DURATEC THINNER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 12/31/2014 Revision date: 12/31/2014 Supersedes: 09/11/9014

12/31/2014 EN (English US) Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : DURATEC THINNER
CAS No : mixture
Product code : 39LAC-3
Formula : na

1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : PAINT THINNER

1.3. Details of the supplier of the safety data sheet
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316

909.877.8477
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887

1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification (GHS-US)
Flam. Liq. 3 H226
Carc. Not classified

2.2. Label elements
GHS-US labeling
Hazard pictograms (GHS-US) :

GHS02

Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H226 – Flammable liquid and vapor
Precautionary statements (GHS-US) : P210 – Keep away from heat;hot surfaces;open flames. – No smoking
P233 – Keep container tightly closed
P240 – Ground/bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment
P242 – Use only non-sparking tools
P243 – Take precautionary measures against static discharge
P280 – Wear eye protection;protective clothing
P303+P361+P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish
P403+P235 – Store in a well-ventilated place. Keep cool
P501 – Dispose of contents/container to in accordance with local, state, and national regulations.

2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available

DURATEC THINNER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/31/2014 EN (English US) 2/10

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
Full text of H-phrases: see section 16

3.2. Mixture

Name Product identifier % Classification (GHS-US)
Solvent Naptha Petroleum Aliphatic (CAS No) Proprietary <= 39 Not classified methyl ethyl ketone (CAS No) 78-93-3 <= 22 Flam. Liq. 2, H225 n-butyl acetate (CAS No) 123-86-4 <= 20 Flam. Liq. 3, H226 isobutyl acetate (CAS No) 110-19-0 <= 11 Flam. Liq. 2, H225 2-propanol (CAS No) 67-63-0 <= 10 Flam. Liq. 2, H225 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see seek medical attention. on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin contact and inhalation.). Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if inhaled. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Highly flammable liquid and vapor. Explosion hazard : May form flammable/explosive vapor-air mixture. Reactivity : No reactivity hazard other than the effects described in sub-sections below. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. DURATEC THINNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/31/2014 EN (English US) 3/10 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES, MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Eliminate all ignition sources if safe to do so. Hygiene measures : Wash HANDS thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. equipment. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters methyl ethyl ketone (78-93-3) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 300 ppm n-butyl acetate (123-86-4) USA ACGIH ACGIH TWA (ppm) 150 ppm USA ACGIH ACGIH STEL (ppm) 200 ppm isobutyl acetate (110-19-0) USA ACGIH ACGIH TWA (ppm) 150 ppm 2-propanol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. DURATEC THINNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/31/2014 EN (English US) 4/10 Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear approved mask. Other information : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : clear. Odor : characteristic. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : >= 79.4 C

Flash point : >= -11.1 C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : No data available

Relative vapor density at 20 C : No data available

Relative density : 0.8

Solubility : No data available

COATING VOC: : 6.67 lb/gl
MATERIAL V.O.C.: : 6.67 lb/gl
Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Explosive limits : No data available

9.2. Other information
No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapor. May form
flammable/explosive vapor-air mixture.

10.3. Possibility of hazardous reactions
Not established.

10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.

10.5. Incompatible materials
strong acids. Strong bases.

10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

DURATEC THINNER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/31/2014 EN (English US) 5/10

DURATEC THINNER ( f )mixture
ATE CLP (dust, mist) 1.500 mg/l/4h

methyl ethyl ketone (78-93-3)
LD50 oral rat 2737 mg/kg (2054 mg/kg; 2328 mg/kg; Rat; Rat; Rat)
LD50 dermal rabbit 6480 mg/kg (>10; Rabbit; Rabbit; Experimental value,>10; Rabbit; Rabbit; Experimental value)
LC50 inhalation rat (mg/l) 34 mg/l/4h (Rat)
LC50 inhalation rat (ppm) 11300 ppm/4h (Rat)
ATE CLP (oral) 2737.000 mg/kg body weight
ATE CLP (dermal) 6480.000 mg/kg body weight
ATE CLP (gases) 11300.000 ppmV/4h
ATE CLP (vapors) 34.000 mg/l/4h
ATE CLP (dust, mist) 34.000 mg/l/4h

n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit)
ATE CLP (oral) 10770.000 mg/kg body weight

isobutyl acetate (110-19-0)
LD50 oral rat 13400 mg/kg (Rat)
LD50 dermal rabbit > 5000 mg/kg (Rabbit)
ATE CLP (oral) 13400.000 mg/kg

