SAFETY DATA SHEET
Date Issued : 06/13/2011
SDS No : TC-680 PART A
Date Revised : 06/14/2021
Revision No : 3
TC-680 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-680 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 3
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Reproductive Toxicity, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 3
Physical:
Flammable Liquids, Category 4
GHS LABEL
Skull and
crossbones
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H227: Combustible liquid.
H331: Toxic if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H360: May damage fertility or the unborn child.
H373: May cause damage to organs through prolonged or repeated exposure.
H412: Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
Page 1 of 7
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P370+P378: In case of fire: Use water spray, carbon dioxide, dry chemical, or foam for extinction.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P311: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Cycloaliphatic diisocyanate prepolymer 60 – 100Proprietary
Dicyclohexylmethane-4,4′-diisocyanate 15 – 205124-30-1
Butyl benzyl phthalate (BBP) 1 – 5 85-68-7
Toluene 0.5 – 1.5108-88-3
Phenyl mercury neodecanoate 0.00926545-49-3
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and isocyanate-containing vapors.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
Page 2 of 7
TC-680 PART A
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Keep away from sources of ignition. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation.
Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and clothing.
Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition and
incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
TC-680 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Dicyclohexylmethane-4,4′-diisocyanate
OSHA PEL
TWA – –
STEL – –
C 0.01
[1]
011
[1]
ACGIH TLV
TWA 0.005 –
STEL – –
NIOSH REL
TWA – –
STEL – –
C 0.01 0.11
Toluene
OSHA PEL
TWA 200 –
STEL – –
C 300 –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA 100 375
STEL 150 560
Phenyl mercury neodecanoate
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA –
[1]
0.1 as Hg
[1]
STEL – –
NIOSH REL
TWA – –
STEL – –
Footnotes:
1. Skin
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
Page 4 of 7
TC-680 PART A
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 1.49
FLASH POINT AND METHOD: 77.8 C (172 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.06 (water=1) at 25 C (77 F)
VISCOSITY #1: 6000 Centipoise at 25 C (77 F)
(VOC): < 15.8 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reacts violently with amines (exothermic). Exothermic reactions with acids, alkalis, powerful
oxidants, and alcohols. Reacts with water, whereby carbon dioxide is produced; pressure may build up in closed containers (danger of bursting).
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and isocyanate-containing vapors.
INCOMPATIBLE MATERIALS: Water, strong bases, strong acids, strong oxidizing agents, alcohols, and amines.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Cycloaliphatic diisocyanate prepolymer No data available No data available No data available
Dicyclohexylmethane-4,4'-diisocyanate 18200 mg/kg Rat > 7000 mg/kg Rat 0.33 mg/l Rat (4 h, dust/mist)
Butyl benzyl phthalate (BBP) 2330 mg/kg Rat > 5000 mg/kg Rabbit No data available
Toluene > 5580 mg/kg Rat 12124 mg/kg Rabbit 25.7 mg/l Rat (4 h)
Phenyl mercury neodecanoate 25 to 200 mg/kg Rat No data available No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Butyl benzyl phthalate (BBP) 3
Toluene 3
REPRODUCTIVE TOXICITY: May damage fertility or the unborn child.
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Page 5 of 7
TC-680 PART A
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Dicyclohexylmethane-4,4′-diisocyanate15 – 205124-30-1Diisocyanate Compounds (Category Code N120)
Toluene 0.5 – 1.5108-88-3
Phenyl mercury neodecanoate 0.00926545-49-3Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Butyl benzyl phthalate (BBP) 1 – 5 100 lbs.
Toluene 0.5 – 1.5 1,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Page 6 of 7
TC-680 PART A
Chemical Name Wt.% Listed
Butyl benzyl phthalate (BBP) 1 – 5 Developmental Toxicity
Toluene 0.5 – 1.5Developmental Toxicity
Phenyl mercury neodecanoate 0.009 Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
BBP RESTRICTIONS: This product contains butyl benzyl phthalate (BBP), CAS# 85-68-7 EINECS# 201-622-7. In the U.S., there is a
Prohibition on the Sale of Certain Products Containing Phthalates. Children’s toys or child care articles shall not contain above 0.1 percent by
weight (one thousand parts per million) of BBP [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In the EU, BBP shall not be used
as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one thousand parts per million) of the
plasticized material, in toys and child care articles. Such toys and childcare articles containing BBP in concentrations greater than the limit
mentioned above shall not be placed on the market [Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 06/14/2021
REVISION SUMMARY: This SDS replaces the 06/12/2018 SDS.
