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SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Print Date: 0810212021
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is impo
the precautions identified in this
appropriate methods or actions.
rtant informationthroughout the document. We expect you to follow
document unless your use conditions would necessitate other
I. IDENTIFICATION
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray Foam Sealant
Recommended use of the chemical and restrictions on use
ldentified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. lf your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Gustomer lnformation Number: 833-338-7668
SDSQ uestion-NA@d u pont. com
EMERGENCY TELEPHONE NUMBER
Z$-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Specific target organ toxicity – repeated exposure – Category 2- Oral
Simple Asphyxiant
Label elements
Hazard pictograms
@rM Trademark of The Dow Chemical Company or an affiliate. DuPont Oval Page 1 of 23
Logo trademark of affiliates of DuPont de Nemours,lnc
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
AF t
o
Signalword: WARNING!
Hazards
Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed
May displace oxygen and cause rapid suffocation.
Preca utionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dusU fume/ gas/ misV vapours/ spray.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
lF ON SKIN: Wash with plenty of soap and water.
lF exposed or concerned: Get medical advice/ attention.
lf skin irritation or rash occurs: Get medical advice/ attention
Wash contaminated clothing before reuse.
Storage
Store locked up.
Protect from sunlight. Store in a well-ventilated place
Disposal
Dispose of contents/ container to an approved waste disposal plant’
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Gomponent CASRN Goncentration
2-Ethylhexanoic acid potassium salt
Tris(‘1 -chloro-2-propyl) phosphate
3164-85-0 >= 1.0 – <= 10.0
oh
>= 10.0 – <= 30.0 %13674-84-5
Page2 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Triethyl phosphate
tra ns- 1 -C hloro-3, 3, 3{rifluoropropene
Polyethylene glycol
Polyester polyol
Diethylene glycol
Dimethylbis((1 -oxoneodecyl)oxy)stannane
78-40-0
102687-65-0
25322-68-3
Not available
111-46-6
68928-76-7
>= ‘1.0 – <= 10.0 %
>= 10.0 – <= 30.0 %
>= 1.0 – < 10.0 %
>= 20.0 – <= 80.0 %
>= 1.0 – < 10.0 %
>= 0.25 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). lf potential for exposure exists refer to Section
B for specific personal protective equipment.
lnhalation: Move person to fresh air. lf not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). lf breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove contaminated clothing immediately. lmmediately wash skin with soap and
plenty of water. Suitable emergency safety shower facility should be available in work area.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reuse. ln the case of skin irritation or allergic reactions see a physician.
Eye contact: ln case of contact, immediately flush eye with plenty of water. Suitable emergency eye
wash facility should be available in work area.
lngestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and lndication of
immediate medical attention and specialtreatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology lnformation.
lndication of any immediate medical attention and specialtreatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. lf breathing is
difficult, oxygen should be administered by qualified personnel. Treatment of exposure should be
directed at the control of symptoms and the clinical condition of the patient.
Page 3 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray lssue Date: 0212312021
Foam Sealant
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption
may occur upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. lsolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. lmmediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological lnformation" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. lf contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. lf this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: lsolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or
poorly ventil-ated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate
area of leak or spill. Confined space entry procedures must be followed before entering the area.
Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety
equipment. For additional information, refer to Section B, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological lnformation.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
Page 4 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Gonditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
1ame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
sO'C (122"F) See Section 10 for more specific information.
