Revision: 6.0 SDS Number: SD.SP.01.08US
Revision date: 25.03.2019 Issue date: 22.11.2009
SAFETY DATA SHEET
AKPEROX A5R
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015.
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1.1. Product identifier
Product name AKPEROX A5R
Chemical name Methyl Ethyl Ketone Peroxide
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial use.
Uses advised against No specific uses advised against are identified.
1.3. Details of the supplier of the safety data sheet
Manufacturer AKPA K MYA AMBALAJ SANAY VE T CARET ANON M RKET
Yenibosna Merkez Mah. Ladin Sok. No:36/70 Kat:12 34197 Townofis
Bah elievler, stanbul, T RK YE
Web: www.akpakimya.com
TEL: +90 212 580 55 59
FAX: +90 212 580 55 21
E-mail: info@akpakimya.com
Contact person Export Department – export@akpakimya.com
1.4. Emergency telephone number
Emergency telephone CHEMTREC: TOLL Free 1-800-424-9300 / Local: +1-703-527-3887
For product information AKPA CHEMICALS US: +1 803 686 2888
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical hazards Org. Perox. D – H242
Health hazards Acute Tox. 4 – H302 Skin Corr. 1B – H314 Repr 2. H361d
Environmental hazards Aquatic Chronic 3 H412
2.2. Label elements
Pictogram
Signal Word Danger
Hazard statements H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
SECTION 1: Identi cation of the substance/mixture and of the company/undertaking
SECTION 2: Hazards identification
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H361d Suspected of damaging the unborn child.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P220 Keep away from acids, alkalis, heavy metal compounds,
oxidizing material, combustible materials.
P234 Keep only in original container.
P280 Wear protective gloves/protective clothing/ eye protection/
face protection.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician
if you feel unwell.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P411+P235 Store at temperatures not exceeding (5) – (30) C. Keep cool.
P501 Dispose of contents/ container in accordance with national
regulations.
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Contains Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-
2,2-diyl dihydroperoxide; 1-isopropyl-2,2-dimethyltrimethylene
diisobutyrate
2.3. Other hazards
This substance is not classified as PBT or vPvB according to current EU
criteria.
3.2. Mixtures
1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
REACH Reg. No: 01-2119451093-47-0000
%40-60
CAS Number 6846-50-0 EC Number 229-934-9
Classification
Repr. 2 H361d
Aquatic Chronic 3 H412
SECTION 3: Composition/information on ingredients
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Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
REACH Reg. No: 01-2119514691-43-0007
%25-40
CAS Number 1338-23-4 EC Number 700-954-4
Classification
Org. Perox. D H242
Acute Tox. 4 H302
Skin Corr. 1B H314
Eye Dam. 1 H318
Acute Tox. 4 H332
Hydrogen Peroxide Solution
REACH Reg. No: 01-2119485845-22-0000
%1-5
CAS Number 7722-84-1 EC Number 231-765-0
Classification
Ox. Liq. 1 H271
Acute Tox. 4 H302
Acute Tox. 4 H332
Skin Corr. 1A H314
Butanone
REACH Reg. No: 01-2119457290-43-0004
%1-5
CAS Number 78-93-3 EC Number 201-159-0
Classification
Flam. Liq. 2 H225
Eye Irrit. 2 H319
STOT SE 3 H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
4.1. Description of first aid measures
General information Get medical attention if any discomfort continues. Show this Safety
Data Sheet to the medical personnel. Chemical burns must be treated
by a physician.
Inhalation Move affected person to fresh air and keep warm and at rest in a
position comfortable for breathing. Maintain an open airway. Loosen
tight clothing such as collar, tie or belt. Rinse nose and mouth with
water. Never give anything by mouth to an unconscious person. Get
medical attention if symptoms are severe or persist.
Ingestion Rinse mouth thoroughly with water. Never give anything by mouth to
an unconscious person. Place unconscious person on their side in the
SECTION 4: First aid measures
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recovery position and ensure breathing can take place. Keep affected
person under observation. Get medical attention.
Skin contact It is important to remove the substance from the skin immediately.
Rinse immediately with plenty of water. Continue to rinse for at least
15 minutes and get medical attention. Chemical burns must be treated
by a physician.
