SDS
CHEMLINE ED77.9 S75 PART B BLACK
CHEMLINE CA, INC
1 PRODUCT AND COMPANY IDENTIFICATION
(310)764-0820
CHEMTREC 800.424.9300 (24 HOURS) CCN 4582
CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Supplier Details:
WWW.CHEMLINE.NET
(310)764-0822
Phone:
Emergency:
Web:
Fax:
2 HAZARDS IDENTIFICATION
Health, Acute toxicity, 4 Oral
Health, Skin sensitization, 1
Health, Carcinogenicity, 2
Environmental, Hazards to the aquatic environment – Chronic, 1
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: WARNING
GHS Hazard Pictograms:
GHS Hazard Statements:
H302 – Harmful if swallowed
H317 – May cause an allergic skin reaction
H351 – Suspected of causing cancer
H410 – Very toxic to aquatic life with long lasting effects
GHS Precautionary Statements:
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash … thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280b – Wear protective gloves/eye protection/face protection.
P281 – Use personal protective equipment as required.
P301 + P330 + P331 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or
shower].
P304 + P341 – IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 – IF exposed or concerned: Get medical advice/ attention.
P314 – Get medical advice/attention if you feel unwell.
P333 + P313 – If skin irritation or rash occurs: Get medical advice/attention.
P363 – Wash contaminated clothing before reuse.
P391 – Collect spillage.
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
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P405 – Store locked up.
P501 – Dispose of contents/ container to an approved waste disposal plant.
Route of Entry:
Target Organs:
Inhalation:
Skin Contact:
Eye Contact:
Eyes; Skin; Respiratory system;
Heating, spraying, foaming or otherwise mechanically dispersing operations way generate vapor
or aerosol concentrations sufficient to cause irritation or other adverse effects. Minimal respiratory
tract irritation may occur with exposure to a large amount of material.
Prolonged or repeated exposure can cause skin irritation or dermatitis in some individuals.
May cause watering of the eye and irritation of the conjunctiva.
Ingestion: May cause nausea or vomiting.
Eyes; Ingestion; Inhalation; Skin;
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Ingredients:
CAS# Chemical Name:
0
102093-68-5
104983-85-9
1333-86-4
%
60-90%
10-30%
0-7%
0-3%
Proprietary polyol blend
1,3-Benzenediamine, 4-methyl-2,6-
bis(methylthio)-
1,3-Benzenediamine, 2-methyl-4,6-
bis(methylthio)-
Carbon black
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility immediately.
Skin Contact:Remove all contaminated clothing and shoes. Wash skin with large quantities of water and soap. Wash
clothing before wearing again and clean shoes. If redness, itching or a burning sensation develops or
persists after the area is washed, consult a physician.
Eye Contact: Flush with large amounts of water for 15 minutes. Use fingers to assure that the eyelids are separated and
that the eye is being irrigated. Get immediate medical attention.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. This material is an
aspiration hazard. Never give anything by mouth to an unconscious person. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flash Point: >300 F
Flash Point Method: COC
Dry powder, foam, carbon dioxide. Use cold water spray to cool fire exposed containers to minimize risk of rupture. A solid
stream of water directed into hot burning liquid could cause frothing. If possible, contain fire run off.
6 ACCIDENTAL RELEASE MEASURES
Spill: Remove all sources of flames, heating elements, gas engines, etc. Emergency clean-up personnel should wear
chemical goggles, rubber or plastic gloves and clothing as required to protect against contact. Prevent spreading and
contamination of surface waters and drinking supplies. Notify local health officials and other appropriate agencies if such
contamination should occur.
Clean up: With adequate ventilation and appropriate personal protective equipment, cover the area with an inert absorbent
material such as clay or vermiculite and transfer to steel waste containers. Ventilate area to remove the remaining vapors.
7 HANDLING AND STORAGE
Handling Precautions: Do not smoke or use naked lights, open flames, space heaters or other ignition sources near
pouring, frothing or spraying operations. If contamination with isocyantes is suspected, do not
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reseal containers. Special Emphasis for spray applications of mixed products containing
isocyanates: Inspect the application area for potential to expose other persons or for
overspray to drift onto buildings, vehicles or other property. When spraying building exteriors,
persons entering or exiting the building as well as those inside could be exposed to
polyisocyanates due to wind conditions, open windows or air intakes. Do not begin application
work until these potential problems have been corrected.
Storage Requirements: When stored between 60 -85 F in sealed containers, typical shelf life is 6 months or more
from the date of manufacture. Open containers must be handled properly to prevent moisture
pickup.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Proprietary polyol blend cas#:(0) [60-90%]
Contains no substance with occupational exposure limits
Carbon black cas#:(1333-86-4) [0-3%]
Components with workplace control parameters
TWA 3.5 mg/m3 USA. ACGIH Threshold Limit Values
(TLV)
Not classifiable as a human carcinogen
Engineering Controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Uses
requiring heating and/or spraying may require more agressive engineering controls or PPE.
