SAFETY DATA SHEET
1. Identification
905 TR Mold Prep CleanerProduct identifier
Other means of identification
TR 905Product code
Solvent.Recommended use
Use in accordance with supplier’s recommendations.Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893 United States
Telephone: (562) 923-5438
Emergency CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2BSerious eye damage/eye irritation
Category 2Reproductive toxicity
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (Central nervous system)Specific target organ toxicity, repeated
exposure
Category 1Aspiration hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Causes skin irritation. Causes eye irritation. Suspected of
damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to
organs (Central nervous system) through prolonged or repeated exposure. May be fatal if
swallowed and enters airways.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye
protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you
feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If
exposed or concerned: Get medical advice/attention. In case of fire: Use water, water spray,
foam, dry powder, carbon dioxide (CO2) to extinguish.
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Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
108-88-3 50 – 52Toluene
CAS number %Chemical name
78-93-3 48 – 50Methyl ethyl ketone
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Composition comments
4. First-aid measures
Move into fresh air and keep at rest. If breathing is difficult, give oxygen. Get medical attention if
discomfort develops or persists.
Inhalation
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing separately before reuse. Get medical attention. Destroy or thoroughly
clean contaminated shoes.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention.
Eye contact
DO NOT induce vomiting. If victim is fully conscious, give a cupful of water. Never give anything by
mouth to an unconscious person. If vomiting occurs, keep head lower than the hips to help prevent
aspiration. Call a physician or poison control center immediately.
Ingestion
Irritant effects. Central nervous system depression. May be fatal if swallowed and enters airways.
Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Keep victim warm. Keep victim under observation. Symptoms may be delayed.Indication of immediate
medical attention and special
treatment needed
Take off contaminated clothing and shoes immediately. Wash contaminated clothing before
re-use. Ensure that medical personnel are aware of the material(s) involved, and take precautions
to protect themselves. Show this safety data sheet to the doctor in attendance.
General information
5. Fire-fighting measures
Water. Water spray. Foam. Dry powder. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
Material will float and may ignite on surface of water. Vapors may form explosive mixtures with air.
Vapors are heavier than air and may travel along the floor and in the bottom of containers. Vapors
may be ignited by a spark, a hot surface or an ember.
Specific hazards arising from
the chemical
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
Special protective equipment
and precautions for firefighters
Move containers from fire area if you can do so without risk. Cool containers with flooding
quantities of water until well after fire is out.
Fire fighting
equipment/instructions
Highly flammable liquid and vapor. Heat may cause the containers to explode.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Local authorities should be advised if significant spillages
cannot be contained. Keep out of low areas. Ventilate closed spaces before entering them. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Personal precautions,
protective equipment and
emergency procedures
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Extinguish all flames in the vicinity. Remove sources of ignition. Should not be released into the
environment. Prevent entry into waterways, sewers, basements or confined areas.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. This material and its container must be
disposed of as hazardous waste.
Methods and materials for
containment and cleaning up
Prevent further leakage or spillage if safe to do so. Do not contaminate water.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat and sources of ignition. Use only with adequate ventilation.
Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Pregnant women should
not work with the product, if there is the least risk of exposure. When using, do not eat, drink or
smoke. Do not taste or swallow. Wash thoroughly after handling.
Precautions for safe handling
Follow rules for flammable liquids. Keep away from heat, sparks and open flame. Keep in a
well-ventilated place. Keep out of the reach of children. Keep away from food, drink and animal
feeding stuffs.
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 590 mg/m3Methyl ethyl ketone (CAS
78-93-3)
200 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
ValueTypeComponents
Ceiling 300 ppmToluene (CAS 108-88-3)
TWA 200 ppm
US. ACGIH Threshold Limit Values
ValueTypeComponents
STEL 300 ppmMethyl ethyl ketone (CAS
78-93-3)
TWA 200 ppm
TWA 20 ppmToluene (CAS 108-88-3)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueTypeComponents
STEL 885 mg/m3Methyl ethyl ketone (CAS
78-93-3)
300 ppm
TWA 590 mg/m3
200 ppm
STEL 560 mg/m3Toluene (CAS 108-88-3)
150 ppm
TWA 375 mg/m3
100 ppm
Biological limit values
ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
2 mg/l MEK Urine *Methyl ethyl ketone (CAS
78-93-3)
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ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
0.3 mg/g o-Cresol, with
hydrolysis
Creatinine
in urine
*Toluene (CAS 108-88-3)
0.03 mg/l Toluene Urine *
0.02 mg/l Toluene Blood *
* – For sampling details, please see the source document.
