3M Hi-Tack Composite Spray Adhesive 71 Green
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Safety Data Sheet
Copyright,2022, 3M Company.All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior
written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the
intention of earning a profit thereon.
Document group:37-8510-2 Version number:3.00Issue Date:28/11/2022Supersedes date:13/07/2022
This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals
Code of Practice (Safe Work Australia, December 2011)
SECTION 1: Identification
1.1. Product identifier
3M Hi-Tack Composite Spray Adhesive 71 Green
Product Identification Numbers
62-4867-4930-2
1.2. Recommended use and restrictions on use
Recommended use
Adhesive, Industrial use.
For Industrial or Professional use only.
1.3. Supplier s details
Address:3M Australia – Building A, 1 Rivett Road, North Ryde NSW 2113Telephone:136 136E Mail:productinfo.au@mmm.comWebsite:www.3m.com.au
1.4. Emergency telephone number
EMERGENCY: 1800 097 146 (Australia only)
SECTION 2: Hazard identification
This product is classified as a hazardous chemical according to the Model Work Health and Safety Regulations, 2011, in
accordance with applicable State and Territory legislation.
Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification.
2.1. Classification of the substance or mixture
Flammable Aerosol: Category 1.
Serious Eye Damage/Irritation: Category 2.
Skin Sensitizer: Category 1B.
Reproductive Toxicity: Category 1.
Specific Target Organ Toxicity (single exposure): Category 1.
Specific Target Organ Toxicity (single exposure): Category 3
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2.2. Label elements
The label elements below were prepared in accordance with the Code of Practice on Preparation of Safety Data Sheets for
Hazardous Chemicals (Safe Work Australia, December 2011). This information may be different from the actual product
label.
Signal word
Danger
Symbols
Flame |Exclamation mark |Health Hazard |
Pictograms
Hazard statements
H222Extremely flammable aerosol.H229Pressurised container: may burst if heated.H319Causes serious eye irritation.H317May cause an allergic skin reaction.H360May damage fertility or the unborn child.H336May cause drowsiness or dizziness.H370Causes damage to organs: cardiovascular system.
Precautionary statements
Prevention:
P201Obtain special instructions before use.P202Do not handle until all safety precautions have been read and understood.P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P211Do not spray on an open flame or other ignition source.P251Do not pierce or burn, even after use.P260Do not breathe dust/fume/gas/mist/vapours/spray.P264Wash thoroughly after handling.P270Do not eat, drink or smoke when using this product.P271Use only outdoors or in a well-ventilated area.P272Contaminated work clothing should not be allowed out of the workplace.P280FWear respiratory protection.
Response:
P302 + P352IF ON SKIN: Wash with plenty of soap and water.P304 + P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P308 + P313IF exposed or concerned: Get medical advice/attention.P312Call a POISON CENTRE or doctor/physician if you feel unwell.P333 + P313If skin irritation or rash occurs: Get medical advice/attention.P337 + P313IF eye irritation persists: Get medical advice/attention.P362 + P364Take off contaminated clothing and wash it before reuse.
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Storage:
P405Store locked up.P410 + P412Protect from sunlight. Do not expose to temperatures exceeding 50 C.
Disposal:
P501Dispose of contents/container in accordance with applicable
local/regional/national/international regulations.
2.3. Other assigned/identified product hazards
3M Intentional misuse by deliberately concentrating and inhaling contents can be harmful or fatal. May displace oxygen
and cause rapid suffocation. Repeated exposure may cause skin dryness or cracking.
2.4. Other hazards which do not result in classification
Toxic to aquatic life.
SECTION 3: Composition/information on ingredients
This material is a mixture.
IngredientCAS Nbr% by WeightAcetone67-64-1 35 – 45Non-hazardous componentsTrade Secret 10 – 251,1-Difluoroethane75-37-6 10 – 20Propane74-98-6 10 – 15Cyclohexane110-82-7 < 10Rosin, Fumarated, Polymer with Glycerol65997-10-6 5 - 10Glycerol Esters of Rosin Acids8050-31-5 1 - 5Resin acids and Rosin acids, esters with
diethylene glycol
68153-38-8 1 - 5Toluene108-88-3 < 1Benzene71-43-2 < 0.05
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. Get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get
medical attention.
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Allergic skin reaction (redness, swelling, blistering, and itching). Central nervous system depression (headache, dizziness, drowsiness,
incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ effects. See Section 11 for additional details.
