-lime-borosilicate glass composition
of 3M glass bubbles provides excellent water resistance to create
more stable emulsions. They are also non-combustible and non-
porous, so they do not absorb resin. And, their low alkalinity gives
3M glass bubbles compatibility with most resins, stable viscosity
and long shelf life.
3M Glass Bubbles K Series, S Series and iM Series are specially
formulated for a high strength-to-weight ratio. This allows greater
survivability under many demanding processing conditions, such
as injection molding. They also produce stable voids, which results
in low thermal conductivity and a low dielectric constant. 3M glass
bubbles are available in a variety of sizes and grades to help you
meet your product and processing requirements.
3M

Glass Bubbles
K Series, S Series and iM Series
Product Information
Product
Test Pressure
(psi)
Target Fractional
Survival
Minimum
Fractional
Survival
K Series
K1 250 90% 80%
K15 300 90% 80%
K20 500 90% 80%
K25 750 90% 80%
K37 3,000 90% 80%
K46 6,000 90% 80%
S Series
S15 300 90% 80%
S22 400 90% 80%
S32 2,000 90% 80%
S35 3,000 90% 80%
S38 4,000 90% 80%
S38HS 5,500 90% 80%
S60 10,000 90% 80%
S60HS 18,000 90% 90%
iM Series
iM16K 16,000 90% 90%
iM30K 28,000 90% 90%
Isostatic Crush Strength
True Density (g/cc)
Product Typical Minimum Maximum
K Series
K1 0.125 0.10 0.14
K15 0.15 0.13 0.17
K20 0.20 0.18 0.22
K25 0.25 0.23 0.27
K37 0.37 0.34 0.40
K46 0.46 0.43 0.49
S Series
S15 0.15 0.13 0.17
S22 0.22 0.19 0.25
S32 0.32 0.29 0.35
S35 0.35 0.32 0.38
S38 0.38 0.35 0.41
S38HS 0.38 0.35 0.41
S60 0.60 0.57 0.63
S60HS 0.60 0.57 0.63
iM Series
iM16K 0.46 0.43 0.49
iM30K 0.60 0.57 0.63
True Density
Typical Properties
Not for specification purposes

Typical Properties
Chemical Resistance
In general, the chemical properties of 3M
Glass Bubbles
resemble those of a soda-lime-borosilicate glass.
Thermal Conductivity
Product
Calculated Thermal Conductivity
(W m-1 K-1) at 70 F (21 C)
K Series
K1 0.047
K15 0.055
K20 0.070
K25 0.085
K37 0.124
K46 0.153
S Series
S15 0.055
S22 0.076
S32 0.108
S35 0.117
S38 0.127
S38HS 0.127
S60 0.200
S60HS 0.200
iM Series
iM16K 0.153
iM30K 0.200
Conductivity increases with temperature and product density. The
thermal conductivity of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Thermal Stability
Appreciable changes in bubble properties may occur above 1112 F
(600 C) depending on temperature and duration of exposure.
Flotation
Floaters (% by bulk volume)
Product Typical Minimum
K Series
K1 96% 90%
K15 96% 90%
K20 96% 90%
K25 96% 90%
K37 94% 90%
K46 92% 90%
S Series
S15 96% 90%
S22 96% 90%
S32 94% 90%
S35 96% 90%
S38 94% 90%
S38HS 96% 90%
S60 92% 90%
S60HS 92% 90%
iM Series
iM16K 96% 90%
iM30K 92% 90%
Packing Factor (Ratio of bulk density to true particle density)
Averages about 60%.
Oil Absorption
0.2 0.6 g oil/cc of 3M glass bubbles, per ASTM D281-84.
Volatile Content
Maximum of 0.5 percent by weight.
Alkalinity
Maximum of 0.5 milliequivalents per gram
pH
Because 3M glass bubbles are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.
Dielectric Constant
K Series: 1.2 to 1.7 @ 100 MHz, based on theoretical calculations.
S Series: 1.2 to 2.0 @ 100 MHz, based on theoretical calculations.
iM Series: 1.2 to 1.7 @ 100 MHz, based on theoretical
calculations
The dielectric constant of a composite will depend on the matrix
material and volume loading of 3M glass bubbles.
Particle Size
Particle Size (microns, by volume) 3M QCM 193.0
Product Distribution
Effective
Top Size10th% 50th% 90th%
K Series
K1 30 65 115 120
K15 30 60 105 115
K20 30 60 90 105
K25 25 55 90 105
K37 20 45 80 85
K46 15 40 70 80
S Series
S15 25 55 90 95
S22 20 35 65 75
S32 20 40 70 80
S35 20 40 65 80
S38 15 40 75 85
S38HS 19 44 70 85
S60 15 30 55 65
S60HS 12 29 48 60
iM Series
iM16K 12 20 30 40
iM30K 8.6 15.3 23.6 26.7
3M

