BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixturesTrade name :BLACK VINYL ESTER HI-GLOSS TOPCOATCAS-No. :mixtureProduct code :1902-045Formula :na
1.2. Recommended use and restrictions on use
Use of the substance/mixture :TOOLING TOPCOAT
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number :ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids
Category 3
H226 Flammable liquid and vaporSkin corrosion/irritation
Category 2
H315 Causes skin irritationSerious eye damage/eye
irritation Category 2A
H319 Causes serious eye irritationCarcinogenicity Category 2H351 Suspected of causing cancerReproductive toxicity
Category 2
H361 Suspected of damaging fertility or the unborn childSpecific target organ
toxicity (single exposure)
Category 3
H335 May cause respiratory irritationSpecific target organ
toxicity (repeated exposure)
Category 1
H372 Causes damage to organs through prolonged or repeated exposure
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS-US labeling
Hazard pictograms (GHS-US) :
GHS02GHS07GHS08
Signal word (GHS-US) :DangerHazard statements (GHS-US) :H226 – Flammable liquid and vapor
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H335 – May cause respiratory irritation
H351 – Suspected of causing cancer
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)2/10 H361 – Suspected of damaging fertility or the unborn child
H372 – Causes damage to organs through prolonged or repeated exposure
Precautionary statements (GHS-US) :P201 – Obtain special instructions before use
P202 – Do not handle until all safety precautions have been read and understood
P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
P233 – Keep container tightly closed
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical, lighting, ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P260 – Do not breathe dust, mist, fume, vapors, spray
P264 – Wash EXPOSED AREA. thoroughly after handling
P270 – Do not eat, drink or smoke when using this product
P271 – Use only outdoors or in a well-ventilated area
P280 – Wear eye protection, protective clothing, protective gloves
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 – If exposed or concerned: Get medical advice/attention
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell
P321 – Specific treatment (see SEEK MEDICAL AID. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention
P337+P313 – If eye irritation persists: Get medical advice/attention
P362 – Take off contaminated clothing and wash it before reuse
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P233 – Store in a well-ventilated place. Keep container tightly closed
P403+P235 – Store in a well-ventilated place. Keep cool
P405 – Store locked up
P501 – Dispose of contents/container to LOCAL, STATE, AND NATIONAL REGULATIONS.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%GHS-US classificationUnsaturated VINYL ESTER Resin(CAS-No.) TRADE SECRET<= 55Not classifiedstyrene, inhibited(CAS-No.) 100-42-5<= 39Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
BLACK DISPERSION(CAS-No.) Proprietary<= 5Not classifiedcobalt(II) 2-ethylhexanoate(CAS-No.) 136-52-7<= 0.5Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general :Never give anything by mouth to an unconscious person. IF exposed or concerned: Get
medical advice/attention.
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)3/10First-aid measures after inhalation :Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/physician if you feel unwell.
First-aid measures after skin contact :Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash
with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention.
Specific treatment (see seek medical attention. on this label).
First-aid measures after eye contact :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects :May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
No additional information available
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard :Highly flammable liquid and vapor. Flammable liquid and vapor.Explosion hazard :May form flammable/explosive vapor-air mixture.Reactivity :No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting :Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures :Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1.For non-emergency personnel
Protective equipment :Gloves. Protective goggles. Protective clothing.Emergency procedures :Evacuate unnecessary personnel.
6.1.2.For emergency responders
Protective equipment :Equip cleanup crew with proper protection.Emergency procedures :Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Dam up the liquid spill. Contain released product, pump into suitable containers.Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)4/10
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed :Handle empty containers with care because residual vapors are flammable.Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor. No open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a
well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against
static discharge. Do not breathe dust/fume/gas/mist/vapors/spray.
Hygiene measures :Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures :Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions :Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed.
