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Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date: 211112020
Version: 8
Language: en-US
Date of first version: 5/2112015
Page: 1of 8
ADVANCED MATERIALS 6NOUP
1. Product and company identification
Product identifier
Trade name: ReleaSe FilmS
Wrightlon@ 5200, 44000, 44000 LFST, Airtech MR1/MR2, RF242, RF260, TF125,
Wrightlon@ 4500.
Relevant identified uses of the substance or mixture and uses advised against
General use: ArtiCle: ReleaSe Film
Details of the supplier of the safety data sheet
companv name:
Airtech lnternational, lnc.
5700 Skylab Road
Huntington Beach, CA 92647
E-mail: airtech@airtechintl.com
Website: www. airtechon line. com
Telephone: +1 714.899.81 00
Department responsible for
information:
Telephone: +1 714.899.8100
E-mail: airtech@airtechintl.com
Tygavac Advanced Materials Ltd.
The Causeway
Broadway Business Park
Chadderton, Oldham
OLg
gXD
United Kingdom
Website: www.tygavac. co. u k
Telephone: +44 161.947.1610
Department responsible for
information:
Telephone: +44 161.947.1610
E-mail: sales@tygavac.co.uk
Emergency phone number
CHEMTREC EMERGENCY PHONE:
Within USA/Canada: 1 -(800)424-9300
lnternational: +1 7 O3-7 41 -5970
Airtech Europe Sarl
Zone industrielle Haneboesch
L-4562 Differdange
Luxembourg
Website: www.airtech.lu
Telephone: +352 582.282
Depadment responsible for information
Telephone: +352 582.282
E-mail: sales@airtech.lu
Airtech Asia Ltd.
No. 161 ofAnyuan Rd
Chagugang County
Wuqing District
301721, Tianjin, P.R. China
Website: www.airtech.asia
Telephone: +86 22 8862 9800
Telefax:: +8622 8862 9900
Department responsible for information:
Telephone: +86 22 8862 9800
E-mail: airtech.asia@airtechasia.com.cn
2. Hazards identification
Emergency overview
Appearance: FOfm: SOlid
Color:varying
odor: OdOfleSS
classification: Article not subject to hazard labelling or classification.
Regulatory status
This material is not considered hazardous by the U.S. OSHA Hazard Communication
Standard (29 CFR 1910.1200).
&fffiT#tr#f
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date: 211112020
Version. 8
Language: en-US
Date of first version: 5/2’ll2015
Page 2ofg
ADVANCE D MATENNLS GROUP
Hazards not otherwise classified
Toxic fumes may be emitted at elevated temperatures. Do not breathe vapor. lnhalation of
fumes from burning or heating may cause polymer fume fever, a temporary flu-like
illness with fever and chills. Processing, e.g. by cutting, sawing or grinding, can produce
particles and dust. Avoid inhalation of dusts, as even inert dusts may functionally affect
respiratory organs.
see section 11: Toxicological information
3. Composition / lnformation on ingredients
Chemical characterization:
Article: Thermoplastic film
*
Hazardous ingredients: applies only to WL4500
Relevant ingredients:
4. First aid measures
lncaseof inhalation: ln caSe Of inhalatiOn Of decomposition prOducts, affected person should be moved into
fresh air and kept still. lf the casualty has difficulty breathing, call a doctor immediately.
Fottowins skin contact: RemOve residueS With soap and water. After contact with molten product, cool skin area
rapidly with cold water. Do not peel solidified product off the skin. Seek medical attention.
Aftereyecontact: ln the event of irritation from processing vapors: lmmediately flush eyes with plenty of
flowing water for 10 to 15 minutes holding eyelids apart. ln case of troubles or persistent
symptoms, consult an opthalmologist.
After swallowing: NOt a prObable rOUte Of eXpOSUre.
ln the case of the formation of dust: Rinse mouth. Seek medical treatment in case of
troubles.
Most important symptoms/effects, acute and delayed
ln case of inhalation:
lnhalation of dust may cause irritation of the respiratory system. lnhalation of fumes from
burning or heating may cause polymer fume fever, a temporary flu-like illness with fever
and chills. The following symptoms may occur: lrritation of nose, throat, lung cough,
discomfort, shorlage of breath, headache, dizziness, nausea, vomiting. Symptoms
usually appear after 2 hours and decline within the next 36 to 48 hours. ln case of
prolonged exposure: Possible danger of damage to liver and kidneys.
After contact with skin: Thermal decomposition products or aerosols can cause irritation.
Other symptoms: ltching redness of the skin and oedema (swelling).
The melted product can cause severe burns.
After eye contact:
Process vapors can irritate the eyes. Dust contact with the eyes can lead to mechanical
irritation.
lnformation to physician
Treat symptomatically.
