Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 01: Chemical Product and Company Identification
Walker Emulsions Inc.
4401 SE Johnson Creek Blvd
Portland, OR, USA 97222
503-659-1708
Manufacturer
As aboveSupplier
Walker Emulsions Inc. – Department of Research and Development
Contact: Steven M. Brown 503-659-1708
Prepared By
May 01, 2012Preparation Date
May 23, 2018Revision Date
Marathon Tool Wash 132Product Name
105030 (prior to 11/1/15: PT2501.32)Product Number
MixtureCAS Number
Not Applicable/MixtureChemical Formula
Alkaline CleanerMaterial Use
Infotrac (800) 535-505324 Hour Emergency Number
Section 02: Hazards Identification
WarningSignal Word:
H319 Causes serious eye irritation.
Serious eye damage/eye irritation, Category 2/2A
H312 Harmful in contact with skin.
Acute toxicity, Category 4
H335 + H336 May cause respiratory irritation, drowsiness or dizziness.
Specific target organ toxicity-single exposure, Category 3
H302 Harmful if swallowed.
Acute toxicity, Category 4
Hazards:
P102 Keep out of reach of children.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
Prevention:
P301 + P315 + P330 + P331 IF SWALLOWED: Get immediate medical
advice/attention. Rinse mouth. DO NOT INDUCE vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and
keep at rest in a position comfortable for breathing.
P315 + P342: If experiencing respiratory symptoms, get medical advice/attention.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.
Response:
P501: Dispose of contents/container in accordance with local regulations.Disposal:
Page 1 of 6
Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 02: Hazards Identification
Effects of Acute Exposure
Causes serious irritation to eyes.Eye Contact
Ingestion of this material may be harmful.Ingestion
Inhalation of vapors or mists may cause pulmonary irritation, dizziness, and
nausea.
Inhalation
May be absorbed through skin.Skin Absorption
Causes serious irritation to skin.Skin Contact
Effects of Chronic Exposure
Prolonged or repeated breathing of sprays, mists, or dusts in excess of the
suggested TLV may cause severe nasal and respiratory irritations.
Inhalation
Prolonged or repeated contact with skin may cause irritation, redness, itching
and/or be potentially absorbed in harmful amounts. Persons with pre-existing
dermatitis may be more susceptible to the effects of this product.
Skin
Section 03: Composition and Information on Ingredients
Hazardous Ingredients
Exposure LevelsC.A.S. # TSCAHazard Rating LD/LC, Route, SpeciesIngred / %
SODIUM METASILICATE
1 – 5 6834-92-0
See Section 11
Not Available
LD/50:
LC/50:
1-METHOXY PROPANOL
1 – 5 107-98-2
See Section 11
See Section 11
LD/50:
LC/50:
DIPROPYLENE GLYCOL METHYL ETHER
1-5 34590-94-8
See Section 11
Not Available
LD/50:
LC/50:
HEALTH: 2, FIRE: 1, REACTIVITY: 0, PPI: XHMIS Rating (0-4)
HEALTH
2
PROTECTIVE
EQUIPMENT
X
REACTIVITY
0
FLAMMABILITY
1
Section 04: First Aid Measures
Remove contaminated clothing and wash affected skin area with soap and water.
If irritation persists, contact a physician.
Skin Contact
Remove person to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Call a physician promptly.
Inhalation
DO NOT induce vomiting. Call a physician promptly. Give large quantities of water
or milk. Never give anything orally to an unconscious or convulsing person.
Ingestion
Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician
promptly.
Eye Contact
Section 05: Fire and Explosion Data
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Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 05: Fire and Explosion Data
>200 F, (93 C), SetaflashFlash Point, Method
IIIAFlammability
Use self-contained breathing apparatus with full facepiece.Special Procedures
Not AvailableFire Hazards
Never use welding or cutting torch on or near drum, even empty, because product
or residue can ignite potentially explosively.
Explosion Hazards
Not AvailableHazardous Combustion Products
Not AvailableExplosive Range:
Water spray, dry chemical, chemical foam, or carbon dioxide.Extinguishing Media
Section 06: Accidental Release Measures
SMALL SPILLS: Use an inert material such as kitty litter, sawdust or cellulosic
based absorbent to absorb spilled product. Flush spill area with plenty of water.
Rinsate may require special processing and approval prior to discharging to a
sanitary sewer system.
LARGE SPILLS: Use caution; spilled material may be extremely slippery. Contain
spilled material immediately and prevent from entering the sewer system. Use inert
materials mentioned above to dam, dike, divert or absorb spill. Absorb or vacuum
spilled material for proper disposal options.
Leak/Spill
Section 07: Handling and Storage
Containers of this material may be hazardous when emptied. Since emptied
containers retain product residues (vapor, liquid, and/or solid), all hazard
precautions given in this data sheet should be observed. Rinse container with 1-2
gallons of water and recycle into end-use process.
