Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01 /201 9
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Dioctyl phthalate
Recommended use of the chemical and restrictions on use
Recommended use : Manufacture of plasticizers.
Plasticizer in the manufacture of PVC resins.
Manufacturer or supplier’s details
Company : Univar Solutions USA, lnc.
Address 3075 Highland Pkwy Suite 200
Downers Grove, lL 60515
United States of America (USA)
Emergency telephone number:
Transport North America: CHEMTREC (1 -800-424-9300
CH EMTREC I NTERNATI ONAL T el # 7 03-527 -3887
Additional Information: Responsible Party: Product Compliance Department
E-mail: SDSNA@univarsolutions.com
SDS Requests: 1 -855-429-2661
Website: www. univarsolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Carcinogenicity
Reproductive toxicity
: Category 2
: Category 1B
GHS labelelements
Hazard pictograms
Signalword
Hazard statements
Danger
H351 Suspected of causing cancer.
H360 May damage fertility or the unborn child
Prevention:
P201 Obtain special instructions before use.
P2O2Do not handle until all safety precautions have been read
and understood.
P2B0 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P308 + P313 lF exposed or concerned: Get medicaladvice/
attention.
Storage:
P405 Store locked up.
Precautionary statements
‘ Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture : Substance
Hazardous components
CAS-No. Chemicalname Weight percent
117-81-7 Dioctvl phthalate 90 – 100
Any Concentration shown as a range is due to batch variation.
Synonyms : bis(2-ethylhexyl),1,2-benzenedicarboxylic acid,
SECTTON 4. FIRST AID MEASURES
General advice :
lf inhaled
ln case of skin contact
ln case of eye contact
lf swallowed
Notes to physician
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance’
Do not leave the victim unattended.
lf unconscious, place in recovery position and seek medical
advice.
lf symptoms persist, call a physician.
lf skin irritation persists, call a physician.
lf on skin, rinse well with water.
lf on clothes, remove clothes.
lmmediately flush eye(s) with plenty of water
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
lf eye irritation persists, consult a specialist.
Clean mouth with water and drink afterwards plenty of water
Do not induce vomiting without medical advice.
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
lf symptoms persist, call a physician.
Take victim immediately to hospital.
Treat symptomatically
SECTION 5. FIREFIGHTING MEASURES
Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards during fire-
fighting
Hazardous combustion prod-
ucts
Specific extinguishing meth-
ods
Further information
Special protective equipment
for firefighters
Water spray
Dry chemical
Carbon dioxide (CO2)
Foam
: High volume water jet
Do not allow run-off from fire fighting to enter drains or water
courses.
Carbon oxides
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Wear self-contained breathing apparatus for firefighting if nec-
essary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : Use personal protective equipment
tive equipment and emer-
gency procedures
Environmental precautions
Methods and materials for
containment and cleaning up
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
lf the product contaminates rivers and lakes or drains inform
respective authorities.
Soak up with inert absorbent material (e.9. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Normal measures for preventive fire protection.
fire and explosion
Advice on safe handling : Do not breathe vapours/dust.
Avoid exposure – obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section B.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Dispose of rinse water in accordance with local and national
regulations.
‘
Univor
”
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
Conditions for safe storage Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Gomponents with workplace control parameters
Personal protective equipment
Respiratory protection
Hand protection
Remarks
No personal respiratory protective equipment normally re-
quired.
ln the case of vapour formation use a respirator with an ap-
proved filter.
