Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
1 / 12
SECTION 1. IDENTIFICATION
Product name : SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Company name : Sika Corporation
201 Polito Avenue
Lyndhurst, NJ 07071
USA
www.sikausa.com
Telephone : (201) 933-8800
Telefax : (201) 804-1076
E-mail address : ehs@sika-corp.com
Emergency telephone : CHEMTREC: 800-424-9300
INTERNATIONAL: +1-703-527-3887
Recommended use of the
chemical and restrictions on
use
: For further information, refer to product data sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Skin corrosion
: Category 1B
Serious eye damage
: Category 1
Skin sensitization
: Category 1
Reproductive toxicity
: Category 2
GHS label elements
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H361 Suspected of damaging fertility or the unborn child.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
2 / 12
Precautionary Statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P261 Avoid breathing mist or vapors.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Additional Labeling
There are no ingredients with unknown acute toxicity used in a mixture at a concentration >= 1%.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixtures
Components
Chemical name CAS-No. Classification Concentra-
tion (% w/w)
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
3 / 12
Adduct XA-P (epoxy amine adduct,
polymer)
110839-13-9 Acute Tox. 4; H302
Skin Sens. 1; H317
>= 10 – < 20
Isophoronediamine 2855-13-2 Acute Tox. 4; H302
Skin Corr. 1B; H314
Eye Dam. 1; H318
Skin Sens. 1A; H317
>= 5 – < 10
m-phenylenebis(methylamine) 1477-55-0 Acute Tox. 4; H302
Acute Tox. 4; H332
Skin Corr. 1B; H314
Skin Sens. 1B; H317
>= 1 – < 5
1-methylimidazole 616-47-7 Flam. Liq. 4; H227
Acute Tox. 4; H302
Acute Tox. 3; H311
Skin Corr. 1B; H314
Eye Dam. 1; H318
Repr. 2; H361
>= 1 – < 5
2,2,4(or 2,4,4)-trimethylhexane-1,6-
diamine
25513-64-8 Acute Tox. 4; H302
Skin Corr. 1A; H314
Eye Dam. 1; H318
Skin Sens. 1A; H317
>= 0.1 – < 1
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Consult a physician.
Show this material safety data sheet to the doctor in attend-
ance.
If inhaled : Move to fresh air.
Consult a physician after significant exposure.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do not induce vomiting without medical advice.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
4 / 12
Most important symptoms
and effects, both acute and
delayed
: Health injuries may be delayed.
corrosive effects
sensitizing effects
Allergic reactions
Dermatitis
May cause an allergic skin reaction.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes severe burns.
Notes to physician : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: In the event of fire, wear self-contained breathing apparatus.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
gency procedures
: Use personal protective equipment.
Deny access to unprotected persons.
Environmental precautions
: Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against
fire and explosion
: Normal measures for preventive fire protection.
Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
5 / 12
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitization problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products.
Conditions for safe storage : Store in original container.
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Store in accordance with local regulations.
Materials to avoid : Explosives
Oxidizing agents
Poisonous gases
Dangerous when wet
Flammable solids
Organic peroxides
Poisonous liquids
Spontaneously Combustible Substances
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
m-phenylenebis(methylamine) 1477-55-0 C 0.018 ppm ACGIH
C 0.1 mg/m3 OSHA P0
The above constituents are the only constituents of the product which have a PEL, TLV or other rec-
ommended exposure limit. At this time, the other constituents have no known exposure limits.
Engineering measures : Use of adequate ventilation should be sufficient to control
worker exposure to airborne contaminants. If the use of this
product generates dust, fumes, gas, vapor or mist, use pro-
cess enclosures, local exhaust ventilation or other engineer-
ing controls to keep worker exposure below any recommend-
ed or statutory limits.
Personal protective equipment
Respiratory protection : Use a properly fitted NIOSH approved air-purifying or air-fed
respirator complying with an approved standard if a risk as-
sessment indicates this is necessary.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
6 / 12
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapor/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.
Eye protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary.
Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.
Hygiene measures : Avoid contact with skin, eyes and clothing.
Wash hands before breaks and immediately after handling the product.
Remove contaminated clothing and protective equipment before entering eating areas.
Wash thoroughly after handling.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : paste
Color : dark gray
Odor : amine-like
Odor Threshold : No data available
pH : Not applicable
Melting point/range / Freezing
point
: No data available
Boiling point/boiling range : No data available
Flash point : 338 F / 170 C
(Method: closed cup)
Evaporation rate : No data available
Flammability (solid, gas)
: No data available
Upper explosion limit / Upper
flammability limit
: No data available
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
7 / 12
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure : 0.02 hpa
Relative vapor density : No data available
Density : 1.19 g/cm3 (68 F / 20 C)
Solubility(ies)
Water solubility : soluble
Solubility in other solvents : No data available
Partition coefficient: n-
octanol/water
: No data available
Autoignition temperature : No data available
Decomposition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Viscosity, kinematic : > 20.5 mm2/s (104 F / 40 C)
Explosive properties : No data available
Oxidizing properties : No data available
Volatile organic compounds
(VOC) content
: Not applicable
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : The product is chemically stable.
Possibility of hazardous reac-
tions
: Stable under recommended storage conditions.
