TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 1 / 19
SECTION 1. IDENTIFICATION
Product name

: TIOXIDE TR93

Manufacturer or supplier’s details
Company name of supplier : Venator Americas LLC
Address : 10001 Woodloch Forest Drive
The Woodlands,
TX 77380
United States of America (USA)
Telephone : (001) 844 831 6720
Telefax : (001) 281 465 6731

E-mail address of person
responsible for the SDS
: msds@venatorcorp.com

Emergency telephone number : USA & Canada: +1-800-424-9300 Other Americas: +1-703-
741-5970 [CCN 820025]

Recommended use of the chemical and restrictions on use
Recommended use

: Pigment
Opacifying agent

Restrictions on use

: Do not use for cosmetics, food additives, drug additives, feed
additives or permanent implant applications., Due to lack of
related experience or data, the supplier cannot approve this
use.

SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.
Other hazards
Handling and/or processing of this material may generate a dust which can cause mechanical
irritation of the eyes, skin, nose and throat.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture

: Substance
Chemical nature

: inorganic

Hazardous components
Chemical name CAS-No. Concentration (% w/w)

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 2 / 19
titanium dioxide 13463-67-7 90 – 100
aluminium oxide 1344-28-1 1 – 5
The specific chemical identity and/or exact percentage (concentration) of composition may be
withheld as a trade secret.

SECTION 4. FIRST AID MEASURES
General advice

: Do not leave the victim unattended.
Treat symptomatically.

If inhaled

: Remove person to fresh air. If signs/symptoms continue, get
medical attention.
If unconscious, place in recovery position and seek medical
advice.

In case of skin contact

: Wash off with soap and water.

In case of eye contact

: Rinse immediately with plenty of water, also under the eyelids.
Remove contact lenses.
Protect unharmed eye.
If eye irritation persists, consult a specialist.

If swallowed

: Rinse mouth with water.
If conscious, make the victim drink the following:
Give small amounts of water to drink.
Do not induce vomiting without medical advice.
Consult a physician if necessary.

Most important symptoms
and effects, both acute and
delayed

: Dust contact with the eyes can lead to mechanical irritation.
Inhalation of dust may cause shortness of breath, tightness of
the chest, a sore throat and cough.
The product is not irritant but as with all fine powders can
absorb moisture and natural oils from the surface of the skin
during prolonged exposure.
Individuals with sensitive skin may experience skin drying on
prolonged or repeated exposure.

Protection of first-aiders

: No action shall be taken involving any personal risk or without
suitable training.

Notes to physician

: No specific measures identified.

SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media

: Product is compatible with standard fire-fighting agents.

Unsuitable extinguishing
media

: High volume water jet

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 3 / 19
Specific hazards during
firefighting

: No information available.

Hazardous combustion
products

: No hazardous combustion products are known

Specific extinguishing
methods

: Cool containers/tanks with water spray.

Further information : Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
No action shall be taken involving any personal risk or without
suitable training.

Special protective equipment
for firefighters

: Wear self-contained breathing apparatus for firefighting if
necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures

: No action shall be taken involving any personal risk or without
suitable training.
Prevent unauthorised persons entering the zone.
Avoid dust formation.
Remove all sources of ignition.
Ventilate the area.
Avoid breathing dust.
Keep people away from and upwind of spill/leak.
Only qualified personnel equipped with suitable protective
equipment may intervene.
Never return spills in original containers for re-use.
Treat recovered material as described in the section “Disposal
considerations”.
For disposal considerations see section 13.
The danger areas must be delimited and identified using
relevant warning and safety signs.

Environmental precautions

: Try to prevent the material from entering drains or water
courses.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

: Clean-up methods – small spillage
Clean up promptly by sweeping or vacuum.
Keep in suitable, closed containers for disposal.

Clean-up methods – large spillage
Approach release from upwind.
Clean up promptly by sweeping or vacuum.
Avoid creating dusty conditions and prevent wind dispersal.
Keep in suitable, closed containers for disposal.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 4 / 19
SECTION 7. HANDLING AND STORAGE
Technical measures

: Ensure that eyewash stations and safety showers are close to
the workstation location.

Local/Total ventilation

: Use only with adequate ventilation.

Advice on protection against
fire and explosion

: Normal measures for preventive fire protection.

Advice on safe handling : For personal protection see section 8.
Avoid creating dust.
Smoking, eating and drinking should be prohibited in the
application area.

