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SAFETY DATA SHEET
Document ID : SDSCLP-03 Issue Date : 03 April 20 15
Revision : 4 Supersedes date : 26 March 2015
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMP ANY
1.1
Identification of product
Product Name
Trade Name
Chemical name
Manufacturer product ID
: Phenolic microspheres
: PHENOSET microspheres
: Phenol formaldehyde polymer, cured
: BJO-0930, BJO-0840, EPO-0360, SPO-0620
1.2
Use of product
Functional filler for composites
1.3
Company Identification
MALAYAN ADHESIVES & CHEMICALS SDN. BHD.
No. 9, Jalan Utas 15/7, 40200 Shah Alam,
Selangor Darul Ehsan, MALAYSIA
Importer/Distributor:
Tel: +603-5566 1188
Fax:+603-5566 1122
1.4 Emergency telephone
+603-5566 1188
2. HAZARDS IDENTIFICATION
Not classified as hazardous for use/supply
Dust may cause irritation, experienced as stinging with excessive blinking and tear production.
Material may contain trace amount (<0.2%) of free formaldehyde, which is listed by IARC, NTP and OSHA
as a carcinogen. There should be minimal risk when adequate ventilation is used due to the very low
formaldehyde concentration.
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3. COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient CAS no. EC no. Weight
%
Risk phrases Hazard Statements
Fully polymerized
phenolic resin, inert
NA NA >99.8 None None
Formaldehyde* 50-00-0 200-001-8 <0.2 R45, R68,
R23/24/25, R34,
R43
H350, H341, H331,
H311, H301, H314,
H317
Note*: Material is not considered hazardous in the classification of product as its concentration is below concentration cut-off point
Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under
REACH article 7(1).
4. FIRST AID MEASURES
Skin contact:
Remove contaminated clothing. Wash skin with soap and water. Obtain medical attention if irritation
persists. Wash clothing before reuse.
Eye contact:
Immediately flush eyes with water and continue for several minutes. Obtain medical attention if discomfort
persists.
Inhalation:
If signs and symptoms develop, remove person to fresh air. If signs or symptoms persist, obtain medical
attention.
Ingestion:
Do not induce vomiting unless instructed to do so by medical personnel. Unless unconscious, give victim
lots of water. Obtain medical attention.
Notes to physician:
There is no specific antidote. Treatment or overexposure should be directed at the control of the symptoms
and the clinical condition of the patient
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing media:
Apply alcohol type or all-purpose type foams by manufacturers recommended techniques for large fires.
Use carbon monoxide or dry chemical media for small fires.
Do not direct a solid stream of water or foam into burning molten material; this may cause spattering and
spread of fire.
Extinguishing media to be avoided:
None
Unusual fire and explosion hazards:
Avoid dispersion of dust in air to reduce potential of dust ignition / explosion.
Special protective equipment for fire fighters:
Use self-contained breathing apparatus and protective coating.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Wear suitable protective clothing.
Methods for cleaning up:
Ventilate with fresh air. Collect as much of the spilled material as possible. Use wet sweeping or water to
avoid dusting. Collect and place in a closed container. Dispose as approved by your State Regulations.
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7. HANDLING AND STORAGE
7.1 Handling
General precaution:
For industrial and professional use only.
Avoid dispersion of dust in air.
Electrically bond and ground equipment.
Avoid sparks and flame under dust conditions.
Use with adequate ventilation.
Ventilation:
Special, local ventilation is recommended in areas where containers are opened and their containers are
discharged or in any areas where dusting conditions may occur.
Other precaution
{Caution] May undergo spontaneous smouldering if stored or heated in bulk above 35
o
C under conditions
allowing air ingress to the product. Store package material in a cool, well-ventilated area.
Do not store in the sun.
Do not dry in package use special drying instructions as below.
Microspheres will undergo oxidation at elevated temperatures. Due to the microspheres excellent
insulating characteristics, the internal temperature of the mass can increase to the point where
spontaneous ignition and smouldering can occur. The temperature at which this occurs is a function of the
geometry, amount of material being heated and available oxygen. Smouldering appears as a soft glow
similar to burning charcoal.