4.3. Indication of any immediate medical attention and special treatment required
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Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Use a fire fighting agent suitable for the surrounding fire.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode. Exposure to extreme heat can give rise to
thermal decomposition.
Hazardous Decomposition or By-Products
Substance ConditionCarbon monoxide.During combustion.Carbon dioxide.During combustion.Hydrogen FluorideDuring combustion.
5.3. Special protective actions for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering
for exposed areas of the head.
Hazchem Code: 2YE
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or
exhaust vapors, in accordance with good industrial hygiene practice. WARNING ! A motor could be an ignition source and
could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. Collect the resulting
residue containing solution per section 6.3.
6.3. Methods and material for containment and cleaning up
If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or
if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is
available. Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill
inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent
until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.
Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for
transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised
person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal
the container. Dispose of collected material as soon as possible in accordance with applicable
local/regional/national/international regulations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid inhalation of thermal decomposition products. Do not handle until all safety precautions have been read and
understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other
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ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in
eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (eg. gloves,
respirators ) as required.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures
exceeding 50 C/122 F. Store away from heat. Store away from acids. Store away from oxidising agents.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientCAS NbrAgencyLimit typeAdditional commentsToluene108-88-3ACGIHTWA:20 ppmA4: Not class. as human
carcinogen, Ototoxicant
Toluene108-88-3Australia OELsTWA(8 hours):191 mg/m3(50
ppm);STEL(15 minutes):574
mg/m3(150 ppm)
SKINCyclohexane110-82-7ACGIHTWA:100 ppmCyclohexane110-82-7Australia OELsTWA(8 hours):350
mg/m3(100 ppm);STEL(15
minutes):1050 mg/m3(300
ppm)
Acetone67-64-1ACGIHTWA:250 ppm;STEL:500 ppmA4: Not class. as human
carcin
Acetone67-64-1Australia OELsTWA(8 hours):1185
mg/m3(500 ppm);STEL(15
minutes):2375 mg/m3(1000
ppm)
Benzene71-43-2ACGIHTWA:0.05 ppm;STEL:2.5 ppmA1: Confirmed human
carcin., SKIN
Benzene71-43-2Australia OELsTWA(8 hours):3.2 mg/m3(1
ppm)
Propane74-98-6ACGIHLimit value not established:asphyxiantPropane74-98-6Australia OELsLimit value not established:Explosion hazard,
asphyxiant
1,1-Difluoroethane75-37-6AIHATWA:2700 mg/m3(1000 ppm)
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment
CMRG : Chemical Manufacturer's Recommended Guidelines
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
Sen: Sensitiser
Sk: Absorption through the skin may be a significant source of exposure.
8.2. Exposure controls
8.2.1. Engineering controls
For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with
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appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure
guidelines. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local
exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control
dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full face shield.
Indirect vented goggles.
Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance
specifications of AS/NZS 1337.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate
if this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Select and use gloves according to AS/NZ 2161.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part
of a full respiratory protection program. Based on the results of the exposure assessment, select from the following
respirator type(s) to reduce inhalation exposure:
For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use a
positive pressure supplied-air respirator.
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
Half facepiece or full facepiece supplied-air respirator.
Organic vapour respirators may have short service life.
For questions about suitability for a specific application, consult with your respirator manufacturer.
Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance
specifications. For information about respirators, call 3M on 1800 024 464.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical stateLiquid. Specific Physical Form: AerosolColourMulticolourOdourSolventOdour thresholdNo data available.
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pHNot applicable.Melting point/Freezing pointNot applicable.Boiling point/Initial boiling point/Boiling range-42.2 C [Details:Acetone]Flash point-104.4 C [Test Method:Closed Cup]Evaporation rate> 1 [Ref Std:BUOAC=1]Flammability (solid, gas)Not applicable.Flammable Limits(LEL)1.3 % volumeFlammable Limits(UEL)12.8 % volumeVapour pressure<=551,553.1 Pa [@ 20 C ]Vapor Density and/or Relative Vapor Density> 1 [Ref Std:AIR=1]Density0.8 g/mlRelative density0.8 [Ref Std:WATER=1]Water solubilityNilSolubility- non-waterNo data available.Partition coefficient: n-octanol/waterNo data available.Autoignition temperatureNo data available.Decomposition temperatureNo data available.Viscosity/Kinematic Viscosity<=100 mPa-s [@ 23 C ]Volatile organic compounds (VOC)No data available.Percent volatile<=80.6 % weightVOC less H2O & exempt solvents<=25 % [ Test Method:calculated per CARB title 2]Molecular weightNo data available.