Glass Bubbles K, S and iM Series

Minimum storage conditions should be unopened cartons in an
unheated warehouse.
Under high humidity conditions with an ambient temperature
cycling over a wide range, moisture can be drawn into the bag
as the temperature drops and the air contracts. The result may
be moisture condensation within the bag. Extended exposure to
these conditions may result in caking of the 3M glass bubbles
to various degrees. To minimize the potential for caking and
prolong the storage life, the following suggestions are made:
1. Carefully re-tie open bags after use.
2. If the polyethylene bag is punctured during shipping or
handling, use this bag as soon as possible, patch the hole,
or insert the contents into an undamaged bag.
3. During humid summer months, store in the driest, coolest
space available.
4. If good storage conditions are unavailable, carry a
minimum inventory, and process on a first in/first

out basis.
Dusting problems that may occur while handling and processing
can be minimized by the following procedures:
1. For eye protection wear chemical safety goggles. For
respiratory system protection wear an appropriate NIOSH/
MSHA approved respirator. (For additional information
about personal protective equipment, refer to Material
Safety Data Sheet.)
2. Use appropriate ventilation in the work area.
3. Pneumatic conveyor systems have been used successfully
to transport 3M glass bubbles without dusting from
shipping containers to batch mixing equipment. Static
eliminators should be used to help prevent static charges.
Diaphragm pumps have been used to successfully convey
3M glass bubbles. Vendors should be consulted for
specific recommendations.
3M glass bubble breakage may occur if the product is improperly
processed. To minimize breakage, avoid high shear processes such
as high speed Cowles Dissolvers, point contact shear such as gear
pumps or 3-roll mills, and processing pressures above the strength
test pressure for each product.
Health and Safety Information
For product Health and Safety Information, refer to product label
and Material Safety Data Sheet (MSDS) before using product.
Particle Size (continued)
Hard Particles (3M QCM 93.4.3)

No hard particles (e.g. glass slag, flow agent, etc.) greater than
U.S. number 40 (420 microns) standard sieve will exist.
Oversize Particles (3M QCM 93.4.4)

For K1, K15, K20 and K25 glass bubbles:
Using a 10 gram sample on a U.S. number 80 standard sieve
(177 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
For K37 and K46 glass bubbles:

Using a 10 gram sample on U.S. number 100 standard sieve
(149 microns), a maximum of one (1) percent by weight glass
bubbles will be retained on the sieve.
For S15, S32, S35, S38, S38HS, S60, S60HS, iM16K and iM30K
glass bubbles:

Using a 10 gram sample on a U.S. number 140 standard sieve
(105 microns), a maximum of three (3) percent by weight glass
bubbles will be retained on the sieve.
For S22 glass bubbles:

Using a 10 gram sample on a U.S. number 200 standard sieve
(74 microns), a maximum of five (5) percent by weight glass
bubbles will be retained on the sieve.
Appearance (3M QCM 22.85)
White to the unaided eye.
Flow (3M QCM 22.83)
3M

Glass Bubbles remain free flowing for at least one year from
the date of shipment if stored in the original, unopened container
in the minimum storage conditions of an unheated warehouse.
Labeling
3M glass bubbles will be packaged in suitable containers to help
prevent damage during normal handling and shipping. Each
container will be labeled with:
1. Name of manufacturer
2. Type of 3M glass bubbles
3. Lot number
4. Quantity in pounds
Storage and Handling
To help ensure ease of storage and handling while maintaining
free flowing properties, 3M

Glass Bubbles have been made
from a chemically stable glass and are packaged in a heavy-duty
polyethylene bag within a cardboard container.

Packaging Information
Small Box (10 Cubic ft.)
A single corrugated box with a plastic liner. All boxes are
banded together and to the wooden pallet. 4 boxes per pallet.
Each box inside diameter is 22 in. 19 in. 39 in.