Manual handling guidelines should be adhered to when
handling sacks.
In the manufacture of titanium dioxide, product is packaged at
temperatures of approximately 100 to 120 C (212 to 248
Fahrenheit). When pigment is shipped shortly after
manufacture, it may stay hot for a very long time depending
on ambient temperatures and inventory storage practices.
Due to the potential of elevated pigment temperature, caution
should be used while handling pigment and in solvent
applications. Each work environment must be assessed to
determine hazards.
Emptying of flexible intermediate bulk containers (FIBC’s) can
generate static electricity. Customers using FIBC’s should
consult leaflet “Tiotainer Handling Guidelines”.
Empty FIBC’s by gravity only (do not empty pneumatically).
Remove all wrapping prior to emptying FIBC’s.
In all cases, the protective cover or wrapping should remain in
place during storage and only be removed immediately prior
to use.
Care should be taken to avoid moisture, particularly with a
partly used pallet of material.
When transferring from one container to another apply
earthing measures and use conductive hose material.

Conditions for safe storage : Store in accordance with the particular national regulations.
Keep only in the original container in a cool, well ventilated place
away from oxidizing agents.
Keep in a dry place.
Keep cool. Protect from sunlight.
Eliminate all ignition sources if safe to do so.
Keep container closed when not in use.
Containers which are opened must be carefully resealed and kept
upright to prevent leakage.
Use appropriate container to avoid environmental contamination.
When using standard pallets, those containing paper or plastics bags
can be stacked to a maximum of 2 high.

Materials to avoid : No materials to be especially mentioned.

Further information on
storage stability
: Keep in a dry place.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 5 / 19

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
titanium dioxide 13463-67-7 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA 10 mg/m3
(Titanium dioxide)
ACGIH
aluminium oxide 1344-28-1 TWA (total
dust)
15 mg/m3 OSHA Z-1
TWA
(respirable
fraction)
5 mg/m3 OSHA Z-1
TWA
(Respirable
fraction)
1 mg/m3
(Aluminium)
ACGIH
Engineering measures : Ensure adequate ventilation, especially in confined areas.
Use engineering controls to keep exposures below the OEL
or DNEL

Personal protective equipment
Respiratory protection

: General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.

Filter type

: P2 filter

Hand protection
Directive : Use gloves approved to relevant standards e.g. EN 374
(Europe), F739 (US).

Eye protection

: Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary
to avoid exposure to liquid splashes, mists or dusts.
Ensure that eyewash stations and safety showers are close
to the workstation location.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 6 / 19
Skin and body protection

: Personal protective equipment for the body should be
selected based on the task being performed and the risks
involved and should be approved by a specialist before
handling this product.

Protective measures

: Wear suitable protective equipment.

Hygiene measures

: Handle in accordance with good industrial hygiene and safety
practice.
Smoking, eating and drinking should be prohibited in the
application area.
Wash face, hands and any exposed skin thoroughly after
handling.
Remove contaminated clothing and protective equipment
before entering eating areas.
Barrier creams may help to protect the exposed areas of
skin, they should however not be applied once exposure has
occurred.
Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance

: powder

Colour

: white

Odour

: slight
Odour Threshold

: No data is available on the product itself.

pH

: 6.5 – 9
Concentration: 100 g/l

Melting point

: ca. 1,800 C

Boiling point/boiling range

: Not applicable
Flash point : Not applicable

Evaporation rate : No data is available on the product itself.

Flammability (solid, gas) : No data is available on the product itself.

Flammability (liquids) : No data is available on the product itself.

Burning rate : Will not burn
Not combustible.

Upper explosion limit / Upper
flammability limit

: No data is available on the product itself.

Lower explosion limit / Lower
flammability limit
: No data is available on the product itself.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 7 / 19

Vapour pressure : No data is available on the product itself.

Relative vapour density : No data is available on the product itself.

Relative density : 4.05 (20 C)

Density : 4.05 g/cm3 (20 C)
Skeletal density

Solubility(ies)
Water solubility : Not applicable

Solubility in other solvents : Solvent: Methanol
Description: insoluble

Partition coefficient: n-
octanol/water
: No data is available on the product itself.

Auto-ignition temperature : No data is available on the product itself.

Thermal decomposition : No data is available on the product itself.

Self-Accelerating
decomposition temperature
(SADT)

: No data is available on the product itself.

Viscosity

: No data is available on the product itself.

Explosive properties

: No data is available on the product itself.

Oxidizing properties

: None.

Impact sensitivity

: Not impact sensitive.

Molecular weight

: No data available
Particle size

: No data is available on the product itself.

SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : No decomposition if stored and applied as directed.
Possibility of hazardous
reactions
: Stable under recommended storage conditions.
No hazards to be specially mentioned.

Conditions to avoid : No data available

Incompatible materials : None known.

Hazardous decomposition
products
: At high temperature, decomposition products could include
trace of alpha-ethyl acrolein and formaldehyde.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 8 / 19
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of
exposure
: No data is available on the product itself.

Acute toxicity
Components:
titanium dioxide:
Acute oral
toxicityComponents
: LD50 (Rat, female): > 5,000 mg/kg
Method: OECD Test Guideline 425
Assessment: The substance or mixture has no acute oral
toxicity

aluminium oxide:
Acute oral
toxicityComponents
: LD50 (Rat, male and female): > 10,000 mg/kg
Method: OECD Test Guideline 401

Components:
titanium dioxide:
Acute inhalation toxicity : LC50 (Rat, male and female): 3.43 – 5.09 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute
inhalation toxicity

aluminium oxide:
Acute inhalation toxicity : LC50 (Rat, male and female): > 2.3 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute
inhalation toxicity

Acute dermal toxicity –
Product
: Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute toxicity (other routes of
administration)
: No data available

Skin corrosion/irritation
Components:
titanium dioxide:
Species: Rabbit
Assessment: No skin irritation
Method: OECD Test Guideline 404
Result: Normally reversible injuries

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 9 / 19
aluminium oxide:
Species: Rabbit
Assessment: No skin irritation
Method: OECD Test Guideline 404
Result: No skin irritation

Serious eye damage/eye irritation
Components:
titanium dioxide:
Species: Rabbit
Result: Normally reversible injuries
Assessment: No eye irritation
Method: OECD Test Guideline 405

aluminium oxide:
Species: Rabbit
Result: No eye irritation
Assessment: No eye irritation
Method: OECD Test Guideline 405

Respiratory or skin sensitisation
Components:
titanium dioxide:
Test Type: Local lymph node assay (LLNA)
Exposure routes: Skin
Species: Mouse
Assessment: Does not cause skin sensitisation.
Method: OECD Test Guideline 429
Result: Does not cause skin sensitisation.

Exposure routes: Skin
Species: Guinea pig
Assessment: Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Result: Does not cause skin sensitisation.

aluminium oxide:
Exposure routes: Skin
Species: Guinea pig
Result: Does not cause skin sensitisation.

Components:
titanium dioxide:
Assessment: No skin irritation, No eye irritation
Does not cause skin sensitisation., Does not cause respiratory
sensitisation.

Germ cell mutagenicity
Components:
titanium dioxide:
Genotoxicity in vitro : Test Type: Ames test
Concentration: 100 – 200 ug/plate

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 10 / 19
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative

Test Type: In vitro mammalian cell gene mutation test
Concentration: 31 – 500 g/L
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative

Test Type: Chromosome aberration test in vitro
Concentration: 125 – 2500 g/L
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative

Components:
titanium dioxide:
Genotoxicity in vivo : Test Type: Micronucleus test
Species: Mouse (males)
Application Route: Inhalation
Exposure time: 5 consecutive days
Dose: 0.8, 7.2, and 28.5 mg/m
Method: OECD Test Guideline 474
Result: negative

Test Type: Micronucleus test
Species: Rat (male and female)
Application Route: Oral
Exposure time: once
Dose: 500, 1000, and 2000 mg/kg bw
Method: OECD Test Guideline 474
Result: negative

Components:
titanium dioxide:
Germ cell mutagenicity-
Assessment
: Tests on bacterial or mammalian cell cultures did not show
mutagenic effects., Animal testing did not show any mutagenic
effects.

Germ cell mutagenicity-
Assessment
: No data available

Carcinogenicity
Components:
titanium dioxide:
Species: Rat, (male and female)
Application Route: Oral
Exposure time: 103 weeks
Dose: 0, 25000, 50000 ppm
Frequency of Treatment: 7 days/week
NOAEL: > 50.000 ppm

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 11 / 19
Method: No information available.
Remarks: Titanium Dioxide: based on the results of chronic inhalation studies (with positive
results only in a single species – rat), IARC has concluded that: “There is inadequate evidence
in humans for the carcinogenicity of titanium dioxide. ” but that : “There is sufficient evidence in
experimental animals for carcinogenicity of titanium dioxide”. IARCs overall evaluation was that
“titanium dioxide is possibly carcinogenic to humans (Group 2B).”