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3. Conditions to avoid
Heat.
Sparks and/or flames.
10.4. Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.5 Incompatible materials
Not determined
10.6 Hazardous decomposition products
SubstanceCondition None known.
Dust created by grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
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present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Simple asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory tract irritation:
Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause
additional health effects (see below).
Skin contact
Dermal Defatting Prolonged or repeated exposure may cause: Dermal Defatting: Signs/symptoms may include localized
redness, itching, drying and cracking of skin. Dermal Defatting: Signs/symptoms may include localised redness, itching,
drying and cracking of skin. Allergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling,
blistering, and itching.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
May cause additional health effects (see below).
Additional Health Effects:
Single exposure may cause target organ effects:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended
guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest
pain, and may be fatal.
Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRouteSpeciesValueOverall productDermalNo data available; calculated ATE >5,000
mg/kg
Overall productInhalation-Vapour(4
hr)
No data available; calculated ATE >50 mg/lOverall productIngestionNo data available; calculated ATE >5,000
mg/kg
AcetoneDermalRabbitLD50 > 15,688 mg/kgAcetoneInhalation-Vapour (4
hours)
RatLC50 76 mg/lAcetoneIngestionRatLD50 5,800 mg/kgPropaneInhalation-Gas (4 RatLC50 > 200,000 ppm
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hours)1,1-DifluoroethaneInhalation-Gas (4
hours)
RatLC50 > 437,000 ppmCyclohexaneDermalRatLD50 > 2,000 mg/kgCyclohexaneInhalation-Vapour (4
hours)
RatLC50 > 32.9 mg/lCyclohexaneIngestionRatLD50 6,200 mg/kgRosin, Fumarated, Polymer with
Glycerol
DermalRatLD50 > 2,000 mg/kgRosin, Fumarated, Polymer with
Glycerol
IngestionRatLD50 > 2,000 mg/kgGlycerol Esters of Rosin AcidsIngestionRatLD50 >300, <2000 mg/kgTolueneDermalRatLD50 12,000 mg/kgTolueneInhalation-Vapour (4
hours)
RatLC50 30 mg/lTolueneIngestionRatLD50 5,550 mg/kgResin acids and Rosin acids, esters
with diethylene glycol
IngestionRatLD50 >300, <2000 mg/kgBenzeneDermalMultiple animal
species
LD50 > 8,260 mg/kgBenzeneInhalation-Vapour (4
hours)
RatLC50 43.8 mg/lBenzeneIngestionRatLD50 5,970 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
NameSpeciesValueAcetoneMouseMinimal irritationPropaneRabbitMinimal irritationCyclohexaneRabbitMild irritantRosin, Fumarated, Polymer with GlycerolRabbitNo significant irritationGlycerol Esters of Rosin AcidsIn vitro dataNo significant irritationTolueneRabbitIrritantResin acids and Rosin acids, esters with diethylene
glycol
In vitro dataNo significant irritationBenzeneRabbitIrritant
Serious Eye Damage/Irritation
NameSpeciesValueAcetoneRabbitSevere irritantPropaneRabbitMild irritantCyclohexaneRabbitMild irritantRosin, Fumarated, Polymer with GlycerolRabbitModerate irritantGlycerol Esters of Rosin AcidsIn vitro dataNo significant irritationTolueneRabbitModerate irritantResin acids and Rosin acids, esters with diethylene
glycol
In vitro dataNo significant irritationBenzeneRabbitSevere irritant
Skin Sensitisation
NameSpeciesValueRosin, Fumarated, Polymer with GlycerolMouseSensitisingGlycerol Esters of Rosin AcidsIn vitro dataNot classifiedTolueneGuinea pigNot classifiedResin acids and Rosin acids, esters with diethylene In vitro dataNot classified
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glycolBenzeneMultiple animal speciesNot classified
Respiratory Sensitisation
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
NameRouteValueAcetoneIn vivoNot mutagenicAcetoneIn VitroSome positive data exist, but the data are not
sufficient for classification
PropaneIn VitroNot mutagenic1,1-DifluoroethaneIn VitroSome positive data exist, but the data are not
sufficient for classification
1,1-DifluoroethaneIn vivoSome positive data exist, but the data are not
sufficient for classification
CyclohexaneIn VitroNot mutagenicCyclohexaneIn vivoSome positive data exist, but the data are not
sufficient for classification
Rosin, Fumarated, Polymer with GlycerolIn VitroNot mutagenicGlycerol Esters of Rosin AcidsIn VitroNot mutagenicTolueneIn VitroNot mutagenicTolueneIn vivoNot mutagenicResin acids and Rosin acids, esters with diethylene
glycol
