RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 08/15/2019
08/15/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : RED SUPER TOOLING
CAS-No. : mixture
Product code : 610-002
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : TOOLING GEL COAT
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 3 H226 Flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2A H319 Causes serious eye irritation.
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Warning
Hazard statements (GHS US) : H226 – Flammable liquid and vapour.
H315 – Causes skin irritation.
H319 – Causes serious eye irritation.
Precautionary statements (GHS US) : P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. heat;hot surfaces;open flames
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P264 – Wash exposed area. thoroughly after handling.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 2/12
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362 – Take off contaminated clothing.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P235 – Store in a well-ventilated place. Keep cool.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin
(CAS-No.) TRADE SECRET <= 47 Not classified styrene, inhibited (CAS-No.) 100-42-5 <= 43.5 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 Repr. 2, H361 STOT SE 3, H335 STOT RE 1, H372 Aquatic Acute 2, H401 LEAD AND CHROME FREE PIGMENT (CAS-No.) Proprietary <= 5 Not classified methyl ethyl ketone (CAS-No.) 78-93-3 <= 4 Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7 <= 0.5 Eye Irrit. 2, H319 Skin Sens. 1, H317 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Chronic 2, H411 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to breathe fresh air. Allow the victim to rest. Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see seek medical attention. on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Potential adverse human health effects and symptoms : Harmful if inhaled. Based on available data, the classification criteria are not met. Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/effects after skin contact : Causes skin irritation. RED SUPER TOOLING Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/15/2019 EN (English) 3/12 Symptoms/effects after eye contact : Causes serious eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapour. Flammable liquid and vapour. Explosion hazard : May form flammable/explosive vapour-air mixture. Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released product, pump into suitable containers. Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapours are flammable. Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. No open flames. No smoking. Use only non- sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Take precautionary measures against static discharge. Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. RED SUPER TOOLING Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/15/2019 EN (English) 4/12 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well- ventilated place. Keep cool. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. SECTION 8: Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 40 ppm cobalt(II) 2-ethylhexanoate (136-52-7) Not applicable methyl ethyl ketone (78-93-3) ACGIH ACGIH TWA (ppm) 200 ppm ACGIH ACGIH STEL (ppm) 300 ppm LEAD AND CHROME FREE PIGMENT (Proprietary) Not applicable Unsaturated Polyester Resin (TRADE SECRET) Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses. Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear appropriate mask Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : red Odour : characteristic RED SUPER TOOLING Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 08/15/2019 EN (English) 5/12 Odour threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : >= 79.4 C
Flash point : >= -6.67 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour. Flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : No data available
Relative density : 1.1
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapour. May form
flammable/explosive vapour-air mixture. Flammable liquid and vapour.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 6/12
styrene, inhibited (100-42-5)
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Not classified
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.).
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 7/12
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
12.2. Persistence and degradability
RED SUPER TOOLING (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
LEAD AND CHROME FREE PIGMENT (Proprietary)
Persistence and degradability Not established.
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3. Bioaccumulative potential
RED SUPER TOOLING (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 8/12
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
LEAD AND CHROME FREE PIGMENT (Proprietary)
Bioaccumulative potential Not established.
Unsaturated Polyester Resin (TRADE SECRET)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1263 Paint, 3, II
UN-No.(DOT) : UN1263
Proper Shipping Name (DOT) : Paint
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 9/12
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
367 - For the purposes of documentation and package marking: a. The proper shipping name
Paint related material may be used for consignments of packages containing Paint and
Paint related material in the same package; b. The proper shipping name Paint related
material, corrosive, flammable may be used for consignments of packages containing Paint,
corrosive, flammable and Paint related material, corrosive, flammable in the same package;
c. The proper shipping name Paint related material, flammable, corrosive may be used for
consignments of packages containing Paint, flammable, corrosive and Paint related material,
flammable, corrosive in the same package; and d. The proper shipping name Printing ink
related material may be used for consignments of packages containing Printing ink and
Printing ink related material in the same package.
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
B131 - When transported by highway, rail, or cargo vessel, waste Paint and Paint related
material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than
26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the
labeling requirements in 172.400(a), when further packed in the following specification and
non-specification bulk outer packagings and under the following conditions:
a. Primary receptacles must conform to the general packaging requirements of subpart B of
part 173 of this subchapter and may not leak. If they do leak, they must be overpacked in
packagings conforming to the specification requirements of part 178 of this subchapter or in
salvage packagings conforming to the requirements in 173.12 of this subchapter.
b. Primary receptacles must be further packed in non-specification bulk outer packagings such
as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers.
Bulk outer packagings must be liquid tight through design or by the use of lining materials.
c. Primary receptacles may also be further packed in specification bulk outer packagings.
Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk
containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk
containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic
liner of at least 6 mil thickness.
d. All inner packagings placed inside bulk outer packagings must be blocked and braced to
prevent movement during transportation that could cause the container to open or fall over.
Specification IBCs and FIBCs are to be secured to a pallet.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
TP28 - A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used
provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous
material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the
MAWP.
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 128
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 10/12
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1263 PAINT, 3, II
UN-No. (IMDG) : 1263
Proper Shipping Name (IMDG) : PAINT
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Limited quantities (IMDG) : 5 L
Air transport
Transport document description (IATA) : UN 1263 Paint, 3, II
UN-No. (IATA) : 1263
Proper Shipping Name (IATA) : Paint
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
LEAD AND CHROME FREE PIGMENT (Proprietary)
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
LEAD AND CHROME FREE PIGMENT (Proprietary)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
Unsaturated Polyester Resin (TRADE SECRET)
Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 11/12
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 08/15/2019
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects.
RED SUPER TOOLING
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
08/15/2019 EN (English) 12/12
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.