SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

1 / 27
SECTION 1. IDENTIFICATION
Trade name

: NOROX

CHP

CAS-No.

: 80-15-9

Manufacturer or supplier’s details
Company name of supplier

: United Initiators, Inc.

Address

: 555 Garden Street
Elyria OH 44035 USA

Telephone

: +1-440-323-3112

Telefax

: +1-440-323-2659

Emergency telephone

: CHEMTREC US (24h): +1-800-424-9300
CHEMTREC WORLD (24h): +1-703-527-3887

E-mail address of person
responsible for the SDS

: cs-initiators.nafta@united-in.com

Recommended use of the chemical and restrictions on use
Recommended use

: polymerization initiators

SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids

: Category 4
Flammable liquids

: Category 4
Organic peroxides

: Type F
Acute toxicity (Oral)

: Category 4
Acute toxicity (Inhalation)

: Category 3
Acute toxicity (Dermal)

: Category 4
Skin corrosion

: Category 1B
Serious eye damage

: Category 1
Carcinogenicity

: Category 1B

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

2 / 27
Specific target organ toxicity
– single exposure

: Category 3 (Respiratory system)
Specific target organ toxicity
– repeated exposure

: Category 2
Aspiration hazard

: Category 1
Short-term (acute) aquatic
hazard

: Category 2
Long-term (chronic) aquatic
hazard

: Category 2
GHS label elements
Hazard pictograms

:

Signal Word

: Danger

Hazard Statements

: H227 Combustible liquid.
H242 Heating may cause a fire.
H302 + H312 Harmful if swallowed or in contact with skin.
H304 May be fatal if swallowed and enters airways.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H350 May cause cancer.
H373 May cause damage to organs through prolonged or
repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P220 Keep/Store away from clothing/ strong acids, bases,
heavy metal salts and other reducing substances /combustible
materials.
P234 Keep only in original container.
P260 Do not breathe mist or vapors.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