In VitroNot mutagenicBenzeneIn VitroSome positive data exist, but the data are not
sufficient for classification
BenzeneIn vivoMutagenic
Carcinogenicity
NameRouteSpeciesValueAcetoneNot specified.Multiple animal
species
Not carcinogenic1,1-DifluoroethaneInhalationRatSome positive data exist, but the data
are not sufficient for classification
TolueneDermalMouseSome positive data exist, but the data
are not sufficient for classification
TolueneIngestionRatSome positive data exist, but the data
are not sufficient for classification
TolueneInhalationMouseSome positive data exist, but the data
are not sufficient for classification
BenzeneDermalMouseCarcinogenic.BenzeneIngestionMultiple animal
species
Carcinogenic.BenzeneInhalationHumanCarcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
NameRouteValueSpeciesTest result Exposure DurationAcetoneIngestionNot classified for
male reproduction
RatNOAEL
1,700
mg/kg/day
13 weeksAcetoneInhalationNot classified for
development
RatNOAEL 5.2
mg/l
during
organogenesis
1,1-DifluoroethaneInhalationNot classified for
development
RatNOAEL
50,000 ppm
during
organogenesis
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CyclohexaneInhalationNot classified for
female reproduction
RatNOAEL 24
mg/l
2 generationCyclohexaneInhalationNot classified for
male reproduction
RatNOAEL 24
mg/l
2 generationCyclohexaneInhalationNot classified for
development
RatNOAEL 6.9
mg/l
2 generationRosin, Fumarated,
Polymer with
Glycerol
IngestionNot classified for
female reproduction
RatNOAEL
15,000 ppm
in the diet
premating into
lactation
Rosin, Fumarated,
Polymer with
Glycerol
IngestionNot classified for
male reproduction
RatNOAEL
3,000 ppm in
the diet
42 daysRosin, Fumarated,
Polymer with
Glycerol
IngestionNot classified for
development
RatNOAEL 622
mg/kg/day
during gestationTolueneInhalationNot classified for
female reproduction
HumanNOAEL Not
available
occupational
exposure
TolueneInhalationNot classified for
male reproduction
RatNOAEL 2.3
mg/l
1 generationTolueneIngestionToxic to developmentRatLOAEL 520
mg/kg/day
during gestationTolueneInhalationToxic to developmentHumanNOAEL Not
available
poisoning and/or
abuse
BenzeneInhalationNot classified for
female reproduction
RatNOAEL 0.96
mg/l
premating into
lactation
BenzeneInhalationNot classified for
development
RatNOAEL
0.032 mg/l
during
organogenesis
BenzeneIngestionToxic to male
reproduction
RatLOAEL 50
mg/kg/day
90 days
Target Organ(s)
Specific Target Organ Toxicity – single exposure
NameRouteTarget
Organ(s)
ValueSpeciesTest result Exposure
Duration
AcetoneInhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
HumanNOAEL Not
available
AcetoneInhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
HumanNOAEL Not
available
AcetoneInhalationimmune systemNot classifiedHumanNOAEL 1.19
mg/l
6 hoursAcetoneInhalationliverNot classifiedGuinea pigNOAEL Not
available
AcetoneIngestioncentral nervous
system
depression
May cause
drowsiness or
dizziness
HumanNOAEL Not
available
poisoning and/or
abuse
PropaneInhalationcardiac
sensitization
Causes damage to
organs
HumanNOAEL Not
available
PropaneInhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
HumanNOAEL Not
available
PropaneInhalationrespiratory
irritation
Not classifiedHumanNOAEL Not
available
1,1-
Difluoroethan
e
Inhalationcardiac
sensitization
Causes damage to
organs
Human and
animal
NOAEL Not
available
poisoning and/or
abuse
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1,1-
Difluoroethan
e
Inhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
Human and
animal
NOAEL 100,000
ppm
1,1-
Difluoroethan
e
Inhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
Not availableNOAEL Not
available
not availableCyclohexaneInhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
Human and
animal
NOAEL Not
available
CyclohexaneInhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
Human and
animal
NOAEL Not
available
CyclohexaneIngestioncentral nervous
system
depression
May cause
drowsiness or
dizziness
Professional
judgement
NOAEL Not
available
Rosin,
Fumarated,
Polymer with
Glycerol
Inhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
similar health
hazards
NOAEL not
available
TolueneInhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
HumanNOAEL Not
available
TolueneInhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
HumanNOAEL Not
available
TolueneInhalationimmune systemNot classifiedMouseNOAEL 0.004
mg/l
3 hoursTolueneIngestioncentral nervous
system
depression
May cause
drowsiness or
dizziness
HumanNOAEL Not
available
poisoning and/or
abuse
BenzeneInhalationcentral nervous
system
depression
May cause
drowsiness or
dizziness
Human and
animal
NOAEL Not
available.