Eye contact Rinse immediately with plenty of water. Do not rub eye. Remove any
contact lenses and open eyelids wide apart. Continue to rinse for at
least 15 minutes and get medical attention.
Protection of first aiders First aid personnel should wear appropriate protective equipment
during any rescue. Wash contaminated clothing thoroughly with water
before removing it from the affected person, or wear gloves. It may be
dangerous for first aid personnel to carry out mouth-to-mouth
resuscitation.
4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the
concentration and the length of exposure.
Inhalation A single exposure may cause the following adverse effects: Corrosive to
the respiratory tract. Symptoms following overexposure may include
the following: Severe irritation of nose and throat.
Ingestion May cause chemical burns in mouth, oesophagus and stomach.
Symptoms following overexposure may include the following: Severe
stomach pain. Nausea, vomiting.
Skin contact Causes severe burns. Symptoms following overexposure may include
the following: Pain or irritation. Redness. Blistering may occur.
Eye contact Causes serious eye damage. Symptoms following overexposure may
include the following: Pain. Profuse watering of the eyes. Redness.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or
water fog.
Unsuitable extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire.
SECTION 5: Firefighting measures
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5.2. Special hazards arising from the substance or mixture
Specific hazards Protection against nuisance dust must be used when the airborne
concentration exceeds 10 mg/m3. Vapours may form explosive
mixtures with air. Forms explosive mixtures with air. May explode when
heated or when exposed to flames or sparks. Containers can burst
violently or explode when heated, due to excessive pressure build-up.
Hazardous decomposition products
Thermal decomposition or combustion products may include the
following substances: Toxic gases or vapours.
5.3. Advice for firefighters
Protective actions during
firefighting
Wear positive-pressure self-contained breathing apparatus (SCBA) and
appropriate protective clothing. Cool containers exposed to flames
with water until well after the fire is out. Fight fire from safe distance
or protected location. Move containers from fire area if it can be done
without risk. Do not use water jet as an extinguisher, as this will spread
the fire. Control run-off water by containing and keeping it out of
sewers and watercourses. If risk of water pollution occurs, notify
appropriate authorities.
Special protective equipment for
firefighters
Wear positive-pressure self-contained breathing apparatus (SCBA) and
appropriate protective clothing. Firefighter’s clothing conforming to
European standard EN469 (including helmets, protective boots and
gloves) will provide a basic level of protection for chemical incidents.
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Wear protective clothing as described in Section 8 of this safety data
sheet. No smoking, sparks, flames or other sources of ignition near
spillage. Avoid inhalation of vapours and contact with skin and eyes.
Provide adequate ventilation.
6.2. Environmental precautions
Environmental precautions Avoid or minimise the creation of any environmental contamination.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up Keep combustible materials away from spillage. Eliminate all sources of
ignition. No smoking, sparks, flames or other sources of ignition near
spillage. Provide adequate ventilation. Absorb in vermiculite, dry sand
or earth and place into containers. Wash thoroughly after dealing with
a spillage. Do not touch or walk into spilled material. Wear suitable
protective equipment, including gloves, goggles/face shield, respirator,
boots, clothing or apron, as appropriate.
SECTION 6: Accidental release measures
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6.4. Reference to other sections
Reference to the other sections For personal protection, see Section 8. See Section 11 for additional
information on health hazards. For waste disposal, see section 13.
7.1. Precautions for safe handling
Usage precautions Keep away from heat, sparks and open flame. Avoid inhalation of
vapours/spray and contact with skin and eyes. Provide adequate
ventilation. Avoid inhalation of vapours. Use approved respirator if air
contamination is above an acceptable level. Do not handle broken
packages without protective equipment.
Advice on general occupational
hygiene
Eye wash facilities and emergency shower must be available when
handling this product. Good personal hygiene procedures should be
implemented. Wash hands and any other contaminated areas of the
body with soap and water before leaving the work site. Good personal
hygiene procedures should be implemented. Mechanical ventilation or
local exhaust ventilation may be required. Container must be kept
tightly closed when not in use.
7.2. Conditions for safe storage, including any incompatibilities
Storage precautions Keep away from oxidising materials, heat and flames. Store in tightly-
closed, original container in a dry, cool and well-ventilated place. Avoid
contact with oxidising agents. Store away from the following materials:
Acids. Alkalis. Keep away from flammable and combustible materials.
