SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute toxicity Oral – Category 5
Carcinogenicity – Category 2
Eye Irritation – Category 2A
Skin Irritation – Category 3
Specific Target Organ Toxicity – Single Exposure – Category 1
Pictograms
Signal Word
Danger
Hazardous Statements – Health
H303 – May be harmful if swallowed
H351 – Suspected of causing cancer.
H319 – Causes serious eye irritation
H316 – Causes mild skin irritation
H370 – Causes damage to organs.
Precautionary Statements – General
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P103 – Read label before use.
Precautionary Statements – Prevention
P201 – Obtain special instructions before use.
10-1404
Sep 27, 2021
SAFETY DATA SHEET
Sep 27, 2021
Polycoat Products
14722 Spring Ave, Santa Fe Springs, CA, US, 90670-5108
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER’S IDENTIFICATION
Version: 1.0
Date Printed: Sep 27, 2021
Supersedes Date: N.A.
Product ID:
Product Name:
10-14101
PC 412-65D-BLACK, B-Side
Emergency Phone:
Information Phone Number:
Chemtrec:800-424-9300 (account: CCN1217) OR International:703-527-3887 (account:CCN1217)
(562) 802-8834
Fax: (562) 921-7363
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 1 Page
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P264 – Wash thoroughly after handling.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P270 – Do not eat, drink or smoke when using this product.
Precautionary Statements – Response
P312 – Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P308 + P311 – IF exposed or concerned: Call a POISON CENTER/doctor.
P321 – Specific treatment (see section 4 on this SDS).
Precautionary Statements – Storage
P405 – Store locked up.
Precautionary Statements – Disposal
P501 – Dispose of contents/ container to an approved waste disposal plant.
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a
POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with
plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Eye Contact
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take
care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion
IF exposed or concerned: Get medical advice/attention.
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery
position.
Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious
person.
CAS Chemical Name % By Weight
0000107-21-1 ETHYLENE GLYCOL 10% – 18%
0005285-60-9 BENZENEAMINE, 4,4′-METHYLENEBIS[n-(1-
METHYLPROPROPYL)-
8% – 14%
0001333-86-4 CARBON BLACK 4% – 7%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 2 Page
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed
materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous
use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Specific Hazards in Case of Fire
Sudden reaction and fire may result when the product is exposed to oxidizing agents.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene),
goggles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing
appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work
area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous
waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
PC 412-65D-BLACK, B-Side 8 www.Polycoat.com of 3 Page
product is used and stored.
Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground
and surround by dikes to contain spills or leaks.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Respiratory Protection
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air
respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
CARBON
BLACK
3.5 1
ETHYLENE
GLYCOL
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
CARBON
BLACK
3.5a 1 3 (I)
ETHYLENE
GLYCOL
25 (v) 50 (v) 10 (I,H)
(I) – Inhalable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Appearance Liquid
Auto Ignition Temp N.A.
Coefficient Water/Oil N.A.
Decomposition Pt N.A.
Evaporation Rate
Flammability
Slower than ether
N/A
8.77 lb/gal
1.05
Density
Specific Gravity
VOC Regulatory
0.00 lb/gal
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 4 Page
Flammability N/A
Flash Point 95 C
Flash Point Symbol N.A.
Freezing Point N.A.
High Boiling Point N.A.
Low Boiling Point 110 C
Lower Explosion Level
Melting Point
Odor Description
Odor Threshold
pH
Upper Explosion Level
Vapor Density
Vapor Pressure
N.A.
N.A.
Amine-Like
N.A.
N.A.
N.A.
Heavier than air
N.A.
Viscosity N.A.
VOC Part A & B Combined N.A.
Water Solubility N.A.
SECTION 10) STABILITY AND REACTIVITY
Stability
Material is stable at standard temperature and pressure.
Conditions to Avoid
Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.
Hazardous Reactions/Polymerization
Will not occur.
Incompatible Materials
This product will react with any material containing isocyanate. Some reactions can be violent.
Hazardous Decomposition Products
Combustion products: organic vapors and thermal decomposition fragments.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Product may be absorbed through skin and cause nausea, headache, and general discomfort.
Causes mild skin irritation
Serious Eye Damage/Irritation
Vapors can irritate the eyes. Chemical burns may result due to overexposure. Affects of exposure may be delayed.
Causes serious eye irritation
Respiratory/Skin Sensitization
Inhalation : Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or
delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.