BenzeneInhalationrespiratory
irritation
Some positive
data exist, but the
data are not
sufficient for
classification
similar health
hazards
NOAEL Not
available.
Specific Target Organ Toxicity – repeated exposure
NameRouteTarget
Organ(s)
ValueSpeciesTest result Exposure
Duration
AcetoneDermaleyesNot classifiedGuinea pigNOAEL Not
available
3 weeksAcetoneInhalationhematopoietic
system
Not classifiedHumanNOAEL 3 mg/l6 weeksAcetoneInhalationimmune systemNot classifiedHumanNOAEL 1.19
mg/l
6 daysAcetoneInhalationkidney and/or
bladder
Not classifiedGuinea pigNOAEL 119
mg/l
not availableAcetoneInhalationheart | liverNot classifiedRatNOAEL 45 mg/l8 weeksAcetoneIngestionkidney and/or
bladder
Not classifiedRatNOAEL 900
mg/kg/day
13 weeks
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AcetoneIngestionheartNot classifiedRatNOAEL 2,500
mg/kg/day
13 weeksAcetoneIngestionhematopoietic
system
Not classifiedRatNOAEL 200
mg/kg/day
13 weeksAcetoneIngestionliverNot classifiedMouseNOAEL 3,896
mg/kg/day
14 daysAcetoneIngestioneyesNot classifiedRatNOAEL 3,400
mg/kg/day
13 weeksAcetoneIngestionrespiratory
system
Not classifiedRatNOAEL 2,500
mg/kg/day
13 weeksAcetoneIngestionmusclesNot classifiedRatNOAEL 2,500
mg/kg
13 weeksAcetoneIngestionskin | bone,
teeth, nails,
and/or hair
Not classifiedMouseNOAEL 11,298
mg/kg/day
13 weeks1,1-
Difluoroethan
e
Inhalationhematopoietic
system | kidney
and/or bladder |
respiratory
system
Not classifiedRatNOAEL 25,000
ppm
2 yearsCyclohexaneInhalationliverNot classifiedRatNOAEL 24 mg/l90 daysCyclohexaneInhalationauditory systemNot classifiedRatNOAEL 1.7
mg/l
90 daysCyclohexaneInhalationkidney and/or
bladder
Not classifiedRabbitNOAEL 2.7
mg/l
10 weeksCyclohexaneInhalationhematopoietic
system
Not classifiedMouseNOAEL 24 mg/l14 weeksCyclohexaneInhalationperipheral
nervous system
Not classifiedRatNOAEL 8.6
mg/l
30 weeksRosin,
Fumarated,
Polymer with
Glycerol
Ingestionheart |
hematopoietic
system | liver |
nervous system |
eyes | kidney
and/or bladder |
respiratory
system
Not classifiedRatNOAEL 1,296
mg/kg/day
90 daysTolueneInhalationauditory system
| eyes | olfactory
system
Causes damage to
organs through
prolonged or
repeated exposure
HumanNOAEL Not
available
poisoning and/or
abuse
TolueneInhalationnervous systemMay cause
damage to organs
though prolonged
or repeated
exposure
HumanNOAEL Not
available
poisoning and/or
abuse
TolueneInhalationrespiratory
system
Some positive
data exist, but the
data are not
sufficient for
classification
RatLOAEL 2.3
mg/l
15 monthsTolueneInhalationheart | liver |
kidney and/or
bladder
Not classifiedRatNOAEL 11.3
mg/l
15 weeksTolueneInhalationendocrine
system
Not classifiedRatNOAEL 1.1
mg/l
4 weeksTolueneInhalationimmune systemNot classifiedMouseNOAEL Not
available
20 daysTolueneInhalationbone, teeth,
nails, and/or hair
Not classifiedMouseNOAEL 1.1
mg/l
8 weeks
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TolueneInhalationhematopoietic
system |
vascular system
Not classifiedHumanNOAEL Not
available
occupational
exposure
TolueneInhalationgastrointestinal
tract
Not classifiedMultiple
animal species
NOAEL 11.3
mg/l
15 weeksTolueneIngestionnervous systemSome positive
data exist, but the
data are not
sufficient for
classification
RatNOAEL 625
mg/kg/day
13 weeksTolueneIngestionheartNot classifiedRatNOAEL 2,500
mg/kg/day
13 weeksTolueneIngestionliver | kidney
and/or bladder
Not classifiedMultiple
animal species
NOAEL 2,500
mg/kg/day
13 weeksTolueneIngestionhematopoietic
system
Not classifiedMouseNOAEL 600
mg/kg/day
14 daysTolueneIngestionendocrine
system
Not classifiedMouseNOAEL 105
mg/kg/day
28 daysTolueneIngestionimmune systemNot classifiedMouseNOAEL 105
mg/kg/day
4 weeksBenzeneInhalationhematopoietic
system
Causes damage to
organs through
prolonged or
repeated exposure
Human and
animal
NOAEL Not
available.
BenzeneInhalationheart | endocrine
system |
gastrointestinal
tract | bone,
teeth, nails,
and/or hair |
liver | immune
system | muscles
| nervous system
| eyes | kidney
and/or bladder |
respiratory
system
Not classifiedRatNOAEL 0.96
mg/l
90 daysBenzeneIngestionhematopoietic
system
Causes damage to
organs through
prolonged or
repeated exposure
RatLOAEL 25
mg/kg/day
90 daysBenzeneIngestionheart | endocrine
system |
gastrointestinal
tract | bone,
teeth, nails,
and/or hair |
liver | immune
system | nervous
system | kidney
and/or bladder |
respiratory
system
Not classifiedRatNOAEL 600
mg/kg/day
90 days
Aspiration Hazard
NameValueCyclohexaneAspiration hazardTolueneAspiration hazard
Exposure Levels
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Refer Section 8.1 Control Parameters of this Safety Data Sheet.
Interactive Effects
Not determined.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. Additional information leading to material classification in
Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be
reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not
expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
GHS Acute 2: Toxic to aquatic life.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available.
MaterialCAS NumberOrganismTypeExposureTest endpointTest resultAcetone67-64-1Algae or other
aquatic plants
Experimental96 hoursEC5011,493 mg/lAcetone67-64-1InvertebrateExperimental24 hoursLC502,100 mg/lAcetone67-64-1Rainbow troutExperimental96 hoursLC505,540 mg/lAcetone67-64-1Water fleaExperimental21 daysNOEC1,000 mg/lAcetone67-64-1BacteriaExperimental16 hoursNOEC1,700 mg/lAcetone67-64-1RedwormExperimental48 hoursLC50>100 Non-hazardous
components
Trade SecretN/AData not available
or insufficient for
classification
N/AN/AN/A 1,1-Difluoroethane75-37-6BacteriaAnalogous
Compound
6 hoursEC50>472.57 mg/l1,1-Difluoroethane75-37-6Rainbow troutAnalogous
Compound
96 hoursLC50291.31 mg/l1,1-Difluoroethane75-37-6Water fleaAnalogous
Compound
48 hoursEC50634.41 mg/lPropane74-98-6N/AData not available
or insufficient for
classification
N/AN/AN/A Cyclohexane110-82-7BacteriaExperimental24 hoursIC5097 mg/lCyclohexane110-82-7Fathead minnowExperimental96 hoursLC504.53 mg/lCyclohexane110-82-7Water fleaExperimental48 hoursEC500.9 mg/lRosin, Fumarated,
Polymer with
Glycerol
65997-10-6Zebra FishAnalogous
Compound
96 hoursLC50>400 mg/lRosin, Fumarated,
Polymer with
Glycerol
65997-10-6Green algaeExperimental72 hoursEL50>100 mg/lRosin, Fumarated,
Polymer with
Glycerol
65997-10-6Water fleaExperimental48 hoursEL50>100 mg/lRosin, Fumarated,
Polymer with
Glycerol
65997-10-6Green algaeExperimental72 hoursNOEL100 mg/lGlycerol Esters of
Rosin Acids
8050-31-5Green algaeEstimated72 hoursNo tox obs at lmt
of water sol
>100 mg/lGlycerol Esters of
Rosin Acids
8050-31-5Rainbow troutEstimated96 hoursNo tox obs at lmt
of water sol
>100 mg/l
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Glycerol Esters of
Rosin Acids
8050-31-5Water fleaEstimated48 hoursNo tox obs at lmt
of water sol
>100 mg/lGlycerol Esters of
Rosin Acids
8050-31-5Green algaeEstimated72 hoursNo tox obs at lmt
of water sol
>100 mg/lResin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Green algaeEstimated72 hoursNo tox obs at lmt
of water sol
>100 mg/lResin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Rainbow troutEstimated96 hoursNo tox obs at lmt
of water sol
>100 mg/lResin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Water fleaEstimated48 hoursNo tox obs at lmt
