SAFETY DATA SHEET
Date Issued : 10/13/2008
SDS No : TC-865 PART A
Date Revised : 02/09/2022
Revision No : 3
TC-865 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-865 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 6
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1′-methylenebis[4-isocyanatobenzene]40 – 709048-57-1
4,4′-Diphenylmethane diisocyanate 15 – 40101-68-8
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 10 – 3025686-28-6
2,4′-Diphenylmethane diisocyanate 0.1 – 15873-54-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
Page 2 of 6
TC-865 PART A
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slightly musty
COLOR: Pale yellow
Page 3 of 6
TC-865 PART A
pH: No data available
FLASH POINT AND METHOD: > 110 C (230 F) Closed Cup
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts with water
SPECIFIC GRAVITY: 1.12 (water=1) at 25 C (77 F)
VISCOSITY #1: 1350 Centipoise at 25 C (77 F)
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, alcohols, amines, bases, and acids.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50
DERMAL
LD
50
INHALATION
LC
50
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with
1,1′-methylenebis[4-isocyanatobenzene]
No data
available
No data
available
No data available
4,4′-Diphenylmethane diisocyanate
> 2000 mg/kg
Rat
> 9400 mg/kg
Rabbit
2.24 mg/l Rat (1 h,
dust/mist)
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
> 5000 mg/kg
Rat
No data
available
0.49 mg/l Rat
2,4′-Diphenylmethane diisocyanate
No data
available
> 9400 mg/kg
Rabbit
0.49 mg/l Rat (4 h)
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
4,4′-Diphenylmethane diisocyanate 3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause respiratory irritation.
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
Page 4 of 6
TC-865 PART A
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 15 – 40101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
4,4′-Diphenylmethane diisocyanate 15 – 40 5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm.
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
Page 5 of 6
TC-865 PART A
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 02/09/2022
REVISION SUMMARY: This SDS replaces the 11/14/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 6 of 6
TC-865 PART A
SAFETY DATA SHEET
Date Issued : 10/13/2008
SDS No : TC-865 PART B
Date Revised : 02/09/2022
Revision No : 3
TC-865 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-865 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Reproductive Toxicity, Category 1
GHS LABEL
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H360: May damage fertility or the unborn child.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 30 – 60Proprietary
Distillates (petroleum), hydrotreated light naphthenic 10 – 3064742-53-6
Calcium carbonate (limestone) 10 – 301317-65-3
N-Methylpyrrolidone 1 – 5 872-50-4
Silicon dioxide 0.5 – 1.57631-86-9
Page 1 of 5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
TC-865 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Calcium carbonate (limestone)
OSHA PEL TWA –
[1]
15T 5R
[1]
NIOSH REL TWA –
[1]
10T 5R
[1]
Silicon dioxide
OSHA PEL TWA 20 mppcf
[2]
80 %SiO2
[2]
NIOSH REL TWA – 6
Footnotes:
1. T = Total dust, R = Respirable fraction
2. Mineral dusts
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Cream
pH: No data available
FLASH POINT AND METHOD: > 107.2 C (225 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.18 (water=1) at 25 C (77 F)
VISCOSITY #1: 1500 Centipoise at 25 C (77 F)
(VOC): < 47.6 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
Page 3 of 5
TC-865 PART B
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyether polyol mixture No data available No data available No data available
Distillates (petroleum), hydrotreated light naphthenic No data available No data available No data available
Calcium carbonate (limestone) No data available No data available No data available
N-Methylpyrrolidone 3914 mg/kg Rat 8000 mg/kg Rabbit> 5100 ppm Rat (4 h)
Silicon dioxide > 3300 mg/kg Rat > 5000 mg/kg Rat 0.139 mg/l Rat (4 h)
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Silicon dioxide 3
REPRODUCTIVE TOXICITY: May damage fertility or the unborn child.
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
Page 4 of 5
TC-865 PART B
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS
N-Methylpyrrolidone 1 – 5872-50-4
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Acrylonitrile < 0.001107-13-1
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer and birth defects or other reproductive harm. For more information, go to
www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
N-Methylpyrrolidone 1 - 5 Developmental Toxicity
Naphthalene < 0.001 Cancer
Acrylonitrile < 0.001 Cancer
Styrene < 0.001 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 02/09/2022
REVISION SUMMARY: This SDS replaces the 11/14/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
TC-865 PART B