T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Issue date: 5/27/2015 Revision date: 8/4/2020 Supersedes: 8/23/2018 Version: 1.10
8/4/2020 (Version: 1.10)EN (English) 1/9
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form
:Mixture
Name
:T-Prime 130-1 Hardener
Type of product
:Hardener (Crosslinker)
Product group
:Hardener
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category
:Industrial use
Industrial/Professional use spec
:For professional use only
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number
:Carechem 24: +44 (0) 1273 289451 24 Hours
Telephone number for use in case of chemical exposure, spillage or fire only.
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 4
H302
Acute toxicity (dermal), Category 4
H312
Skin corrosion/irritation, Category 1, Sub-Category 1B
H314
Serious eye damage/eye irritation, Category 1
H318
Skin sensitisation, Category 1
H317
Hazardous to the aquatic environment Chronic Hazard, Category 3
H412
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
Harmful in contact with skin. Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious
eye damage. Harmful to aquatic life with long lasting effects.
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP)
: GHS05 GHS07
Signal word (CLP)
:Danger
Hazardous ingredients
:3-aminomethyl-3,5,5-trimethylcyclohexylamine
Gurit (UK) Ltd
St Cross Business Park
Newport
PO30 5WU Isle of Wight – United Kingdom
T +44 (0) 1983 828 000 (All Technical and Commercial Enquiries)
Regulatory@gurit.com – www.gurit.com
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 2/9
Hazard statements (CLP)
:H302+H312 – Harmful if swallowed or in contact with skin.
H314 – Causes severe skin burns and eye damage.
H317 – May cause an allergic skin reaction.
H412 – Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP)
:P260 – Do not breathe vapours.
P264 – Wash hands thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear eye protection, protective clothing, protective gloves.
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
NameProduct identifier%Classification according to
Regulation (EC) No.
1272/2008 [CLP]
3-aminomethyl-3,5,5-trimethylcyclohexylamine(CAS-No.) 2855-13-2
(EC-No.) 220-666-8
(EC Index-No.) 612-067-00-9
(REACH-no) 01-2119514687-32
50Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Dermal), H312
Skin Corr. 1B, H314
Skin Sens. 1, H317
Aquatic Chronic 3, H412
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general
:Call a physician immediately.
First-aid measures after inhalation
:Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact
:Rinse skin with water/shower. Take off immediately all contaminated clothing. Call a
physician immediately.
First-aid measures after eye contact
:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Call a physician immediately.
First-aid measures after ingestion
:Rinse mouth. Do not induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact
:Burns. May cause an allergic skin reaction.
Symptoms/effects after eye contact
:Serious damage to eyes.
Symptoms/effects after ingestion
:Burns.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
:Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media
:Do not use a heavy water stream.
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 3/9
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of fire
:Toxic fumes may be released.
5.3. Advice for firefighters
Precautionary measures fire
:Evacuate area.
Firefighting instructions
:Exercise caution when fighting any chemical fire.
Protection during firefighting
:Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
Other information
:Collect contaminated fire fighting water seperately. It must not enter drains.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment
:Protective clothing.
Emergency procedures
:Ventilate spillage area. Avoid contact with skin, eyes and clothing. Do not breathe vapours.
6.1.2. For emergency responders
Protective equipment
:Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: “Exposure controls/personal protection”.
Emergency procedures
:Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment
:Collect spillage.
Methods for cleaning up
:Take up liquid spill into absorbent material.
Other information
:Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13. For further information refer to section 8: “Exposure controls/personal protection”.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling
:Ensure good ventilation of the work station. Do not get in eyes, on skin, or on clothing. Wear
personal protective equipment. Do not breathe vapours.
Hygiene measures
:Wash contaminated clothing before reuse. Contaminated work clothing should not be
allowed out of the workplace. Do not eat, drink or smoke when using this product. Always
wash hands after handling the product. Separate working clothes from town clothes.
Launder separately. Wash hands and other exposed areas with mild soap and water before
eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions
:Store locked up. Store in a well-ventilated place. Keep cool.
