SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

1 / 20
SECTION 1. IDENTIFICATION
Trade name

: BENOX

L-40LV

Manufacturer or supplier’s details
Company name of supplier

: United Initiators, Inc.

Address

: 555 Garden Street
Elyria OH 44035 USA

Telephone

: +1-440-323-3112

Telefax

: +1-440-323-2659

Emergency telephone

: CHEMTREC US (24h): +1-800-424-9300
CHEMTREC WORLD (24h): +1-703-527-3887

E-mail address of person
responsible for the SDS

: cs-initiators.nafta@united-in.com

Recommended use of the chemical and restrictions on use
Recommended use

: Curing chemical

SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Organic peroxides

: Type E
Eye irritation

: Category 2B
Skin sensitization

: Category 1
Short-term (acute) aquatic
hazard

: Category 1
Long-term (chronic) aquatic
hazard

: Category 1
GHS label elements
Hazard pictograms

:

Signal Word

: Warning

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

2 / 20
Hazard Statements

: H242 Heating may cause a fire.
H317 May cause an allergic skin reaction.
H320 Causes eye irritation.
H410 Very toxic to aquatic life with long lasting effects.

Precautionary Statements

:
Prevention:
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P220 Keep/Store away from clothing/ strong acids, bases,
heavy metal salts and other reducing substances /combustible
materials.
P234 Keep only in original container.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
Storage:
P410 Protect from sunlight.
P411 + P235 Store at temperatures not exceeding 30 C/
86 F. Keep cool.
P420 Store away from other materials.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture

: Mixture
Chemical nature

: Organic Peroxide
Liquid mixture

Components

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

3 / 20
Chemical name CAS-No. Concentration (% w/w)
Dibenzoyl peroxide 94-36-0

>= 35 – < 40 Zinc stearate 557-05-1 >= 1 – < 5 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Do not leave the victim unattended. Call a physician immediately. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. If breathed in, move person into fresh air. In case of skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before re-use. If on skin, rinse well with water. If on clothes, remove clothes. If symptoms persist, call a physician. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Call a physician immediately. Most important symptoms and effects, both acute and delayed : May cause an allergic skin reaction. Causes eye irritation. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing Notes to physician : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray jet Alcohol-resistant foam SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 4 / 20 Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self- accelerating decomposition reaction with release of flammable vapors which may auto-ignite. The product burns violently. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. The product will float on water and can be reignited on surface water. Cool closed containers exposed to fire with water spray. Specific extinguishing meth- ods : Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Remove all sources of ignition. Follow safe handling advice and personal protective equipment recommendations. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Never return spills in original containers for re-use. Treat recovered material as described in the section "Disposal considerations". Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 5 / 20 Methods and materials for containment and cleaning up : Contact with incompatible substances can cause decomposition at or below SADT. Clear spills immediately. Suppress (knock down) gases/vapors/mists with a water spray jet. To clean the floor and all objects contaminated by this material, use plenty of water. Soak up with inert absorbent material. Isolate waste and do not reuse. Non-sparking tools should be used. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from combustible material. Advice on safe handling : Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Avoid formation of aerosol. Take precautionary measures against static discharges. Never return any product to the container from which it was originally removed. Provide sufficient air exchange and/or exhaust in work rooms. Avoid confinement. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Smoking, eating and drinking should be prohibited in the application area. Wash thoroughly after handling. For personal protection see section 8. Persons susceptible to skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Protect from contamination. Conditions for safe storage : Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in original container. SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 6 / 20 Keep containers tightly closed in a cool, well-ventilated place. Store in accordance with the particular national regulations. Materials to avoid : Keep away from strong acids, bases, heavy metal salts and other reducing substances. Recommended storage tem- perature : 0 - 30 C 32 - 86 F Further information on stor- age stability : No decomposition if stored normally. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Dibenzoyl peroxide 94-36-0 TWA 5 mg/m3 ACGIH TWA 5 mg/m3 NIOSH REL TWA 5 mg/m3 OSHA Z-1 TWA 5 mg/m3 OSHA P0 Zinc stearate 557-05-1 TWA (Res- pirable) 5 mg/m3 NIOSH REL TWA (total) 10 mg/m3 NIOSH REL TWA (total dust) 15 mg/m3 OSHA Z-1 TWA (respir- able fraction) 5 mg/m3 OSHA Z-1 TWA (Total dust) 10 mg/m3 OSHA P0 TWA (respir- able dust fraction) 5 mg/m3 OSHA P0 TWA (Inhal- able particu- late matter) 10 mg/m3 ACGIH TWA (Res- pirable par- ticulate mat- ter) 3 mg/m3 ACGIH Engineering measures : Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 7 / 20 Filter type : ABEK-filter Hand protection Material : butyl-rubber Break through time : 480 min Glove thickness : 0.5 mm Material : Nitrile rubber Break through time : 480 min Glove thickness : 0.5 mm Remarks : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Tightly fitting safety goggles Please wear suitable protective goggles. Also wear face protection if there is a splash hazard. Ensure that eyewash stations and safety showers are close to the workstation location. Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Hygiene measures : Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Emulsion Color : white Odor : characteristic pH : Not applicable Melting point/range : No data available SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 8 / 20 Boiling point/boiling range : Decomposition: Decomposes below the boiling point. Flash point : Not applicable Evaporation rate : Not applicable Flammability (solid, gas) : does not ignite Upper explosion limit / Upper flammability limit : Not applicable Lower explosion limit / Lower flammability limit : Not applicable Vapor pressure : Not applicable Density : 1.2 g/cm3 (25 C) Solubility(ies) Water solubility : insoluble Partition coefficient: n- octanol/water : Not applicable Self-Accelerating decomposi- tion temperature (SADT) : 50 C Method: UN-Test H.4 SADT-Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-accelerating decomposition reaction. Viscosity Viscosity, dynamic : 1 mPa.s Viscosity, kinematic : Not applicable Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. Organic peroxide SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable under recommended storage conditions. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reac- tions : Vapors may form explosive mixture with air. SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 9 / 20 Conditions to avoid : Protect from contamination. Contact with incompatible substances can cause decomposition at or below SADT. Heat, flames and sparks. Avoid confinement. Incompatible materials : Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents Hazardous decomposition products : Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Components: Dibenzoyl peroxide: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401
Assessment: The substance or mixture has no acute oral tox-
icity