Skin sensitization may develop after repeated and/or prolonged contact.
Based on available data, the classification criteria are not met.
Carcinogenicity
Suspected of causing cancer.
Germ Cell Mutagenicity
Based on available data, the classification criteria are not met.
Reproductive Toxicity
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 5 Page
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity – Single Exposure
Causes damage to organs.
Specific Target Organ Toxicity – Repeated Exposure
Based on available data, the classification criteria are not met.
0000107-21-1 ETHYLENE GLYCOL
The substance may cause effects on kidneys as a result of repeated ingestion.
Aspiration Hazard
Based on available data, the classification criteria are not met.
Acute Toxicity
If ingested : In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and
injury may be severe and cause death.
Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.
May be harmful if swallowed
Likely Routes of Exposure
Inhalation, Ingestion, Skin contact, Eye contact
0000107-21-1 ETHYLENE GLYCOL
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.
Chronic Exposure
0001333-86-4 CARBON BLACK
CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon
black for which there is inadequate human evidence, but sufficient animal evidence.
Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced
pulmonary function.
Potential Health Effects – Miscellaneous
0001333-86-4 CARBON BLACK
Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is
unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is
known to the State of California to cause cancer.
0001333-86-4 CARBON BLACK
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)
0000107-21-1 ETHYLENE GLYCOL
LD50 (oral, rat): 5.89 g/kg; 8.54 g/kg; 13.0 g/kg (5)
LD50 (oral, mouse): 7.5 g/kg; 15.28 g/kg (5,6)
LD50 (oral, guinea pig): 6.6 g/kg; 11.0 g/kg (5)
LD50 (oral, rabbit): 5.0 g/kg (5)
LD50 (dermal, rabbit): 9.5 g/kg (6)
SECTION 12) ECOLOGICAL INFORMATION
Toxicity
Based on available data, the classification criteria are not met.
Mobility in Soil
0000107-21-1 ETHYLENE GLYCOL
Adsorption to solid soil phase is not expected. Ethylene glycol will preferentially be distributed into the compartment water.
Other Adverse Effects
No data available.
Bioaccumulative Potential
0000107-21-1 ETHYLENE GLYCOL
No potential for bioaccumulation.
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 6 Page
No potential for bioaccumulation.
Persistence and Degradability
0000107-21-1 ETHYLENE GLYCOL
Readily biodegradable.
0001333-86-4 CARBON BLACK
Carbon Black’s insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the
natural environment.
Results of the PBT and vPvB assessment
0000107-21-1 ETHYLENE GLYCOL
The substance is not PBT/vPvB.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA
criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
Not regulated.
IATA Information
Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000107-21-1 ETHYLENE GLYCOL 10% – 18% SARA313,
DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA,CA_Prop65 –
California Proposition 65
0005285-60-9 BENZENEAMINE, 4,4′-
METHYLENEBIS[n-(1-
METHYLPROPROPYL)- 8% – 14% DSL,SARA312,TSCA
0001333-86-4 CARBON BLACK 4% – 7% DSL,SARA312,TSCA,CA_Prop65 –
California Proposition 65
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for
the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases,
our system will say UN GHS.
GLOSSARY
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California
Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical
Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC-
Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 7 Page
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
ACGIH – American Conference of Governmental Industrial Hygienists; CAS – Chemical Abstracts Service ; Chemtrec – Chemical
Transportation Emergency Center; DSL – Domestic Substances List; ESL- Effects screening levels; GHS – “Globally Harmonized System
of Classification and Labelling of Chemicals” developed by the United Nations; HMIS – Hazardous Material Information Service; IATA –
Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG – International Maritime Dangerous Goods Code; LC – Lethal
Concentration; LD – Lethal Dose; NFPA – National Fire Protection Association; OEL – Occupational Exposure Limits; OSHA- Occupational
Safety and Health Administration, US Department of Labor; PEL – Permissible Exposure Limit; SARA 313 – Superfund Amendments and
Reauthorization Act, Section 313; SCBA – Self Contained Breathing Apparatus; ppm – parts per million; STEL – Short-term exposure limit;
TLV – Threshold Limit Value; TSCA – Toxic Substances Control Act Public Law 94-469; TWA – Time-weighted average; US DOT- US
Department of Transportation.
Version 1.0:
Revision Date: Sep 27, 2021
Version 1.0
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the
information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product.
Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
information.
PC 412-65D-BLACK, B-Side 8 www.Polycoat.com of 8 Page