Storage stability
Storage Period: 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
lf exposure limits exist, they are listed below. lf no exposure limits are displayed, then no values are
licable
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. lf there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
Component Regulation Type of listing Value
Triethvl phosphate US WEEL TWA 7.45 mg/m3
trans-1 -Ch loro-3, 3, 3-
trifluoropropene
US WEEL TWA 800 ppm
Polyethylene glycol US WEEL TWA aerosol 10 mg/m3
Diethylene glycol US WEEL TWA 10 mg/m3
Dimethylbis((1-
oxoneodecvl)oxy)sta n nane
OSHA Z-1 TWA 0.1 mg/m3 , Tin
ACGIH TWA 0.1 mg/m3 , Tin
Further information: 44: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
ACGIH STEL 0.2 ms/m3 , Tin
Further rn-rnration: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
CAL PEL PEL 0.1 mq/m3 , Tin
Further information: S: Skin
CAL PEL STEL 0.2 Tin
Further information: S: Skin
Page 5 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
lndividual protection measures
Eye/face protection: Use safety glasses (with side shields). Where contact with the liquid is likely,
chemical goggles are recommended.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove
barrier materiils include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled, physical requirements (cuUpuncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. lf there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
poiitive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. ln confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
9. PHYSICAL AND CHEMICAT PROPERTIES
Appearance
Physicalstate
Color
Odor
Odor Threshold
pH
Melting poinUrange
Freezing point
Boiling point (760 mmHg)
Flash point
Evaporation Rate (ButYl Acetate
=1)
Flammability (solid, gas)
Lower explosion limit
Upper explosion limit
Vapor Pressure
Relative Vapor Density (air = 1)
Relative Density (water = 1)
Liquefied gas
yellow
No information available
No data available
No data available
No data available
No datai available
No data available
>200’c (>392’F)
Not available
Not applicable to liquids Not expected to form explosive dust-
air mixtures.
Not applicable
Not applicable
No data available
No data available
No data available
Page 6 of 23
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Water solubility
Partition coefficient: n-
octanol/water
Auto-ignition temperatu re
Decomposition temperature
Kinematic Viscosity
Explosive properties
Oxidizing properties
Molecular weight
Not applicable
No data available
No data available
No test data available
No data available
Not applicableNot explosive
No data available
No data available
NOTE: The physical data presented above are typicalvalues and should not be construed as a
specification.
IO. STABILITY AND REACTIVITY
Reactivity: No data available
Ghemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Will not occur by itself’
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
lncompatible materiats: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
1 I. TOXTCOLOGICAT INFORMATION
Toxicological information appears in this section when such data is available
Acute toxicity
Acute oraltoxicitY
Product test data not available. Refer to component data.
Acute dermaltoxicity
Product test data not available. Refer to component data
Acute inhalation toxicity
PageT of23
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data’
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product test data not available. Refer to component data
Mutagenicity
Product test data not available. Refer to component data
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCING TOXIGOLOGY:
2-Ethvlhexanoic acid potassium salt
Acute oraltoxicitY
Based on information for a similar material
Guideline 401
1D50, Rat, female, 2,043 mg/kg OECD Test
Acute dermal toxicity
Based on information for a similar material: LD50, Rabbit, > 2,000 mg/kg OECD Test
Guideline 402 No deaths occurred at this concentration.
Acute inhalation toxicitY
At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated
material may cause respiratory irritation. Prolonged excessive exposure to mist may cause
adverse effects.
LC50, Rat, 4 Hour, vapour, > 0.14 mg/l No deaths occurred following exposure to a saturated
atmosphere.
Page B of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Skin corrosion/irritation
Brief contact may cause moderate skin irritation with local redness
Effects may be slow to heal.
Serious eye damage/eye irritation
May cause severe eye irritation.
May cause corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
For similar active ingredient(s).
ln animals, effects have been reported on the following organs:
Liver.
Carcinogenicity
No relevant data found
Teratogenicity
For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the
mother. Did not cause birth defects in laboratory animals.
Reproductive toxicity
For similar material(s): ln laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals.
Mutagenicity
For similar material(s): ln vitro genetic toxicity studies were negative. Animalgenetic toxicity
studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
Tris(1 -chloro-2-propvl) phosphate
Acute oraltoxicity
1D50, Rat, male and female, >1,000 mg/kg
Acute dermaltoxicity
1D50, Rabbit, > 5,000 mg/kg
Acute inhalation toxicity
No deaths occurred at this concentration. LC50, Rat, 4 Hour, dusVmist, > 7 mg/l
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Page 9 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
No data available.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Garcinogenicity
No relevant data found
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
No relevant data found.