Personal Protective
Equipment:
HMIS PP, X | Consult your supervisor for special instructions
Personal protective equipment
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate
use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole means of
protection, use a full-face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact with this
product. Dispose of contaminated gloves after use in accordance with applicable laws and
good laboratory practices. Wash and dry hands. Splash contact Material: Nitrile rubber
Minimum layer thickness: 0.4 mm Break through time: 120 min Material tested:Camatril (KCL
730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49
(0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of the
CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by
our customers. It should not be construed as offering an approval for any specific use
scenario.
Eye protection: Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
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TWA 3.5 mg/m3 USA. OSHA – TABLE Z-1 Limits for
Air Contaminants – 1910.1000
TWA 3.5 mg/m3 USA. Occupational Exposure Limits
(OSHA) – Table Z-1 Limits for Air
Contaminants
TWA 3.5 mg/m3 USA. NIOSH Recommended
Exposure Limits
TWA 0.1 mg/m3 USA. NIOSH Recommended
Exposure Limits
Potential Occupational Carcinogen
Carbon black in presence of polycyclic aromatic hydrocarbons
(PAHs)
See Appendix C
See Appendix A
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pigmented liquid.
9.14 lbs/gal
>500 F
None Flammable
<1
Flash Point:
Vapor Density:
>200 F
>1
Spec Grav./Density:
Boiling Point:
Flammability:
Evap. Rate:
Physical State: Odor:Liquid Mild
10 STABILITY AND REACTIVITY
Reactivity: No specific data
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
No specific data
No specific data
Under normal storage conditions hazardous decomposition products should not be produced.
Will not occur.
11 TOXICOLOGICAL INFORMATION
Proprietary polyol blend cas#:(0) [60-90%]
Finished product has not been tested.
Carbon black cas#:(1333-86-4) [0-3%]
Information on toxicological effects
Acute toxicity:
LD50 Oral – rat – male and female – > 8,000 mg/kg (OECD Test Guideline 401)
Inhalation: no data available
LD50 Dermal – rabbit – > 3,000 mg/kg
Skin corrosion/irritation: Skin – rabbit Result: No skin irritation – 24 h (OECD Test Guideline 404)
Serious eye damage/eye irritation: Eyes – rabbit Result: No eye irritation (OECD Test Guideline 405)
Respiratory or skin sensitisation: – guinea pig Result: Did not cause sensitisation on laboratory animals. (OECD Test Guideline 406)
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Germ cell mutagenicity: Ames test S. typhimurium Result: negative
Hamster ovary
DNA repair rat – female
Carcinogenicity:
Carcinogenicity – rat – Inhalation:
Tumorigenic:Carcinogenic by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA
classification.
Limited evidence of carcinogenicity in animal studies
IARC: 2B – Group 2B: Possibly carcinogenic to humans (Carbon black)
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
OSHA.
Reproductive toxicity: no data available
Specific target organ toxicity – single exposure: no data available
Specific target organ toxicity – repeated exposure: no data available
Aspiration hazard: no data available
Additional Information:
RTECS: FF5800000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
12 ECOLOGICAL INFORMATION
Carbon black cas#:(1333-86-4) [0-3%]
Information on ecological effects
Toxicity:
Toxicity to fish LC50 – Danio rerio (zebra fish) – > 1,000 mg/l – 96 h.
Toxicity to daphnia and static test EC50 – Daphnia magna (Water flea) – > 5,600 mg/l – 24 h.
other aquatic (OECD Test Guideline 202) invertebrates
Toxicity to algae static test EC50 – Desmodesmus subspicatus (green algae) – > 10,000 mg/l -:
72 h (OECD Test Guideline 201)
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects: no data available
13 DISPOSAL CONSIDERATIONS
Disposal: Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical
additions, processing or otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal compliance are the
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responsibility solely of the party generating the waste or deciding to discard or dispose of the material.
Do not allow material to enter sewers, a body of water, or contact the ground. Refer to RCRA 40 CFR 261, and/or any other
appropriate federal, state or local requirements for proper classification information.
14 TRANSPORT INFORMATION
DOT – Non DOT/Non RCRA regulated
IATA/IMDG/ICAO – Not dangerous goods
15 REGULATORY INFORMATION
[%] RQ (CAS#) Substance – Reg Codes
—————————————————————-
[10-30%] 1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- (102093-68-5) TSCA
[0-7%] 1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- (104983-85-9) TSCA
[0-3%] Carbon black (1333-86-4) IARC, MASS, OSHAWAC, PA, PROP65, TSCA, TXAIR
Regulatory Code Legend
—————————————————————-
IARC = IARC Carcinogen Risks
TSCA = Toxic Substances Control Act
MASS = MA Massachusetts Hazardous Substances List
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
PROP65 = CA Prop 65
TXAIR = TX Air Contaminants with Health Effects Screening Level
This product can expose you to chemicals including Carbon black (airborne, unbound particles of respirable size), which
is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
WARNING
16 OTHER INFORMATION
Disclaimer:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility
regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose(s).
Revision Date: 2/27/2019
Health = 1, Fire = 0, Reactivity = 0, Specific Hazard = None
Health = 1, Fire = 1, Physical Hazard = 0
X – Consult your supervisor for special instructions
NFPA:
HMIS III:
HMIS PPE:
0
1
None
1
0
X
1
0
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