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye wash bottle with pure water
Tightly fitting safety goggles
lmpervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday
Eye protection
Skin and body protection
Hygiene measures
CAS-No Components Value type
(Form of
exposure)
Controlparame-
ters / Permissible
concentration
Basis
117-81-7 Dioctvl phthalate TWA 5 mq/m3 ACGIH
TWA 5 mo/m3 NIOSH REL
ST 10 mq/m3 NIOSH REL
TWA 5 mq/m3 OSHA Z-1
TWA 5 mq/m3 OSHA PO
STEL 10 mq/m3 OSHA PO
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : colourless
Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
Odour
Odour Threshold
pH
Freezing Point (Freezing
Point)
Boiling Point (Boiling
poinUboiling range)
Flash point
Evaporation rate
Flammability (solid, gas)
Upper explosion limit
Lower explosion limit
Vapour pressure
Relative vapour density
Relative density
Density
Solubility(ies)
Water solubility
Solubility in other solvents
Partition coefficient: n-
octanol/water
Auto-ignition tem perature
Thermal decomposition
Viscosity
Viscosity, dynamic
Viscosity, kinematic
slight, mild
No data available
No data available
-50 “c (-58 “F)
: 384 “C (723’F)
201 “C (394 ‘F)
Method: closed cup
not determined
No data available
No data available
No data available
> 1.2 mmHg @20″C (68’F)
13.5 @ 20 – 25’C (68 – 77 “F)
(Air = 1.0)
0.985 @ 20’C (68’F)
Reference substance: (water = 1)
0.9622 g/cm3
@20
– 25’C (68 -77 “F)
0.1 – 0.285 g/l soluble
No data available
Pow: 75,858
log Pow: 4.88 – 7.6
370 – 382’C
> 393’C
56.6 mPa.s @ 25’C (77 ‘F)
57.46 mm2ls @25″C
(77 “F)
SECTION 10. STABILITY AND REACTIVITY
.
”
,’ Univor
: (- I ,’
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01 /201 9
Reactivity
Chemical stability
Possibility of hazardous reac-
tions
Conditions to avoid
lncompatible materials
Hazardous decom position
products
Stable under recommended storage conditions.
Stable under normal conditions.
No hazards to be specially mentioned.
Keep away from heat, flame, sparks and other ignition
sources.
Strong oxidizing agents
carbon dioxide and carbon monoxide
SECTION 11. TOXICOLOGICAL INFORMATION
Carcinogenicity
Product:
Carcinogenicity – Assess-
ment
IARC
OSHA
NTP
Reproductive toxicity
Gomponents:
117-81-7l.
Effects on fertility
: Suspected human carcinogens
Group 2B: Possibly carcinogenic to humans
117-81-7 Dioctyl phthalate
No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
Reasonably anticipated to be a human carcinogen
117-81-7 Dioctyl phthalate
Test Type: multigeneration study
Species: Rat, male and female
Application Route: Oral
Dose: 1.5 – 10,000 ppm
General Toxicity – Parent: NOAEL: 300 ppm
General Toxicity F1: NOAEL: 300 ppm
Fertility: NOAEL: 1,000 ppm
Early Embryonic Development: NOAEL: 100 ppm
Sym ptoms: Reduced fertility Testicular effects
Result: Embryotoxic effects and adverse effects on the off-
spring were detected.
Effects on foetal develop- Species: Rat
Univor
Sclutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
ment
Reproductive toxicity – As-
sessment
Teratogenicity – Assessment
Further information
Product:
Remarks: No data available
Application Route: Oral
Dose: 0, 357,666, 586, 1055 mg/kg
Duration of Single Treatment: 21 d
General Toxicity Maternal: NOAEL: 357 mg/kg body weight
Teratogenicity: NOAEL: >= 1,055 mg/kg bodyweight
DevelopmentalToxicity: NOAEL: 357 mg/kg body weight
Symptoms: Maternal toxicity, Reduced number of viable fe-
tuses, Preimplantation loss
Result: Embryotoxic effects and adverse effects on the off-
spring were detected.
Clear evidence of adverse effects on sexual function and fertil-
ity, based on animalexperiments.
Clear evidence of adverse effects on development, based on
animal experiments.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
Product:
Ozone-Depletion Potential
Additional ecological infor-
mation
Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class ll ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B)
An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
Very toxic to aquatic life with long lasting effects.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues
Contaminated packaging
Dispose of in accordance with all applicable local, state and
federal regulations.
For assistance with your waste management needs – including
disposal, recycling and waste stream reduction, contact Uni-
var Solutions ChemCare: 1 -800-909-4897
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
DOT (Department of Transportation) :
UN3082, Environmentally hazardous substances, liquid, n.o.s., (BlS(2-ETHYLHEXYL) PHTHALATE), 9, lll
IATA (lnternational Air Transport Association): Not regulated as a dangerous good
IMDG-Code: Not regulated as a dangerous good
Special Notes: This material is shipped as a Class 9, Packing Group lll when
each package meets or exceeds the reportable quantity, oth-
enrise it may be shipped as not regulated.