Venator has examined all of the available animal carcinogenicity and mechanistic data together
with workplace epidemiology data for titanium dioxide and concludes that the weight of scientific
evidence indicates that there is no causative link between titanium dioxide exposure and cancer
risk in humans and that workplace exposures in compliance with applicable exposure standards
will not result in lung cancer or chronic respiratory diseases in humans.

Components:
titanium dioxide:
Carcinogenicity –
Assessment
: Not classifiable as a human carcinogen.

IARC

Group 2B: Possibly carcinogenic to humans

titanium dioxide

ACGIH

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Reproductive toxicity
Components:
aluminium oxide:
Effects on fertility : Species: Rat, male and female
Application Route: Oral
Dose: 1000 milligram per kilogram
Method: OECD Test Guideline 422
Result: Animal testing did not show any effects on fertility.

Components:
titanium dioxide:
Effects on foetal
development
: Species: Rat, male and female
Application Route: Oral
Dose: 100, 300, and 1000 mg/kg bw/
Duration of Single Treatment: 20 d
Frequency of Treatment: 7 days/week
General Toxicity Maternal: No observed adverse effect level:
1,000 mg/kg body weight
Developmental Toxicity: No observed adverse effect level:
1,000 mg/kg body weight
Method: OECD Test Guideline 414

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 12 / 19
Result: No adverse effects

aluminium oxide:
Species: Rat
Application Route: Oral
General Toxicity Maternal: No observed adverse effect level:
266 mg/kg body weight
Method: OECD Test Guideline 414
Result: No teratogenic effects

Components:
titanium dioxide:
Reproductive toxicity –
Assessment
: No evidence of adverse effects on sexual function and fertility,
or on development, based on animal experiments.

STOT – single exposure
No data available

STOT – repeated exposure
No data available

Repeated dose toxicity
Components:
titanium dioxide:
Species: Rat, male and female
: 3500 mg/m3
Application Route: Ingestion
Test atmosphere: dust/mist
Exposure time: 2 yr
Number of exposures: 5 d
Method: Chronic toxicity

Species: Rat, male and female
: 10 – 50 mg/m3
Application Route: Inhalation
Exposure time: 2 yr
Number of exposures: 6 hours/day, 5 days/week
Method: Chronic toxicity

Components:
titanium dioxide:
Repeated dose toxicity –
Assessment
: No skin irritation, No eye irritation
No adverse effect has been observed in chronic toxicity tests.

Aspiration toxicity
No data available

Experience with human exposure
General Information: No data available

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 13 / 19

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution
No data available

Neurological effects
No data available

Further information
Product:
Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
titanium dioxide:
Toxicity to fish

: LC50 (Cyprinodon variegatus (sheepshead minnow)): >
10,000 mg/l
Exposure time: 96 h
Test Type: semi-static test
Test substance: Marine water
Method: OECD Test Guideline 203

aluminium oxide:
Toxicity to fish

: LC50 (Fish): > 50 mg/l
Exposure time: 96 h
Test Type: static test
Test substance: Fresh water

Components:
aluminium oxide:
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 100 mg/l
Exposure time: 48 h

Components:

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 14 / 19
aluminium oxide:
Toxicity to algae : IC50 (Selenastrum capricornutum (green algae)): > 100 mg/l
Exposure time: 72 h

M-Factor (Acute aquatic
toxicity)
: No data available

Toxicity to fish (Chronic
toxicity)
: No data available

Toxicity to daphnia and other
aquatic invertebrates
(Chronic toxicity)
: No data available

M-Factor (Chronic aquatic
toxicity)
: No data available

Toxicity to microorganisms : No data available

Toxicity to soil dwelling
organisms
: No data available

Components:
titanium dioxide:
Plant toxicity : NOEC: 100,000 mg/kg
Exposure time: 480 h

Components:
titanium dioxide:
Sediment toxicity : (Gammarus pulex (Amphipod)): > 100000 mg/kgsedimentdw
Study: Acute
Test Type: semi-static test
Water: Fresh water
Exposure duration: 28 d
Method: ASTM Method, other

(Gammarus pulex (Amphipod)): 100000 mg/kgsedimentdw
Study: Chronic
Test Type: semi-static test
Water: Fresh water
Exposure duration: 28 d
Method: ASTM Method, other

(Gammarus pulex (Amphipod)): 14989 mg/kgsedimentdw
Study: Acute
Test Type: semi-static test
Water: Marine water
Exposure duration: 10 d

Components:
titanium dioxide:
Toxicity to terrestrial
organisms
: NOEC: 10,000 mg/kg
Exposure time: 672 h

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 15 / 19
Ecotoxicology Assessment
Components:
aluminium oxide:
Acute aquatic toxicity : This product has no known ecotoxicological effects.