3 / 27
face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/ doctor.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.
P391 Collect spillage.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P405 Store locked up.
P410 Protect from sunlight.
P411 + P235 Store at temperatures not exceeding < 30 C/ < 86 F. Keep cool. P420 Store away from other materials. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Substance Chemical nature : Organic Peroxide Substance name : Cumene hydroperoxide CAS-No. : 80-15-9 Components Chemical name CAS-No. Concentration (% w/w) SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 4 / 27 Cumene hydroperoxide 80-15-9 >= 80 – < 85 Cumene 98-82-8 >= 10 – < 15 Benzenemethanol, alpha,alpha- dimethyl- 617-94-7 >= 1 – < 5 acetophenone 98-86-2 >= 1 – < 5 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Take off contaminated clothing and shoes immediately. Call a physician immediately. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Do not leave the victim unattended. Symptoms of poisoning may appear several hours later. No artificial respiration, mouth-to-mouth or mouth to nose. Use suitable instruments/apparatus. If inhaled : Administer oxygen if breathing is difficult or cyanosis is observed. Call a physician immediately. If breathed in, move person into fresh air. If not breathing, give artificial respiration. Contact a poison control center. Respiratory tract burning possible if aerosols are inhaled. Call a physician or poison control center immediately. If unconscious, place in recovery position and seek medical advice. Keep respiratory tract clear. In case of skin contact : If symptoms persist, call a physician. Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before re-use. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 5 / 27 of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Call a physician immediately. Contact a poison control center. Rinse mouth thoroughly with water. Keep respiratory tract clear. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Harmful if swallowed or in contact with skin. May be fatal if swallowed and enters airways. Causes serious eye damage. Toxic if inhaled. May cause respiratory irritation. May cause cancer. May cause damage to organs through prolonged or repeated exposure. Causes severe burns. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing Notes to physician : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray jet Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during fire fighting : Risk of explosion if heated under confinement. Possible emission of gaseous decomposition products may lead to a dangerous pressure build-up. Avoid confinement. Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self- accelerating decomposition reaction with release of flammable vapors which may auto-ignite. The product burns violently. Flash back possible over considerable distance. Do not allow run-off from fire fighting to enter drains or water courses. SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 6 / 27 Vapors may form explosive mixtures with air. The product will float on water and can be reignited on surface water. Cool closed containers exposed to fire with water spray. Specific extinguishing meth- ods : Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use a water spray to cool fully closed containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Follow safe handling advice and personal protective equipment recommendations. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Never return spills in original containers for re-use. Treat recovered material as described in the section "Disposal considerations". Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Contact with incompatible substances can cause decomposition at or below SADT. Clear spills immediately. Suppress (knock down) gases/vapors/mists with a water spray jet. To clean the floor and all objects contaminated by this material, use plenty of water. Soak up with inert absorbent material. Isolate waste and do not reuse. SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 7 / 27 Non-sparking tools should be used. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Advice on protection against fire and explosion : Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Keep away from combustible material. Do not spray on a naked flame or any incandescent material. Advice on safe handling : Open drum carefully as content may be under pressure. Protect from contamination. Do not swallow. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Avoid formation of aerosol. Take precautionary measures against static discharges. Never return any product to the container from which it was originally removed. Provide sufficient air exchange and/or exhaust in work rooms. Avoid confinement. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Smoking, eating and drinking should be prohibited in the application area. Wash thoroughly after handling. For personal protection see section 8. Conditions for safe storage : Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in cool place. Contamination may result in dangerous pressure increases - closed containers may rupture. Prevent unauthorized access. Observe label precautions. Store in accordance with the particular national regulations. Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Electrical installations / working materials must comply with the technological safety standards. SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 8 / 27 Containers which are opened must be carefully resealed and kept upright to prevent leakage. Materials to avoid : Keep away from strong acids, bases, heavy metal salts and other reducing substances. Recommended storage tem- perature : < 30 C < 86 F Further information on stor- age stability : No decomposition if stored normally. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Cumene hydroperoxide 80-15-9 TWA 1 ppm US WEEL Cumene 98-82-8 TWA 5 ppm ACGIH TWA 50 ppm 245 mg/m3 NIOSH REL TWA 50 ppm 245 mg/m3 OSHA Z-1 TWA 50 ppm 245 mg/m3 OSHA P0 acetophenone 98-86-2 TWA 10 ppm ACGIH TWA 10 ppm US WEEL Engineering measures : Minimize workplace exposure concentrations. Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Filter type : ABEK-filter Use NIOSH approved respiratory protection. Hand protection Material : Nitrile rubber Break through time : < 30 min Glove thickness : 0.40 mm Material : butyl-rubber Break through time : < 30 min Glove thickness : 0.70 mm SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 9 / 27 Remarks : The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be obtained from the producer of the protective glove. Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. Please follow all applicable local/national requirements when selecting protective measures for a specific workplace. Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded. Tightly fitting safety goggles Please wear suitable protective goggles. Also wear face protection if there is a splash hazard. Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Additional body garments should be used based upon the task being performed (e.g., sleevelets, apron, gauntlets, disposable suits) to avoid exposed skin surfaces. Wear as appropriate: Flame retardant antistatic protective clothing. Protective measures : The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures : Avoid contact with skin, eyes and clothing. Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : Colorless to pale yellow SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 10 / 27 Odor : aromatic Odor Threshold : No data available pH : 5 - 6 Melting point/range : -9 C Boiling point/boiling range : 53 C (0.13 hPa) Flash point : ca. 63 C Method: closed cup Flammability (solid, gas) : Not applicable Flammability (liquids) : Flammable liquid Self-ignition : The substance or mixture is not classified as pyrophoric. Upper explosion limit / Upper flammability limit : Upper explosion limit No data available Lower explosion limit / Lower flammability limit : Lower explosion limit No data available Vapor pressure : 0.044 hPa (25 C) Relative vapor density : ca. 5.4 (20 C) Relative density : not determined Density : 1.06 g/cm3 (20 C) Solubility(ies) Water solubility : 13.9 g/l slightly soluble (25 C) Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Autoignition temperature : not determined Self-Accelerating decomposi- tion temperature (SADT) : 80 C Method: UN-Test H.4 SADT-Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-accelerating decomposition reaction. SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 11 / 27 Viscosity Viscosity, dynamic : ca. 12.5 mPa.s (20 C) Viscosity, kinematic : not determined Explosive properties : Not explosive In use, may form flammable/explosive vapor-air mixture. Oxidizing properties : The substance or mixture is not classified as oxidizing. Organic peroxide Self-heating substances : The substance or mixture is not classified as self heating. SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable under recommended storage conditions. Heating may cause a fire or explosion. Chemical stability : Stable under recommended storage conditions. No decomposition if stored normally. Possibility of hazardous reac- tions : Vapors may form explosive mixture with air. Conditions to avoid : Protect from contamination. Contact with incompatible substances can cause decomposition at or below SADT. Heat, flames and sparks. Avoid confinement. Incompatible materials : Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents Hazardous decomposition products : Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Harmful if swallowed or in contact with skin. Toxic if inhaled. Product: Acute oral toxicity : LD50 (Rat): 382 mg/kg Acute inhalation toxicity : LC50: 1.370 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The component/mixture is toxic after short term SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 12 / 27 inhalation. Acute dermal toxicity : LD50: 1,200 - 1,520 mg/kg Assessment: The component/mixture is moderately toxic after single contact with skin. Components: Cumene hydroperoxide: Acute oral toxicity : LD50 Oral (Rat): 382 mg/kg Acute inhalation toxicity : LC50: 1.370 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The component/mixture is toxic after short term inhalation. Acute dermal toxicity : LD50: 1,200 - 1,520 mg/kg Assessment: The component/mixture is moderately toxic after single contact with skin. Cumene: Acute oral toxicity : LD50 (Rat): 2,260 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: No mortality observed at this dose.