CAS No. Desiqnation Content Classification
CAS 127-19-5 N,N-Dimethylacetamide < 1 % Acute Toxicity - dermal - Category 4.
Acute Toxicity - inhalative - Category 4.
Eye lrritation - Category 2A. Reproductive toxicant -
Category 18.
A{ffiTtrtr&f
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date: 211112020
Version: 8
Language: en-US
Date of first vercton: 512112015
Page 3ofB
ADVANCED MATERIALS G BOUP
5. Fire fighting measures
Flash point/flash point range:
No data available
Auto-ignition temperature:
No data available
Suitable extinguishing media:
Water spray jet, dry chemical powder, foam, carbon dioxide
Extinguishing media which must not be used for safety reasons:
Fullwater jet.
Specific hazards arising from the chemical
This material is combustible, but will not ignite readily. Toxic fumes may be emitted at
elevated temperatures.
ln case of fire may be liberated: Hydrogen fluoride, Carbonyl difluoride,
Tetrafluoroethylene, Hexafluoropropylene, Perfluoroisobutylene, Carbon monoxide and
carbon dioxide.
Protective equipment and precautions for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing.
Additional information: Seal off endangered area. Cool endangered containers with water spray and, if possible,
remove from danger zone. Use a water fog to control vapors. Do not breathe fumes. Do
not allow fire water to penetrate into surface or ground water.
6. Accidental release measures
Personal precautions: Handle in accordance with good industrial hygiene and safety praCtiCe.
At processing: Avoid the formation of aerosol/vapors. Avoid dust formation. Avoid
inhalation and contact with skin and eyes. Wear appropriate protective equipment. Keep
unprotected people away. Ensure adequate ventilation, especially in confined areas.
Environmental precautions:
Do not allow to penetrate into soil, waterbodies or drains.
Methods for ctean-up: Take up mechanically, placing in appropriate containers for disposal. Dispose of waste
according to applicable legislation.
7. Handling and storage
Handling
Advices on safe handlins: Handle in acCordance with good industrial hygiene and Safety practice.
At processing: Provide adequate ventilation, and local exhaust as needed. Avoid dust
formation. Avoid the formation of aerosol/vapors. Avoid inhalation and contact with skin
and eyes. Wear appropriate protective equipment. Keep unprotected people away.
When using do not eat, drink or smoke.
Precautions against fire and explosion:
Take standard precautions to prevent fire.
Storage
Requirements for storerooms and containers:
Keep in a cool place. Keep container dry. Protect from direct sunlight. Keep away from
incompatible materials. Store at room temperature.
Hints on joint storase: lncompatible materials: Strong bases, strong acids, strong oxidizing agents.
Keep away from food and drinks.
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ADVANCED MATERIAL.5 GfIOUP
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date:
Version:
Lang u ag e:
Date of first version
2t11t2020
8
en-US
5t21t2015
Page 4of8
8. Exposure controls / personal protection
Exposure guidelines
Occupational exposure limit values:
CAS No. Desiqnation Tvpe Limit value
Release Films
127-19-5 N,N-
Dimethylacetamide
USA:ACGIH:TWA
USA- ACGIH:TWA
USA: OSHA: TWA
USA: OSHA: TWA
USA:ACGIH:TWA
USA: NIOSH:TWA
USA: OSHA:TWA
10 rng/m"
(Dust limit value, inhalable fraction)
3 mg/m3
(Dust limit value, respirable fraction)
15 mg/m"
(Dust limit value, inhalable fraction)
5 mg/m"
(Dust limit value, respirable fraction)
10 ppm
(may be absorbed through the skin)
35 mg/m"; 10 ppm
(may be absorbed through the skin)
35 mg/m"; 10 ppm
(may be absorbed through the skin)
Biological limit values
CAS No. Desiqnation Tvpe Limit value Parameter Samplinq
127-19-5 N,N- USA:
Dimethylacetamide ACGIH-BEl,
unne
30 mg/g creatinine N- end of shift at end
Methylacetamide of workweek
Engineering controls
Provide good ventilation and/or an exhaust system in the work area.
ln case of development of vapors or dust (at processing): Use local exhaust.
See also information in chapter 7, section storage.
Personal protection equipment (PPE)
Eye/face protection: At processing (recommended): Safety glasses in accordance with OSHA 29 CFR:
1 91 0. 1 33 or ANSI 287.1-2010.
skin protection: At processing (recommended): Wear suitable protective clothing.
Recommendation:
Protective gloves according to OSHA Standard - 29 CFR: 1910.138.
Glove material: nitrile rubber, neoprene (0.11 mm)
Breakthrough time: >480 min.
