SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Issue date: 6/23/2015 Revision date: 5/16/2022 Supersedes: 10/7/2019 Version: 2.0
5/16/2022 (Revision date) EN (English US) 1/9
SECTION 1: Identification
1.1. Identification
Product form
: Article
Name
: SA 80 Adhesive Film
1.2. Recommended use and restrictions on use
Recommended use
: The product is intended for professional use
1.3. Supplier
Supplier
Gurit (USA) Inc
115 Broadcommon Road
Rhode Island, 2809
USA
T +1 401 396 5008 (All Technical and Commercial Enquiries)
marine-na@gurit.com – www.Gurit.com
Manufacturer
Gurit (Spain) Ltd
Pol gono Industrial Romica C/K
Parcela 11C, APDO.447
Albacete, 02080
Spain
T +34 967 254 507 – F +34 967 254 005
Regulatory@gurit.com – www.Gurit.com
1.4. Emergency telephone number
Emergency number
: Carechem 24: +1 646 844 7309
Carechem 24 (Toll Free): +1 866 928 0789
Telephone number for use in case of chemical exposure, spillage or fire only.
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS US classification
Skin corrosion/irritation Category 2
H315 Causes skin irritation
Skin sensitization, Category 1
H317 May cause an allergic skin reaction
Hazardous to the aquatic environment Chronic Hazard Category 3
H412 Harmful to aquatic life with long lasting effects
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labeling
Hazard pictograms (GHS US)
:
Signal word (GHS US)
: Warning
Hazard statements (GHS US)
: H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H412 – Harmful to aquatic life with long lasting effects
Precautionary statements (GHS US)
: P261 – Avoid breathing vapors.
P264 – Wash hands thoroughly after handling.
P272 – Contaminated work clothing must not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear protective gloves, protective clothing, eye protection.
P302+P352 – If on skin: Wash with plenty of soap and water.
P321 – Specific treatment (see a doctor on this label).
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5/16/2022 (Revision date) EN (English US) 2/9
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P501 – Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification Phenol, polymer with formaldehyde, glycidyl ether CAS-No.: 28064-14-4 10 50 Skin Irrit. 2, H315
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Formaldehyde, polymer with (chloromethyl)oxirane and phenol CAS-No.: 9003-36-5 10 25 Skin Irrit. 2, H315
Skin Sens. 1, H317
Aquatic Chronic 2, H411
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number
average molecular weight 700)
CAS-No.: 1675-54-3 3 5 Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures after inhalation
: Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact
: Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs:
Get medical advice/attention.
First-aid measures after eye contact
: Rinse eyes with water as a precaution.
First-aid measures after ingestion
: Call a poison center/doctor/physician if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after skin contact
: Irritation. May cause an allergic skin reaction.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media
: Water spray. Dry powder. Foam. Carbon dioxide.
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5/16/2022 (Revision date) EN (English US) 3/9
Unsuitable extinguishing media
: Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Hazardous decomposition products in case of fire
: Toxic fumes may be released.
5.3. Special protective equipment and precautions for fire-fighters
Precautionary measures fire
: Evacuate area.
Firefighting instructions
: Exercise caution when fighting any chemical fire.
Protection during firefighting
: Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
Other information
: Collect contaminated fire fighting water seperately. It must not enter drains.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures
: Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing vapors.
6.1.2. For emergency responders
Protective equipment
: Do not attempt to take action without suitable protective equipment. For further information refer
to section 8: “Exposure controls/personal protection”.
6.2. Environmental precautions
Avoid release to the environment. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment
: Collect spillage.
Methods for cleaning up
: Mechanically recover the product.
Other information
: Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13. For further information refer to section 8: “Exposure controls/personal protection”.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling
: Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal
protective equipment. Avoid breathing vapors. Handle in accordance with good industrial
hygiene and safety practice.
Handling temperature
: 35 ( 0) C
Hygiene measures
: Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed
out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands
after handling the product. Separate working clothes from town clothes. Launder separately.
Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions
: Store in a well-ventilated place. Keep cool.
Maximum storage period
: 2 year
Storage temperature
: -23 13 C
Storage area
: Store away from heat. Store in a well-ventilated place.
Special rules on packaging
: Keep only in original container.
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5/16/2022 (Revision date) EN (English US) 4/9
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
SA 80 Adhesive Film No additional information available
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) No additional information available
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4) No additional information available
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) No additional information available
8.2. Appropriate engineering controls
Appropriate engineering controls
: Ensure good ventilation of the work station.
Environmental exposure controls
: Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Hand protection: Protective gloves. Time of penetration is to be checked with the glove producer Type Material Permeation Thickness (mm) Penetration Disposable gloves Nitrile rubber (NBR)
Eye protection: Safety glasses
Skin and body protection: Wear suitable protective clothing. Long sleeved protective clothing Type Tyvek Gown/Coveralls
Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Where exposure through inhalation may occur from use, respiratory protection
equipment is recommended
Device Filter type Condition Disposable half mask Gas/vapor filter vapor protection
Personal protective equipment symbol(s):
Other information:
Industrial and professional. Perform risk assessment prior to use. Do not eat, drink or smoke during use.
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5/16/2022 (Revision date) EN (English US) 5/9
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
: Solid
Appearance
: Flexible Sheet.