Exposure guidelines
US – California OELs: Skin designation
Toluene (CAS 108-88-3) Can be absorbed through the skin.
US – Minnesota Haz Subs: Skin designation applies
Toluene (CAS 108-88-3) Skin designation applies.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Use
explosion-proof equipment. Provide easy access to water supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear approved safety glasses or goggles. Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear protective gloves. Suitable gloves can be recommended by the glove supplier.Hand protection
Skin protection
Wear suitable protective clothing.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. In the United States of America, if
respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR
1910.134. Respirator type: Air-purifying respirator with an appropriate, government approved
(where applicable), air-purifying filter, cartridge or canister.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Clear, colorless liquid.Appearance
Liquid.Physical state
Liquid.Form
Colorless, clear.Color
Hydrocarbon.Odor
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
> 175 F (> 79.44 C)
Flash point 33.4 F (0.8 C) Closed Cup (Calculated)
Evaporation rate > 1 (Butyl acetate = 1)
Not applicable.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
1.3
Flammability limit – upper
(%)
11.5
Explosive limit – lower (%)Not available.
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Explosive limit – upper (%)Not available.
Vapor pressure > 22 mmHg
Vapor density > 1 (Air= 1)
Relative density 0.83 (Water = 1)
Solubility(ies)
Solubility (water) Partially soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Risk of ignition. Stable at normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Heat, flames and sparks. Electrostatic discharge. Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents. Strong acids. Strong bases.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause central nervous system depression.
Skin contact Causes skin irritation.
Eye contac
t Causes eye irritation.
Ingestion May be fatal if swallowed and enters airways.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritant effects. May cause central nervous system effects. May be fatal if swallowed and enters
airways. May cause damage to organs (central nervous system) through prolonged or repeated
exposure.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Causes skin irritation.Skin corrosion/irritation
Causes eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
Not a skin sensitizer.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.
NTP Report on Carcinogens
Not listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Suspected of damaging fertility or the unborn child.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness or dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to the following organs through prolonged or repeated exposure: Central
nervous system.
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Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects Prolonged inhalation may be harmful. Prolonged or repeated exposure may cause lung injury.
May cause central nervous system effects.
Further information Symptoms may be delayed.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
No data is available on the degradability of this product.Persistence and degradability
No data available on bioaccumulation.Bioaccumulative potential
Expected to be slightly to moderately mobile in soil.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not
incinerate sealed containers. Do not dispose of waste into sewer. Do not contaminate ponds,
waterways or ditches with chemical or used container. Dispose of in accordance with local
regulations.
Disposal instructions
D001: Waste Flammable material with a flash point <140 FHazardous waste code
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB2, T7, TP1, TP8, TP28Special provisions
150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
NoEnvironmental hazards
3HERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (toluene, methyl ethyl ketone)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
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3Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
F-E, S-EEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Methyl ethyl ketone (CAS 78-93-3) LISTED
Toluene (CAS 108-88-3) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
YesSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Toluene 108-88-3 50 - 52
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Toluene (CAS 108-88-3)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Hazardous substanceClean Water Act (CWA)
Section 112(r) (40 CFR
68.130)
Not regulated.Safe Drinking Water Act
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Methyl ethyl ketone (CAS 78-93-3) 6714
Toluene (CAS 108-88-3) 6594
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Methyl ethyl ketone (CAS 78-93-3) 35 %WV
Toluene (CAS 108-88-3) 35 %WV
DEA Exempt Chemical Mixtures Code Number
Methyl ethyl ketone (CAS 78-93-3) 6714
Toluene (CAS 108-88-3) 594
WARNING: This product contains a chemical known to the State of California to cause birth
defects or other reproductive harm.
US state regulations
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US. Massachusetts RTK - Substance List
Methyl ethyl ketone (CAS 78-93-3)
Toluene (CAS 108-88-3)
US. New Jersey Worker and Community Right-to-Know Act
Methyl ethyl ketone (CAS 78-93-3)
Toluene (CAS 108-88-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Methyl ethyl ketone (CAS 78-93-3)
Toluene (CAS 108-88-3)
US. Rhode Island RTK
Methyl ethyl ketone (CAS 78-93-3)
Toluene (CAS 108-88-3)
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Toluene (CAS 108-88-3)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
10-April-2014Issue date
18-December-2015Revision date
Version # 02
NFPA ratings
02
3
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
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