Pallet size is 42 in. 48 in.
Large Box (50 Cubic ft.)*
A single corrugated box with a plastic liner. Top enclosed
with interlocking double cover banded. Bottom is normal box
closure, entire box banded to wooden pallet.
Each box inside diameter is 48 in. 42 in. 44 in. Overall
load size is 48
3
/4 in. 42
3
/4 in. 50 in. including pallet.
Pallet size is 42 in. 48 in.
*S60 and S60HS large boxes are 38 cubic ft.
Product
Small
Box
Large
Box*
Truckload Large Box*
44 Pallets
K Series
K1 40 lb. 210 lb. 9,240 lb.
K15 50 lb. 265 lb. 11,660 lb.
K20 60 lb. 350 lb. 15,400 lb.
K25 80 lb. 430 lb. 18,920 lb.
K37 100 lb.660 lb. 29,040 lb.
K46 125 lb.815 lb. 35,860 lb.
S Series
S15 50 lb. 265 lb. 11,660 lb.
S22 60 lb. 385 lb. 16,940 lb.
S32 100 lb.525 lb. 23,100 lb.
S35 100 lb.630 lb. 27,720 lb.
S38 100 lb.680 lb. 29,920 lb.
S38HS 100 lb.680 lb. 29,920 lb.
S60 125 lb.850 lb. 37,400 lb.
S60HS 125 lb.850 lb. 37,400 lb.
iM Series
iM16K 99 lb. 800 lb.
iM30K 125 lb.850 lb. 37,400 lb.
Box Weights
*Box weights may vary due to manufacturing tolerances on each product.
Resources
3M
Glass Bubbles are supported by global sales, technical and
customer service resources, with fully-staffed technical service
laboratories in the U.S., Europe, Japan, Latin America and
Southeast Asia. Users benefit from 3M s broad technology base

and continuing attention to product development, performance,
safety and environmental issues.
For additional technical information on 3M glass bubbles in the
United States, call 3M Advanced Materials Division, 800-367-8905 .
For other 3M global offices, and information on additional 3M
products, visit our website at: www.3M.com/engineeredadditives .
3M

Glass Bubbles K, S and iM Series
Please recycle. Printed in USA.
3M 2013. All rights reserved.
Issued: 3/13 9049HB
98-0212-3859-1
3M is a trademark of 3M. Used under license
by 3M subsidiaries and affiliates.
3M Center
St. Paul, MN 55144-1000

1-800-367-8905
www.3M.com/engineeredadditives
3
Warranty, Limited Remedy, and Disclaimer: Many factors beyond 3M s control and uniquely within user s knowledge and control can affect the use and performance of a 3M product
in a particular application. User is solely responsible for evaluating the 3M product and determining whether it is fit for a particular purpose and suitable for user s method of application.
Unless a different warranty is specifically stated in the applicable product literature or packaging insert, 3M warrants that each 3M product meets the applicable 3M product specification at
the time 3M ships the product. 3M MAKES NO OTHER WARRANTIES OR CONDITIONS, EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. If the 3M
product does not conform to this warranty, then the sole and exclusive remedy is, at 3M s option, replacement of the 3M product or refund of the purchase price.
Limitation of Liability: Except where prohibited by law, 3M will not be liable for any loss or damages arising from the 3M product, whether direct, indirect, special, incidental or
consequential, regardless of the legal theory asserted, including warranty, contract, negligence or strict liability.
Technical Information: Technical information, recommendations, and other statements contained in this document or provided by 3M personnel are based on tests or experience that 3M
believes are reliable, but the accuracy or completeness of such information is not guaranteed. Such information is intended for persons with knowledge and technical skills sufficient to
assess and apply their own informed judgment to the information. No license under any 3M or third party intellectual property rights is granted or implied with this information.

24WF200_SDS.pdf

COMPOSITION MATERIALS CO., INC. 249 PEPES FARM RD, MILFORD, CT 06460 (203) 874-6500
MATERIAL SAFETY DATA SHEET

Rev. Jan. 2012
Page 1 of 4 pages

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name: WALNUT SHELL GRIT & FLOUR

Chemical Family: Walnut Shell (Organic)

Composition Materials Co., Inc. 249 Pepes Farm Road – Milford, CT 06460
Phone – 203-874-6500 Fax – 203-874-6505

2. COMPOSITION/INFORMATION ON INGREDIENTS

Natural Walnut Shell

Hazardous Ingredients: None

3. HAZARDS IDENTIFICATION

Material is light brown with no odor. Grit is granular, and flour is powdery.
Avoid creating airborne dust. Avoid ignition sources. Provide ventilation.
Avoid breathing dust. Spilled material can be slippery and cause falls if
walked on.

Potential Health Effects

EYE: Solid or dusts may cause irritation or scratch the surface of the eye.
SKIN: N/A
INGESTION: N/A
INHALATION: Potential respiratory tract irritation.
Chronic Health Effects: None known.

SARA: This material is not considered hazardous.

COMPOSITION MATERIALS CO., INC. 249 PEPES FARM RD, MILFORD, CT 06460 (203) 874-6500

MSDS – WALNUT SHELL GRIT & FLOUR Page 2 of 4

4. FIRST AID MEASURES

EYES: Flush with water.

SKIN: Wash thoroughly with soap and water.

INGESTION: N/A

INHALATION: Remove to fresh air. Call physician if irritation persists.

5. FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES: FLASH POINT: 380 F

FLAMMABLE LIMITS: 470 F

HAZARDOUS COMBUSTION PRODUCTS : None

EXTINGUISHING MEDIA: Water

Unusual Fire and Explosion Hazards: None. If improperly handled, stored,
and/or exposed to an ignition source, this material may burn.

6. ACCIDENTAL RELEASE MEASURES

Sweep up and place in appropriate disposal container. Spilled material can be a
slipping hazard. Eliminate flames, sparks, excessive temperatures.

7. HANDLING AND STORAGE

HANDLING: Avoid contact with eyes. Use in a well-ventilated area.

STORAGE: Store in closed, properly labeled containers in a cool, ventilated
area. Keep away from heat, open flames.

COMPOSITION MATERIALS CO., INC. 249 PEPES FARM RD, MILFORD, CT 06460 (203) 874-6500
MSDS – WALNUT SHELL GRIT & FLOUR Page 3 of 4

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS : Local exhaust – nuisance dust levels.

RESPIRATORY PROTECTION : N/A

SKIN PROTECTION: N/A

EYE PROTECTION: Safety glasses, goggles and/or a face shield

OTHER PROTECTIVE EQUIPMENT : None necessary.

9. PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT: N/A
MELTING POINT: N/A
VAPOR PRESSURE : N/A
VAPOR DENSITY: N/A
SOLUBILITY IN WATER: N/A
EVAPORATION RATE : N/A
SPECIFIC GRAVITY (H
2O=1): 1.2 – 1.35
pH: 4 to 5 @ 25 C
ODOR: No Odor
APPEARANCE: Granular or powdery, light brown.

10. STABILITY AND REACTIVITY

CHEMICAL STABILITY(CONDITIONS TO AVOID):Excessive heat, ignition
sources.
INCOMPATIBILITY: None known.
HAZARDOUS DECOMPOSITION PRODUCTS : None.
HAZARDOUS POLYMERIZATION : Will not Occur.
STABILITY: Stable

11. TOXICOLOGICAL INFORMATION

Toxic Substance Control Act (TSCA): Walnut shell is an organic product and not
subject to TSCA requirements.

COMPOSITION MATERIALS CO., INC. 249 PEPES FARM RD, MILFORD, CT 06460 (203) 874-6500
MSDS – WALNUT SHELL GRIT & FLOUR Page 4 of 4

12. ECOLOGICAL INFORMATION

Non-hazardous. Always comply with Federal, State and Local environmental
regulations.

13. DISPOSAL CONSIDERATIONS

Dispose as solid waste in sanitary landfill according to Federal, State and
Local regulations.

14. TRANSPORT INFORMATION

DOT: Not Regulated. NMF CLASSIFICATION: Class 55 – Item 175480

15. REGULATORY INFORMATION

N/A

16. OTHER INFORMATION

The information in this MSDS was obtained from sources we believe are reliable. However, it is
provided without any representation or warranty, expressed or implied, regarding accuracy or
correctness. The conditions or methods of handling, storage, use and disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons, we do not
assume responsibility and expressly disclaim liability for loss, damage or expense arising out of
or in any way connected with the handling, storage, use or disposal of the product.

24VIC1515_SDS.pdf

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Issue date: 9/11/2012 Revision date: 5/13/2021 Supersedes: 3/18/2015 Version: 2.1

5/13/2021 (Revision date) EN (English US) 1/10

SECTION 1: Identification
1.1. Identification
Product form : Mixture
Product name : VICRON

15-15, VICRON

25-11
Product code : C-MS-AT-3000ADVIC1515
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Mineral additive
1.3. Supplier
Specialty Minerals Inc.,
260 Columbia Street,
Adams,
MA 01220
USA
Telephone: 1-877-684-7627
1.4. Emergency telephone number
Emergency number : +1 413-743-0591 / +1 760-476-3962
3E Global Emergency Response Services. Access code: 333336 (if you mention SDS name and
company name-you don t need the access code)
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Carcinogenicity Category 1A H350 May cause cancer (Inhalation)
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Danger
Hazard statements (GHS US) : H350 – May cause cancer (Inhalation)
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P260 – Do not breathe dust.
P280 – Wear protective gloves, protective clothing, eye protection.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P405 – Store locked up.
2.3. Other hazards which do not result in classification
Other hazards which do not result in classification : Prolonged and/or massive exposure to respirable crystalline silica-containing dust may cause
silicosis, a nodular pulmonary fibrosis caused by deposition in the lungs of fine respirable
particles of crystalline silica. Dust may cause mechanical irritation of the eyes, skin and upper
respiratory tract.