SECTION 1 5. REGULATORY INFORMATION
WHMIS Classification : D2A: Very Toxic Material Causing Other Toxic Effects
EPCRA – Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 3′,’11312 Hazards : Carcinogenicity
Reproductive toxicity
Components CAS-No Component RQ
(lbs)
Calculated product RQ
(lbs)
Dioctvl ohthalate 117-81-7 100 100
. ‘ :
Univor
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01 /201 9
SARA 302 No chemicals in this material are subject to the reporting re-
quirements of SARA Title lll, Section 302.
SARA 313 : The following components are subject to reporting levels es-
tablished by SARA Title lll, Section 313:
117-81-7 Dioctyl phthalate
Clean Air Act
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
117-81-7 Dioctyl phthalate
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental
Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI lnter-
mediate or FinalVOC’s (40 CFR 60.489).
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section
31 1, Table 1 16.4A.
This product does not contain any Hazardous Chemicals listed under the U.S, CleanWater Act, Section 311,
Table 1 17.3.
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know
117-81-7 Dioctyl phthalate
Pennsylvania Right To Know
117-81-7 Dioctyl phthalate
California Prop 65
A WenrulruG: This product can expose you to chemicals including Dioctyl phthalate, which
is/are known to the State of California to cause cancer and birth defects or other reproductive
harm. For more information go to www.P65Warnings.ca.gov.
The components of this product are reported in the following inventories:
TSCA : On TSCA lnventory
DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory
NZIoC : On the inventory, or in compliance with the inventory
ENCS : On the inventory, or in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compliance with the inventory
.’ , Univqr
. r- I ..
)oluttons
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01 /201 9
SECTIONl 6. OTHER INFORMATION
NFPA:
Flammability
Legacy SDS:
HMIS III
Special hazard
0 = not significant, 1 =Slight,
2=Moderate,3=High
4=Extreme,*=Chronic
The information accumulated is based on the data of which we are aware and is believed
to be correct as of the date hereof. Since this information may be applied under conditions
beyond our control and with which we may be unfamiliar and since data made become
available subsequently to the date hereof, we do not assume any responsibility for the
results of its use. Recipients are advised to confirm in advance of need that the information
is current, applicable, and suitable to their circumstances. This SDS has been prepared by
U n iva r Sol utions Prod uct Co m plia nce De pa rtm ent (1 -855-429-266 1
)
SDSNA@univarsolutions. com.
Revision Date
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Material number:
16114352,16041615,16040040,16010403,641124,554178,127695,104226,16062074,
16020449,546066,546065,546064,87234,69100,95497,71469,103619,52729,53999,
87 235, 527 1 9, 53996, BB2B 1, 53993, 1 04227, 201 80, 2017 9, 2017 8, 20177
PHYSICAL HAZARD
HEALTH
FLAMMABILITY
Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Govern-
ment lndustrial Hyqienists
LD50 Lethal Dose 50%
AICS Australia, lnventory of Chemical
Substances
LOAEL Lowest Observed Adverse Effect
Level
DSL Canada, Domestic Substances ListNFPA National Fire Protection Aqencv
NDSL Canada, Non-Domestic Substanc-
es List
NIOSH National lnstitute for Occupational
Safety & Health
CNS Central Nervous System NTP National Toxicoloqv Prooram
CAS Chemical Abstract Service NZIoC New Zealand lnventory of Chemi-
cals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
Univor
Solutions
Safety Data Sheet
Dioctyl phthalate
Version 1.3 Revision Date: 09/01/201 9
EGEST EOSCA Generic Exposure Scenar-
io Tool
OSHA Occupational Safety & Health
Administration
EOSCA European Oilfield Specialty Chem-
icals Association
PEL Permissible Exposure Limit
EINECS European lnventory of Existing
Chemical Substances
PICCS Philippines lnventory of Commer-
cial Chemical Substances
MAK Germany Maximum Concentration
Values
PRNT Presumed Not Toxic
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Shortterm Exposure Limit
lc50 lnhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC lnternational Agency for Research
on Cancer
TLV Threshold Limit Value
IECSC lnventory of Existing Chemical
Substances in China
TWA Time Weighted Average
ENCS Japan, lnventory of Existing and
New Chemical Substances
TSCA Toxic Substance Control Act
KECI Korea, Existing Chemical lnventoryUVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Bioloqical Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials
lnformation System
LC50 Lethal Concentration 50%