Color
: Green
Odor
: odorless
Odor threshold
: No data available
pH
: Not applicable
Melting point
: Not applicable
Freezing point
: Not applicable
Boiling point
: Not applicable
Flash point
: > 100 C Estimated on the basis of the constituents :
Relative evaporation rate (butyl acetate=1)
: No data available
Flammability (solid, gas)
: > 100 C estimated
Non flammable.
Vapor pressure
: Not applicable
Relative vapor density at 20 C
: Not applicable
Relative density
: No data available
Solubility
: insoluble in water.
Partition coefficient n-octanol/water (Log Pow)
: No data available
Auto-ignition temperature
: Not applicable
Decomposition temperature
: No data available
Viscosity, kinematic
: Not applicable
Viscosity, dynamic
: No data available
Explosion limits
: Not applicable
Explosive properties
: Product is not explosive.
Oxidizing properties
: No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport. Product is not explosive.
10.2. Chemical stability
Stable under normal conditions. Stable at ambient temperature and under normal conditions of use.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
5/16/2022 (Revision date) EN (English US) 6/9
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral)
: Not classified
Acute toxicity (dermal)
: Not classified
Acute toxicity (inhalation)
: Not classified
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) LD50 oral rat > 10000 mg/kg LD50 dermal rat > 2000 mg/kg
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) LD50 oral rat > 2000 mg/kg body weight Animal: rat, Animal sex: female, Guideline: OECD Guideline 420
(Acute Oral Toxicity – Fixed Dose Method)
LD50 dermal rat > 2000 mg/kg body weight Animal: rat, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity), Guideline: EU Method B.3 (Acute Toxicity (Dermal))
Skin corrosion/irritation
: Causes skin irritation.
pH: Not applicable
Serious eye damage/irritation
: Not classified
pH: Not applicable
Respiratory or skin sensitization
: May cause an allergic skin reaction.
Germ cell mutagenicity
: Not classified
Carcinogenicity
: Not classified
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) NOAEL (chronic,oral,animal/male,2 years) 15 mg/kg body weight Animal: rat, Animal sex: male, Guideline: OECD Guideline 453
(Combined Chronic Toxicity / Carcinogenicity Studies), Guideline: EPA OPPTS 870.4300
(Combined Chronic Toxicity / Carcinogenicity), Guideline: other:, Remarks on results: other:
NOAEL (chronic,oral,animal/female,2 years) 100 mg/kg body weight Animal: rat, Animal sex: female, Guideline: OECD Guideline 453
(Combined Chronic Toxicity / Carcinogenicity Studies), Guideline: EPA OPPTS 870.4300
(Combined Chronic Toxicity / Carcinogenicity), Guideline: other:, Remarks on results: other:
IARC group 3 – Not classifiable
Reproductive toxicity
: Not classified
STOT-single exposure
: Not classified
STOT-repeated exposure
: Not classified
Aspiration hazard
: Not classified
Viscosity, kinematic
: Not applicable
Symptoms/effects after skin contact
: Irritation. May cause an allergic skin reaction.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general
: Harmful to aquatic life with long lasting effects.
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) LC50 – Fish [1] < 1 mg/l reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) LC50 - Fish [1] 1.2 mg/l Test organisms (species): Oncorhynchus mykiss (previous name: Salmo gairdneri) LC50 - Fish [2] 2 mg/l SA 80 Adhesive Film Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5/16/2022 (Revision date) EN (English US) 7/9 reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) LOEC (chronic) 1 mg/l Test organisms (species): Daphnia magna Duration: '21 d' NOEC (chronic) 0.3 mg/l Test organisms (species): Daphnia magna Duration: '21 d' 12.2. Persistence and degradability reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) Persistence and degradability May cause long-term adverse effects in the environment. 12.3. Bioaccumulative potential reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Regional legislation (waste) : Disposal must be done according to official regulations. Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. Product/Packaging disposal recommendations : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT / IMDG / IATA DOT IMDG IATA 14.1. UN number Not regulated for transport 14.2. Proper Shipping Name Not applicable Not applicable Not applicable 14.3. Transport hazard class(es) Not applicable Not applicable Not applicable 14.4. Packing group Not applicable Not applicable Not applicable 14.5. Environmental hazards Not applicable Not applicable Not applicable No supplementary information available SA 80 Adhesive Film Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5/16/2022 (Revision date) EN (English US) 8/9 14.6. Special precautions for user DOT No data available IMDG No data available IATA No data available 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture is not known to contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR 372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 15.2. International regulations CANADA Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) Listed on the Canadian DSL (Domestic Substances List) Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4) Listed on the Canadian DSL (Domestic Substances List) reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) Listed on the EU NLP (No Longer Polymers) inventory reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) Listed on the EU NLP (No Longer Polymers) inventory SA 80 Adhesive Film Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 5/16/2022 (Revision date) EN (English US) 9/9 National regulations Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5) Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing New Chemical Substances) inventory Listed on KECL/KECI (Korean Existing Chemicals Inventory) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals) Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4) Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing New Chemical Substances) inventory Listed on KECL/KECI (Korean Existing Chemicals Inventory) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (1675-54-3) Listed introduction on Australian Industrial Chemicals Introduction Scheme (AICIS Inventory) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing New Chemical Substances) inventory Listed on KECL/KECI (Korean Existing Chemicals Inventory) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 05/16/2022 Full text of H-phrases H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects Safety Data Sheet (SDS), USA This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product The information contained within this document is Gurit copyright and any distribution or publication beyond the recipient's organization is prohibited without Gurit's prior written consent.