Drying instructions for the Phenoset microspheres:
To reduce the moisture content of this product to less than 4%, dry a two-inch layer of the product at a
maximum temperature of 75
o
C for 24 hours. To prevent oven or product contamination, the metal drying
tray should be covered with a cloth that will allow the product moisture to evaporate. 7.2 Storage
Keep container closed.
7.3 Specific use (s)
For industrial and professional use only.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1
Exposure limit values .
No exposure limit has been established.
8.2
8.2.1
Exposure controls
Occupational exposure controls
Respiratory protection:
Hand protection :
Eye protection :
Other protective equipment:
Dust respirator, if dusting occurs
General working gloves are acceptable.
Safety glasses
Eye bath and safety shower. Adequate ventilation
.
8.2.2 Environmental exposure controls
None established.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Red brown, fine powder
Odour: Odourless
Molecular weight: >10,000, Fully cured C-stage
Relative density: 0.20 0.80
Self-ignition temperature: 500
o
C (ASTM D1929)
Boiling point: Does not boil
Melting point: Does not melt
Solubility: Not soluble in water
10. STABILITY AND REACTIVITY
General : Stable
Conditions to avoid: None known
Materials to avoid: Strong acids and base, halogens , acyl halides
Hazardous decomposition products: Carbon monoxide, car bon dioxide, formaldehyde and phenol
derivatives upon decomposition.
Hazardous polymerisation: Will not occur.
11. TOXICOLOGICAL INFORMATION
Effects from inhalation:
Upper respiratory tract irritation signs/symptoms may include sneezing, cough, and nasal discharge.
Effects from ingestion:
Gastrointestinal irritation.
Effects from skin contact:
Mechanical skin irritation. May result in itching.
Effects from eye contact:
Mechanical eye irritation. Signs and symptoms may include pain, redness and tears.
Significant data with possible relevance to human health
Formaldehyde has been shown to cause cancer in laboratory animals and mutations in a variety of in-vitro
test systems. The relevance of these findings for human is unknown. Formaldehyde is listed as a
carcinogen by IARC, NTP and OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity: None known.
Mobility: Does not dissolve in water.
Persistence and degradability: Not determined.
Bioaccumulative potential: Unknown.
13. DISPOSAL CONSIDERATIONS
Dispose off in accordance with appropriate National and local regulations.
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14. TRANSPORT INFORMATION
UN Number, ADR/RID:
IMDG/ICAO:
MONT-BLANC:
Not restricted for transportation.
Not restricted for transportation.
Not restricted for transportation.
15. REGULATORY INFORMATION
Label Elements [Regulations (EC) No. 1272/2008]
None Not classified as hazardous
Inventory Listed In:
China IECSC, EU EINECS, US TSCA, Canada DSL, Japan ENCS, Korea KECL, Taiwan NECI,
Philippine PICCS, Australia AICS, New Zealand NZIoC
16. OTHER INFORMATION
Text of R phrases referred to under headings 3
R45 May cause cancer
R68 Possible risk of irreversible effects
R23/24/25 Toxic by inhalation, in contact and if s wallowed
R34 Causes burns
R43 May cause sensitization by skin contact
H317 May cause an allergic skin reaction
Text of H phrases referred to under headings 3
H350 May cause cancer
H341 Suspected of causing genetic defects
H331 Toxic if inhaled
H311 Toxic in contact with skin
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
Product category:
Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under
REACH article 7(1).
Text on Label:
CAUTION! May undergo spontaneous smouldering if stored or heated in bulk above 35C under conditions
allowing air ingress to the product.
Store in cool, well-ventilated area.
Do not store in the sun
Do not dry in package refer special drying instructions.
FOR INDUSTRIAL USE ONLY
Recommended usage and restrictions:
Please consult the product and/or applications information bulletins for this product.
Disclaimer
The information contains herein is correct to the best of our knowledge. We disclaim any liability as to the
recommendations or completeness of the information. The final evaluation on the fitness of use lies on the
user digression. All material has hidden hazards and should be used with extreme care. Even though
various hazards had been listed herein, we do not warranty that those are the only existing hazards.
Revision Date: 03 April 2015
Revision Summary: Section 3 classification of formaldehyde.
Section 16 Text of R- and H-phrases