Storage Class IIA
7.3. Specific end use(s)
Specific end use(s) The identified uses for this product are detailed in Section 1.2.
8.1. Control Parameters
Occupational exposure limits
Ingredients CAS No. Value Control
Parameters
Note
Hydrogen peroxide 7722-84-1
TWA 1 ppm ACGIH
PEL
1 ppm
1,4 mg/m
3
OSHA Z-1
STEL
2 ppm
2,8 mg/m
3
ACGIH
SECTION 7: Handling and storage
SECTION 8: Exposure Controls/personal protection
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Reaction mass of
butane-2,2-diyl
dihydroperoxide and
dioxydibutane-2,2-diyl
dihydroperoxide
1338-23-4 C
0.2 ppm ACGIH
0.2 ppm
1.5 mg/m
3
NIOSH REL
0.7 ppm
5 mg/m
3
OSHA P0
0.2 ppm
1.5 mg/m
3
CAL PEL
Methyl Ethyl Ketone 78-93-3
TWA 200 ppm ACGIH
MPC-TWA 200 mg/m
3
RU OEL Vapour and/or gas
STEL 300 ppm ACGIH
MPC-STEL 400 mg/m
3
RU OEL Vapour and/or gas
TWA
200 ppm
590 mg/m
3
NIOSH REL
OSHA Z-1
OSHA P0
CAL PEL
ST
300 ppm
885 mg/m
3
NIOSH REL
OSHA P0
CAL PEL
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health effects Value
1-isopropyl-2,2-
dimethyltrimethylene
diisobutyrate
Workers Inhalation Long-term exposure 17,62 mg/m
3
Workers Dermal Long-term exposure 5 mg/kg bw/day
General Population Inhalation Long-term exposure 4,35 mg/m
3
General Population Dermal Long-term exposure 5 mg/kg bw/day
General Population Oral Long-term exposure 5 mg/kg bw/day
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
1-isopropyl-2,2-
dimethyltrimethylene
diisobutyrate
Water 0,014 mg/l
Marine water 0,0014 mg/l
Aqua Intermittent 0,14 mg/l
Fresh water sediment 5,29 mg/kg
Marine sediment 0,529 mg/kg
Soil 1,05 mg/kg
Sewage treatment plant 3 mg/l
Secondary Poisoning 83,3 mg/kg
8.2. Exposure controls
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Protective equipment
Appropriate engineering controls
Provide adequate ventilation. Avoid inhalation of vapours. Observe
any occupational exposure limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk
assessment indicates eye contact is possible. The following protection
should be worn: Chemical splash goggles or face shield.
Hand protection
Wear protective gloves made of the following material: Neoprene.
Nitrile rubber. Rubber (natural, latex). The most suitable glove should
be chosen in consultation with the glove supplier/manufacturer, who
can provide information about the breakthrough time of the glove
material.
Other skin and body protection Appropriate footwear and additional protective clothing complying
with an approved standard should be worn if a risk assessment
indicates skin contamination is possible.
Hygiene measures Provide eyewash station and safety shower. Do not smoke in work
area. Wash hands at the end of each work shift and before eating,
smoking and using the toilet. Promptly remove any clothing that
becomes contaminated. Wash promptly with soap and water if skin
becomes contaminated. Use appropriate skin cream to prevent drying
of skin. When using do not eat, drink or smoke.
Respiratory protection If ventilation is inadequate, suitable respiratory protection must be
worn. Check that the respirator fits tightly and the filter is changed
regularly.
Environmental exposure controls Residues and empty containers should be taken care of as hazardous
waste according to local and national provisions.
9.1. Information on basic physical and chemical properties
Appearance Clear liquid.
Colour Colorless.
Odour Characteristic.
SECTION 9: Physical and Chemical Properties
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Density 1 0,005 gr/cm
3
@20 C
Solubility(ies) Slightly soluble in water.
Flammability (solid, gas) Not applicable.
Viscosity, dynamic No data available.
9.2. Other information
SADT 60 C
Active Oxygen Content 8,5 – 8,95 %
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this
product.
10.2. Chemical stability
Stability Stable at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Not available.