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Triethvl phosphate
Acute oral toxicity
1D50, Rat, 1,131 mg/kg
Acute dermaltoxicity
1D50, Guinea pig, > 21,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dusUmist, > 2.35 mg/l No deaths occurred at this concentration
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
Page 10 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
No relevant data found
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Triethyl phosphate is considered to be a weak cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination,
muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils,
blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found
Reproductive toxicity
ln laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
ln vitro genetic toxicity studies were predominantly negative. Animalgenetic toxicity studies
were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
tra ns-1 -Ch loro-3.3.3-trifluoropropene
Acute oraltoxicity
Single dose oral LD50 has not been determined
Acute dermaltoxicity
The dermal LD50 has not been determined
Acute inhalation toxicity
LC50, Rat,4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant
Page 11 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found
Teratogenicity
No relevant data found
Reproductive toxicity
No relevant data found
Mutagenicity
This materialwas not mutagenic in an Ames bacterial assay
Aspiration Hazard
Based on available information, aspiration hazard could not be determined
Polvethvlene qlvcol
Acute oraltoxicity
Typical for this family of materials. 1D50, Rat, > 10,000 mg/kg Estimated
Acute dermaltoxicity
Typical for this family of materials. 1D50, Rabbit, > 20,000 mg/kg
Acute inhalation toxicity
Typicalfor this family of materials. LC50, Rat, 6 Hour, dusVmist, > 2.5 mg/l No deaths
occurred at this concentration.
Skin corrosion/irritation
Prolonged exposure not likely to cause significant skin irritation.
May cause more severe response if skin is abraded (scratched or cut)
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Corneal injury is unlikely.
Sensitization
For this family of materials:
Did not cause allergic skin reactions when tested in humans.
For this family of materials, sensitization studies done in guinea pigs have been negative
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Recent findings of kidney failure and death in burn patients, as well as some studies using
animal burn models, suggest that polyethylene glycol may have been a factor.
Page 12 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
fssue Date: 0212312021
The use of topical applications containing this material may not be appropriate in severely
burned patients.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
Polyethylene glycols did not cause cancer in long-term animal studies.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
ln animal studies, did not interfere with reproduction
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
Diethvlene qlvcol
Acute oral toxicity
ln humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. lngestion of quantities (approximately65 mL(2o2.) fordiethylene
glycol or 100 mL (3 oz.) forethylene glycol) has caused death in humans. May cause nausea
and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney
failure. 1D50, Rat, male, 19,600 mg/kg
Lethal Dose, Human, adult, 2 Ounces Estimated.
Acute dermaltoxicity
1D50, Rabbit, 13,330 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dusVmist, > 4.6 mg/l The LC50 value is greater than the Maximum
Attainable Concentration. No deaths occurred at this concentration,
Skin corrosion/irritation
Prolonged contact is essentially nonirritating to skin
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Corneal injury is unlikely.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Page 13 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
The substance or mixture is not classified as specific target organ toxicant, single exposure
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to
pose a carcinogenic risk to man.
Teratogenicity
Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic,
high doses in animals. Other animal studies have not reproduced birth defects even at much
higher doses that caused severe maternal toxicity.
Reproductive toxicity
Diethylene glycol did not interfere with reproduction in animal studies except at very high
doses.
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
No aspiration toxicity classification
Dimethvlbis((1 -oxoneodecvlloxv)stan nane
Acute oraltoxicity
1D50, Rat, 892 mg/kg
Acute dermaltoxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact may cause skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Sensitization
Has caused allergic skin reactions when tested in guinea pigs
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity
Specific Target Organ Systemic Toxicity (Repeated Exposure)
No relevant data found.