HMIS RATING
HEALTH * 3
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
2
3 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 7 of 7
TC-680 PART A
SAFETY DATA SHEET
Date Issued : 06/13/2011
SDS No : TC-680 PART B
Date Revised : 06/14/2021
Revision No : 3
TC-680 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-680 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Reproductive Toxicity, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Acute Hazards to the Aquatic Environment, Category 1
Chronic Hazards to the Aquatic Environment, Category 1
GHS LABEL
Health hazard Exclamation
mark
Environment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H360: May damage fertility or the unborn child.
H373: May cause damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
Page 1 of 6
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Butyl benzyl phthalate (BBP) 60 – 100 85-68-7
Diethylmethylbenzenediamine 10 – 3068479-98-1
2,6-di-tert-butyl-p-cresol < 0.1 128-37-0
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 6
TC-680 PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
2,6-di-tert-butyl-p-cresol NIOSH REL TWA - 10
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Amber
pH: No data available
PERCENT VOLATILE: 0.04
FLASH POINT AND METHOD: 157.2 C (315 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.09 (water=1) at 25 C (77 F)
VISCOSITY #1: 60 Centipoise at 25 C (77 F)
(VOC): < 0.5 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
Page 3 of 6
TC-680 PART B
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong oxidizing agents, and strong acids.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Butyl benzyl phthalate (BBP) 2330 mg/kg Rat > 5000 mg/kg Rabbit No data available
Diethylmethylbenzenediamine > 500 mg/kg Rat > 2000 mg/kg Rat No data available
2,6-di-tert-butyl-p-cresol > 2900 mg/kg Rat > 2000 mg/kg Rat No data available
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Butyl benzyl phthalate (BBP) 3
2,6-di-tert-butyl-p-cresol 3
REPRODUCTIVE TOXICITY: May damage fertility or the unborn child.
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally hazardous substances, liquid, n.o.s. (See Note)
TECHNICAL NAME: (butyl benzyl phthalate)
PRIMARY HAZARD CLASS/DIVISION: 9
Page 4 of 6
TC-680 PART B
UN/NA NUMBER: UN3082
PACKING GROUP: III
NAERG: 171
REPORTABLE QUANTITY (RQ) UNDER CERCLA: 100 lbs. of butyl benzyl phthalate
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
OTHER SHIPPING INFORMATION: Applies ONLY to containers with a RQ of butyl benzyl phthalate (100 lbs.), otherwise not regulated.
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substances, liquid, n.o.s. (See Note)
TECHNICAL NAME: (butyl benzyl phthalate)
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
ERG: 9L
LABEL: Class 9 (miscellaneous hazardous materials)
NOTE: Applies ONLY to containers with a RQ of butyl benzyl phthalate (100 lbs.), otherwise not regulated.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL NAME: (butyl benzyl phthalate)
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
EmS: F-A,S-F
MARINE POLLUTANT #1: Yes
LABEL: Class 9 (miscellaneous hazardous materials)
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Butyl benzyl phthalate (BBP) 60 – 100 100 lbs.
Benzene < 0.0001 10 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No. 68479-98-1) which is subject to TSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
Page 5 of 6
TC-680 PART B
known to the State of California to cause cancer and birth defects or other reproductive harm. For more information, go to
www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Butyl benzyl phthalate (BBP) 60 - 100 Developmental Toxicity
Benzene < 0.0001
Cancer
Developmental Toxicity
Male Reproductive
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
BBP RESTRICTIONS: This product contains butyl benzyl phthalate (BBP), CAS# 85-68-7 EINECS# 201-622-7. In the U.S., there is a
Prohibition on the Sale of Certain Products Containing Phthalates. Children's toys or child care articles shall not contain above 0.1 percent by
weight (one thousand parts per million) of BBP [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In the EU, BBP shall not be used
as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one thousand parts per million) of the
plasticized material, in toys and child care articles. Such toys and childcare articles containing BBP in concentrations greater than the limit
mentioned above shall not be placed on the market [Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 06/14/2021
REVISION SUMMARY: This SDS replaces the 06/12/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 6 of 6
TC-680 PART B