SECTION 2) HAZARDS IDENTIFICATION
Classification
Eye Irritation – Category 2
Skin Irritation – Category 2
Pictograms
Signal Word
Warning
Hazardous Statements – Health
H319 – Causes serious eye irritation
H315 – Causes skin irritation
Precautionary Statements – General
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P103 – Read label before use.
Precautionary Statements – Prevention
P264 – Wash thoroughly after handling.
P280 – Wear protective gloves,protective clothing,eye protection/face protection.
Precautionary Statements – Response
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P302 + P352 – IF ON SKIN: Wash with plenty of water.
P321 – Specific treatment (see section 4 on this SDS).
PCF 2131-12-50S-NAT, B-Side
Jun 21, 2022
SAFETY DATA SHEET
Jun 21, 2022
Polycoat Products
14722 Spring Ave, Santa Fe Springs, CA, US, 90670-5108
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER’S IDENTIFICATION
Version: 1.0
Date Printed: Jun 21, 2022
Supersedes Date: N.A.
Product ID:
Product Name:
10-14369
PCF 2131-12-50S-NAT, B-Side
Emergency Phone:
Information Phone Number:
Chemtrec:800-424-9300 (account: CCN1217) OR International:703-527-3887 (account:CCN1217)
(562) 802-8834
Fax: (562) 921-7363
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
PCF 2131-12-50S-NAT, B-Side 7www.Polycoat.com of 1 Page
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P362 + P364 – Take off contaminated clothing. And wash it before reuse.
Precautionary Statements – Storage
No precautionary statement available.
Precautionary Statements – Disposal
No precautionary statement available.
Acute toxicity of less than one percent of the mixture is unknown
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Skin Contact
Rinse/wash with lukewarm, gently flowing water and mild soap for 15-20 minutes or until product is removed. If skin irritation occurs or you
feel unwell: Get medical advice/attention.
Eye Contact
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take
care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion
Rinse mouth. If you feel unwell/If concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures.
Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water
on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media
Water and foam may cause violent frothing and possibly endanger the life of the fire fighter, especially if sprayed into containers of hot,
burning material.
Specific Hazards in Case of Fire
Hazardous combustion products include oxides of carbon and nitrogen, various hydrocarbons.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
CAS Chemical Name % By Weight
0127087-87-0 NONYL PHENOL ETHOXYLATE 0.7% – 1.1%
0000108-01-0 DIMETHYLETHANOLAMINE 0.5% – 0.9%
0025265-71-8 DIPROPYLENE GLYCOL 0.4% – 0.7%
0000280-57-9 1,4-DIAZOBICYCLO (2,2,2)OCTANE 0.2% – 0.3%
0025322-68-3 POLYETHYLENE GYLCOL Trace
0009014-93-1 DINONYLPHENYL POLYOXYETHYLENE Trace
0000075-21-8 ETHYLENE OXIDE Trace
0000123-91-1 1,4-DIOXANE Trace
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
PCF 2131-12-50S-NAT, B-Side 7www.Polycoat.com of 2 Page
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Care should always be exercised in dust/mist areas.
Wear protective pressure self-contained breathing apparatus (SCBA)and full turnout gear.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.
Personal Precautions
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing
appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Confine spillage and absorb on sand, sawdust, or other suitable absorbent material and transfer to a sealed container.
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Vent containers before melting the material.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye protection
Wear eye protection with side shields or goggles.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
PCF 2131-12-50S-NAT, B-Side 7 www.Polycoat.com of 3 Page
decontaminated.
Respiratory protection
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
1,4-DIOXANE 100 360 1 1
ETHYLENE
OXIDE
1 (a) 1 1 <0.1b
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
1,4-DIOXANE 1 20
ETHYLENE
OXIDE
<0.18b 1 1
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
VOC Part A & B Combined N.A.
Appearance Liquid
Odor Threshold N.A.
Odor Description Amine-like
pH N.A.
Water Solubility N.A.
Flammability
Flash Point Symbol
Flash Point
N.A.
95 C
Viscosity N.A.
Lower Explosion Level N.A.
Upper Explosion Level N.A.
Vapor Pressure N.A.
Vapor Density
Freezing Point
Melting Point
Low Boiling Point
Heavier than air
N.A.
N.A.
100 C
High Boiling Point N.A.
Auto Ignition Temp N.A.
Decomposition Pt N.A.
Evaporation Rate Slower than ether
Coefficient Water/Oil N.A.
Density 9.03 lb/gal
Specific Gravity 1.08
VOC Regulatory 0.00 lb/gal
PCF 2131-12-50S-NAT, B-Side 7www.Polycoat.com of 4 Page
N.A.
SECTION 10) STABILITY AND REACTIVITY
Conditions To Avoid
Avoid storage at low or high temperatures.
Hazardous Reactions/Polymerization
Contact with isocyanates and strong oxidizers may cause highly exothermic polymerization reaction, which can be violent.
