Safety Data Sheet

ISOPROPANOL 99% USP
Version 1.7 Revision Date: 08/22/2022

SDS Number: 100000004142 1 / 11 ISOPROPANOL 99% USP

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : ISOPROPANOL 99% USP
Recommended use of the chemical and restrictions on use
Recommended use : Industrial chemical
Manufacturer or supplier’s details
Company : Univar Solutions USA, Inc.
Address

3075 Highland Pkwy Suite 200
Downers Grove, IL 60515
United States of America (USA)
Emergency telephone number:
Transport North America: CHEMTREC (1-800-424-9300)
CHEMTREC INTERNATIONAL Tel # 703 -527-3887
Additional Information: : Responsible Party: Product Compliance Department
E-mail: SDSNA@univarsolutions.com
SDS Requests: 1-855-429-2661
Website: www.univarsolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids

: Category 2
Eye irritation

: Category 2A
Specific target organ toxicity
– single exposure

: Category 3 (Central nervous system)
GHS label elements
Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.

Precautionary statements

: Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting equip-
ment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.

Safety Data Sheet

ISOPROPANOL 99% USP
Version 1.7 Revision Date: 08/22/2022

SDS Number: 100000004142 2 / 11 ISOPROPANOL 99% USP

P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/
doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P370 + P378 In case of fire: Use dry sand, dry chemical or alco-
hol-resistant foam to extinguish.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Substance
Hazardous components
CAS-No. Chemical name Weight percent
67-63-0 Isopropyl alcohol 90 – 100
Any Concentration shown as a range is due to batch variation.

Synonyms : 2-PROPANOL; ISOPROPYL ALCOHOL; IPA ,

SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : Consult a physician after significant exposure.
If unconscious, place in recovery position and seek medical
advice.
In case of skin contact : If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Immediately flush eye(s) with plenty of water.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

Safety Data Sheet

ISOPROPANOL 99% USP
Version 1.7 Revision Date: 08/22/2022

SDS Number: 100000004142 3 / 11 ISOPROPANOL 99% USP

If swallowed : Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Do not induce vomiting without medical advice.

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during fire-
fighting
: Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion prod-
ucts

: Carbon oxides
formaldehyde
corrosive vapors
Nitrogen oxides (NOx)

Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored sepa-
rately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if nec-
essary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures

: Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentra-
tions. Vapours can accumulate in low areas.

Environmental precautions

: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Contain spillage, and then collect with non-combustible ab-
sorbent material, (e.g. sand, earth, diatomaceous earth, ver-
miculite) and place in container for disposal according to local
/ national regulations (see section 13).

SECTION 7. HANDLING AND STORAGE

Safety Data Sheet

ISOPROPANOL 99% USP
Version 1.7 Revision Date: 08/22/2022

SDS Number: 100000004142 4 / 11 ISOPROPANOL 99% USP

Advice on protection against
fire and explosion

: Do not spray on a naked flame or any incandescent material.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours). Use only
explosion-proof equipment. Keep away from open flames, hot
surfaces and sources of ignition.

Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours/dust.
Avoid exposure – obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Container may be opened only under exhaust ventilation
hood.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : No smoking.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
CAS-No. Components Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
67-63-0 Isopropyl alcohol TWA 200 ppm ACGIH

STEL 400 ppm ACGIH

TWA 400 ppm
980 mg/m3
NIOSH REL

ST 500 ppm
1,225 mg/m3
NIOSH REL

TWA 400 ppm
980 mg/m3
OSHA Z-1

TWA 400 ppm
980 mg/m3
OSHA P0

STEL 500 ppm
1,225 mg/m3
OSHA P0

PEL 400 ppm
980 mg/m3
CAL PEL

STEL 500 ppm
1,225 mg/m3
CAL PEL
Personal protective equipment

Safety Data Sheet

ISOPROPANOL 99% USP
Version 1.7 Revision Date: 08/22/2022

SDS Number: 100000004142 5 / 11 ISOPROPANOL 99% USP

Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are un-
known, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any hazardous
chemical is limited. Use a positive pressure air supplied respi-
rator if there is any potential for uncontrolled release, expo-
sure levels are unknown, or any other circumstance where air
purifying respirators may not provide adequate protection.
Hand protection

Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection : Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : Clear, Colorless
Odour : alcohol-like, characteristic
Odour Threshold : 200 ppm

pH : No data available

Freezing Point (Melting
point/freezing point)
: -88 C (-126 F)

Boiling Point (Boiling
point/boiling range)
: 82 – 83 C (180 – 181 F)
(1013 hPa)