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 2/10

2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
Calcium carbonate CAS-No.: 1317-65-3 > 99 Not classified
Quartz CAS-No.: 14808-60-7 0.4 Carc. 1A, H350
STOT SE 3, H335
STOT SE 1, H370
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep at rest in a position comfortable for breathing. If symptoms
develop obtain medical attention.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse. If symptoms develop, obtain medical attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If symptoms develop, obtain medical attention.
First-aid measures after ingestion : Do NOT induce vomiting. Rinse mouth. Give 100 – 200 ml of water to drink. If symptoms
develop, obtain medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects : Dust may cause mechanical irritation of the eyes, skin and upper respiratory tract.
Chronic symptoms : May cause cancer (if inhaled).
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing media : None known.
5.2. Specific hazards arising from the chemical
Fire hazard : Not flammable.
Reactivity in case of fire : Calcium carbonate: decomposes on heating. Thermal decomposition generates : Carbon
dioxide. Calcium oxide.
Hazardous decomposition products in case of fire : Carbon dioxide. Calcium oxide.

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 3/10

5.3. Special protective equipment and precautions for fire-fighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Ventilate area. Avoid dust formation. Do not breathe dust. Avoid contact with skin, eyes and
clothing. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. Where excessive dust may
result, wear approved mask.
Emergency procedures : Ventilate area. Avoid dust formation. Do not breathe dust. Avoid contact with skin, eyes and
clothing. Wear independent breathing equipment.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if large amounts of the product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Stop leak, if possible without risk.
Methods for cleaning up : Collect using vacuum cleaner fitted with HEPA filter. – OR -. Sweep or shovel spills into
appropriate container for disposal. Minimize generation of dust. Do not dry sweep dust. Store
away from other materials.
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Provide appropriate exhaust ventilation at places where dust is formed. Avoid
dust formation. Do not breathe dust. Avoid contact with skin and eyes.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or
smoke when using this product. Wash hands and other exposed areas with mild soap and water
before eating, drinking or smoking and when leaving work. Take off contaminated clothing and
wash it before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in original container. Store in a dry, cool and well-ventilated place. Keep container
closed when not in use. Store locked up.
Incompatible materials : Acids.

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 4/10

SECTION 8: Exposure controls/personal protection
8.1. Control parameters

Calcium carbonate (1317-65-3)
USA – OSHA – Occupational Exposure Limits
Local name Calcium Carbonate (Limestone; Marble)
OSHA PEL (TWA) (mg/m ) 15 mg/m Total dust
5 mg/m Respirable Fraction
Regulatory reference (US-OSHA) OSHA Annotated Table Z-1
USA – NIOSH – Occupational Exposure Limits
NIOSH REL (TWA) 10 mg/m Total dust
5 mg/m Respirable dust

Quartz (14808-60-7)
USA – ACGIH – Occupational Exposure Limits
Local name Silica crystaline – quartz
ACGIH TWA (mg/m ) 0.025 mg/m (R – Respirable particulate matter)
Remark (ACGIH) TLV

Basis: Pulm fibrosis; lung cancer. Notations: A2 (Suspected Human Carcinogen)
Regulatory reference ACGIH 2021
USA – OSHA – Occupational Exposure Limits
Local name Quartz (Respirable) (Silica: Crystalline)
OSHA PEL (TWA) (mg/m ) 0.05 mg/m [Action level: 0.025 mg/m ]
Remark (OSHA) Table Z-3. For OSHA PEL (TWA): Use formulas: (250 / (%SiO2+5)) for mppcf and (10 mg/m3 /
(%SiO2+2)) for mg/m3. CAS No. source: eCFR Table Z-1.
Regulatory reference (US-OSHA) OSHA Annotated Table Z-3 Mineral Dusts
8.2. Appropriate engineering controls
Appropriate engineering controls : Provide adequate ventilation, including appropriate local extraction, to ensure that occupational
exposure limits are not exceeded. Provide appropriate exhaust ventilation at places where dust
is formed.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.

Hand protection:
Wear chemically resistant protective gloves. The exact breakthrough time has to be found out by the manufacturer of the protective gloves and has to
be observed. Gloves should be removed and replaced if there are any signs of degradation or breakthrough.

Eye protection:
Chemical goggles or safety glasses

Skin and body protection:
Long-sleeved protective clothing

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 5/10

Respiratory protection:
Dust mask or respirator

Thermal hazard protection:
Not required for normal conditions of use.
Other information:
Do not eat, drink or smoke during use. Handle in accordance with good industrial hygiene and safety procedures.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Powder.
Color : White
Odor : Odorless
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Not flammable.
Vapor pressure : No data available
Relative vapor density at 20 C : No data available
Relative density : 2.71 (Water = 1)
Solubility : Water: Partially soluble
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : Not explosive.
Oxidizing properties : Not oxidizing.
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under recommended handling and storage conditions (see section 7).
10.2. Chemical stability
Stable under recommended handling and storage conditions (see section 7).
10.3. Possibility of hazardous reactions
Contact with acids or strong heating liberates carbon dioxide, sometimes violently.
10.4. Conditions to avoid
Heat. Dust formation.