Incompatible Materials
Strong mineral acids and strong alkalis will seriously degrade material. Heat may be involved.
Hazardous Decomposition Products
Combustion by-products: Oxides of carbon, various hydrocarbons.
Stability
Material is stable at standard temperature and pressure.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Causes skin irritation
Serious Eye Damage/Irritation
Causes serious eye irritation
Respiratory/Skin Sensitization
Based on available data, the classification criteria are not met.
Carcinogenicity
Based on available data, the classification criteria are not met.
Germ Cell Mutagenicity
Based on available data, the classification criteria are not met.
Reproductive Toxicity
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity - Single Exposure
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity - Repeated Exposure
Based on available data, the classification criteria are not met.
Aspiration Hazard
Based on available data, the classification criteria are not met.
Acute Toxicity
Based on available data, the classification criteria are not met.
Likely Routes of Exposure
Inhalation, Ingestion, Skin contact, Eye contact
0000075-21-8 ETHYLENE OXIDE
LC 50 (rat): 1460 ppm ( 4 -hour exposure).( 30 )
LC 50 (mouse): 835 ppm ( 4 -hour exposure).( 30 )
LD 50 (oral, rat): 330 mg/kg ( 31 ); a lower value of 72 mg/kg cannot be confirmed.( 32 )
LD 50 (oral, guinea pig): 270 mg/kg.( 31 )
PCF 2131-12-50S-NAT, B-Side 7 www.Polycoat.com of 5 Page
0000123-91-1 1,4-DIOXANE
LC 50 (mouse): 5150 ppm ( 4 -hour exposure); cited as 37000 mg/m 3 ( 10300 ppm) ( 2 -hour exposure) ( 16,19 , unconfirmed)
LC 50 (female rat): 14250 ppm ( 4 -hour exposure); cited as 51.3 mg/L ( 4 -hour exposure) ( 20 )
LD 50 (oral, rat): 5340 mg/kg; cited as 5.17 cc/kg ( 21 )
LD 50 (oral, rabbit): 2060 mg/kg; cited as 2 cc/kg ( 21 )
LD 50 (dermal, rabbit): 7600 mg/kg (cited as 7600 microL/kg) ( 16 , unconfirmed)
SECTION 12) ECOLOGICAL INFORMATION
Toxicity
Based on available data, the classification criteria are not met.
Persistence and Degradability
0025265-71-8 DIPROPYLENE GLYCOL
Biodegradable.
Bioaccumulative Potential
0025265-71-8 DIPROPYLENE GLYCOL
Bioaccumulation is not expected.
Mobility in Soil
No data available.
Other Adverse Effects
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA
criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
Not regulated.
IATA Information
Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0127087-87-0 NONYL PHENOL ETHOXYLATE 0.7% - 1.1% SARA313, DSL,SARA312,TSCA
0000108-01-0 DIMETHYLETHANOLAMINE 0.5% - 0.9% DSL,SARA312,VOC,TSCA
PCF 2131-12-50S-NAT, B-Side 7 www.Polycoat.com of 6 Page
0025265-71-8 DIPROPYLENE GLYCOL 0.4% - 0.7% DSL,SARA312,VOC,TSCA
0000280-57-9 1,4-DIAZOBICYCLO (2,2,2)OCTANE 0.2% - 0.3% DSL,SARA312,TSCA
0025322-68-3 POLYETHYLENE GYLCOL Trace DSL,SARA312,TSCA
0000075-21-8 ETHYLENE OXIDE Trace DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA,RCRA,CA_Prop65 -
California Proposition 65
0000123-91-1 1,4-DIOXANE Trace DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA,RCRA,CA_Prop65 -
California Proposition 65
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
Note: As per GHS, category 1 is the greatest level of hazard within each class.
Glossary
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California
Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical
Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC-
Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
ACGIH - American Conference of Governmental Industrial Hygienists; CAS - Chemical Abstracts Service ; Chemtrec - Chemical
Transportation Emergency Center; DSL - Domestic Substances List; ESL- Effects screening levels; GHS - "Globally Harmonized System
of Classification and Labelling of Chemicals" developed by the United Nations; HMIS - Hazardous Material Information Service; IATA -
Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG - International Maritime Dangerous Goods Code; LC - Lethal
Concentration; LD - Lethal Dose; NFPA - National Fire Protection Association; OEL - Occupational Exposure Limits; OSHA- Occupational
Safety and Health Administration, US Department of Labor; PEL - Permissible Exposure Limit; SARA 313 - Superfund Amendments and
Reauthorization Act, Section 313; SCBA - Self Contained Breathing Apparatus; ppm - parts per million; STEL - Short-term exposure limit;
TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act Public Law 94-469; TWA - Time-weighted average; US DOT- US
Department of Transportation.
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the
information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product.
Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
information.
PCF 2131-12-50S-NAT, B-Side 7 www.Polycoat.com of 7 Page