Benzenemethanol, alpha,alpha-dimethyl-:
Acute oral toxicity

: Acute toxicity estimate: 500 mg/kg
Assessment: The component/mixture is moderately toxic after
single ingestion.
Remarks: Expert judgment

Acute inhalation toxicity

: Remarks: No data available

Acute dermal toxicity

: LD50: Method: Expert judgment
Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on available data, the classification criteria
are not met.

acetophenone:
Acute oral toxicity

: Acute toxicity estimate: 500.0 mg/kg
Method: Expert judgment
Assessment: The component/mixture is moderately toxic after
single ingestion.

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

13 / 27
Remarks: Based on harmonised classification in EU regulation
1272/2008, Annex VI

Acute dermal toxicity

: LD50 (Rat): 3,300 mg/kg
Method: OECD Test Guideline 402

Skin corrosion/irritation
Causes severe burns.
Product:
Species : Rabbit
Result : Causes burns.

Remarks : Extremely corrosive and destructive to tissue.

Components:
Cumene hydroperoxide:
Species : Rabbit
Result : Causes burns.

Remarks : Extremely corrosive and destructive to tissue.

Cumene:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation

Benzenemethanol, alpha,alpha-dimethyl-:
Species : Rabbit
Result : Severe skin irritation

acetophenone:
Species : Rabbit
Method : OECD Test Guideline 404
Result : No skin irritation

Remarks : May cause skin irritation in susceptible persons.

Serious eye damage/eye irritation
Causes serious eye damage.
Product:
Species : Rabbit
Result : Corrosive

Remarks : May cause irreversible eye damage.

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

14 / 27
Components:
Cumene hydroperoxide:
Species : Rabbit
Result : Corrosive

Remarks : May cause irreversible eye damage.

Cumene:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405

Benzenemethanol, alpha,alpha-dimethyl-:
Result : Irritating to eyes.

acetophenone:
Species : Rabbit
Result : Eye irritation
Method : No information available.
Remarks : Based on harmonised classification in EU regulation
1272/2008, Annex VI

Remarks : May cause irreversible eye damage.

Respiratory or skin sensitization
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Product:
Result : Does not cause skin sensitization.
Remarks : Based on available data, the classification criteria are not met.

Components:
Cumene hydroperoxide:
Result : Does not cause skin sensitization.

Cumene:
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

15 / 27
acetophenone:
Test Type : Draize Test
Routes of exposure : Skin contact
Species : Guinea pig
Result : Does not cause skin sensitization.

