WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 3/13
Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 5/13
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 8/13
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.