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 6/10

10.5. Incompatible materials
Acids.
10.6. Hazardous decomposition products
Contact with acids or strong heating liberates carbon dioxide, sometimes violently. Thermal decomposition generates : Calcium oxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer (Inhalation).

Quartz (14808-60-7)
IARC group 1 – Carcinogenic to humans

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

Quartz (14808-60-7)
STOT-single exposure May cause respiratory irritation. Causes damage to organs (lungs) (Inhalation).

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified
Viscosity, kinematic : No data available

Potential Adverse human health effects and
symptoms
: Dust may cause mechanical irritation of the eyes, skin and upper respiratory tract. May cause
cancer (if inhaled).
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
VICRON

15-15, VICRON

25-11
Bioaccumulative potential No bioaccumulation.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
No additional information available

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 7/10

SECTION 13: Disposal considerations
13.1. Disposal methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Empty containers should
be taken to an approved waste handling site for recycling or disposal.
Additional information : Handle empty containers with care.
Ecology – waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with Department of Transport / Transportation of Dangerous Goods / IMDG / IATA
14.1. UN number
Not regulated for transport
14.2. UN proper shipping name
Proper Shipping Name (DOT) : Not applicable
Proper Shipping Name (TDG) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
14.3. Transport hazard class(es)
DOT
Transport hazard class(es) (DOT) : Not applicable

TDG
Transport hazard class(es) (TDG) : Not applicable

IMDG
Transport hazard class(es) (IMDG) : Not applicable

IATA
Transport hazard class(es) (IATA) : Not applicable
14.4. Packing group
Packing group (DOT) : Not applicable
Packing group (TDG) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
14.5. Environmental hazards
Other information : No supplementary information available.
14.6. Special precautions for user
Special transport precautions : No special precautions required

DOT
No data available

TDG
No data available

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 8/10

IMDG
No data available

IATA
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
VICRON

15-15, VICRON

25-11
SARA Section 311/312 Hazard Classes Health hazard – Carcinogenicity

Calcium carbonate (1317-65-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory

Quartz (14808-60-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
Calcium carbonate (1317-65-3)
Listed on the Canadian NDSL (Non-Domestic Substances List)

Quartz (14808-60-7)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
VICRON

15-15, VICRON

25-11
Determined as “Generally Recognized As Safe” (GRAS) by FDA – see 21 CFR 184.1409

Quartz (14808-60-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
WARNING:
This product can expose you to Quartz, which is known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.

Component State or local regulations
Calcium carbonate(1317-65-3) U.S. – Massachusetts – Right To Know List; U.S. – New Jersey – Right to Know Hazardous
Substance List; U.S. – Pennsylvania – RTK (Right to Know) List

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 9/10

Component State or local regulations
Quartz(14808-60-7) U.S. – Massachusetts – Right To Know List; U.S. – New Jersey – Right to Know Hazardous
Substance List; U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Revision date : 05/13/2021
Data sources : U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical Agents and Biological
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens. US OSHA HazCom (GHS) 25 May 2012.
Other information : None.

Full text of H-phrases
H335 May cause respiratory irritation
H350 May cause cancer
H370 Causes damage to organs

Abbreviations and acronyms
ACGIH (American Conference of Government Industrial Hygienists)
DOT (Department Of Transportation (US))
CAS (Chemical Abstracts Service) number
EC50 (Effective Concentration 50%)
IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association)
IMDG (International Maritime Dangerous Goods Code)
IMO (International Maritime Organisation)
LC50 (Lethal Concentration 50%)
LD50 (Lethal Dose 50%)
NIOSH (National Institute for Occupational Safety and Health)
OECD (Organisation for Economic Co-operation and Development)
OSHA (Occupational Safety and Health Administration) (US)
PEL (Permissible Exposure Limit)
STEL (Short Term Exposure Limit)
TLV (Threshold Limit Value) (ACGIH)
TSCA (Toxic Substances Control Act) (US)
TWA (Time Weighted Average)
UNxxxx (Number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods)

VICRON

15-15, VICRON

25-11
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

5/13/2021 (Revision date) EN (English US) 10/10

NFPA health hazard : 1 – Materials that, under emergency conditions, can cause significant
irritation.

NFPA fire hazard : 0 – Materials that will not burn under typical fire conditions, including
intrinsically noncombustible materials such as concrete, stone, and
sand.
NFPA reactivity : 0 – Material that in themselves are normally stable, even under fire
conditions.