Conditions to avoid : No data available
Incompatible materials : No data available
Hazardous decomposition
products
: No decomposition if stored and applied as directed.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
8 / 12
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified due to lack of data.
Components:
Adduct XA-P (epoxy amine adduct, polymer):
Acute oral toxicity : LD50 Oral (Rat): 300 – 2,000 mg/kg
Method: OECD Test Guideline 423
Isophoronediamine:
Acute oral toxicity : LD50 Oral (Rat): 1,030 mg/kg
Acute inhalation toxicity : LC50 (Rat): > 10 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : LD50 (Rabbit): > 2,000 – 5,000 mg/kg
m-phenylenebis(methylamine):
Acute oral toxicity : LD50 Oral (Rat): 930 mg/kg
Acute inhalation toxicity : LC50 (Rat): 1.34 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: Corrosive to the respiratory tract.
Acute dermal toxicity : LD50 Dermal (Rat): > 3,100 mg/kg
1-methylimidazole:
Acute oral toxicity : LD50 Oral (Rat): 1,144 mg/kg
Acute dermal toxicity : LD50 Dermal (Rat): 400 mg/kg
2,2,4(or 2,4,4)-trimethylhexane- 1,6-diamine:
Acute oral toxicity : LD50 Oral (Rat): 910 mg/kg
Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization
Skin sensitization
May cause an allergic skin reaction.
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
9 / 12
Respiratory sensitization
Not classified due to lack of data.
Germ cell mutagenicity
Not classified due to lack of data.
Carcinogenicity
Not classified due to lack of data.
IARC Not applicable
OSHA Not applicable
NTP Not applicable
Reproductive toxicity
Suspected of damaging fertility or the unborn child.
STOT-single exposure
Not classified due to lack of data.
STOT-repeated exposure
Not classified due to lack of data.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
Aspiration toxicity
Not classified due to lack of data.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
Isophoronediamine:
Toxicity to algae/aquatic
plants
: ErC50 (Desmodesmus subspicatus (green algae)): > 10 – 100
mg/l
NOEC (Desmodesmus subspicatus (green algae)): 1.5 mg/l
m-phenylenebis(methylamine):
Toxicity to fish : LC50 (Oryzias latipes (Japanese medaka)): > 10 – 100 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 10 – 100 mg/l
Exposure time: 48 h
2,2,4(or 2,4,4)-trimethylhexane- 1,6-diamine:
Toxicity to algae/aquatic
plants
: EC50 (Scenedesmus capricornutum (fresh water algae)): 29.5
mg/l
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
10 / 12
Toxicity to fish (Chronic tox-
icity)
: LC50 (Leuciscus idus (Golden orfe)): 174 mg/l
Exposure time: 48 h
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological infor-
mation
: Do not empty into drains; dispose of this material and its con-
tainer in a safe way.
Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Disposal of this product, solutions and any by-products should
at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional
local authority requirements.
Contaminated packaging : Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.
SECTION 14. TRANSPORT INFORMATION
International Regulations
IATA-DGR
UN/ID No. : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo
aircraft)
: 855
Packing instruction (passen-
ger aircraft)
: 851
IMDG-Code
UN number : UN 2735
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
11 / 12
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Domestic regulation
49 CFR
UN/ID/NA number : UN 2735
Proper shipping name : Amines, liquid, corrosive, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
Class : 8
Packing group : II
Labels : CORROSIVE
ERG Code : 153
Marine pollutant : no
DOT: For Limited Quantity exceptions reference 49 CFR 173.154 (b)
IMDG: For Limited Quantity special provisions reference IMDG Code Chapter 3.4
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based
upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in
regional or country regulations.
SECTION 15. REGULATORY INFORMATION
TSCA list : All chemical substances in this product are either listed as ac-
tive on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards
: Respiratory or skin sensitization
Reproductive toxicity
Skin corrosion or irritation
Serious eye damage or eye irritation
Safety Data Sheet
according to OSHA 1910.1200 Hazard Communication Standard
SikaBiresin L325 HT (formerly EL-325HTTC) Part B
Revision Date 08/17/2023
Print Date 08/17/2023
12 / 12
SARA 313
: This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61).
California Prop. 65
WARNING: This product can expose you to chemicals including glass, oxide, chemicals, which is
known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
SECTION 16. OTHER INFORMATION
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
values)
ACGIH / C : Ceiling limit
OSHA P0 / C : Ceiling limit
Notes to Reader
The information contained in this Safety Data Sheet applies only to the actual Sika Corporation
(“Sika”) product identified and described herein. This information is not intended to address, nor
does it address the use or application of the identified Sika product in combination with any other
material, product or process. All of the information set forth herein is based on technical data re-
garding the identified product that Sika believes to be reliable as of the date hereof. Prior to each
use of any Sika product, the user must always read and follow the warnings and instructions on
the product’s current Product Data Sheet, product label and Safety Data Sheet for each Sika
product, which are available at web site and/or telephone number listed in Section 1 of this SDS.
SIKA MAKES NO WARRA NTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY
ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER
ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRING E ON ANY
PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at
www.sikausa.com or 201- 933-8800.
Revision Date 08/17/2023
100000035332
US / Z8