Flash point : 12 C (54 F)
Method: Tag closed cup

Evaporation rate : < 3.9 (Butyl Acetate = 1) Flammability (solid, gas) : No data available Upper explosion limit : 13 %(V) Lower explosion limit : 2 %(V) Vapour pressure : No data available Relative vapour density : < 2.1 @ 15 - 20 C (59 - 68 F) (Air = 1.0) Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 6 / 11 ISOPROPANOL 99% USP Relative density : 0.785 - 0.787 @ 20 C (68 F) Reference substance: (water = 1) Density : 0.785 - 0.787 g/cm3 @ 20 C (68 F) Solubility(ies) Water solubility : completely miscible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : log Pow: 0.05 @ 25 C (77 F) Auto-ignition temperature : 399 - 425 C Thermal decomposition : No data available Viscosity Viscosity, dynamic : 2.4 mPa.s @ 20 C (68 F) Viscosity, kinematic : 2.66 mm2/s @ 25 C (77 F) Surface tension : 22.7 mN/m, 20 C SECTION 10. STABILITY AND REACTIVITY Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- tions : Vapours may form explosive mixture with air. Conditions to avoid : Keep away from heat, flame, sparks and other ignition sources. Incompatible materials : Strong acids Aldehydes Oxidizing agents Rubber Oils Plastics Amines Metals Halogenated compounds Peroxides Bases Hazardous decomposition products : Carbon oxides Sulphur oxides SECTION 11. TOXICOLOGICAL INFORMATION Serious eye damage/eye irritation Components: 67-63-0: Species: Rabbit Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 7 / 11 ISOPROPANOL 99% USP Result: Irritating to eyes. Carcinogenicity IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH Confirmed animal carcinogen with unknown relevance to hu- mans 64-17-5 Ethanol STOT - single exposure Components: 67-63-0: Assessment: The substance or mixture is classified as specific target organ toxicant, single ex- posure, category 3 with narcotic effects. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vom- iting. Concentrations substantially above the TLV value may cause narcotic effects. Solvents may degrease the skin. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity No data available Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 8 / 11 ISOPROPANOL 99% USP Other adverse effects Product: Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Uni- var Solutions ChemCare: 1-800-637-7922 Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION DOT (Department of Transportation): UN1219, ISOPROPANOL, 3, II IATA (International Air Transport Association): UN1219, ISOPROPANOL, 3, II IMDG (International Maritime Dangerous Goods): UN1219, ISOPROPANOL, 3, II, Flash Point:12 C(54 F) SECTION 15. REGULATORY INFORMATION WHMIS Classification : B2: Flammable liquid D2B: Toxic Material Causing Other Toxic Effects EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard Acute Health Hazard Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 9 / 11 ISOPROPANOL 99% USP SARA 302 : No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: 67-63-0 Isopropyl alcohol Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Sec- tion 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): 67-63-0 Isopropyl alcohol Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know 67-63-0 Isopropyl alcohol 90 - 100 % Pennsylvania Right To Know 67-63-0 Isopropyl alcohol 90 - 100 % New Jersey Right To Know 67-63-0 Isopropyl alcohol 90 - 100 % 64-17-5 Ethanol 0.1 - 1 % California Prop 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other re- productive harm. The components of this product are reported in the following inventories: TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory ENCS : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PHIL : On the inventory, or in compliance with the inventory Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 10 / 11 ISOPROPANOL 99% USP IECSC : On the inventory, or in compliance with the inventory SECTION16. OTHER INFORMATION NFPA: HMIS III: The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Univar Solutions Product Compliance Department (1-855-429-2661) SDSNA@univarsolutions.com. Revision Date : 08/22/2022 Legacy SDS: : R0053741 Material number: 16191967, 16143651, 16144388, 16176285, 16174729, 16174654, 16170112, 16168841, 16137803, 16132688, 16131163, 16103146, 36643, 16020852, 16001817, 554337, 87782, 106230, 55961, 71764, 504926 Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of Govern- ment Industrial Hygienists LD50 Lethal Dose 50% AICS Australia, Inventory of Chemical Substances LOAEL Lowest Observed Adverse Effect Level DSL Canada, Domestic Substances List NFPA National Fire Protection Agency NDSL Canada, Non-Domestic Substanc- es List NIOSH National Institute for Occupational Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi- cals EC50 Effective Concentration NOAEL No Observable Adverse Effect Flammability Health Instability 2 3 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 3 0 2 Special hazard 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 =Extreme, * = Chronic Safety Data Sheet ISOPROPANOL 99% USP Version 1.7 Revision Date: 08/22/2022 SDS Number: 100000004142 11 / 11 ISOPROPANOL 99% USP Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure Scenar- io Tool OSHA Occupational Safety & Health Administration EOSCA European Oilfield Specialty Chem- icals Association PEL Permissible Exposure Limit EINECS European Inventory of Existing Chemical Substances PICCS Philippines Inventory of Commer- cial Chemical Substances MAK Germany Maximum Concentration Values PRNT Presumed Not Toxic GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research
on Cancer
TLV Threshold Limit Value
IECSC Inventory of Existing Chemical
Substances in China
TWA Time Weighted Average
ENCS Japan, Inventory of Existing and
New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50%