DIMETHYLANILINE (DMA)
Benzenamine, N,N-dimethyl-; Dimethylaniline; Dimethylaniline (N-Dimethyl-aniline); N,N-
Dimethylphenylamine; N,N-Dimethylbenzeneamine; Aniline, N,N-dimethyl-; N,N-Diethyl
aniline; Dimethylphenylamine; N,N-Dimethylbenzenamine; Benzenamine, N,N-dimethyl
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of
identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Chemical name :N,N-dimethylaniline
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
DIMETHYLANILINE (DMA)
Material uses
Product code :1005
Product use :Industrial applications.
CHEMTREC 24-Hour Emergency Telephone 800.424.9300
Section 2. Hazards identification
ACUTE TOXICITY: ORAL – Category 3
ACUTE TOXICITY: SKIN – Category 3
ACUTE TOXICITY: INHALATION – Category 3
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Toxic if swallowed, in contact with skin or if inhaled.
Hazard pictograms :
Precautionary statements
Prevention :Wear protective gloves. Wear protective clothing. Use only outdoors or in a well-
ventilated area. Avoid breathing vapor. Do not eat, drink or smoke when using this
product. Wash hands thoroughly after handling.
Response :IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or physician. IF SWALLOWED: Immediately call
a POISON CENTER or physician. Rinse mouth. IF ON SKIN: Take off immediately all
contaminated clothing. Wash with plenty of soap and water. Call a POISON CENTER
or physician if you feel unwell. Wash contaminated clothing before reuse.
Storage :Store containers in a safe place.
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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DIMETHYLANILINE (DMA)1005
Section 2. Hazards identification
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
N,N-Dimethylaniline > 99.5 121-69-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Chemical name :N,N-dimethylaniline
Other means of
identification
:Benzenamine, N,N-dimethyl-; Dimethylaniline; Dimethylaniline (N-Dimethyl-aniline); N,N-
Dimethylphenylamine; N,N-Dimethylbenzeneamine; Aniline, N,N-dimethyl-; N,N-Diethyl
aniline; Dimethylphenylamine; N,N-Dimethylbenzenamine; Benzenamine, N,N-dimethyl
CAS number :121-69-7
Substance/mixture
Product code :1005
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Substance
Any concentration shown as a range is to protect confidentiality or is due to batch variation. Any concentration shown as
exact is based on formula.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. If necessary, call a
poison center or physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
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DIMETHYLANILINE (DMA)1005
Section 4. First aid measures
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion :
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician :In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Toxic if inhaled. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Toxic if swallowed.:Ingestion
Skin contact :Toxic in contact with skin.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
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DIMETHYLANILINE (DMA)1005
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in “For non-
emergency personnel”.
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep
in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Empty containers retain product residue and can be
hazardous. Do not reuse container.
:
Precautions for safe handling
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DIMETHYLANILINE (DMA)1005
Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
:
N,N-Dimethylaniline ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 25 mg/m 10 hours.
STEL: 10 ppm 15 minutes.
STEL: 50 mg/m 15 minutes.
OSHA PEL (United States, 2/2013).
Absorbed through skin.
TWA: 5 ppm 8 hours.
TWA: 25 mg/m 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
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DIMETHYLANILINE (DMA)1005
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: safety glasses with side-
shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Oily liquid.]
1.5 to 2.5 C (34.7 to 36.5 F)
0.96
4.2 [Air = 1]
0.067 kPa (0.5 mm Hg) [room temperature]
Not available.
Characteristic. Amine-like.Odor
pH
Straw. Brown. Yellow.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
371.11 C (700 F)
Closed cup: 75 C (167 F)
1.171
Not available.
Not available.Odor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :193 to 194 C (379.4 to 381.2 F)
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Lower: 1%
Upper: 7%
Burning rate Not applicable.:
Burning time :Not applicable.
Solubility in water :1.2 g/l
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DIMETHYLANILINE (DMA)1005
Section 9. Physical and chemical properties
Viscosity Not available.:
SADT Not available.:
Decomposition temperature:Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Not available.
Section 11. Toxicological information
Acute toxicity
N,N-Dimethylaniline LD50 Dermal Rabbit 1770 mg/kg –
LD50 Oral Rat 951 mg/kg –
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Irritation/Corrosion
N,N-Dimethylaniline Eyes – Moderate irritantRabbit – 24 hours 20
milligrams
–
Eyes – Moderate irritantRabbit – 20 milligrams-
Skin – Mild irritant Rabbit – 24 hours 500
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on toxicological effects
Classification
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DIMETHYLANILINE (DMA)1005
Section 11. Toxicological information
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
routes of exposure
Inhalation :Toxic if inhaled. Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Toxic if swallowed.:Ingestion
Skin contact :Toxic in contact with skin.
No known significant effects or critical hazards.:Eye contact
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact :No specific data.
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
N,N-Dimethylaniline – 3 –
Product/ingredient name NTPIARCOSHA
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DIMETHYLANILINE (DMA)1005
Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Not available.
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
N,N-Dimethylaniline 1.171 16 low
Toxicity
N,N-Dimethylaniline Acute EC50 22000 g/l Fresh water Algae – Chlorella pyrenoidosa72 hours
Acute EC50 2.3 mg/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52600 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 14000 g/l Fresh waterAlgae – Chlorella pyrenoidosa72 hours
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary :Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
:Disposal methods
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DIMETHYLANILINE (DMA)1005
Section 14. Transport information
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
N,N-
Dimethylaniline
(N,N-
dimethylaniline)
6.1
II
N,N-
Dimethylaniline
(N,N-
dimethylaniline)
6.1
II
N,N-
Dimethylaniline
(N,N-
dimethylaniline)
UN2253
6.1
II
UN2253 UN2253
Reportable
quantity
100 lbs / 45.4
kg [12.549 gal /
47.504 L]
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
– –
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Yes. Yes. No.
Mexico
Classification
UN2253
N,N-
Dimethylaniline
(N,N-
dimethylaniline)
6.1
II
Yes.
–
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DIMETHYLANILINE (DMA)1005
No products were found.
Section 15. Regulatory information
U.S. Federal regulations
This material is listed.Massachusetts
:
:
SARA 313
Product name CAS number %
N,N-dimethylaniline 121-69-7 100.00
N,N-dimethylaniline 121-69-7 100.00
Form R – Reporting
requirements
Supplier notification
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :This material is listed.
New Jersey :This material is listed.
Pennsylvania :This material is listed.
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): This material is listed or exempted.
SARA 302/304
SARA 304 RQ :Not applicable.
Composition/information on ingredients
SARA 311/312
Classification :Immediate (acute) health hazard
Canada inventory :This material is listed or exempted.
Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: This material is listed or exempted.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): This material is listed or exempted.
International regulations
International lists :
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DIMETHYLANILINE (DMA)1005
Section 16. Other information
6/15/2015.
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :OSHA Hazard Communication Standard, March 2012 (29 CFR 1910.1200)
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. (“Marpol” = marine pollution)
UN = United Nations
6/15/2015.
4/30/2015.
3.01
Hazardous Material Information System (U.S.A.)
2
2
0
0
2
3
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Health, Safety and Environmental Department
Email :For questions regarding the SDS contact:iasafety@ip-corporation.com
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DIMETHYLANILINE (DMA)1005
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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