10.4. Conditions to avoid
Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials to avoid Strong alkalis. Strong acids. Strong reducing agents. Strong
oxidising agents. Some metals.
10.6. Hazardous decomposition products
Hazardous decomposition Products Oxides of carbon. Carbon monoxide (CO). Carbon dioxide (CO2).
Hydrocarbons.
11.1. Information on toxicological effects
Product Information
Toxicological information The product is not tested.
Serious eye damage/irritation: Corrosivity to eyes is assumed.
Skin corrosion/irritation: Causes burns.
Respiratory or skin sensitisation:
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation Based on available data the classification criteria are not met.
SECTION 10: Stability and reactivity
SECTION 11: Toxicological information
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Germ cell mutagenicity: Genotoxicity – In Vitro – In Vivo Based on available data the
classification criteria are not met.
Carcinogenicity: Based on available data the classification criteria are not met.
Reproductive Toxicity – Fertility Suspected of damaging the unborn child.
Reproductive Toxicity
Development
Based on available data the classification criteria are not met.
Specific target organ toxicity – single exposure:
STOT – Single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity – repeated exposure:
STOT – Repeated exposure Based on available data the classification criteria are not met.
Aspiration Hazard Based on available data the classification criteria are not met.
Inhalation Corrosive to the respiratory tract. Symptoms following overexposure
may include the following: Severe irritation of nose and throat.
Ingestion May cause chemical burns in mouth, oesophagus and stomach.
Symptoms following overexposure may include the following: Severe
stomach pain. Nausea, vomiting.
Skin contact Causes severe burns. Symptoms following overexposure may include
the following: Pain or irritation. Redness. Blistering may occur.
Eye contact Causes serious eye damage. Symptoms following overexposure may
include the following: Pain. Profuse watering of the eyes. Redness.
Route of entry Ingestion Inhalation Skin and/or eye contact
Target organs Respiratory system, lungs
Medical considerations Skin disorders and allergies.
Toxicology Data For The Ingredients:
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Acute oral toxicity LD50: 1017 mg/kg Species: Rat
Acute dermal toxicity LD50: 4000 mg/kg Species: Rat
Acute inhalation toxicity LC50 (Rat): 17 mg/l Exposure time: 4h
1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
Acute oral toxicity LD50: >2000 mg/kg Species: Rat
Acute dermal toxicity LD50: >2000 mg/kg Species: Rabbit
Acute inhalation toxicity LC50 (Rat): >0,12 mg/l Exposure time: 6h
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Butanone
Acute oral toxicity LD50: 2,737 mg/kg Species: Rat
Acute dermal toxicity LD50: 6,480 mg/kg Species: Rabbit
Hydrogen Peroxide
Acute oral toxicity LD50: >225 mg/kg Species: Rat
Acute inhalation toxicity LC50 (Rat): >0,17 mg/l Exposure time: 4h
12.1. Toxicity
Ecological information on ingredients.
Reaction mass of butane-2,2-diyl dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide
Toxicity to fish LC50, 96h: 44,2 mg/l
Toxicity to algae ErC50, 72h: 5,6 mg/ll
Toxicity to bacteria EC10, 0,5h: 5,6 mg/l
Toxicity to daphnia and other
aquatic invertebrates
39 mg/l, 48h
Butanone
Toxicity to fish LC50, 96h: 3.220 mg/l
1-isopropyl-2,2-dimethyltrimethylene diisobutyrate
Toxicity to fish LC50, 96h: 6 mg/l
Toxicity to algae EC50, 72h: >7,49 mg/l
Toxicity to daphnia and other
aquatic invertebrates
1,46 mg/l, 48h
Toxicity to daphnia and other
aquatic invertebrates (Chronic
Toxicity)
EC10, 21d: >1,3 mg/l
12.2. Persistence and degradability
Persistence and degradability The product is readily biodegradable.
12.3. Bio accumulative potential
Bio accumulative potential No data available on bioaccumulation.
12.4. Mobility in soil
Mobility The product is partly miscible with water and may spread in the aquatic
environment.
SECTION 12: Ecological Information
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12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects None known.
