SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 06/23/2015 Revision date: 06/10/2016 Supersedes: 06/10/2016 Version: 1.3
06/10/2016 USA ()Page 1
SECTION 1: Identification
1.1. Identification
Product form :MixtureName :SA 80 Adhesive Film
1.2. Relevant identified uses of the substance or mixture and uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Gurit (USA) Inc
RHODE ISLAND, 2809 – USA
T 18198689182 – F 001 819 847 2572
marine-na@gurit.com – www.Gurit.com
1.4. Emergency telephone number
Emergency number :+44 (0) 2392 242148
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Skin corrosion/irritation,
Category 2
H315Sensitisation Skin,
Category 1
H317Hazardous to the
aquatic environment
Chronic Hazard,
Category 3
H412
Full text of H statements : see section 16
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS07
Signal word (GHS-US) :WarningHazard statements (GHS-US) :H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H412 – Harmful to aquatic life with long lasting effects
Precautionary statements (GHS-US) :P261 – Avoid breathing fume
P264 – Wash hands thoroughly after handling
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment
P280 – Wear protective gloves, protective clothing, eye protection
P302+P352 – If on skin: Wash with plenty of water
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()2/7NameProduct identifier%GHS-US classificationFormaldehyde, polymer with (chloromethyl)oxirane and phenol(CAS No) 9003-36-525 – 50Skin Irrit. 2, H315
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Bisphenol A diglycidyl ether – bisphenol A copolymer(CAS No) 25036-25-325 – 50Skin Irrit. 2, H315reaction product: bisphenol-A-(epichlorhydrin), epoxy resin
(number average molecular weight 700)
(CAS No) 25068-38-63 – 5Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general :If you feel unwell, seek medical advice (show the label where possible).First-aid measures after inhalation :Move the affected person away from the contaminated area and into the fresh air. Call a
POISON CENTER or doctor/physician if you feel unwell. If breathing is difficult, remove victim
to fresh air and keep at rest in a position comfortable for breathing.
First-aid measures after skin contact :Remove affected clothing and wash all exposed skin area with mild soap and water, followed
by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :Do not induce vomiting. Get immediate medical advice/attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries :Not expected to present a significant hazard under anticipated conditions of normal use.Symptoms/injuries after inhalation :None under normal use.Symptoms/injuries after skin contact :May cause an allergic skin reaction. May cause moderate irritation.Symptoms/injuries after eye contact :May cause slight irritation.Symptoms/injuries after ingestion :None under normal use.Symptoms/injuries upon intravenous
administration
:None under normal use.Chronic symptoms :Skin irritation, dermatitis and sensitisation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media :Carbon dioxide. Dry powder. Foam. Water spray.Unsuitable extinguishing media :Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard :None under normal use.Explosion hazard :None under normal use.Reactivity :Product is not explosive.
5.3. Advice for firefighters
Precautionary measures fire :Evacuate area.Firefighting instructions :Exercise caution when fighting any chemical fire.Protection during firefighting :Self-contained breathing apparatus.Other information :Collect contaminated fire fighting water seperately. It must not enter drains.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1.For non-emergency personnel
Protective equipment :Protective clothing.
6.1.2.For emergency responders
Emergency procedures :Ventilate area.
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()3/7
6.2. Environmental precautions
Avoid release to the environment. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment :Collect spillage.Methods for cleaning up :This material and its container must be disposed of in a safe way, and as per local legislation.
Mechanically recover the product.
6.4. Reference to other sections
For further information refer to section 13. For further information refer to section 8: “Exposure controls/personal protection”.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling :Ensure good ventilation of the work station.Hygiene measures :Do not eat, drink or smoke when using this product. Separate working clothes from town
clothes. Launder separately. Contaminated work clothing should not be allowed out of the
workplace. Wash contaminated clothing before reuse. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions :Keep container closed when not in use. Keep cool. Protect from sunlight.Storage area :Store away from heat. Store in a well-ventilated place.Special rules on packaging :Keep only in original container.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
SA80 ADHESIVE FILM OSHAOSHA PEL (TWA) (mg/m )15 mg/m Assessed dust without specific effect (other
particles, not classified anywhere else)
OSHARemark (OSHA)Use care during processing to minimize generation of
dust
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)Not applicablereaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Not applicableBisphenol A diglycidyl ether – bisphenol A copolymer (25036-25-3)Not applicable
8.2. Exposure controls
Appropriate engineering controls :Ensure good ventilation of the work station.Personal protective equipment :Gloves. Protective clothing. Safety glasses.