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Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Carcinogenicity
No relevant data found
Teratogenicity
No relevant data found
Reproductive toxicity
No relevant data found
Mutagenicity
Not mutagenic in Ames Test
Aspiration Hazard
No aspiration toxicity classification
I 2. ECOLOGICAT INFORMATION
Ecotoxicological information appears in this section when such data is available
Toxicity
2-Ethvlhexanoic acid potassium salt
Acute toxicity to fish
Based on information for a similar material:
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
Tris(1 -chloro-2-propvl) phosphate
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
‘100 mg/L in the most sensitive species tested).
1C50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/|, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mgll, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mgll, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring ,32 mgll
Triethvl phosphate
Acute toxicity to fish
Material is practically nontoxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
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Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
LC50, Leuciscus idus (Golden orfe), static test, 48 Hour,2,140 mg/|, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/|, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72Hour, Growth rate inhibition, 900 mg/|,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/|, OECD 209 Test
tra ns-1 -C h loro-3.3,3-trif luoroprope ne
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/|, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mgll, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae),72Hour, Growth rate,
‘l’15 mg/l
Polvethvlene qlvcol
Acute toxicity to fish
Material is practically nontoxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), statictest,96 Hour, > 10,000 mg/|, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
1C50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Skeletonema costatum (marine diatom),72Hour, Growth rate, > 100 mg/l
Diethvlene qlvcol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 75,200 mg/|,
OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea),24 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
Based on data from similar materials
Page 16 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
EC50, Selenastrum capricornutum (green algae),96 Hour,6,500 – 13,000 mg/l
Toxicity to bacteria
EC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic toxicity to fish
Based on data from similar materials
NOEC, Pimephales promelas (fathead minnow), 7 d,
‘15,380
mgil
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea),21d, > 15,000 mg/l
Dimethvlbis((1-oxon lsfannane
Acute toxicity to aquatic invertebrates
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/|, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72Hour,7.6 mg/|, OECD Test Guideline
201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1.2 mgll, OECD Test
Guideline 201
Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mgll
Persistence and degradability
2-Ethvlhexanoic acid potassium salt
Biodegradability: Based on information for a similar material: Material is expected to be
readily biodegradable. Material is ultimately biodegradable (reaches >70o/o mineralization in
OECD test(s) for inherent biodegradability).
Tris(1 -chloro-2-propvl) phosphate
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability. Material is ultimately biodegradable
(reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
’10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Not applicable
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 3024 or Equivalent
Theoretical Oxygen Demand: 1.17 mglmg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
Page 17 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Atmospheric half-life: 0.24 d
Method: Estimated.
Triethvl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
trans-1 -Ch loro-3.3.3-trif luoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 30’1D
Polvethvlene qlvcol
Biodegradability: Material is readily biodegradable. Passes OECD test(s)for ready
biodegradability.
1O-day Window: Pass
Biodegradation: 85 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 1.67 mg/mg
Diethvlene qlvcol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
1O-day Window: Pass
Biodegradation: 90 – 100
o/o
Exposure time: 20 d
Method: OECD Test Guideline 301A or Equivalent
1O-day Window: Not applicable
Biodegradation: 82 – 98 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Theoretical Oxygen Demand: 1.51 mg/mg
Dimethvlbis((1 -oxoneodecvl)oxv)stan na ne
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 3018 or Equivalent
Bioaccumulative potential
Page 1B of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
2-Ethvlhexanoic acid potassium salt
Bioaccumulation: Based on information for a similar material: Bioconcentration potential is
low (BCF < 100 or Log Pow < 3).