13.1. Waste treatment methods
General information Waste should be treated as controlled waste. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. When handling waste, the safety
precautions applying to handling of the product should be considered.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the
requirements of the local Waste Disposal Authority. Containers should
be thoroughly emptied before disposal because of the risk of an
explosion. Environmental Manager must be informed of all maj r
spillages.
General information For limited quantity packaging/limited load information, consult the
relevant modal documentation using the data shown in this section.
14.1. UN number
UN No. (ADR/RID) 3105
UN No. (IMDG) 3105
UN No. (ICAO) 3105
UN No. (ADN) 3105
14.2. UN proper shipping name
Proper Shipping name(ADR/RID) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (IMDG) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ICAO) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
Proper Shipping name (ADN) ORGANIC PEROXIDE TYPE D, LIQUID (Reaction mass of butane-2,2-diyl
dihydroperoxide and dioxydibutane-2,2-diyl dihydroperoxide)
14.3. Transport hazard class(es)
ADR/RID class 5.2
SECTION 13: Disposal considerations
SECTION 14: Transport information
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ADR/RID label 5.2
IMDG class 5.2
ICAO class/division 5.2
ADN class 5.2
Transport labels
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant
No.
14.6. Special precautions for user
Always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
EmS F-J, S-R
Emergency Action Code 2WE
Hazard Identification Number –
(ADR/RID)
Tunnel restriction code (D)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to
Annex II of MARPOL
Not Applicable.
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended). The Chemicals
(Hazard Information and Packaging for Supply) Regulations 2009 (SI
2009 No. 716).
The Carriage of Dangerous Goods and Use of Transportable Pressure
Equipment Regulations 2009 (SI 2009 No. 1348) (as amended) [“CDG
2009”]. EH40/2005 Workplace exposure limits.
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the
Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH) (as amended).
SECTION 15: Regulatory information
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Regulation (EC) No 1272/2008 of the European Parliament and of the
Council of 16 December 2008 on classification, labelling and packaging
of substances and mixtures (as amended).
Storage Class IIA
15.2. Chemical safety assessment
No chemical safety assessment has been carried out.
Key literature references and
sources for data
This SDS is prepared based on the information received from the
product owner.
Classification procedures according
to Regulation (EC) 1272/2008
Skin Corr. 1B – H314; Acute Tox. 4 H302; Repr. 2 – H361d; Aquatic
Chronic 3 – H412: Calculation Method. Org. Perox. D – H242: Expert
Judgement.
Training advice Read and follow manufacturer’s recommendations. Only trained
personnel should use this material.
Revision comments Added REACH Numbers.
Issued By Simge ARIK – lab@akpakimya.com +90 282 361 80 99
Issued Date 22.11.2009
Revision date 25.03.2019
Revision 6.0
Hazard statements in full
H225
H242
Highly flammable liquid and vapour.
Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H412 Harmful to aquatic life with long lasting effects.
Other abbreviations
ACGIH USA, ACGIH Thershold Limit Values (TLV)
SECTION 16: Other information
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CAL PEL California permissible exposure limits for chemical contaminants (Title
8, Article 107)
NIOSH REL USA NIOSH Recommended Exposure Limits
OSHA P0 USA OSHA TABLE Z-1 Limits for air contaminants 1910.1000
OSHA Z-1 Usa Occupational Exposure Limits (OSHA) Table Z-1 Limits for air
contaminants
ACGIH/TWA 8-hour, time-weighted average
ACGIH/STEL Short-term exposure limit
ACGIH/C Ceiling limit
CAL PEL/STEL Short term exposure limit
CAL PEL/PEL Permissible exposure limit
CAL PEL/C Ceiling
NIOSH REL/TWA Time-weighted average concentration for up to a 10-hour workday
during a 40-hour workweek
NIOSH REL/ST STEL-15minute TWA exposure that should not be exceeded at any
time during a workday
NIOSH REL/C Celing value not be exceeded at any time
OSHA P0/TWA 8-hour time weighted average
OSHA P0/STEL Short-term exposure limit
OSHA P0/C Ceiling limit
OSHA Z-1/TWA 8-hour time weighted average
RU OEL / MPC-STEL Russia. Maximum Permissible Concentration Short Term Exposure
RU OEL / MPC-TWA Russia. Maximum Permissible Concentration Time Weighted
Average
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