Incompatible products :Strong bases. Strong acids.Incompatible materials :Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)ACGIHACGIH TWA (ppm)20 ppm (Styrene, monomer; USA; Time-weighted
average exposure limit 8 h; TLV - Adopted Value)
ACGIHACGIH STEL (ppm)40 ppm (Styrene, monomer; USA; Short time value;
TLV - Adopted Value)
cobalt(II) 2-ethylhexanoate (136-52-7)Not applicableUnsaturated VINYL ESTER Resin (TRADE SECRET)Not applicableBLACK DISPERSION (Proprietary)Not applicable
8.2. Appropriate engineering controls
Appropriate engineering controls :Ensure exposure is below occupational exposure limits (where available).
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:Avoid all unnecessary exposure.
Hand protection:Wear protective glovesEye protection:Chemical goggles or safety glassesSkin and body protection:Wear suitable protective clothing
Respiratory protection:Wear appropriate mask
Other information:Do not eat, drink or smoke during use.
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)5/10
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Liquid
Color :Black
Odor :characteristic
Odor threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :146 C
Flash point :32.2 C
Relative evaporation rate (butyl acetate=1) :No data available
Flammability (solid, gas) :Highly flammable liquid and vapor. Flammable liquid and vapor.
Vapor pressure :No data available
Relative vapor density at 20 C :No data available
Relative density :No data available
Specific gravity / density :1.1Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosion limits :No data available
Explosive properties :No data available
Oxidizing properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2.Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture. Flammable liquid and vapor.
10.3.Possibility of hazardous reactions
Not established.
10.4.Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5.Incompatible materials
Strong acids. Strong bases.
10.6.Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classifiedstyrene, inhibited (100-42-5)LD50 oral rat5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)LD50 dermal rat2820 mg/kg (Rat; Literature study; OECD 402: Acute Dermal Toxicity; >2000 mg/kg
bodyweight; Rat; Experimental value)
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)6/10
styrene, inhibited (100-42-5)
LD50 dermal rabbit5010 mg/kg (Rabbit; Literature study)LC50 inhalation rat (mg/l)12 mg/l/4h (Rat; Literature study)LC50 inhalation rat (ppm)2770 ppm/4h (Rat; Literature study)ATE US (oral)5000.000 mg/kg body weightATE US (dermal)2820.000 mg/kg body weightATE US (gases)2770.000 ppmV/4hATE US (vapors)12.000 mg/l/4hATE US (dust, mist)1.500 mg/l/4hcobalt(II) 2-ethylhexanoate (136-52-7)LD50 oral rat3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat> 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)ATE US (oral)3129.000 mg/kg body weightSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Causes serious eye irritation.Respiratory or skin sensitization :Not classifiedGerm cell mutagenicity :Not classifiedCarcinogenicity :Suspected of causing cancer.styrene, inhibited (100-42-5)IARC group2B – Possibly carcinogenic to humanscobalt(II) 2-ethylhexanoate (136-52-7)IARC group2B – Possibly carcinogenic to humansReproductive toxicity :Suspected of damaging fertility or the unborn child.
Based on available data, the classification criteria are not met
Specific target organ toxicity single exposure:May cause respiratory irritation.Specific target organ toxicity repeated
exposure
:Causes damage to organs through prolonged or repeated exposure.Aspiration hazard :Not classifiedPotential Adverse human health effects and
symptoms
:Harmful if inhaled. Based on available data, the classification criteria are not met.Symptoms/effects after inhalation :Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact :Causes skin irritation.Symptoms/effects after eye contact :Causes serious eye irritation.
SECTION 12: Ecological information
12.1.Toxicity
cobalt(II) 2-ethylhexanoate (136-52-7)LC50 fish 146.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 10.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)LC50 fish 254.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 20.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)Threshold limit algae 1144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 232.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)7/10
12.2.Persistence and degradabilityBLACK VINYL ESTER HI-GLOSS TOPCOAT (mixture)Persistence and degradabilityNot established.styrene, inhibited (100-42-5)Persistence and degradabilityReadily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD)0.42cobalt(II) 2-ethylhexanoate (136-52-7)Persistence and degradabilityReadily biodegradable in water. No (test)data on mobility of the substance available.Unsaturated VINYL ESTER Resin (TRADE SECRET)Persistence and degradabilityNot established.BLACK DISPERSION (Proprietary)Persistence and degradabilityNot established.