Hazard Rating
Health : 1 Slight Hazard – Irritation or minor reversible injury possible
: * – Chronic (long-term) health effects may result from repeated overexposure
Flammability : 0 Minimal Hazard – Materials that will not burn
Physical : 0 Minimal Hazard – Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.

Indication of changes:
Section Changed item Change Comments
2 Hazards identification Modified
4 First aid measures Modified
6 Accidental release measures Modified
7 Handling and storage Modified
8 Exposure controls / Personal protection equipment Modified
10 Stability and reactivity Modified
11 Toxicological information Modified
15 Regulatory information Modified
16 Other information Modified
Safety Data Sheet (SDS), USA
Neither Minerals Technologies Inc., nor any of its affiliates (“MTI”) shall be responsible for the use of information, product, method, or apparatus herein
presented (“Information”), and you must make your own determination as to its suitability and completeness for your own use, for the protection of the
environment, and for health and safety purposes. You assume the entire risk of relying on this information. In no event shall MTI be responsible for
damages of any nature whatsoever resulting from the use of or reliance upon this information. By providing this information, MTI neither can nor intends
to control the method or manner by which you use, handle, store, or transport MTI products. Nothing herein shall be construed as a recommendation or
license to use any Information that conflicts with any patent, trademark or copyright. Material Safety Data Sheets providing safety precautions that
should be observed in handling and storing MTI products are available upon request. You should obtain and review the available material safety
information before handling any of these products.

MTI MAKES NO PRESENTAT IONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF MERCHANTABILITY, FITNESS FOR A PARTICULAR
PURPOSE OR OF ANY OTHER NATURE REGARDING THIS INFORMATION, AND NOTHING HEREIN WAIVES ANY CONDITIONS OF SALE. This
information could include technical inaccuracies or typographical errors. Changes are periodically added to the information herein; these changes will be
incorporated in revisions of the information. MTI may make improvements and/or changes in the product(s) described in this information at any given
time.

24SIL42-18_SDS.pdf

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SAFETY DATA SHEE]
No.: 141 Rev. No.: 14.4
Date Revised. 03/01 12420
NFPA FIRE HAZARD SYMBOL
See NFPA 704 for detailed explunation
SECTION I – Chemical Product and Company Identification
Trade Name(s): Sil-Cell@- All Grades
CAS #: 93763-70-3
Chemical Name: Sodium Potassium Aluminum Silicate
Formula: Mixture
Product Use: Insulation, Construction, Industrial, and Horticultural Applications
Manufacturer: SILBRICO CORPORATION
Address: 6300 River Road City: Hodgkins State: Illinois Zip: 60525
Telephone: 708/354-3 350
Emergency : 7 08 I 3 54-3 3 50
Suppliei’s Name (if different)
Street Address
City, Province/State, Postal/Zip Code
Emergency Telephone Number
Fax Number
Preparation date of SDS: January 9,2015
SDS Prepared By: Kenneth Wiener (Phone: 310-371-7977)
SECTION 2 -Hazards Identification
Signal word: None
GHS Pictogram: None
Route of entry:
Skin contact: Repeated or prolonged contact may cause irritation
Skin absorption: N/A
Eye contact: May irritate or injure eyes, mechanically
Inhalation: Upper Respiratory Irritant: May aggravate pre-existing respiratory conditions. Levels of
Respirable Crystalline Silica in Sil-Cell, if present at all, are undetectable. Because it is known that
long-term inhalation of respirable crystalline silica can cause disabling lung disease (silicosis), OSHA
has published revised exposure limits. The current Action Level (AL) and Permissible Exposure Limit
(PEL) as an average during 8 hours of continuous exposure are 25 pglm3 (Air) and 50 pglm3 (Air),
respectively.
Potential Health Effects: See above regarding long term exposure: skin initation, silicosis and eye
irritation
g