2-propanol (67-63-0)
LD50 oral rat 5045 mg/kg (5840 mg/kg bodyweight; Rat; Rat; Experimental value,5840 mg/kg bodyweight;
Rat; Rat; Experimental value)
LD50 dermal rabbit 12870 mg/kg (16.4; Rabbit; Rabbit; Experimental value,16.4; Rabbit; Rabbit; Experimental
value)
LC50 inhalation rat (mg/l) 73 mg/l/4h (Rat)
ATE CLP (oral) 5045.000 mg/kg body weight
ATE CLP (dermal) 12870.000 mg/kg body weight
ATE CLP (vapors) 73.000 mg/l/4h
ATE CLP (dust, mist) 73.000 mg/l/4h

Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified.

2-propanol (67-63-0)
IARC group 3 – Not classifiable

Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated
exposure)
: Not classified
Based on available data, the classification criteria are not met

Aspiration hazard : Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : Causes skin irritation.
Symptoms/injuries after eye contact : Causes serious eye irritation.

DURATEC THINNER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/31/2014 EN (English US) 6/10

SECTION 12: Ecological information

12.1. Toxicity

methyl ethyl ketone (78-93-3)
LC50 fish 1 1690 mg/l (96 h; Lepomis macrochirus; LETHAL)
EC50 Daphnia 1 308 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
LC50 fish 2 2990 mg/l (96 h; Pimephales promelas)
TLM fish 1 5600 mg/l (96 h; Gambusia affinis)
TLM fish 2 1690 mg/l (96 h; Lepomis macrochirus)
TLM other aquatic organisms 1 > 1000 ppm (96 h)
Threshold limit algae 1 110 mg/l (168 h; Microcystis aeruginosa)
Threshold limit algae 2 4300 mg/l (192 h; Scenedesmus quadricauda)

n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (96 h; Pimephales promelas)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 10 – 100 mg/l (48 h; Daphnia magna; Static system)
EC50 other aquatic organisms 1 320 mg/l (96 h; Algae)
LC50 fish 2 62 mg/l (96 h; Brachydanio rerio)
EC50 Daphnia 2 24 – 205 mg/l (24 h; Daphnia magna)
TLM fish 1 10 – 100,96 h; Pisces
Threshold limit other aquatic organisms 1 10 – 100,96 h
Threshold limit algae 1 21 mg/l (168 h; Scenedesmus quadricauda; GROWTH RATE)
Threshold limit algae 2 280 mg/l (192 h; Microcystis aeruginosa; GROWTH RATE)

isobutyl acetate (110-19-0)
LC50 fish 1 100 mg/l (96 h; Lepomis macrochirus; Static system)
LC50 other aquatic organisms 1 10 – 100 mg/l (96 h)
EC50 Daphnia 1 44 mg/l (48 h; Daphnia magna; NOCIVITY TEST)
LC50 fish 2 101 mg/l (48 h; Leuciscus idus)
EC50 Daphnia 2 146 – 192 mg/l (Daphnia magna)
TLM fish 1 > 1000 ppm (96 h; Pisces)
Threshold limit other aquatic organisms 1 411 mg/l (72 h; Protozoa)
Threshold limit algae 1 205 mg/l (192 h; Microcystis aeruginosa)
Threshold limit algae 2 80 mg/l (192 h; Scenedesmus quadricauda)

2-propanol (67-63-0)
LC50 fish 1 4200 mg/l (96 h; Rasbora heteromorpha; Flow-through system)
EC50 Daphnia 1 > 10000 mg/l (48 h; Daphnia magna)
LC50 fish 2 9640 mg/l (96 h; Pimephales promelas; LETHAL)
EC50 Daphnia 2 13299 mg/l (48 h; Daphnia magna)
Threshold limit algae 1 > 1000 mg/l (72 h; Scenedesmus subspicatus; GROWTH RATE)
Threshold limit algae 2 1800 mg/l (72 h; Algae; CELL NUMBERS)