Germ cell mutagenicity
Not classified based on available information.
Product:
Genotoxicity in vitro

: Test Type: in vitro test
Test system: Salmonella typhimurium
Result: positive

Genotoxicity in vivo

: Test Type: Micronucleus test
Species: Mouse
Application Route: Skin contact
Result: negative

Components:
Cumene hydroperoxide:
Genotoxicity in vitro

: Test Type: in vitro test
Test system: Salmonella typhimurium
Result: positive

Genotoxicity in vivo

: Test Type: Micronucleus test
Species: Mouse
Application Route: Skin contact
Result: negative

Cumene:
Genotoxicity in vitro

: Method: OECD Test Guideline 473
Result: negative

Method: OECD Test Guideline 471
Result: negative

Method: OECD Test Guideline 476
Result: negative

Method: OECD Test Guideline 482
Result: negative

Test Type: Ames test
Result: positive

Genotoxicity in vivo

: Species: Rat
Application Route: Intraperitoneal
Exposure time: 72 h

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

16 / 27
Method: OECD Test Guideline 474
Result: Equivocal

Species: Mouse
Application Route: inhalation (gas)
Exposure time: 14 w
Method: OECD Test Guideline 474
Result: negative

acetophenone:
Genotoxicity in vitro

: Method: OECD Test Guideline 473
Result: negative

Method: OECD Test Guideline 476
Result: negative

Method: OECD Test Guideline 471
Result: negative

Genotoxicity in vivo

: Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative

Carcinogenicity
May cause cancer.
Product:
Remarks : This information is not available.

Components:
Cumene hydroperoxide:
Remarks : This information is not available.

Cumene:
Species : Rat, male and female
Application Route : inhalation (vapor)
Result : carcinogenic effects

Species : Mouse, male and female
Application Route : inhalation (vapor)
Result : carcinogenic effects

Carcinogenicity – Assess-
ment

: Sufficient evidence of carcinogenicity in animal experiments

IARC Group 2B: Possibly carcinogenic to humans
Cumene 98-82-8

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

17 / 27

OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA s list of regulated carcinogens.

NTP Reasonably anticipated to be a human carcinogen
Cumene 98-82-8

Reproductive toxicity
Not classified based on available information.
Components:
Cumene hydroperoxide:
Effects on fertility

: Remarks: No data available

Effects on fetal development

: Remarks: No data available

Cumene:
Effects on fetal development

: Species: Rabbit
Application Route: inhalation (vapor)
General Toxicity Maternal: LOAEL: 500
Developmental Toxicity: NOAEL: 2,300
Method: OECD Test Guideline 414

acetophenone:
Effects on fertility

: Species: Rat
Application Route: Ingestion
General Toxicity Parent: NOAEL: 225 mg/kg body weight
General Toxicity F1: NOAEL: 225 mg/kg body weight
Method: OECD Test Guideline 422
Result: negative

Species: Rat
Application Route: Ingestion
General Toxicity Parent: LOAEL: 750 mg/kg body weight
General Toxicity F1: LOAEL: 750 mg/kg body weight
Method: OECD Test Guideline 422

Effects on fetal development

: Species: Mouse
Application Route: Ingestion
General Toxicity Maternal: NOAEL: 125 mg/kg body weight
Embryo-fetal toxicity.: NOAEL: 125 mg/kg body weight
Method: OECD Test Guideline 414

STOT-single exposure
May cause respiratory irritation.
Product:
Assessment : May cause respiratory irritation.

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

18 / 27
Components:
Cumene:
Assessment : May cause respiratory irritation.

STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
Product:
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Components:
Cumene hydroperoxide:
Assessment : May cause damage to organs through prolonged or repeated
exposure.

Repeated dose toxicity
Product:
Species : Rat
NOAEC : 31 mg/m
Application Route : inhalation (gas)
Exposure time : 90 d
Method : OECD Test Guideline 413

Components:
Cumene hydroperoxide:
Species : Rat
NOAEC : 31 mg/m
Application Route : inhalation (gas)
Exposure time : 90 d

Cumene:
Species : Rat
NOAEL : 154 mg/kg
Application Route : Oral
Method : OECD Test Guideline 413

acetophenone:
Species : Rat
NOAEL : 225 mg/kg
LOAEL : 750 mg/kg
Application Route : Ingestion
Method : OECD Test Guideline 422

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

19 / 27
Aspiration toxicity
May be fatal if swallowed and enters airways.
Product:
May be fatal if swallowed and enters airways.