Hand protection :Protective gloves.Eye protection :Safety glasses.Environmental exposure controls :Avoid release to the environment.Other information :Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state :Solid
Colour :Green
Odour :odourless characteristic
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()4/7Odour threshold :No data available
pH :No data available
Melting point :No data available
Freezing point :No data available
Boiling point :No data available
Flash point :No data available
Relative evaporation rate (butylacetate=1) :No data available
Flammability (solid, gas) :No data available
Vapour pressure :No data available
Relative vapour density at 20 C :No data available
Relative density :No data available
Solubility :No data available
Log Pow :No data available
Auto-ignition temperature :No data available
Decomposition temperature :No data available
Viscosity, kinematic :No data available
Viscosity, dynamic :No data available
Explosive limits :No data available
Explosive properties :No data available
Oxidising properties :No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1.Reactivity
Product is not explosive.
10.2.Chemical stability
Stable under normal conditions.
10.3.Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4.Conditions to avoid
Heat.
10.5.Incompatible materials
No additional information available
10.6.Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1.Information on toxicological effects
Acute toxicity :Not classifiedFormaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)LD50 oral rat> 2 g/kgreaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)LD50 oral rat11400 mg/kgATE US (oral)11400.000 mg/kg bodyweightSkin corrosion/irritation :Causes skin irritation.Serious eye damage/irritation :Not classifiedRespiratory or skin sensitisation :May cause an allergic skin reaction.Germ cell mutagenicity :Not classifiedCarcinogenicity :Not classified
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()5/7Reproductive toxicity :Not classifiedSpecific target organ toxicity (single exposure):Not classifiedSpecific target organ toxicity (repeated
exposure)
:Not classifiedAspiration hazard :Not classifiedSymptoms/injuries after inhalation :None under normal use.Symptoms/injuries after skin contact :May cause an allergic skin reaction. May cause moderate irritation.Symptoms/injuries after eye contact :May cause slight irritation.Symptoms/injuries after ingestion :None under normal use.Symptoms/injuries upon intravenous
administration
:None under normal use.Chronic symptoms :Skin irritation, dermatitis and sensitisation.
SECTION 12: Ecological information
12.1.Toxicity
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)LC50 fish 1< 1 mg/lreaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)LC50 fish 11.5 mg/lLC50 fish 22 mg/l
12.2.Persistence and degradability
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Persistence and degradabilityMay cause long-term adverse effects in the environment.
12.3.Bioaccumulative potential
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Bioaccumulative potentialNot established.
12.4.Mobility in soil
No additional information available
12.5.Other adverse effects
Effect on the global warming :No known effects from this product.GWPmix comment :No known effects from this product.
SECTION 13: Disposal considerations
13.1.Waste treatment methods
Regional legislation (waste) :Disposal must be done according to official regulations.Waste treatment methods :Dispose of contents/container in accordance with licensed collector s sorting instructions.Waste disposal recommendations :Avoid release to the environment. Dispose in a safe manner in accordance with local/national
regulations.
Ecology - waste materials :Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Not applicable
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()6/7
TDG
Transport by sea
Not applicable
Air transport
Not applicable
SECTION 15: Regulatory information
15.1. US Federal regulations
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)Listed on the United States TSCA (Toxic Substances Control Act) inventoryreaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Listed on the United States TSCA (Toxic Substances Control Act) inventoryBisphenol A diglycidyl ether - bisphenol A copolymer (25036-25-3)Listed on the United States TSCA (Toxic Substances Control Act) inventoryEPA TSCA Regulatory FlagY2 - Y2 - indicates an exempt polymer that is a polyester and is made only from reactants
included in a specified list of low concern reactants that comprises one of the eligibility criteria
for the exemption rule
15.2. International regulations
CANADA
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)Listed on the Canadian DSL (Domestic Substances List)reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Listed on the Canadian DSL (Domestic Substances List)WHMIS ClassificationClass D Division 2 Subdivision B - Toxic material causing other toxic effectsBisphenol A diglycidyl ether - bisphenol A copolymer (25036-25-3)Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)Listed on the EU NLP (No Longer Polymers) inventoryreaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Listed on the EU NLP (No Longer Polymers) inventory
National regulations
Formaldehyde, polymer with (chloromethyl)oxirane and phenol (9003-36-5)Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on INSQ (Mexican national Inventory of Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
reaction product: bisphenol-A-(epichlorhydrin), epoxy resin (number average molecular weight 700) (25068-38-6)Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
Listed on CICR (Turkish Inventory and Control of Chemicals)
SA 80 Adhesive Film
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
06/10/2016 USA ()7/7Bisphenol A diglycidyl ether - bisphenol A copolymer (25036-25-3)Listed on the AICS (Australian Inventory of Chemical Substances)
Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China)
Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory
Listed on the Korean ECL (Existing Chemicals List)
Listed on NZIoC (New Zealand Inventory of Chemicals)
Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances)
15.3. US State regulations
No additional information available
SECTION 16: Other information
Revision date :06/10/2016Full text of H-statements:------H315Causes skin irritation------H317May cause an allergic skin reaction------H319Causes serious eye irritation------H400Very toxic to aquatic life------H411Toxic to aquatic life with long lasting effects------H412Harmful to aquatic life with long lasting effects
SDS US (GHS HazCom 2012)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product