12.3.Bioaccumulative potential
BLACK VINYL ESTER HI-GLOSS TOPCOAT (mixture)Bioaccumulative potentialNot established.styrene, inhibited (100-42-5)BCF fish 135.5 (BCF)Log Pow2.96 (Experimental value; OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method; 25 C)
Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500). Not established.cobalt(II) 2-ethylhexanoate (136-52-7)BCF fish 11.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)Bioaccumulative potentialLow potential for bioaccumulation (BCF < 500).Unsaturated VINYL ESTER Resin (TRADE SECRET)Bioaccumulative potentialNot established.BLACK DISPERSION (Proprietary)Bioaccumulative potentialNot established.
12.4.Mobility in soil
styrene, inhibited (100-42-5)Surface tension0.032 N/m (19 C)Log KocKoc,352; Estimated value; log Koc; 2.55; Estimated valuecobalt(II) 2-ethylhexanoate (136-52-7)Surface tension0.064 N/m (20 C; 1 g/l)
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.Other information :Avoid release to the environment.
SECTION 13: Disposal considerations
13.1.Disposal methods
Product/Packaging disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information :Handle empty containers with care because residual vapors are flammable.Ecology - waste materials :Avoid release to the environment.
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)8/10
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Proper Shipping Name (DOT) :RESIN SOLUTIONClass (DOT) :3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120Packing group (DOT) :III - Minor DangerHazard labels (DOT) :3 - Flammable liquidOther information :No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IMDG) :1866Proper Shipping Name (IMDG) :RESIN SOLUTIONClass (IMDG) :3 - Flammable liquidsPacking group (IMDG) :III - substances presenting low danger
Air transport
Transport document description (IATA) :UN 1866 RESIN SOLUTION, 3, IIIUN-No. (IATA) :1866Proper Shipping Name (IATA) :RESIN SOLUTIONClass (IATA) :3 - Flammable LiquidsPacking group (IATA) :III - Minor Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)CERCLA RQ1000 lbSARA Section 311/312 Hazard ClassesImmediate (acute) health hazard
Reactive hazard
Fire hazard
Delayed (chronic) health hazard
15.2. International regulations
CANADA
No additional information available
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)Listed on EPA's Hazardous Air Pollutants (HAPS)
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)9/10
15.3. US State regulations
styrene, inhibited (100-42-5)U.S. - California -
Proposition 65 -
Carcinogens List
U.S. - California -
Proposition 65 -
Developmental Toxicity
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity -
Male
No significant risk
level (NSRL)
NoNoNoNo0.1 g/daystyrene, inhibited (100-42-5)U.S. - Massachusetts - Right To Know List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List
SECTION 16: Other information
Other information :None.Full text of H-phrases:---
---
H226Flammable liquid and vapor---
---
H315Causes skin irritation---
---
H317May cause an allergic skin reaction---
---
H319Causes serious eye irritation---
---
H332Harmful if inhaled---
---
H335May cause respiratory irritation---
---
H351Suspected of causing cancer---
---
H361Suspected of damaging fertility or the unborn child---
---
H372Causes damage to organs through prolonged or repeated exposure---
---
H400Very toxic to aquatic life---
---
H411Toxic to aquatic life with long lasting effectsNFPA health hazard :2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard :3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity :2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard RatingHealth :2 Moderate Hazard - Temporary or minor injury may occurFlammability :3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical :1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
:HPersonal protection H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
BLACK VINYL ESTER HI-GLOSS TOPCOAT
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
04/13/2018EN (English US)10/10
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.