12.2. Persistence and degradability
DURATEC THINNER (mixture)
Persistence and degradability Not established.

methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 1.92 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
BOD (% of ThOD) 0.79 % ThOD

n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance

DURATEC THINNER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12/31/2014 EN (English US) 7/10

n-butyl acetate (123-86-4)
ThOD 2.21 g O /g substance
BOD (% of ThOD) 46 % ThOD

isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 60 % ThOD

2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.40 g O /g substance
BOD (% of ThOD) 0.49 % ThOD

Solvent Naptha Petroleum Aliphatic (Proprietary)
Persistence and degradability May cause long-term adverse effects in the environment.

12.3. Bioaccumulative potential
DURATEC THINNER (mixture)
Bioaccumulative potential Not established.

methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value; 40 C,Experimental value; 40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established. n-butyl acetate (123-86-4) BCF fish 1 14 (Pisces) Log Pow 1.79 - 2.06 Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. isobutyl acetate (110-19-0) BCF fish 1 4 - 9.7 (Pisces; Estimated value) Log Pow 1.59 - 1.78 Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. 2-propanol (67-63-0) Log Pow 0.05 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established. Solvent Naptha Petroleum Aliphatic (Proprietary) Bioaccumulative potential Not established. 12.4. Mobility in soil methyl ethyl ketone (78-93-3) Surface tension 0.024 N/m (20 C) Ecology - soil Slightly harmful to plants. n-butyl acetate (123-86-4) Surface tension 0.0145 N/m (25 C) isobutyl acetate (110-19-0) Surface tension 0.024 N/m (20 C) 2-propanol (67-63-0) Surface tension 0.021 N/m (25 C) 12.5. Other adverse effects Other information : Avoid release to the environment. DURATEC THINNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/31/2014 EN (English US) 8/10 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to approved disposal site. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT UN-No.(DOT) : UN1263 DOT Proper Shipping Name : PAINT RELATED MATERIAL Department of Transportation (DOT) Hazard Classes : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Hazard labels (DOT) : 3 - Flammable liquid Packing group (DOT) : II - Medium Danger Additional information Other information : No supplementary information available. ADR Transport document description : UN 1263, 3, II, (D/E) Packing group (ADR) : II Class (ADR) : 3 - Flammable liquid Hazard identification number (Kemler No.) : 33 Classification code (ADR) : F1 Danger labels (ADR) : 3 - Flammable liquids Orange plates : Tunnel restriction code : D/E LQ : 5L Excepted quantities (ADR) : E2 Transport by sea UN-No. (IMDG) : 1263 Proper Shipping Name (IMDG) : PAINT RELATED MATERIAL Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : II - substances presenting medium danger Air transport UN-No.(IATA) : 1263 Proper Shipping Name (IATA) : PAINT RELATED MATERIAL Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : II - Medium Danger DURATEC THINNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/31/2014 EN (English US) 9/10 SECTION 15: Regulatory information 15.1. US Federal regulations methyl ethyl ketone (78-93-3) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 5000 lb n-butyl acetate (123-86-4) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 5000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Fire hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 2 H225 Acute Tox. 4 (Inhalation:dust,mist) H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Muta. 1B H340 Carc. 1B H350 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC Carc.Cat.2; R45 Muta.Cat.2; R46 F; R11 Xn; R20 Xi; R36/38 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available 15.3. US State regulations No additional information available SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information : None. Full text of H-phrases: see section 16: ------ Carc. Not classified Carcinogenicity Not classified DURATEC THINNER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12/31/2014 EN (English US) 10/10 ------ Flam. Liq. 2 Flammable liquids Category 2 ------ Flam. Liq. 3 Flammable liquids Category 3 ------ H225 Highly flammable liquid and vapor ------ H226 Flammable liquid and vapor NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 3 - Liquids and solids that can be ignited under almost all ambient conditions. NFPA reactivity : 2 - Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 3 Serious Hazard Physical : 1 Slight Hazard Personal Protection : H SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.