Components:
Cumene:
May be fatal if swallowed and enters airways.

Further information
Product:
Remarks : Solvents may degrease the skin.

Components:
acetophenone:
Remarks : No data available

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 18.8 mg/l
Exposure time: 48 h
Test Type: Immobilization
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EC50 (Desmodesmus subspicatus (green algae)): 3.1 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Desmodesmus subspicatus (green algae)): 1 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to microorganisms

: NOEC (Pseudomonas putida): 50 mg/l
End point: Growth rate
Exposure time: 16 h

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

20 / 27
Ecotoxicology Assessment
Acute aquatic toxicity

: Toxic to aquatic life.

Chronic aquatic toxicity

: Toxic to aquatic life with long lasting effects.

Components:
Cumene hydroperoxide:
Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 3.9 mg/l
Exposure time: 96 h
Test Type: semi-static test
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 18.8 mg/l
Exposure time: 48 h
Test Type: Immobilization
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EC50 (Desmodesmus subspicatus (green algae)): 3.1 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Desmodesmus subspicatus (green algae)): 1 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to microorganisms

: NOEC (Pseudomonas putida): 50 mg/l
End point: Growth rate
Exposure time: 16 h

Cumene:
Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 4.8 mg/l
Exposure time: 96 h

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 2.14 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202

Toxicity to algae/aquatic
plants

: EC50 (Desmodesmus subspicatus (green algae)): 2.01 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)

: NOEC (Daphnia magna (Water flea)): 0.35 mg/l
Exposure time: 21 d
Method: OECD Test Guideline 211

Toxicity to microorganisms

: EC50: > 2,000 mg/l
Exposure time: 3 h
Method: OECD Test Guideline 209

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

21 / 27
Ecotoxicology Assessment
Chronic aquatic toxicity

: Toxic to aquatic life with long lasting effects.

Benzenemethanol, alpha,alpha-dimethyl-:
Ecotoxicology Assessment
Acute aquatic toxicity

: This product has no known ecotoxicological effects.

Chronic aquatic toxicity

: This product has no known ecotoxicological effects.

acetophenone:
Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 162 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other
aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 528 mg/l
Exposure time: 48 h

Toxicity to algae/aquatic
plants

: EC50 (Pseudokirchneriella subcapitata (green algae)): 86.4
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

NOEC (Pseudokirchneriella subcapitata (green algae)): 24.8
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

Persistence and degradability
Product:
Biodegradability

: Result: Not readily biodegradable.
Method: OECD Test Guideline 301B

Components:
Cumene hydroperoxide:
Biodegradability

: Result: Not readily biodegradable.
Method: OECD Test Guideline 301B

Cumene:
Biodegradability

: Result: Readily biodegradable.

Benzenemethanol, alpha,alpha-dimethyl-:
Biodegradability

: Remarks: No data available

acetophenone:

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

22 / 27
Biodegradability

: Result: Readily biodegradable.
Method: OECD Test Guideline 301C

Bioaccumulative potential
Components:
Cumene hydroperoxide:
Partition coefficient: n-
octanol/water

: log Pow: 1.6

Cumene:
Bioaccumulation

: Bioconcentration factor (BCF): 94.69
Remarks: Calculation

Partition coefficient: n-
octanol/water

: log Pow: 3.55 (23 C / 23 C)

Benzenemethanol, alpha,alpha-dimethyl-:
Partition coefficient: n-
octanol/water

: Remarks: No data available

acetophenone:
Bioaccumulation

: Bioconcentration factor (BCF): 0.48

Partition coefficient: n-
octanol/water

: log Pow: 1.63

Mobility in soil
No data available
Other adverse effects
Product:
Ozone-Depletion Potential

: Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone – CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological infor-
mation

: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

23 / 27
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of wastes in an approved waste disposal facility.
The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.