Handling
Section 08: Exposure Control and Personal Protection
Protective Equipment
Wear approved splashproof chemical goggles.Eye/Type
None normally required.Respiratory/Type
Neoprene rubber gloves are recommended.Gloves/Type
Use adequate ventilation to keep airborne concentrations below the exposure
standard.
Ventilation Requirements
Use as needed to keep this material off clothing and skin.Other Protective Equipment
SODIUM METASILICATE 1-METHOXY PROPANOL DIPROPYLENE
GLYCOL
METHYL ETHER
Occupational Exposure Limits
N/est 100.00 PPM 100.00 PPMACGIH TLV
N/est N/est N/estACGIH TLV-C
N/est 150.00 PPM 150.00 PPMACGIH STEL
N/est 150.00 PPM 150.00 PPMOSHA STEL
N/est 100.00 PPM 100.00 PPMOSHA PEL
Section 09: Physical and Chemical Properties
LiquidPhysical State
Page 3 of 6
Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 09: Physical and Chemical Properties
BlueAppearance
Not AvailableViscosity (cPs, water=1)
Not AvailableVolatility (wt%)
Not applicableVolatility (vol%)
1.04839Specific Gravity
11.95-12.05pH
MiscibleSolubility in Water
Slight glycol etherOdor
Not AvailableOdor threshold (ppm)
(WATER) 17 @ 68 F (20 C)Vapor Pressure (mm Hg)
Non volatileVapor Density (air=1)
UnavailableEvaporation Rate (n-butyl
acetate=1)
Not AvailableCoefficient of water/oil distribution
(WATER) 212 F (100 C)Boiling Range
Not AvailablePartition Coefficient
Not AvailableFreezing Point
Not AvailableMelting Point
Not availableVOC
Not AvailableFlash Point (TCC)
MixtureMolecular Weight
Not AvailableExplosive limits
Not AvailableFlammability (solid, gas)
Not AvailableAuto-ignition temperature
Not Available Decomposition temperature
Section 10: Stability and Reactivity Data
Hazardous polymerization will not occur.Hazardous Polymerization
This product is stable.Chemical Stability
Acids, strong oxidizing agents.Incompatibility
Acids, strong oxidizing agents.Conditions to Avoid
Not AvailableReactivity Conditions
Carbon monoxide and/or carbon dioxide.Hazardous Products of
Decomposition (thermal)
Section 11: Toxicological Information
Eye contact, potential skin absorption, inhalation, and ingestion.Routes of Entry
Exposure Limits
Page 4 of 6
Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 11: Toxicological Information
SODIUM METASILICATE:
Oral, Rat, adult 1,153 mg/kg
Skin, Rat, adult 250 PPM
1-METHOXY PROPANOL:
Oral, Rat, adult 5,660 PPM
Skin, Rat, adult 13,000 PPM
DIPROPYLENE GLYCOL METHYL ETHER:
Oral, Rat, adult 5.4 ml/kg
Skin, Rabbit, adult 20
LD/50
1-METHOXY PROPANOL:
Inhalation, Rat, adult 7,000 PPM
LC/50
Not AvailableTWA
This product does not contain any substance(s) listed as a carcinogen by NTP,
IARC, or OSHA.
Carcinogenicity
None KnownTeratogenicity/Mutagenicity
None KnownReproductive Effects
None KnownSynergistic Materials
None available for product.Additional Toxicological Data
Section 12: Ecological Information
Not AvailableEnvironmental
Aquatic toxicity not available.Ectotoxicological Information
Not AvailableBiodegradability
Section 13: Disposal Considerations
NONEEPA Hazardous Waste Number
Waste product must be disposed of properly under Federal and State regulations
for industrial waste. Absorbed material on cellulosic or similar synthetic absorbents
may be incinerated pending approvals. This product, as delivered, when spilled or
disposed of is not regulated under 40 CFR Part 261 of the RCRA Hazardous
Waste Regulations.
Waste Disposal
Section 14: Transport Information
NONEU.N. #
NAT.D.G. Classification
Not HazardousD.O.T. Classification
D2BWHMIS Classification
Section 15: Regulatory Information
IrritantEEC Classification
This product is not regulated as a hazardous substance.U.S. Federal Regulations
Page 5 of 6
Safety
Data SheetA Walker Industries Company
PRODUCT: Marathon Tool Wash 132
Section 15: Regulatory Information
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the reporting
requirements of Section 313 of the Emergency Planning and Community Right to
Know Act of 1986 and of 40 CFR 372:
Chemical Name: DIPROPYLENE GLYCOL METHYL ETHER, CAS#: 34590-94-8,
<5%
U.S. Federal Regulations
All ingredients are listed in the TSCA inventory.US TSCA
Section 16: Other Information
Do not dilute or mix with other materials unless advised by supplier.
The information and recommendations contained herein are based upon data believed to be correct. However, no
guarantee or warranty of any kind, expressed or implied, is made with respect to the information provided.
Page 6 of 6