Observe glove manufacturer’s instructions concerning penetrability and breakthrough time
Respiratory protection: Respiratory protection is not necessary if room is well ventilated.
At processing:
When vapors form, use respiratory protection. The filter class must be suitable for the
maximum contaminant concentration (gas/vapour/aerosol/particulates) that may arise
when handling the product. lf the concentration is exceeded, self-contained breathing
apparatus must be used.
General hygiene considerataons:
Handle in accordance with good industrial hygiene and safety practice. Wash hands
before breaks and after work. When using do not eat, drink or smoke.
At processing.
Avoid contactwith skin, eyes, and clothing. Do not breathe vapor. Do not breathe dust.
ffisffiY#tr&g
ADVANCED MATENIALS GROUP
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date:
Version:
Language.
Date of first version
2t11 12020
B
en-US
5t21t2015
Page: 5 of 8
9. Physical and chemical properties
Information on basic physical and chemical properties
Appearance: FOfm: SOlid
Color:varying
Odor: OdOrleSS
odor threshold: NO data aVailable
pH value:
Melting point/freezing point:
lnitial boiling point and boiling range:
Flash point/flash point range:
Evaporation rate:
Flammability:
Explosion limits:
Vapor pressure:
Vapor density:
Density:
Water solubility:
Partition coeffrcient: n-octanol/water:
Auto-ignition temperature:
Thermal decomposition:
No data available
No data available
No data available
No data available
No data available
This material is combustible, but will not ignite readily
No data available
No data available
No data available
No data available
insoluble
No data available
No data available
No data available
Additional information: No data available
10. Stability and reactivity
Reactivity: Refer to section: Possibility of hazardous reactions.
chemical stability: Stable under recommended storage conditiOnS.
Possibility of hazardous reactions:
No dangerous reactions with proper and specified storage and handling
conditions to avoid: Keep away from heat. Protect from direct sunlight. Avoid generation of dust. Avoid the
formation of aerosol/vapors.
lncompatible materials: StrOng baSeS, StrOng aCidS, StrOng Oxidizing agentS.
Hazardous decomposition products:
Toxic fumes may be emitted at elevated temperatures.
> 270 “C: Hydrogen fluoride; > 380 ‘C: Carbonyl difluoride, Tetrafluoroethylene,
Hexafluoropropylene, Perfluoroisobutylene, carbon monoxide and carbon dioxide.
Thermal decomposition: NO data aVailable
A{ffiYtrtrF:f
ADVANCED ilTATERIALS 6NOUP
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date:
Version:
Language:
Date of first version
2t11t2020
8
en-US
5121 12015
Page 6ofB
1 1. Toxicological information
Toxicological tests
roxicolosical effects: The statements are derived from the propedies of the single components. No tOxicOlogical
data is available for the product as such.
Acute toxicity (oral): Lack of data.
Acute toxicity (dermal). Lack of data.
Acute toxicity (inhalative): Lack of data.
Skin corrosion/irritation: Lack of data.
Serious eye damage/irritation: Lack of data.
Sensitisation to the respiratory tract: Lack of data.
Skin sensitisation: Lack of data.
Germ cell mutagenicity/Genotoxicity: Lack of data.
Carcinogenicity: Lack of data.
Reproductive toxicity: Lack of data.
Effects on or via lactation: Lack of data.
Specific target organ toxicity (single exposure): Lack of data.
Specific target organ toxicity (repeated exposure): Lack of data.
Aspiration hazard: Lack of data.
other information: Toxic fumes may be emitted at elevated temperatures. Processing, e.g. by cutting,
sawing or grinding, can produce particles and dust. Dust may irritate ainrvays and cause
bronchitis symptoms.
Symptoms
ln case of inhalation:
lnhalation of dust may cause irritation of the respiratory system. lnhalation of fumes from
burning or heating may cause polymer fume fever, a temporary flu-like illness with fever
and chills. The following symptoms may occur: lrritation of nose, throat, lung cough,
discomfort, shortage of breath, headache, dizziness, nausea, vomiting. Symptoms
usually appear after 2 hours and decline within the next 36 to 48 hours. ln case of
prolonged exposure: Possible danger of damage to liver and kidneys.
After contact with skin: Thermal decomposition products or aerosols can cause irritation.
Other symptoms: ltching redness of the skin and oedema (swelling).
The melted product can cause severe burns.
After eye contact:
Process vapors can irritate the eyes. Dust contact with the eyes can lead to mechanical
irritation.
12. Ecolog ical information
Ecotoxicity
Effects in sewase planls: The insoluble part can be precipitated mechanically in suitable sewage treatment plants.