Acute inhalation toxicity

: LC50 (Rat): > 24.3 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
Assessment: The substance or mixture has no acute inhala-
tion toxicity

Acute dermal toxicity

: Remarks: No data available

Zinc stearate:
Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg
Method: OECD Test Guideline 401
Assessment: The substance or mixture has no acute oral tox-
icity

Acute inhalation toxicity

: LC50 (Rat): > 200 mg/l
Exposure time: 1 h
Test atmosphere: dust/mist

Acute dermal toxicity

: LD50 (Rabbit): > 2,000 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity

Skin corrosion/irritation
Not classified based on available information.

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

10 / 20
Product:
Remarks : May cause skin irritation in susceptible persons.

Components:
Dibenzoyl peroxide:
Species : Rabbit
Result : No skin irritation

Zinc stearate:
Species : Rabbit
Method : Draize Test
Result : No skin irritation

Serious eye damage/eye irritation
Causes eye irritation.
Product:
Remarks : Vapors may cause irritation to the eyes, respiratory system
and the skin.

Species : Rabbit
Result : Eye irritation
Remarks : Information refers to the main ingredient.

Components:
Dibenzoyl peroxide:
Species : Rabbit
Result : Irritation to eyes, reversing within 7 days

Zinc stearate:
Species : Rabbit
Result : No eye irritation
Method : Draize Test

Respiratory or skin sensitization
Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Product:
Remarks : Causes sensitization.

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

11 / 20
Components:
Dibenzoyl peroxide:
Routes of exposure : Skin contact
Species : Mouse
Method : Local lymph node assay (LLNA)
Result : May cause sensitization by skin contact.

Zinc stearate:
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.
Remarks : Information given is based on data obtained from similar sub-
stances.

