SAFETY DATA SHEET
1. Identification
Product identifier Gel Gloss GG-1, GG-8, GG-64, GG-128
Other means of identificationNot available.
Recommended use Surface gloss.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893 United States
Telephone: (562) 923-5438
Emergency CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 3Flammable LiquidsPhysical hazards
Category 2Skin corrosion/irritationHealth Hazards
Category 1Serious eye damage/eye irritation
Category 1Sensitization, skin
Category 1Aspiration hazard
Category 2Hazardous to the aquatic environment,
long-term hazard
Environmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation.
Causes serious eye damage. Toxic to aquatic life with long lasting effects. May cause an allergic
skin reaction.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Contaminated work clothing
must not be allowed out of the workplace. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection.
Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a poison center/doctor. Collect spillage.
Storage Store in a well-ventilated place. Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
3. Composition/information on ingredients
Mixtures
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5989-27-5 1 – 5D-Limonene
CAS number %Chemical name
68551-19-9 30-35C12-C14 isoalkanes
112-80-1 1-5Oleic acid
14808-60-7 1-5Quartz
110-91-8 <5Morpholine
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume. Components not listed are either non-hazardous or are below reportable
limits.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give
anything by mouth to an unconscious person.
Most important
symptoms/effects, acute and
delayed
Diarrhea. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose
and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye
damage including blindness could result. Skin irritation. May cause redness and pain. May cause
an allergic skin reaction.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from
the chemical
Vapors may form explosive mixtures with air.
Thermal decomposition may produce CO, CO2, oxides of nitrogen and other potentially toxic
gases.
Special protective equipment
and precautions for firefighters
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.
Fire fighting
equipment/instructions
Cool containers exposed to heat with water spray and remove container, if no risk is involved.
General fire hazards Flammable liquid and vapor. Heat may cause the containers to explode.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor.
Do not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Ventilate closed spaces before entering them. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
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Methods and materials for
containment and cleaning up
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is without risk.
Dike the spilled material, where this is possible.
Large Spills: Use water spray to reduce vapors or divert vapor cloud drift. Cover with plastic sheet
to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent product from entering drains.
Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases.
7. Handling and storage
Precautions for safe handlingDo not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Should be handled in
closed systems, if possible. Wear appropriate personal protective equipment. Wash hands
thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene
practices.
Conditions for safe storage,
including any incompatibilities
Store locked up. Keep away from heat and sources of ignition. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place.
Refrigeration recommended. Keep out of the reach of children. Keep in an area equipped with
sprinklers. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents PEL 70 mg/m3Morpholine (CAS 110-91-8)
20 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
ValueType FormComponents
TWA 0.3 mg/m3 Total dust.Quartz (CAS 14808-60-7)
0.1 mg/m3 Respirable.
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 20 ppmMorpholine (CAS 110-91-8)
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueType FormComponents
STEL 105 mg/m3Morpholine (CAS 110-91-8)
30 ppm
TWA 70 mg/m3
20 ppm
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueTypeComponents
TWA 165.5 mg/m3D-Limonene (CAS
5989-27-5)
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US. Workplace Environmental Exposure Level (WEEL) Guides
ValueTypeComponents
30 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines
US - California OELs: Skin designation
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Morpholine (CAS 110-91-8) Skin designation applies.
US - Tennessee OELs: Skin designation
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US ACGIH Threshold Limit Values: Skin designation
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US. NIOSH: Pocket Guide to Chemical Hazards
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Morpholine (CAS 110-91-8) Can be absorbed through the skin.
Appropriate engineering
controls
Use explosion-proof ventilation equipment. Use process enclosures, local exhaust ventilation, or
other engineering controls to control airborne levels below recommended exposure limits. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear approved chemical safety goggles. Wear face shield if there is risk of splashes.
Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air
purifying respirator as needed to control exposure. Consult with respirator manufacturer to
determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator
for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow
respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator
use.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance Milky white liquid.
Physical state Liquid.
Form Liquid.
Color Milky white.
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
> 302 F (> 150 C)
Flash point 140.0 – 200.0 F (60.0 – 93.3 C)
Evaporation rate 0.1 Estimated.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
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Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
Vapor pressure Not available.
Vapor density 4.9 Estimated.
