PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 12/05/2016 Revision date: 01/25/2019 Version: SBE-262-2019a
01/25/2019 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixture
Product name : PRO-SET SBE-262 Hardener
Product code : SBE-262, SBE-262-1, SBE-262-2, SBE-262-4, SBE-262-G
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Oral)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
Aquatic Acute 3
Aquatic Chronic 3
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful to aquatic life with long lasting
effects.
Precautionary statements (GHS)
:
Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Store locked up.
Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international
regulation.
Other hazards
No additional information available.
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 2/8
Unknown acute toxicity
No additional information available.
SECTION 3: Composition/information on ingredients
Substances
Not applicable
Mixtures
Name Product identifier HPR %
Trimethylhexamethylenediamine
(CAS-No.) 25620-58-0 10 – 30
Benzyl alcohol
(CAS-No.) 100-51-6 10 – 30
1,3-Cyclohexanedimethanamine
(CAS-No.) 2579-20-6 10 – 30
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-
cyclohexanedimethanamine
(CAS-No.) 60112-98-3 10 – 30
Diethylene glycol bis(3-aminopropyl) ether
(CAS-No.) 4246-51-9 1 – 5
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with
2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine
(CAS-No.) 111850-23-8 3 – 7
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate
(CAS-No.) 41556-26-7 0.1 – 1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory tract irritation.
Symptoms/effects after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/effects after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Nitrogen oxides.
Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. Phenolics. When mixed with sawdust,
wood chips, or other cellulosic material, spontaneous combustion can occur under certain
conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
Reactivity : No dangerous reactions known under normal conditions of use.
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 3/8
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
No additional information available
Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or
other combustible absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray.
Do not swallow. Handle and open container with care. Do not eat, drink or smoke when using
this product. Use personal protective equipment as required. When mixed with epoxy resin this
product causes an exothermic reaction, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in
composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature: 40 F (4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Trimethylhexamethylenediamine (25620-58-0)
Not applicable
Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm
1,3-Cyclohexanedimethanamine (2579-20-6)
Not applicable
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
Not applicable
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
ACGIH ACGIH Ceiling (mg/m ) 1 mg/m
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
Not applicable
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 4/8
Diethylene glycol bis(3-aminopropyl) ether (4246-51-9)
Not applicable
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle in accordance with good industrial hygiene and
safety procedures.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : No data available
Colour : Clear
Odour : Ammonia-like
Odour threshold : No data available
pH : 12.28
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C)
Flash point : > 200 F (93 C) Estimated based similar product.
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 C : No data available
Relative density : 0.99
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : 108 mm /s @ 68 F (20 C)
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
Other information
VOC content : SBE-160 / SBE-262: 10.38 g/L (0.09 lbs/gal)
SBE-163 / SBE-262: 10.38 g/L (0.09 lbs/gal)
SBE-166 / SBE-262: 11.03 g/L (0.09 lbs/gal)
Bulk density : 825 lb/gal (0.99 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reactions known under normal conditions of use.
Chemical stability : Stable under normal conditions.
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 5/8
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon. Nitrogen oxides. Amines. Ammonia. Nitric
acid. Aldehydes. Nitrosamines. Phenolics.
SECTION 11: Toxicological information
Information on toxicological effects
Trimethylhexamethylenediamine (25620-58-0)
LD50 oral rat 910 mg/kg
Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
LC50 inhalation rat > 4.18 mg/l/4h
1,3-Cyclohexanedimethanamine (2579-20-6)
LD50 oral rat 700 – 780 mg/kg
LD50 dermal rabbit 1700 mg/kg
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
LD50 oral rat 700 – 780 mg/kg
LD50 dermal rabbit 1700 mg/kg
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LD50 oral rat 2615 mg/kg
Diethylene glycol bis(3-aminopropyl) ether (4246-51-9)
LD50 oral rat 4290 mg/kg
Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Not classified.
STOT-single exposure : Not classified.
STOT-repeated exposure : Not classified.
Aspiration hazard : Not classified.
PRO-SET SBE-262 Hardener
Viscosity, kinematic (calculated value) (40 C) 108 mm /s @ 68 F (20 C)
Symptoms/effects after inhalation : May cause respiratory tract irritation.
Symptoms/effects after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/effects after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Harmful to aquatic life with long lasting effects.
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 6/8
Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LC50 fish 1 0.97 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])
Persistence and degradability
PRO-SET SBE-262 Hardener
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET SBE-262 Hardener
Bioaccumulative potential Not established.
Trimethylhexamethylenediamine (25620-58-0)
Partition coefficient n-octanol/water 0.77 (at 23 C)
Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
Partition coefficient n-octanol/water 0.37 (at 25 C)
Mobility in soil
PRO-SET SBE-262 Hardener
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name CAS# Ecotoxicity Classification Information
Trimethylhexane-1,6-diamine 25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Benzyl alcohol 100-51-6 Not classified
1,3-cyclohexanedimethanamine 2579-20-6 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Phenol, 4,4′-(1-methylethylidene) bis-, polymer with 2-
(chromethyl) oxirane and 1,3-cyclohexanedimethanamine
60112-98-3 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin, bisphenol A, and
trimethylhexane-1,6-diamine
111850-23-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
3,3′-(Oxybis(2,1-ethane-diyloxy))bis-1-propanamine 4246-51-9 No data available
Decanedioic acid, 1, 10-bis(1,2,2,6,6-pentamethyl-4-
piperidinyl) ester
41556-26-7 No data available
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: This material must be disposed of in accordance with all local, state, provincial, and federal
regulations. The generation of waste should be avoided or minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (1,3-cyclohexanedimethanamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : III
Marine Pollutant No
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 7/8
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (1,3-cyclohexanedimethanamine)
Class (IMDG) : 8
EmS Number : F-A, S-B
Packing group (IMDG) : III
Marine Pollutant No
Transport by air
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (1,3-cyclohexanedimethanamine)
Class (IATA) : 8
Packing group (IATA) : III
Marine Pollutant No
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
EPA TSCA Regulatory Flag N – N – indicates a polymeric substance containing no free-radical initiator in its Inventory
name but is considered to cover the designated polymer made with any free-radical initiator
regardless of the amount used.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
International regulations
No additional information available
US State regulations
California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
Trimethylhexamethylenediamine (25620-58-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 12/05/2016
Revision date : 01/25/2019
Other information : None.
PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English) 8/8
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
Hazard Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.