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1 Identification
Product identifier
Trade name: XTEND 1110EP
Application of the substance / the mixtureRelease agent
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Axel Plastics Research Laboratories, Inc.
50 Cambridge Drive
Monroe, CT 06468 USA
info@axelplastics.com
Information department:Product safety department
Emergency telephone number:
USA and Canada: 1-800-424-9300 (24 hours)
Outside of USA and Canada: 001-703-527-3887 (24 hours)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
heptane
Naphtha (petroleum), light alkylate
Naphtha (petroleum), heavy alkylate
2,2,4-trimethylpentane
Hazard statements
Highly flammable liquid and vapor.
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Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Precautionary statements
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
2
3
0
Health = 2
Fire = 3
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
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3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Component Information:
142-82-5 heptane 25 50%
64741-66-8 Naphtha (petroleum), light alkylate 10 25%
64741-65-7 Naphtha (petroleum), heavy alkylate 10 25%
142-96-1 di-n-butyl ether 2.5 < 10%
Proprietary/Alternative Chemical Name Pending 1 2.5%
4 First-aid measures
Description of first aid measures
General information:Immediately remove any clothing soiled by the product.
After inhalation:In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:If symptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:Water with full jet
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Protective equipment:No special measures required.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not
breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
Environmental precautions:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the
relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Do not allow to enter sewers/ surface or ground water.
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Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-
soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill: Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent
entry into sewers, water courses, basements or confined areas. Wash spillage into an effluent treatment plant or
proceed as follow. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section
13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same
hazard as the spilled product. Note: See Section 1 for emergency contact information and Section 13 for waste
disposal.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Store in cool, dry place in tightly closed receptacles.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and
clothing. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Avoid freezing.
Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
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Control parameters
Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
142-82-5 heptane
PEL Long-term value: 2000 mg/m , 500 ppm
REL Long-term value: 350 mg/m , 85 ppm
Ceiling limit value: 1800* mg/m , 440* ppm
*15-min
TLV Short-term value: 2050 mg/m , 500 ppm
Long-term value: 1640 mg/m , 400 ppm
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
If a risk assessment indicates engineering controls are not sufficient to protect worker health or comply with
relevant legislation, use an approved respirator. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respirators to be
considered for this material include: Half-face filter respirator with Type A filter material.
For the European Union, refer to Standardization (CEN) standards EN 136, 140 and 405 for respirator masks and
EN 149 and 143 for filter recommendations. In the United States of America, refer to OSHA Respiratory
Protection Standard, 29 CFR 1910.134 and ANSI Z88.2 for respiratory selection, use and maintenance.
Protection of hands:
Hand Protection: Glove suitability depends on the conditions of use. Use gauntlet style gloves if
forearms are likely to be exposed. Contact glove manufacturer for appropriate glove selection.
Minimally, chemical resistant gloves in accordance with CEN standards EN 420 and EN 374 should be
used. Skin Protection: Chemical/oil resistant clothing is recommended.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Chemical safety glasses with side shields, goggles or face shield. Do not wear contact lenses.
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Body protection:Protective work clothing
* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Color: Clear
Odor: Aliphatic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 94 - 195 C
Flash Point (C.O.C.): < 23 C (< 73.4 F)
Percentage Volatile 98.55 %
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Oxidizing properties Not determined.
Vapor pressure at 50 C (122 F):124 hPa (93 mm Hg)
Density: Not determined.
Relative density 0.714
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity: < 15 cps @ 25C
Dynamic: Not determined.
Kinematic: Not determined.
VOC content: Not determined.
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stabilityThe product is stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
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Incompatible materials:No further relevant information available.
Hazardous decomposition products:No dangerous decomposition products known.
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
ATE (Acute Toxicity Estimate)
Oral LD50 49,057 mg/kg (Rat)
Dermal LD50 > 13,367 mg/kg
Inhalative LC50/4 h > 39 mg/l (rat)
64741-65-7 Naphtha (petroleum), heavy alkylate
Oral LD50 > 6,000 mg/kg (rat)
Dermal LD50 > 3,000 mg/kg (rabbit)
Inhalative LC50/4 h > 7.8 mg/l (rat)
Primary irritant effect:
on the skin:Irritant to skin and mucous membranes.
on the eye:Irritating effect.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
IARC Monographs
Group 1: Carcinogenic to humans
Group 2A: Probably carcinogenic to humans
Group 2B: Possibly carcinogenic to humans
Group 3: Not classifiable as to its carcinogenicity to humans
Group 4: Probably not carcinogenic to humans
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
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Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions
and any by-products should at all times comply with the requirements of environmental protection and waste
disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully
compliant with the requirements of all authorities with jurisdiction.
The classification of the product may meet the criteria for a hazardous waste.
Uncleaned packagings:
Recommendation:
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible.