SECTION 3 – Composition/Information on Ingredients
Product Description/Components: Expanded perlite powder or granules, CAS# 93163-70-3
Hazardous
IngredientsCAS# %
ACGIH
TLV. mg/cu.m. NIOSH. mg/cu.m OSHA PEL. mg/cu.m
Quartz 14808-60-7 <0.1 0.025 (Respirable) 0.05 (Respirable) 0.1 (Respirable) LDso: Not Available LCso: Not Available SECTION 4 - First Aid Measures Skin Contact: Wash off with soap and water Eye Contact: Flush eyes with generous amounts of water for at least 5 minutes. Remove contact lenses if easy to do so. Continue rinsing. Inhalation: Remove to fresh air. Seek medical attention if victim is not breathing or uncomfortable. Ingestion: Do not induce vomiting. Seek medical attention if victim is not breathing or uncomfortable SECTION 5 - Fire Fighting Measures Flammable: No Means of Extinction: Use extinguishing media appropriate for surrounding material that is on fire or could be set on fire. Flashpoint ('C) and Method (oc or cc): N/A Upper Flammable Limit (%by volume): N/A Lower Flammable Limit (%by volume): NiA Autoignition Temperature ('C): N/A Explosion Data - Sensitivity to Impact: N/A Explosion Data - Sensitivity to Static Discharge: None; silicates are considered non-combustible dust Hazardous Combustion Products: N/A NFPA: Health: 0, Flammability: 0, Reactivity: 0, Other: None HMIS Ratings: Health: *(See SDS), Flammability: 0, Reactivity: 0, Personal Protection: E SECTION 6 - Accidental Release Measures Leak and Spill Procedures: Normal clean-up procedures. Care should be taken to avoid causing dust to become airborne. Vacuum cleaning systems are recommended. Wetting spilled material with water may control dust and make clean up easier. SECTION 7 - Handling and Storage Handling Procedures and Equipment: Avoid creating unnecessary dust. Storage Requirements: Store with other dusty materials, away from products that could be affected by dust. SECTION 8 - Exposure Control/Personal Protection Exposure Limits ACGIH TLV: 10 mg/m3 total dust 3 mglm3 respirable dust OSHA PEL: 15 mg/m3 total dust 5 mg/m'respirable dust Engineering Controls o General: Good housekeeping rules apply . Local Exhaust from work stations using this material Recommended Personal Protective Equipment: r Plastic or Rubber Gloves if skin irritation occurs r Respirator * NIOSH/OSHA approved dust mask adequate for contaminant concentrations encountered r Eye protection recommended o Disposable footwear for frequent handling of this material o Coveralls for frequent handling of this material SECTION 9 - Physical and Chemical Properties Physical State: Solid powder or granules odor and Appearance: white to off white powder or granules with no odor Odor Threshold (ppm): N/A Specific Gravity: 2.35 Vapor Density (air:l): N/A Vapor Pressure (mmHg): N/A Evaporation Rate: N/A Boiling Point (oC): N/A Freezing Point ('C): N/A pH: 6.5 - 7 .5, as I|Yo slurry in distilled water Coefficient of Water/Oil Distribution: N/A Solubility in Water: Negligible Visual Detection Method Only SECTION 10 - Stability and Reactivity Chemically Stable?: Yes Incompatibility with other substances? Yes: Hydrofluoric acid (HF) Reactivity, and under what conditions?: Toxic silicon tetrafluoride gas will result with contact with hydrofluoric acid. Hazardous Decomposition Products: See above SECTION 11 - Toxicological Information Effects of Acute Exposure: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), or in case of inhalation (initant). Effects of Chronic Exposure: Irritancy of Product: Potential irritant for Skin Sensitization, Respiratory Sensitization: Upper Respiratory Irritant: May aggravate pre-existing respiratory conditions. Levels of Respirable Crystalline Silica in Sil-Cell, if present at all, are undetectable. Because it is known that long-term inhalation of respirable crystalline silica can cause disabling lung disease (silicosis), OSHA has published revised exposure limits. The current Action Level (AL) and Permissible Exposure Limit (PEL) as an average during 8 hours of continuous exposure are 25 pglm3 (Air) and 50 pglm3 (Air), respectively. Carcinogenicity: These products contain less than 0.1Yo cryslalline silica, and low percentages of particles of respirable size, hence present very low risk. IARC: Not reviewed ACGIH: PNOS (Particulates Not Otherwise Specified), Not carcinogenic Reproductive Toxicity: Not available Teratogenicity: Not established Embryotoxicity: Not available Mutagenicity: Ames: Not available SECTION 12 - Ecological Information Aquatic Toxicity: Low hazard for usual industrial or commercial handling. Approved for use in soils. SECTION l3 - Disposal Considerations Waste Disposal: Dispose of this product in accordance with all applicable local, state and Federal regulations. SECTION 14 - Transport Information Special Shipping Information DOT: No special requirements IMO: Non-hazardous ICAO: Non-hazardous SECTION 15 - Regulatory Information WHMIS CLASSIFICATION: D2B (Toxic) OSHA: Label as required by Hazard Communication Standard2g CFR 1910.1200 (0 and applicable state and local laws and regulations TSCA: Included as a naturally occurring material CANADA DSL: Included or exempt EUROPE: Exempt from REACh as a naturally occurring mineral, not chemically modified. Status confirmed in Annex V Guidance Document Version 1.1, November 2012 SECTION 16 - Other Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR. Information provided in this document is believed to be accurate as of January 9, 2015 and may be subject to change without notice. The information is provided in good faith to comply with applicable federal and state laws. However, no wananty or representation with respect to such information is intended or given. It is the responsibility of the user to comply with all applicable federal, state, and local laws and regulations.