of water sol
>100 mg/lResin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Green algaeEstimated72 hoursNo tox obs at lmt
of water sol
>100 mg/lToluene108-88-3Coho SalmonExperimental96 hoursLC505.5 mg/lToluene108-88-3Grass ShrimpExperimental96 hoursLC509.5 mg/lToluene108-88-3Green algaeExperimental72 hoursEC5012.5 mg/lToluene108-88-3Leopard frogExperimental9 daysLC500.39 mg/lToluene108-88-3Pink SalmonExperimental96 hoursLC506.41 mg/lToluene108-88-3Water fleaExperimental48 hoursEC503.78 mg/lToluene108-88-3Coho SalmonExperimental40 daysNOEC1.39 mg/lToluene108-88-3DiatomExperimental72 hoursNOEC10 mg/lToluene108-88-3Water fleaExperimental7 daysNOEC0.74 mg/lToluene108-88-3Activated sludgeExperimental12 hoursIC50292 mg/lToluene108-88-3BacteriaExperimental16 hoursNOEC29 mg/lToluene108-88-3BacteriaExperimental24 hoursEC5084 mg/lToluene108-88-3RedwormExperimental28 daysLC50>150 mg per kg of
bodyweight
Toluene108-88-3Soil microbesExperimental28 daysNOEC<26 mg/kg (Dry Weight)Benzene71-43-2Green algaeExperimental72 hoursEC50100 mg/lBenzene71-43-2Rainbow troutExperimental96 hoursLC505.3 mg/lBenzene71-43-2Water fleaExperimental48 hoursEC5010 mg/lBenzene71-43-2Fathead minnowExperimental32 daysNOEC0.8 mg/lBenzene71-43-2Green algaeExperimental72 hoursEC1034 mg/lBenzene71-43-2Water fleaExperimental7 daysNOEC3 mg/lBenzene71-43-2BacteriaExperimental24 hoursIC5013 mg/l
12.2. Persistence and degradability
MaterialCAS NumberTest typeDurationStudy TypeTest resultProtocolAcetone67-64-1Experimental
Biodegradation
28 daysBOD78 %BOD/ThODOECD 301D - Closed bottle
test
Acetone67-64-1Experimental
Photolysis
Photolytic half-life
(in air)
147 days (t 1/2)Non-hazardous
components
Trade Secret Data not
available-
insufficient
N/AN/AN/AN/A1,1-Difluoroethane75-37-6Analogous
Compound
Biodegradation
28 daysBOD3 %BOD/ThODOECD 301D - Closed bottle
test
1,1-Difluoroethane75-37-6Modeled Photolysis Photolytic half-life
(in air)
916 days (t 1/2)Episuite Propane74-98-6Experimental
Photolysis
Photolytic half-life
(in air)
27.5 days (t 1/2)Cyclohexane110-82-7Experimental
Biodegradation
28 daysBOD77 %BOD/ThODOECD 301F - Manometric
respirometry
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Cyclohexane110-82-7Experimental
Photolysis
Photolytic half-life
(in air)
4.14 days (t 1/2)Rosin, Fumarated,
Polymer with
Glycerol
65997-10-6Analogous
Compound
Biodegradation
28 daysCO2 evolution5 %CO2
evolution/THCO2
evolution
OECD 301B - Modified
sturm or CO2
Glycerol Esters of
Rosin Acids
8050-31-5Estimated
Biodegradation
28 daysCO2 evolution0 %CO2
evolution/THCO2
evolution
OECD 301B - Modified
sturm or CO2
Glycerol Esters of
Rosin Acids
8050-31-5Estimated
Biodegradation
28 daysCO2 evolution19.7 %CO2
evolution/THCO2
evolution
OECD 301B - Modified
sturm or CO2
Resin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Estimated
Biodegradation
28 daysCO2 evolution0 %CO2
evolution/THCO2
evolution
OECD 301B - Modified
sturm or CO2
Resin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8Estimated
Biodegradation
28 daysCO2 evolution19.7 %CO2
evolution/THCO2
evolution
OECD 301B - Modified
sturm or CO2
Toluene108-88-3Experimental
Biodegradation
20 daysBOD80 %BOD/ThODAPHA Std Meth
Water/Wastewater
Toluene108-88-3Experimental
Photolysis
Photolytic half-life
(in air)
5.2 days (t 1/2)Benzene71-43-2Experimental
Biodegradation
28 daysBOD96 %BOD/ThODOECD 301F - Manometric
respirometry
Benzene71-43-2Experimental