Relative density < 1 Estimated.
Solubility(ies)
Solubility (water) Negligible in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Percent volatile < 65 %
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents. Strong acids. Strong bases. Amines.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact Causes skin irritation. May cause an allergic skin reaction.
Eye contac
t Causes serious eye damage.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious
chemical pneumonia.
Symptoms related to the
physical, chemical and
toxicological characteristics
Diarrhea. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose
and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye
damage including blindness could result. Skin irritation. May cause redness and pain. May cause
an allergic skin reaction.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Morpholine (CAS 110-91-8)
LD50 Rabbit
Dermal
Acute
500 mg/kg
500 mg/kg, 24 Hours
0.31 - 0.81 ml/kg, 24 Hours
LC50 Rat
Inhalation
8000 ppm, 8 hours
LD50 Guinea pig
Oral
900 mg/kg
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Test ResultsComponents Species
Rat 1050 mg/kg
1.05 g/kg
Oleic acid (CAS 112-80-1)
LD50 Rat
Oral
Acute
74 g/kg
Polyalkyl siloxane (CAS 63148-62-9)
LD50 Rabbit
Dermal
Acute
>= 5000 mg/kg
LD50 Rat
Oral
>= 17000 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye
irritation
Causes serious eye damage.
Respiratory or skin sensitization
Respiratory sensitizationNot classified.
Skin sensitization May cause an allergic skin reaction.
Germ cell mutagenicity Not classified.
Carcinogenicity Due to the form of the product, exposure to the potentially carcinogenic components is not
expected.
IARC Monographs. Overall Evaluation of Carcinogenicity
D-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans.
Morpholine (CAS 110-91-8) 3 Not classifiable as to carcinogenicity to humans.
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Not classified.
Specific target organ toxicity –
single exposure
Not classified.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard May be fatal if swallowed and enters airways.
Chronic effects May be harmful if absorbed through skin.
12. Ecological information
Ecotoxicity Toxic to aquatic life with long lasting effects.
Persistence and degradabilityNo data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Morpholine (CAS 110-91-8) -0.86
Mobility in soil The product is insoluble or slightly soluble in water.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Dispose in accordance with all applicable regulations. Must be incinerated in a suitable
incineration plant holding a permit delivered by the competent authorities. This material and its
container must be disposed of as hazardous waste. Do not allow this material to drain into
sewers/water supplies.
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Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN1268UN number
Petroleum products, n.o.s. (D-Limonene; C12-C14 isoalkanes)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIIPacking group
yesMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
144, B1, IB3, T4, TP1, TP29Special provisions
150Packaging exceptions
203Packaging non bulk
242Packaging bulk
IATA
UN1268UN number
Petroleum products, n.o.s. (D-Limonene, C12-C14 isoalkanes)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
yesEnvironmental hazards
3LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1268UN number
Petroleum products, n.o.s. (D-Limonene, C12-C14 isoalkanes)UN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
IIIPacking group
yesMarine pollutant
Environmental hazards
F-E, S-EEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
This substance/mixture is not intended to be transported in bulk.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
One or more components are not listed on TSCA.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
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CERCLA Hazardous Substance List (40 CFR 302.4)
Morpholine (CAS 110-91-8) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Morpholine (CAS 110-91-8)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
D-Limonene (CAS 5989-27-5)
Morpholine (CAS 110-91-8)
Quartz (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Morpholine (CAS 110-91-8)
Oleic acid (CAS 112-80-1)
Quartz (CAS 14808-60-7)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Benzene (CAS 71-43-2)
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
NoPhilippines
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Country(s) or region Inventory name On inventory (yes/no)*
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date 15-September-2014
Revision date -
Version # 01
NFPA ratings
03
2
List of abbreviations LD50: Lethal Dose, 50%.
LC50: Lethal Concentration, 50%.
EC50: Effective concentration, 50%.
STEL: Short term exposure limit.
TWA: Time weighted average.
DOT: Department of Transportation. ADR: European Agreement concerning the International
Carriage of Dangerous Goods by Road.
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.
RID: Regulations concerning the International Carriage of Dangerous Goods by Rail.
References RTECS
HSDB - Hazardous Substances Data Bank
GESTIS Substance Database
C&L Inventory database.
Disclaimer This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.
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