Tris(1 -chloro-2-propvl) phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Pa rtition coefficient: n-octanol/water( log Pow) : 2. 59 Measu red
Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured
Triethvl ohosnhate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3)
Partition coefficient: n-octanol/water(log Pow): 0.80 Measured
trans-1-Chloro-3.3.3-f rifluoronrotrene
Bioaccumulation: No relevant data found
Polvethvlene glvcol
Partition coefficient: n-octanol/water(log Pow): -0.698 Pow: 0.2 at 30 "C
Diethvlene qlvcol
Bioaccumulation: Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 'C
Bloconcentration factor (BCF): 100 Fish Measured
Dimethvlbis((1 -oxoneodecvlloxv)stannane
Partition coefficient: n-octanol/water(log Pow): 5.503
Mobility in soil
2-Ethvlhexanoic acid potassium salt
Based on information for a similar material:
Potential for mobility in soil is very high (Koc between 0 and 50)
Tris(1 -chloro-2-propvl) phosphate
Potential for mobility in soil is slight (Koc betwebn 2000 and 5000)
Partition coefficient (Koc): 1300 Estimated.
Triethvl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): 48 Estimated.
tra ns-1 -Chloro-3.3.3-triflu oropropene
No relevant data found.
Polvethvlene qlvcol
No relevant data found
Diethvlee olvcol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Page 19 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Partition coefficient (Koc): < 1 Estimated
Dimethvlbis((1 -oxoneodecvl)oxv)stan nane
No relevant data found.
I 3. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED lN MSDS SECTION: Composition lnformation. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. lncinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage lnformation, MSDS Section 7 Stability & Reactivity
lnformation, MSDS Sectionl0 Regulatory lnformation, MSDS Section 15
I 4. TRANSPORT INFORMATION
DOT
Proper shipping name
UN number
Glass
Packing group
Chemical under pressure, n.o.s.(lnert Gases)
uN 3500
2.2
Classification for SEA transport (lMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S.(lnert Gases)
UN number UN 3500
Glass 2.2
Packing group
Marine pollutant No
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or ll
of MARPOL 73178 and the
IBG or IGC Gode
Classification for Al R transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(lnert Gases)
UN number UN 3500
Class 2.2
Packing group
Page20 ol 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. lt is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
I 5. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title lll(Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Reproductive toxicity
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title lll (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title lll, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
This material does not contain any components with a CERCLA RQ.
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components
Diethylene glycol
CASRN
111-46-6
Galifornia Prop.65
This product contains a chemical that is at or below California Propositions 65's "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.
United States TSCA lnventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S
Toxic Substances ControlAct (TSCA) Chemical Substance lnventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
Page 21 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Health Flammability
Physical
Hazard
2* 1 3
*
= Chronic Effects (See Hazards ldentification)
Revision
ldentification Number: 12069399 I A749 / lssue Dale:0212312021 lVersion: 1.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
nd
Full text of other abbreviations
AllC - Australian lnventory of lndustrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German lnstitute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials ldentification System; IARC - lnternational
Agency for Research on Cancer; IATA - lnternational Air Transport Association; IBC - lnternational
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; lC50 - Half
maximal inhibitory concentration; ICAO - lnternational CivilAviation Organization; IECSC - lnventory of
Existing Chemical Substances in China; IMDG - lnternational Maritime Dangerous Goods; IMO -
lnternational Maritime Organization; ISHL - lndustrial Safety and Health Law (Japan); ISO
lnternational Organisation for Standardization; KECI - Korea Existing Chemicals lnventory; LC50 -
Lethal Concentration to 50
o/o
of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - lnternational Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand lnventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines lnventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and RecoveryAct; REACH - Regulation (EC) No 190712006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance lnventory; TSCA - Toxic Substances ControlAct (United States); UN - United Nations;
ACGIH USA. ACGIH Threshold Limit Values (TLV)
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107
USA. Occupational Exposure Limits (OSHA) - Table Z-'1 Limits for Air
Contaminants
OSHA Z-1
PEL Permissible exposure limit
Short-term exposure limitSTEL
TWA B-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Page 22 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative
lnformation Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. lt is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. lf you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
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