Storage temperature
: 30 C Possible pressure build-up
Storage area
:Store away from heat. Store in a well-ventilated place.
Special rules on packaging
:Keep only in original container.
7.3. Specific end use(s)
No additional information available
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 4/9
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Exposure controls
Appropriate engineering controls:
Ensure good ventilation of the work station.
Hand protection:Protective glovesTypeMaterialPermeationThickness (mm)PenetrationStandardDisposable glovesNitrile rubber (NBR)EN ISO 374Eye protection:Safety glassesSkin and body protection:Wear suitable protective clothingTypeStandardTyvek Gown/CoverallsEN 13034Respiratory protection:In case of insufficient ventilation, wear suitable respiratory equipment. Where exposure through inhalation may occur from use, respiratory
protection equipment is recommended
Device Filter typeConditionStandardDisposable half maskGas/vapour filterVapour protectionEN 405
Personal protective equipment symbol(s):
Environmental exposure controls:
Avoid release to the environment.
Other information:
Industrial and professional. Perform risk assessment prior to use. Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
:Liquid
Appearance
:Colorless liquid.
Colour
:clear.
Odour
:Amine-like.
Odour threshold
:No data available
pH
: 11.5
Relative evaporation rate (butylacetate=1)
:No data available
Melting point
:Not applicable
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 5/9
Freezing point
:No data available
Boiling point
:No data available
Flash point
:> 112 C
Auto-ignition temperature
:No data available
Decomposition temperature
:No data available
Flammability (solid, gas)
:Not applicable
Vapour pressure
:No data available
Relative vapour density at 20 C
:No data available
Relative density
:No data available
Density
:0.974 g/cm
Solubility
:No data available
Partition coefficient n-octanol/water (Log Pow)
:No data available
Viscosity, kinematic
:31.211 mm /s
Viscosity, dynamic
:30.4 cP
Explosive properties
:Product is not explosive.
Oxidising properties
:No data available
Explosive limits
:No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport. Product is not explosive.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral)
:Harmful if swallowed or in contact with skin.
Acute toxicity (dermal)
:Harmful in contact with skin or if inhaled.
Acute toxicity (inhalation)
:Not classified
T-Prime 130-1 Hardener ATE CLP (oral)506.57 mg/kg bodyweightATE CLP (dermal)1114.454 mg/kg bodyweight3-aminomethyl-3,5,5-trimethylcyclohexylamine (2855-13-2)LD50 oral rat1030 mg/kg
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 6/9
LD50 dermal rat> 2000 mg/kgLC50 inhalation rat (Dust/Mist – mg/l/4h)5.01 mg/l/4h
Skin corrosion/irritation
:Causes severe skin burns.
pH: 11.5
Serious eye damage/irritation
:Causes serious eye damage.
pH: 11.5
Respiratory or skin sensitisation
:May cause an allergic skin reaction.
Germ cell mutagenicity
:Not classified
Carcinogenicity
:Not classified
Reproductive toxicity
:Not classified
STOT-single exposure
:Not classified
STOT-repeated exposure
:Not classified
Aspiration hazard
:Not classified
T-Prime 130-1 Hardener Viscosity, kinematic31.211 mm /s
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general
:Harmful to aquatic life with long lasting effects.
Hazardous to the aquatic environment, short-term
(acute)
:Not classified
Hazardous to the aquatic environment, long-term
(chronic)
:Harmful to aquatic life with long lasting effects.
3-aminomethyl-3,5,5-trimethylcyclohexylamine (2855-13-2)EC50 Daphnia 114.6 21.5 mg/l (48 h – Species: Daphnia magna [semi-static])EC50 72h algae (1)37 mg/l (Species: Desmodesmus subspicatus)
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
3-aminomethyl-3,5,5-trimethylcyclohexylamine (2855-13-2)Partition coefficient n-octanol/water (Log Pow)0.79 (at 23 C)
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 7/9
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste)
:Disposal must be done according to official regulations.
