Safety Data Sheet
HP 8200 SERIES A-SIDE
Safety Data Sheet dated: 7/28/2023 – version 5
Date of first edition: 4/13/2023
1. IDENTIFICATION
Product identifier
Mixture identification:
Trade name: HP 8200 SERIES A-SIDE
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use: N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company: ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable: N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Label elements
Skin irritation, Category 2 Causes skin irritation.
Eye irritation, Category 2A Causes serious eye irritation.
Respiratory Sensitization, Category 1 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Skin Sensitization, Category 1 May cause an allergic skin reaction.
Carcinogenicity, Category 2 Suspected of causing cancer.
Specific target organ toxicity following single exposure, Category 3 May cause respiratory irritation.
Specific target organ toxicity following repeated exposure, Category 2 May cause damage to organs through prolonged or repeated exposure.
Acute toxicity (inhalation), Category 4 Harmful if inhaled.
Hazard pictograms and Signal Word
Danger
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Page n. of1 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
Hazards not otherwise classified identified during the classification process:
None
Additional classification information
Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … Thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302+P352 IF ON SKIN: Wash with plenty of water/
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER/doctor/ if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … On this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to …
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
N.A.
Mixtures
Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:
List of components
Qty Name Ident. Numb. Classification Registration Number
60-80 % DIPHENYLMETHANEDIISOCYANATE CAS:9016-87-9 Skin Irrit. 2, H315; Eye Irrit. 2A,
H319; STOT SE 3, H335; STOT RE
Page n. of2 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
HMIS Health: 2 = MODERATE
HMIS Flammability: 1 = Combustible if heated
HMIS Reactivity: 0 = MINIMAL
HMIS P.P.E.: Safety glasses, gloves
NFPA Health: 2 = MODERATE
NFPA Flammability: 1 = Combustible if heated
NFPA Reactivity: 0 = MINIMAL
NFPA Special Risk: NONE
60-80 % DIPHENYLMETHANEDIISOCYANATE CAS:9016-87-9
H319; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334
30-70 % 4,4′-METHYLENEDIPHENYL
DIISOCYANATE
CAS:101-68-8 Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Carc. 2,
H351; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334;
Skin Sens. 1, H317
The actual concentration of the components listed above is withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Remove contaminated clothing immediatley and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
Page n. of3 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Exercise the greatest care when handling or opening the container.
Do not use on extensive surface areas in premises where there are occupants.
Use localized ventilation system.
Don’t use empty container before they have been cleaned.
Before making transfer operations, assure that there aren’t any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Storage temperature: N.A.
Always keep in a well ventilated place.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Appropriate engineering controls: N.A.
Individual protection measures
Eye protection:
Use close fitting safety goggles, don’t use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment.
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance and colour: brown
Odour: Slightly Musty
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.A.
Initial boiling point and boiling range: 300 C (572 F)
Flash point: N.A.
Evaporation rate: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour density: 8.5
Vapour pressure: 0.000004 mmHg @ 25 C
Relative density: 9.00 lbm/gal
Solubility in water: N.A.
Solubility in oil: N.A.
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A. Notes: >600 C
Decomposition temperature: N.A.
Viscosity: 1,100.00 cPo
Explosive properties: N.A.
Oxidizing properties: N.A.
Solid/gas flammability: N.A.
Other information
Substance Groups relevant properties N.A.
Miscibility: N.A.
Fat Solubility: N.A.
Page n. of4 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
Fat Solubility: N.A.
Conductivity: N.A.
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Toxicological Information of the Preparation
a) acute toxicity The product is classified: Acute toxicity (inhalation), Category 4(H332)
b) skin corrosion/irritation The product is classified: Skin irritation, Category 2(H315)
c) serious eye damage/irritation The product is classified: Eye irritation, Category 2A(H319)
d) respiratory or skin sensitisationThe product is classified: Respiratory Sensitization, Category 1(H334), Skin
Sensitization, Category 1(H317)
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity The product is classified: Carcinogenicity, Category 2(H351)
g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure The product is classified: Specific target organ toxicity following single exposure, Category 3(H335)
i) STOT-repeated exposure The product is classified: Specific target organ toxicity following repeated exposure, Category 2(H373)
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Substance(s) listed on the IARC Monographs:
None
Substance(s) listed as OSHA Carcinogen(s):
None
Substance(s) listed as NIOSH Carcinogen(s):
None
Substance(s) listed on the NTP report on Carcinogens:
None
12. ECOLOGICAL INFORMATION
Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Persistence and degradability
Bioaccumulative potential
List of Eco-Toxicological properties of the product
Not classified for environmental hazards.