Germ cell mutagenicity
Not classified based on available information.
Components:
Dibenzoyl peroxide:
Genotoxicity in vitro

: Method: OECD Test Guideline 471
Result: negative

Method: OECD Test Guideline 476
Result: negative

Genotoxicity in vivo

: Test Type: dominant lethal test
Species: Mouse
Result: negative

Zinc stearate:
Genotoxicity in vitro

: Method: OECD Test Guideline 471
Result: negative
Remarks: Information given is based on data obtained from
similar substances.

Genotoxicity in vivo

: Test Type: Chromosomal aberration
Species: Rat
Result: Equivocal

Carcinogenicity
Not classified based on available information.
Components:
Dibenzoyl peroxide:
Remarks : This information is not available.

IARC No ingredient of this product present at levels greater than or equal to 0.1% is

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

12 / 20
identified as probable, possible or confirmed human carcinogen by IARC.

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA s list of regulated carcinogens.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity
Not classified based on available information.
Components:
Dibenzoyl peroxide:
Effects on fertility

: Species: Rat, male
Application Route: Oral
General Toxicity Parent: NOAEL: 1,000 mg/kg body weight
Method: OECD Test Guideline 422

Species: Rat, female
Application Route: Oral
General Toxicity Parent: NOAEL: 500 mg/kg body weight
Method: OECD Test Guideline 422

Reproductive toxicity – As-
sessment

: No evidence of adverse effects on sexual function and fertility,
or on development, based on animal experiments.

Zinc stearate:
Effects on fertility

: Species: Rat
Application Route: oral (gavage)
General Toxicity F1: NOAEL: 7.5 mg/kg body weight
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials

Effects on fetal development

: Species: Mouse
Application Route: oral (gavage)
General Toxicity Maternal: NOAEL: 30 mg/kg body weight
Teratogenicity: NOAEL: 30 mg/kg body weight
Remarks: Based on data from similar materials

STOT-single exposure
Not classified based on available information.
Components:
Dibenzoyl peroxide:
Routes of exposure : Ingestion
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

13 / 20
STOT-repeated exposure
Not classified based on available information.
Components:
Dibenzoyl peroxide:
Routes of exposure : Ingestion
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity
Components:
Dibenzoyl peroxide:
Species : Rat
NOAEL : 1,000 mg/kg
Application Route : Oral
Exposure time : 28 d
Method : OECD Test Guideline 422

Zinc stearate:
Species : Mouse
NOAEL : 458 mg/kg
Application Route : Oral
Method : OECD Test Guideline 408

Aspiration toxicity
Not classified based on available information.
Components:
Dibenzoyl peroxide:
No aspiration toxicity classification

Further information
Product:
Remarks : No data available

Components:
Zinc stearate:
Remarks : No data available

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

14 / 20
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Ecotoxicology Assessment
Acute aquatic toxicity

: Very toxic to aquatic life.

Chronic aquatic toxicity

: Very toxic to aquatic life with long lasting effects.

Components:
Dibenzoyl peroxide:
Toxicity to fish

: EC50 (Oncorhynchus mykiss (rainbow trout)): 0.06 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 0.11 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EC50 (Pseudokirchneriella subcapitata (green algae)): 0.071
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Pseudokirchneriella subcapitata (green algae)): 0.02
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

M-Factor (Acute aquatic tox-
icity)

: 10
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)

: EC10 (Daphnia magna (Water flea)): 0.001 mg/l
Exposure time: 21 d
Test Type: semi-static test
Method: OECD Test Guideline 211

M-Factor (Chronic aquatic
toxicity)

: 10
Toxicity to microorganisms

: EC50 (Bacteria): 35 mg/l
Exposure time: 30 min
Method: OECD Test Guideline 209

Ecotoxicology Assessment
Acute aquatic toxicity

: Very toxic to aquatic life.

Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

15 / 20

Zinc stearate:
Toxicity to fish

: LC50 (Danio rerio (zebra fish)): > 10,000 mg/l
Exposure time: 96 h
Method: Directive 67/548/EEC, Annex V, C.1.