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied
containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
14 Transport information
UN-Number
DOT, IMDG, IATA UN1866
UN proper shipping name
DOT Resin solution
IMDG RESIN SOLUTION (Naptha Light Distillate with 0.1 to 0.25 %
2,2,4 Trimethylpentane), MARINE POLLUTANT
IATA RESIN SOLUTION
Transport hazard class(es)
DOT
Class 3 Flammable liquids
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Label 3
IMDG
Class 3 Flammable liquids
Label 3
IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for user Warning: Flammable liquids
EMS Number: F-E,S-E
Stowage Category B
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Remarks: Special marking with the symbol (fish and tree).
UN “Model Regulation”: UN 1866 RESIN SOLUTION, 3, II, ENVIRONMENTALLY
HAZARDOUS
* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act) (Substances not listed):
All ingredients are listed.
TSCA new (21st Century Act) (Substances not listed)
64741-65-7 Naphtha (petroleum), heavy alkylate
Proposition 65
Chemicals known to cause cancer:
71-43-2 benzene
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Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
71-43-2 benzene
Chemicals known to cause developmental toxicity:
108-88-3 toluene
71-43-2 benzene
US State Regulations
Connecticut – Hazardous Air Pollutants – HLVs (30 min)
None of the ingredients is listed.
Connecticut – Hazardous Air Pollutants – HLVs (8 hr)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Emission Levels (ELs)
None of the ingredients is listed.
Idaho – Non-Carcinogenic Toxic Air Pollutants – Acceptable Ambient Concentrations
None of the ingredients is listed.
Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
Michigan – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Minnesota – Hazardous Substance List
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Minnesota – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – 24-Hour
None of the ingredients is listed.
New Hampshire – Regulated Toxic Air Pollutants – Ambient Air Levels (AALs) – Annual
None of the ingredients is listed.
New York – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
New York – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 1-Hour
None of the ingredients is listed.
North Dakota – Air Pollutants – Guideline Concentrations – 8-Hour
None of the ingredients is listed.
Oregon – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
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Tennessee – Occupational Exposure Limits – Skin Designations
None of the ingredients is listed.
Tennessee – Occupational Exposure Limits – TWAs
None of the ingredients is listed.
Texas – Effects Screening Levels – Long Term
None of the ingredients is listed.
Texas – Effects Screening Levels – Short Term
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Vermont – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – Skin Designations
None of the ingredients is listed.
Washington – Permissible Exposure Limits – STELs
None of the ingredients is listed.
Washington – Permissible Exposure Limits – TWAs
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 25 Feet to Less
Than 40 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 40 Feet to Less
Than 75 Feet
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights 75 Feet or Greater
None of the ingredients is listed.
Wisconsin – Hazardous Air Contaminants – All Sources – Emissions From Stack Heights Less Than 25 Feet
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
142-82-5 heptane D
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
EPA Carcinogen Category Key
EPA 2005 Guidelines:
CaH – Carcinogenic to humans.
L – Likely to be carcinogenic to humans.
SC – Suggestive evidence of carcinogenic potential.
II – Inadequate information to assess carcinogenic potential.
NL – Not likely to be carcinogenic to humans.
EPA 1999 Guidelines:
CaH – Carcinogenic to humans.
L – Likely to be carcinogenic to humans.
S – Suggestive evidence of carcinogenicity, but not sufficient to assess human carcinogenic potential.
I – Data are inadequate for an assessment of human carcinogenic potential.
NL – Not likely to be carcinogenic to humans.
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EPA 1996 Guidelines:
K/L – Known/likely human carcinogen.
CBD – Carcinogenic potential cannot be determined.
NL – Not likely to be carcinogenic to humans.
EPA 1986 Guidelines:
A – Human carcinogen
B1 – Probable human carcinogen – based on limited evidence of carcinogenicity in humans and sufficient evidence
of carcinogenicity in animals.
B2 – Probable human carcinogen – based on sufficient evidence of carcinogenicity in animals.
C – Possible human carcinogen.
D – Not classifiable as to human carcinogenicity.
E – Evidence of non-carcinogenicity for humans.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02GHS07GHS08
Signal wordDanger
Hazard-determining components of labeling:
heptane
Naphtha (petroleum), light alkylate
Naphtha (petroleum), heavy alkylate
2,2,4-trimethylpentane
Hazard statements
Highly flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Precautionary statements
If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapors/spray
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
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Call a poison center/doctor if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
The components of this product are listed on the USA (TSCA) inventory.
The components of this product are listed on the Canadian (DSL) inventory.
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
Disclaimer: This data is offered in good faith as typical values and not as a product specification. No warranty,
either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures
are believed to be generally applicable. However, each user should review recommendations in the specific context
of the intended use and determine whether they are appropriate.
Procedure used to derive the classification
Test data.
Calculation method.
Contact:info@axelplastics.com
Date of preparation / last revision11/01/2018 / 10
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
Asp. Tox. 1: Aspiration hazard Category 1
* Data compared to the previous version altered.
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