Further details: NO data available
Mobility in soil
No data available
Persistence and degradability
Further details: ProdUCt iS not biOdegradable.
ffi9ffiTfftr&s
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date: 211112020
Version: I
Language: en-US
Date of first version: 5121 12015
Page: 7 of I
ABVANCE D MATEN|ALS GNOUP
Additional ecological information
ceneral information: DO nOt allOw tO penetrate intO sOil, waterbOdieS Or drainS
1 3. Disposal considerations
Product
Recommendation: Disposal of fluoropolymer containing wastes must follow applicable federal, state and local
regulations.
Waste must not be mixed with domestic or industrial waste that will be incinerated unless
the facilities are equipped and permitted to handle acidic combustion products. Preferred
options for disposal are recycling and landfill. lncinerate only if the incinerator is fitted
and permitted to scrub out hydrogen fluoride and other acidic combustion gases.
Gontaminated packaging
Recommendation: Dispose of waste according to applicable legislation. Handle contaminated packages in
the same way as the substance itself. Non-contaminated packages may be recycled. Do
not remove label until container is thoroughly cleaned.
1 4. T ransport i nformation
USA: Department of Transportation (DOT)
Proper shipping name: NOt feStfiCted
Sea transport (IMDG)
Proper shipping name: NOt feStriCted
Marine pollutant:
nO
Air transport (IATA)
Proper shipping name: NOt feStriCted
Further information
No dangerous good in sense of these transport regulations.
1 5. Regulatory information
National regulations – U.S. Federal Regulations
Product: This product is an article as defined by TSCA regulations, and is exempt from
TSCA inventory listing requirements.
N,N-Dimethylacetamide: NIOSH Recommendations:
Occupational Health Guideline: 021 B
National regulations – U.S. State Regulations
N,N-Dimethylacetamide: ldaho Air Pollutant List:
Title 585: AAC: 1.75 – EL: 2,33 – OEL: 35 – Title 586: –
Massachusetts Haz. Substance codes: 2,4,6
Minnesota Haz. Substance:
Codes: AO – Ratings: – Status: –
Pennsylvania Haz. Substance code: –
California Proposition 65: cancer
ffiiffiY#tr#f
Safety information sheet
Voluntary product information following the Safety Data Sheet format
Release Films
Material number 1088
Revision date: 211112020
Version: 8
Language: en-US
Date of first version: 5/21l2015
Page: 8of8
ADVANCED MATERIALS GROUP
National regulations – Great Britain
Hazchem-Code
16. Other information
Hazard rating syslems:
NFPA HaZafd Rating
Health: 1 (Slight)
Fire: 1 (Slight)
Reactivity: 0 (Minimal)
HMIS Version lll Rating:
Health: 1 (Slight)
Flammability: 1 (Slight)
Physical Hazard’. 0 (Minimal)
Personal Protection: X = Consult your supervisor
Abbreviations and acronyms:
ADN: European Agreement concerning the lnternational Carriage of Dangerous Goods
by lnland Watenruays
ADR: European Agreement concerning the lnternational Carriage of Dangerous Goods
by Road
CAS: Chemical Abstracts Service
CFR: Code of Federal Regulations
CLP: Classiflcation, Labelling and Packaging
DMEL: Derived minimal effect level
DNEL: Derived no-effect level
EC: European Community
EN: European Standard
IATA: lnternational Air Transport Association
IBC Code: lnternational Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IMDG Code: lnternational Maritime Dangerous Goods Code
MARPOL: Maritime Pollution: The lnternational Convention for the Prevention of Pollution
from Ships
OSHA: Occupational Safety and Health Administration
PBT: Persistent, bioaccumulative and toxic
PNEC: Predicted no-effect concentration
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals
RID: Regulations Concerning the lnternational Carriage of Dangerous Goods by Rail
SVHC: Substance of Very High Concern
TSCA: Toxic Substance ControlAct
vPvB: Very persistent and very bioaccumulative
Reason of change: Genefal feViSiOn
Department issuing data sheet
contact person: see Section 1: Department respOnsible for information
This data sheet cannot cover all possible situations which the user may experience during processing. Each
aspect of your operation should be examined to determine if, and which additional precautions may be
necessary. All health and safety information contained in this data sheet should be provided to your
employees and customers. lt is your responsibility to develop appropriate workplace instructions and training
programs for employees.
As the conditions and methods of use are beyond our control, we do not assume any responsibility and
expressly disclaim any liability for any use of this product. The information supplied on this safety data sheet
complies with our current level of knowledge as well as with national and EU regulations. All statements or
suggestions are made without warranty, expressed or implied, regarding accuracy of information, the
hazards connected with the use of the product or the results to be obtained from the use thereof.
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