Toxicity to daphnia and other
aquatic invertebrates

: LC50 (Daphnia magna (Water flea)): > 100 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EL50 (Pseudokirchneriella subcapitata (green algae)): > 100
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to microorganisms

: NOEC (Pseudomonas putida): 1,000 mg/l
Exposure time: 0.5 h
Method: DIN 38 412 Part 8

Persistence and degradability
Components:
Dibenzoyl peroxide:
Biodegradability

: Result: Biodegradable
Method: OECD Test Guideline 301D

Zinc stearate:
Biodegradability

: Result: Readily biodegradable.
Method: OECD Test Guideline 301D

Bioaccumulative potential
Components:
Dibenzoyl peroxide:
Partition coefficient: n-
octanol/water

: log Pow: 3.2 (20 C / 20 C)

Zinc stearate:
Partition coefficient: n-
octanol/water

: Remarks: No data available

Mobility in soil
No data available
Other adverse effects
Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

16 / 20
tection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor-
mation

: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Very toxic to aquatic life with long lasting effects.

Components:
Zinc stearate:
Additional ecological infor-
mation

: No data available

SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of wastes in an approved waste disposal facility.

Contaminated packaging

: Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
Dispose of in accordance with local regulations.

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
UN number : UN 3107
Proper shipping name : ORGANIC PEROXIDE TYPE E, LIQUID
(DIBENZOYL PEROXIDE )
Class : 5.2
Packing group : Not assigned by regulation
Labels : 5.2
IATA-DGR
UN/ID No. : UN 3107
Proper shipping name : Organic peroxide type E, liquid
(Dibenzoyl peroxide)
Class : 5.2
Packing group : Not assigned by regulation
Labels : Organic Peroxides, Keep Away From Heat

SAFETY DATA SHEET

BENOX

L-40LV

Version
4.0
Revision Date:
08/09/2021
SDS Number:
600000000152
Date of last issue: 12/04/2019
Date of first issue: 06/27/2017

17 / 20
Packing instruction (cargo
aircraft)
: 570
Packing instruction (passen-
ger aircraft)
: 570
IMDG-Code
UN number : UN 3107
Proper shipping name : ORGANIC PEROXIDE TYPE E, LIQUID
(DIBENZOYL PEROXIDE )
Class : 5.2
Packing group : Not assigned by regulation
Labels : 5.2
EmS Code : F-J, S-R
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 3107
Proper shipping name : Organic peroxide type E, liquid
(Dibenzoyl peroxide, <=42%) Class : 5.2 Packing group : Not assigned by regulation Labels : ORGANIC PEROXIDE ERG Code : 145 Marine pollutant : yes Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Organic peroxides Respiratory or skin sensitization Serious eye damage or eye irritation SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 18 / 20 Dibenzoyl perox- ide 94-36-0 Zinc stearate 557-05-1 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 Zinc stearate 557-05-1 This product does not contain any priority pollutants related to the U.S. Clean Water Act California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. International Regulations Gefahrgruppe nach DGUV 13 Vorschrift 13 (bisher BGV B4): II (German regulatory requirements) The ingredients of this product are reported in the following inventories: TCSI (TW) : On the inventory, or in compliance with the inventory TSCA (US) : All substances listed as active on the TSCA inventory AICS (AU) : On the inventory, or in compliance with the inventory DSL (CA) : All components of this product are on the Canadian DSL KECI (KR) : On the inventory, or in compliance with the inventory IECSC (CN) : On the inventory, or in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 19 / 20 SECTION 16. OTHER INFORMATION Further information This material safety datasheet only contains information relating to safety and does not replace any product information or product specification. These safety instructions also apply to empty packaging which may still contain product residues. Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 08/09/2021 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8 Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA P0 / TWA : 8-hour time weighted average OSHA Z-1 / TWA : 8-hour time weighted average AICS - Australian Inventory of Chemical Substances; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Substances List (Canada); ECx - Concen- tration associated with x% response; EHS - Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Prac- tice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Con- struction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal in- hibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Ex- isting Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - In- ternational Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - Interna- SAFETY DATA SHEET BENOX L-40LV Version 4.0 Revision Date: 08/09/2021 SDS Number: 600000000152 Date of last issue: 12/04/2019 Date of first issue: 06/27/2017 20 / 20 tional Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Me- dian Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - Na- tional Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Invento- ry of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relation- ship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8