Photolysis
Photolytic half-life
(in air)
26 days (t 1/2)
12.3 : Bioaccumulative potential
MaterialCAS NumberTest typeDurationStudy TypeTest resultProtocolAcetone67-64-1Experimental BCF
- Other
Bioaccumulation
factor
0.65 Acetone67-64-1Experimental
Bioconcentration
Log Kow-0.24 Non-hazardous
components
Trade Secret Data not available
or insufficient for
classification
N/AN/AN/AN/A1,1-Difluoroethane75-37-6Modeled
Bioconcentration
Log Kow1.13 Episuite Propane74-98-6Experimental
Bioconcentration
Log Kow2.36 Cyclohexane110-82-7Experimental BCF
- Fish
56 daysBioaccumulation
factor
129 OECD305-BioconcentrationRosin, Fumarated,
Polymer with
Glycerol
65997-10-6Experimental
Bioconcentration
Log Kow>6.5 OECD 117 log Kow HPLC
method
Rosin, Fumarated,
Polymer with
Glycerol
65997-10-6Experimental
Bioconcentration
Log Kow2.48 OECD 117 log Kow HPLC
method
Glycerol Esters of
Rosin Acids
8050-31-5 Data not available
or insufficient for
classification
N/AN/AN/AN/AResin acids and
Rosin acids, esters
with diethylene
glycol
68153-38-8 Data not available
or insufficient for
classification
N/AN/AN/AN/AToluene108-88-3Experimental BCF
– Other
72 hoursBioaccumulation
factor
90 Toluene108-88-3Experimental
Bioconcentration
Log Kow2.73 Benzene71-43-2Experimental BCF
– Other
Bioaccumulation
factor
<10 similar to OECD 305Benzene71-43-2Experimental
Bioconcentration
Log Kow2.13
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12.4. Mobility in soil
Please contact manufacturer for more details
12.5 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion
products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an
acceptable permitted waste disposal facility.
SECTION 14: Transport Information
Australian Dangerous Goods Code (ADG) - Road/Rail Transport
UN No.: UN1950
Proper shipping name: AEROSOLS
Class/Division: 2.1
Sub Risk: Not applicable.
Packing Group: Not applicable.
Special Instructions: Limited quantity may apply
Hazchem Code: 2YE
IERG: 49
International Air Transport Association (IATA) - Air Transport
UN No.: UN1950
Proper shipping name: AEROSOLS, FLAMMABLE
Class/Division: 2.1
Sub Risk: Not applicable.
Packing Group: Not applicable.
International Maritime Dangerous Goods Code (IMDG)- Marine Transport
UN No.: UN1950
Proper shipping name: AEROSOLS
Class/Division: 2.1
Sub Risk: Not applicable.
Packing Group: Not applicable.
Marine Pollutant: Not applicable.
Special Instructions: Limited quantity may apply
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Australian Inventory Status:
All components of this product are listed on or exempt from the Australian Inventory of Industrial Chemicals (AIIC).
Conditions may apply prior to introduction for direct importers of this product, Please contact 3M Australia on 136 136 for
further details.
Poison Schedule:This product is intended for Industrial or Professional Use only and therefore is not packaged and labelled in accordance
with the requirements of the Standard for the Uniform Scheduling of Medicines and Poisons.
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SECTION 16: Other information
Revision information:
Complete document review.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of
the product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Greenguard is a United States based program. The Low VOC reference related to United States Federal and State
regulations exemptions for some solvents.
3M Australia SDSs are available at www.3m.com.au