Contaminated packaging

: Dispose of in accordance with local regulations.
Clean container with water.
Dispose of contents/ container to an approved waste disposal
plant.
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
UN number : UN 3109
Proper shipping name : ORGANIC PEROXIDE TYPE F, LIQUID
(CUMYL HYDROPEROXIDE )
Class : 5.2
Subsidiary risk : 8
Packing group : Not assigned by regulation
Labels : 5.2 (8)
IATA-DGR
UN/ID No. : UN 3109
Proper shipping name : Organic peroxide type F, liquid
(Cumyl hydroperoxide)
Class : 5.2
Subsidiary risk : 8
Packing group : Not assigned by regulation
Labels : Organic Peroxides, Keep Away From Heat, Corrosive
Packing instruction (cargo
aircraft)
: 570
Packing instruction (passen-
ger aircraft)
: 570
IMDG-Code
UN number : UN 3109
Proper shipping name : ORGANIC PEROXIDE TYPE F, LIQUID
(CUMYL HYDROPEROXIDE )
Class : 5.2
Subsidiary risk : 8
Packing group : Not assigned by regulation

SAFETY DATA SHEET

NOROX

CHP

Version
3.0
Revision Date:
08/07/2023
SDS Number:
600000000292
Date of last issue: 04/09/2021
Date of first issue: 12/19/2016

24 / 27
Labels : 5.2 (8)
EmS Code : F-J, S-R
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 3109
Proper shipping name : Organic peroxide type F, liquid
(Cumyl hydroperoxide,<= 90%) Class : 5.2 Subsidiary risk : 8 Packing group : Not assigned by regulation Labels : ORGANIC PEROXIDE , CORROSIVE ERG Code : 145 Marine pollutant : yes Special precautions for user The transport classification(s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Cumene hydroperoxide 80-15-9 10 12 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Organic peroxides Acute toxicity (any route of exposure) Carcinogenicity Specific target organ toxicity (single or repeated exposure) Aspiration hazard Skin corrosion or irritation Serious eye damage or eye irritation SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 25 / 27 Cumene hydrop- eroxide 80-15-9 Cumene 98-82-8 acetophenone 98-86-2 Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR 61): Cumene 98-82-8 acetophenone 98-86-2 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi- ate or Final VOC's (40 CFR 60.489): Cumene hydroperoxide 80-15-9 Cumene 98-82-8 acetophenone 98-86-2 Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 This product does not contain any priority pollutants related to the U.S. Clean Water Act California Prop. 65 WARNING: This product can expose you to chemicals including Cumene, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. International Regulations Gefahrgruppe nach DGUV 13 Vorschrift 13 (bisher BGV B4): Ib (German regulatory requirements) The ingredients of this product are reported in the following inventories: TCSI (TW) : On the inventory, or in compliance with the inventory TSCA (US) : All substances listed as active on the TSCA inventory AIIC (AU) : On the inventory, or in compliance with the inventory DSL (CA) : All components of this product are on the Canadian DSL ENCS (JP) : On the inventory, or in compliance with the inventory ISHL (JP) : On the inventory, or in compliance with the inventory KECI (KR) : On the inventory, or in compliance with the inventory SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 26 / 27 PICCS (PH) : On the inventory, or in compliance with the inventory IECSC (CN) : On the inventory, or in compliance with the inventory NZIoC (NZ) : On the inventory, or in compliance with the inventory TECI (TH) : On the inventory, or in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification requirements. SECTION 16. OTHER INFORMATION Further information This material safety datasheet only contains information relating to safety and does not replace any product information or product specification. These safety instructions also apply to empty packaging which may still contain product residues. The hazards on the label also apply to residues in the container. Sources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen- cy, http://echa.europa.eu/ Revision Date : 08/07/2023 Full text of other abbreviations ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values) OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants US WEEL : USA. Workplace Environmental Exposure Levels (WEEL) ACGIH / TWA : 8-hour, time-weighted average NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek OSHA P0 / TWA : 8-hour time weighted average OSHA Z-1 / TWA : 8-hour time weighted average US WEEL / TWA : 8-hr TWA AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the SAFETY DATA SHEET NOROX CHP Version 3.0 Revision Date: 08/07/2023 SDS Number: 600000000292 Date of last issue: 04/09/2021 Date of first issue: 12/19/2016 27 / 27 German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza- tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi- cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre- vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth- erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern- ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / Z8