Waste treatment methods
:Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations
:Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations.
Ecology – waste materials
:Avoid release to the environment.
European List of Waste (LoW) code
:08 04 09* – waste adhesives and sealants containing organic solvents or other dangerous
substances
SECTION 14: Transport information
In accordance with ADR / IATA / IMDG
ADRIMDG IATA14.1. UN numberUN 2289UN 2289 UN 228914.2. UN proper shipping nameISOPHORONEDIAMINEISOPHORONEDIAMINE IsophoronediamineTransport document descriptionUN 2289
ISOPHORONEDIAMINE, 8,
III, (E)
UN 2289
ISOPHORONEDIAMINE, 8,
III
UN 2289 Isophoronediamine, 8, III14.3. Transport hazard class(es)88 8
14.4. Packing groupIIIIII III14.5. Environmental hazardsDangerous for the
environment : No
Dangerous for the
environment : No
Marine pollutant : No
Dangerous for the environment : NoNo supplementary information available
14.6. Special precautions for user
Overland transport
Classification code (ADR)
:C7
Limited quantities (ADR)
:5l
Excepted quantities (ADR)
:E1
Packing instructions (ADR)
:P001, IBC03, LP01, R001
Mixed packing provisions (ADR)
:MP19
Portable tank and bulk container instructions (ADR)
:T4
Portable tank and bulk container special provisions
(ADR)
:TP1
Tank code (ADR)
:L4BN
Vehicle for tank carriage
:AT
Transport category (ADR)
:3
Special provisions for carriage – Packages (ADR)
:V12
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 8/9
Hazard identification number (Kemler No.)
:80
Orange plates
:
Tunnel restriction code (ADR)
:E
EAC code
:2X
Transport by sea
Limited quantities (IMDG)
:5 L
Excepted quantities (IMDG)
:E1
Packing instructions (IMDG)
:P001, LP01
IBC packing instructions (IMDG)
:IBC03
Tank instructions (IMDG)
:T4
Tank special provisions (IMDG)
:TP1
EmS-No. (Fire)
:F-A
EmS-No. (Spillage)
:S-B
Stowage category (IMDG)
:A
Properties and observations (IMDG)
:Colourless, slightly hygroscopic liquid with a slight amine odour. Combustible. Miscible with
water. Harmful if swallowed. Irritating to skin, eyes and mucous membranes.
Air transport
PCA Excepted quantities (IATA)
:E1
PCA Limited quantities (IATA)
:Y841
PCA limited quantity max net quantity (IATA)
:1L
PCA packing instructions (IATA)
:852
PCA max net quantity (IATA)
:5L
CAO packing instructions (IATA)
:856
CAO max net quantity (IATA)
:60L
ERG code (IATA)
:8L
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export
and import of hazardous chemicals.
Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent
organic pollutants
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Full text of H- and EUH-statements:Acute Tox. 4 (Dermal)Acute toxicity (dermal), Category 4Acute Tox. 4 (Oral)Acute toxicity (oral), Category 4Aquatic Chronic 3Hazardous to the aquatic environment Chronic Hazard, Category 3
T-Prime 130-1 Hardener
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/4/2020 (Version: 1.10)EN (English) 9/9
Skin Corr. 1BSkin corrosion/irritation, Category 1, Sub-Category 1BSkin Sens. 1Skin sensitisation, Category 1H302Harmful if swallowed.H312Harmful in contact with skin.H314Causes severe skin burns and eye damage.H317May cause an allergic skin reaction.H318Causes serious eye damage.H412Harmful to aquatic life with long lasting effects.Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:Acute Tox. 4 (Oral)H302Calculation methodAcute Tox. 4 (Dermal)H312Calculation methodSkin Corr. 1BH314Calculation methodEye Dam. 1H318Calculation methodSkin Sens. 1H317Calculation methodAquatic Chronic 3H412Calculation method
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product The information contained within this
document is Gurit copyright and any distribution or publication beyond the recipient’s organisation is prohibited without Gurit’s prior written consent.