Components:
aluminium oxide:
Chronic aquatic toxicity : This product has no known ecotoxicological effects.

Toxicity Data on Soil : No data available

Other organisms relevant to
the environment
: No data available

Persistence and degradability
Biodegradability – Product : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

Biochemical Oxygen
Demand (BOD)

: No data available

Chemical Oxygen Demand
(COD)
: No data available

BOD/COD : No data available

ThOD : No data available

BOD/ThOD : No data available

Dissolved organic carbon
(DOC)
: No data available

Physico-chemical
removability
: No data available

Stability in water : No data available

Photodegradation : No data available

Impact on Sewage
Treatment
: No data available

Bioaccumulative potential
Components:
titanium dioxide:
Bioaccumulation : Species: Oncorhynchus mykiss (rainbow trout)
Bioconcentration factor (BCF): 19 – 352
Exposure time: 14 d
Test substance: Fresh water
Method: semi-static test
Remarks: Does not bioaccumulate.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 16 / 19

Partition coefficient: n-
octanol/water

: No data available

Mobility in soil
Mobility : No data available

Components:
titanium dioxide:
Distribution among
environmental compartments
: Remarks: No data available

Stability in soil : No data available

Other adverse effects
Environmental fate and
pathways
: No data available

Results of PBT and vPvB
assessment
: No data available

Endocrine disrupting
potential
: No data available

Adsorbed organic bound
halogens (AOX)
: No data available

Hazardous to the ozone layer
Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82
Protection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was
manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A +
B).

Additional ecological
information – Product
: No data available

Global warming potential
(GWP)
: No data available

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
This material and its container must be disposed of in a safe
way.
In accordance with local and national regulations.
Dispose of wastes in an approved waste disposal facility.

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 17 / 19
If recycling is not practicable, dispose of in compliance with
local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulations
IATA
Not regulated as dangerous goods
IMDG
Not regulated as dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
DOT Classification
Not regulated as dangerous goods

SECTION 15. REGULATORY INFORMATION
EPCRA – Emergency Planning and Community Right -to-Know Act

SARA 311/312 Hazards

: No SARA Hazards

SARA 313

: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 112 (40 CFR 61).

California Prop. 65
Titanium dioxide (airborne, unbound particles of respirable size) is known to the state of California
to cause cancer. This listing does not cover titanium dioxide when it remains bound within a
product matrix.
WARNING: This product can expose you to chemicals including titanium dioxide, which is/are
known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
The components of this product are reported in the following inventories:
CH INV : On the inventory, or in compliance with the inventory

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 18 / 19
DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory
NZIoC : On the inventory, or in compliance with the inventory
ENCS : On the inventory, or in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
TCSI : On the inventory, or in compliance with the inventory
TSCA : On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)

TSCA – 5(a) Significant New Use Rule List of Chemicals
No substances are subject to a Significant New Use Rule.

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707,
Subpt D)
No substances are subject to TSCA 12(b) export notification requirements.

SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS IV:

HMIS ratings are based on a 0-4 rating
scale, with 0 representing minimal
hazards or risks, and 4 representing
significant hazards or risks. The “*”
represents a chronic hazard, while the “/”
represents the absence of a chronic
hazard.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as
a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
Sources of key data used to
compile the Safety Data
Sheet
: Information taken from reference works and the literature.,
Information derived from practical experience.

Flammability

Health

Instability

1 0

Special hazard.
FLAMMABILITY
0
PHYSICAL HAZARD
HEALTH
0

1
0

SAFETY DATA SHEET

TIOXIDE TR93
Version
2.2
Revision Date:
03/14/2018
SDS Number:
400001007136
Date of last issue: 05/23/2017
Date of first issue: 09/01/2016

SDS_US-PI EN 400001007136 19 / 19
Revision Date

: 03/14/2018
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) – Table Z-1
Limits for Air Contaminants
ACGIH / TWA : 8-hour, time-weighted average
OSHA Z-1 / TWA : 8-hour time weighted average
The information and recommendations in this publication are to the best of our knowledge,
information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE
CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE
APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE
SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE
CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE
THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are
dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and
behaviour should be determined by the user and made known to handlers, processors and end
users.

The trademarks above are the property of Venator Materials PLC or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED VENATOR EMPLOYEE IS
AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR VENATOR
PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN
INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.