No data available for the product
N.A.
Page n. of5 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
Bioaccumulative potential
Mobility in soil
Other adverse effects
N.A.
N.A.
N.A.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.
14. TRANSPORT INFORMATION
UN number
ADR-UN number: 3082
DOT-UN Number: UN3082
IATA-Un number: 3082
IMDG-Un number: 3082
UN proper shipping name
ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
DOT Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
IATA-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport hazard class(es)
ADR-Class: 9
DOT Hazard Class: 9
IATA-Class: 9
IMDG-Class: 9
Packing group
ADR-Packing Group: III
DOT Packing Group: III
IATA-Packing group: III
IMDG-Packing group: III
Environmental hazards
Marine pollutant: No
Environmental Pollutant: N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
Special precautions
Department of Transportation (DOT):
DOT-Special Provision(s): 8, 146, 173, 335, IB3, T4, TP1, TP29
DOT Label(s): 9
DOT Symbol: N/A
DOT Cargo Aircraft: No limit
DOT Passenger Aircraft: No limit
DOT Bulk: 241
DOT Non-Bulk: 203
Road and Rail (ADR-RID):
ADR-Label: 9
ADR – Hazard identification number: 90
ADR-Transport category (Tunnel restriction code): 3 (-)
Air (IATA):
IATA-Passenger Aircraft: 964
IATA-Cargo Aircraft: 964
IATA-Label: 9
IATA-Subrisk: –
IATA-Erg: 9L
IATA-Special Provisions: A97 A158 A197 A215
Page n. of6 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
IATA-Special Provisions: A97 A158 A197 A215
Sea (IMDG):
IMDG-Stowage Code: Category A
IMDG-Stowage Note: –
IMDG-Subrisk: –
IMDG-Special Provisions: 274 335 969
IMDG-EMS: F-A, S-F
15. REGULATORY INFORMATION
USA – Federal regulations
TSCA – Toxic Substances Control Act
SARA – Superfund Amendments and Reauthorization Act
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
CAA – Clean Air Act
CWA – Clean Water Act
USA – State specific regulations
California Proposition 65
Massachusetts Right to know
Pennsylvania Right to know
New Jersey Right to know
TSCA inventory:
No substances listed
TSCA listed substances:
No substances listed
Section 302 – Extremely Hazardous Substances:
No substances listed
Section 304 – Hazardous substances:
No substances listed
Section 313 – Toxic chemical list:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under CERCLA:
No substances listed
CAA listed substances:
No substances listed
CWA listed substances:
No substances listed
Substance(s) listed under California Proposition 65:
No substances listed
Substance(s) listed under Massachusetts Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under Pennsylvania Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under New Jersey Right to know:
No substances listed
16. OTHER INFORMATION
Code Description
Page n. of7 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate
Safety Data Sheet dated: 7/28/2023 – version 5
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality. The information relates only to the specific material and may not be valid for such material
used in combination with any other material or in any process.
This document was prepared by a competent person who has received appropriate training.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the “International Civil Aviation Organization” (ICAO).
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
CLP: Classification, Labeling, Packaging.
EINECS: European Inventory of Existing Commercial Chemical Substances.
INCI: International Nomenclature of Cosmetic Ingredients.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO: Ordinance on Hazardous Substances, Germany.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
DNEL: Derived No Effect Level.
PNEC: Predicted No Effect Concentration.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
WGK: German Water Hazard Class.
KSt: Explosion coefficient.
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided without any
warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety preventive measures for the users
who have got professional training. The personal user who obtained this SDS should make independent judgment for the
applicability of this SDS under special conditions. In these special cases, we do not assume responsibility for the damage.
Paragraphs modified from the previous revision:
– 9. PHYSICAL AND CHEMICAL PROPERTIES
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Code Hazard class and hazard category Description
A.1/4/Inhal Acute Tox. 4 Acute toxicity (inhalation), Category 4
A.2/2 Skin Irrit. 2 Skin irritation, Category 2
A.3/2A Eye Irrit. 2A Eye irritation, Category 2A
A.4.1/1 Resp. Sens. 1 Respiratory Sensitization, Category 1
A.4.2/1 Skin Sens. 1 Skin Sensitization, Category 1
A.6/2 Carc. 2 Carcinogenicity, Category 2
A.8/3 STOT SE 3 Specific target organ toxicity following single exposure, Category 3
A.9/2 STOT RE 2 Specific target organ toxicity following repeated exposure, Category 2
Page n. of8 87/28/2023 Production Name HP 8200 SERIES A-SIDEDate