SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
Section 1 IDENTIFICATION
Product Name: BD300/BD305/BD315/BD330 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: lou@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: Big Dog Acrylic Structural Bonding Adhesive BD300/BD305/BD315/BD330
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel.
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
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SAFETY DATA SHEET
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BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
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P270 Do not eat, drink, or smoke when using this product.
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
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SAFETY DATA SHEET
SDS Number:
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BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
3
Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Methacrylic Acid 79-41-4 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
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SAFETY DATA SHEET
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BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Methacrylic Acid (CAS 79-41-4): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPa-s): 20K 200K 20K 200K
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
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SAFETY DATA SHEET
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BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
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VOC: < 50 g/L of mixed product < 50 g/L of mixed product
Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Methacrylic Acid (CAS 79-41-4): LC50 = 7100 mg/m
3
(4 hour inhalation, rat)
LD50 > 7550 mg/kg (oral, rat)
LD50 = 1600 mg/kg (oral, mouse)
LD50 > 500 mg/kg (dermal, rabbit
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment.
Persistence and Degradability: Not Available.
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Acrylic Structural Bonding Adhesive – Cartridges
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Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of by landfill or incineration.
Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Methacrylic Acid (CAS 79-41-4)
All quantities in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Methacrylic Acid (CAS 79-41-4) X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
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SAFETY DATA SHEET
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BD300/BD305/BD315/BD330
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Revision Date:07/09/2018
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International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT