25TC879-F_SDS.pdf

SAFETY DATA SHEET
Date Issued : 9/4/2008
MSDS No : TC-879 PART A
Date-Revised : 12/9/2013
Revision No : 1
TC-879 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-879 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929

CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 3
Skin Irritation, Category 2
Eye Irritation, Category 2
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
Skull and
crossbones
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H331: Toxic if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENT(S)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P285: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
Page 1 of 7

Response:
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P311: Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Clear colorless liquid with a slight odor.
IMMEDIATE CONCERNS: Toxic by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and
skin contact. This product is a respiratory irritant and potential respiratory sensitizer: repeated inhalation of vapour or aerosol at levels
above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even minimal concentrations of
diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes irritation and possible allergic sensitivity. Skin inflammation is characterized by itching, scaling, or reddening.
INGESTION: Harmful if swallowed. Aspiration hazard. This material can enter the lungs during swallowing or vomiting and cause lung
inflammation and damage. It may also cause irritation to the mucous membranes of the mouth, throat, and digestive tract.
INHALATION: Toxic by inhalation of aerosol or mist. If misted, irritation of mucous membranes, nose, eyes, and throat may occur.
Extremely high vapor concentrations may cause lung damage. Inhalation at levels above the occupational exposure limit could cause
respiratory sensitization and risk of damage to the respiratory system. The onset of the respiratory system may be delayed for several hours
after exposure. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitized persons.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin and respiratory reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Dicyclohexylmethane-4,4′-diisocyanate 75 – 855124-30-1
Cycloaliphatic polymer 15 – 25Proprietary
Phenyl mercuric acetate (60% as Hg) 0.0092 62-38-4
4. FIRST AID MEASURES
EYES: Immediately rinse with water. Remove contact lenses. Hold eyelids apart and flush eyes with water for at least 15 minutes. Get
immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
Page 2 of 7
TC-879 PART A

develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical
attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxides, and HCN.
EXPLOSION HAZARDS: Avoid contact with strong oxidizers and strong acids, as sudden reaction may result in fire and toxic fumes. Reacts
slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
TC-879 PART A

EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Dicyclohexylmethane-4,4′-diisocyanate
TWA NE NE 0.005 0.054 0.01
[1]
0.11
[1]
STEL NE NE NE NE NE NE
Cycloaliphatic polymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Phenyl mercuric acetate (60% as Hg)
TWA NE NE NE NE NE
[1]
0.01
[1]
STEL NE NE NE NE NE
[3]
0.03
[3]
OSHA TABLE COMMENTS:
1. NIOSH REL (ceiling)
2. NIOSH REL
3. NIOSH REL (skin)
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Colorless
pH: Not Applicable
PERCENT VOLATILE: 0.1
FLASHPOINT AND METHOD: 207 C (405 F) Pensky-Martens CC
VAPOR PRESSURE: < 0.001 mmHg at 25 C (77 F) VAPOR DENSITY: Not Established BOILING POINT: Decomposes SOLUBILITY IN WATER: Insoluble, reacts slowly with water SPECIFIC GRAVITY: 1.08 (water=1) at 25 C (77 F) VISCOSITY: 650 Centipoise at 25 C (77 F) Page 4 of 7 TC-879 PART A VOC (Volatile Organic Compound): 1.080 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY STABILITY: This product is stable under normal ambient conditions of temperature and pressure. POLYMERIZATION: Product may foam when exposed to heat and moisture. CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxide, and HCN. INCOMPATIBLE MATERIALS: Moisture, strong acids, amines, and metal carboxylates. 11. TOXICOLOGICAL INFORMATION TOXICITY TO ANIMALS Chemical Name ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC 50 (rat) Dicyclohexylmethane-4,4'-diisocyanate 9900 mg/kg > 10000 mg/kg 0.29 to 0.30 mg/l
(4 h of aerosols)
Cycloaliphatic polymer Not Established Not Established Not Established
Phenyl mercuric acetate (60% as Hg) 41 mg/kg Not Established Not Established
EYE EFFECTS: Serious eye irritation.
SKIN EFFECTS: Causes skin irritation. May cause an allergic skin reaction.
IRRITATION: Causes eye, skin, and respiratory irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: Mercury has toxic effects on bacteria, daphnia magna, fish, and other aquatic organisms.
Mercury can accumulate in organisms, danger of bioaccumulation.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
AQUATIC TOXICITY
96-HOUR LC
50: >= 8.1 mg/l Brachydanio rerio
48-HOUR EC
50: >= 8.3 mg/l Daphnia magna
96-HOUR EC
50: >= 5.0 mg/l Scenedesmus subspicatus (72 hours)
Notes: This information is based only on the Dicyclohexylmethane-4,4′-diisocyanate.
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
Page 5 of 7
TC-879 PART A

AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Dicyclohexylmethane-4,4′-diisocyanate 75 – 855124-30-1Diisocyanate Compounds (Category Code N120)
Phenyl mercuric acetate (60% as Hg) 0.009262-38-4Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Phenyl mercuric acetate (60% as Hg) 0.0092100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Phenyl mercuric acetate (60% as Hg) 0.0092Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Page 6 of 7
TC-879 PART A

D1A – Very
Toxic
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D1A: Material causing immediate and serious toxic effects (Very toxic).
Class D2A: Material causing other toxic effects (Very toxic).
Class D2B: Material causing other toxic effects (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D1A – Acute lethality
D2A – Respiratory tract sensitization
D2B – Eye irritation
D2B – Skin irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: The D1A classification applies for this material in aerosol or mist form.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 9/4/2008 MSDS.
HMIS RATING
HEALTH * 3
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES

1
3 1

HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 7 of 7
TC-879 PART A

SAFETY DATA SHEET
Date Issued : 9/4/2008
MSDS No : TC-879 PART B
Date-Revised : 12/9/2013
Revision No : 2
TC-879 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-879 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929

CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Reproductive Toxicity, Category 1
Environmental:
Aquatic Toxicity, Category 3
GHS LABEL
Exclamation
mark
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H360: May damage fertility or the unborn child .
H412: Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
Page 1 of 6

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P321: Specific treatment (see on this label).
P363: Wash contaminated clothing before reuse.
P308+P313: IF exposed or concerned: Get medical advice/attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Clear pale yellow liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye irritation. May cause allergic skin reaction.
Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: May cause irritation and possible allergic sensitivity with repeated contact.
INGESTION: May be harmful if swallowed.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye and skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 50 – 60Proprietary
Hydroxy terminated poly(oxyalkylated) polyol 20 – 30102-60-3
aspartic acid, n,n’-(methylenedi-4,1-cyclohexanediyl)bis-, 1,1′,4,4′-tetraethyl ester 10 – 20136210-30-5
Phenyl mercuric neodecanoate (35% as Hg) 0.57326545-49-3
4. FIRST AID MEASURES
EYES: Immediately rinse with water. Remove contact lenses. Hold eyelids apart and flush eyes with water for at least 15 minutes. Get
immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical
attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
Page 2 of 6
TC-879 PART B

HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and amines.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Hydroxy terminated poly(oxyalkylated) polyol
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
aspartic acid, n,n’-(methylenedi-4,1-cyclohexanediyl)bis-,
1,1′,4,4′-tetraethyl ester
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Phenyl mercuric neodecanoate (35% as Hg)
TWA NE 0.1 NE 0.1 NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Page 3 of 6
TC-879 PART B

PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: Not Established
PERCENT VOLATILE: 0.17
FLASHPOINT AND METHOD: > 163 C (325 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.03 (water=1) at 25 C (77 F)
VISCOSITY: 1625 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 1.760 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY STABILITY: This product is stable under normal ambient conditions of temperature and pressure. POLYMERIZATION: Product will not undergo polymerization. CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon dioxide, nitrogen oxides, and amines. INCOMPATIBLE MATERIALS: Isocyanates, strong oxidizing agents, and acids. 11. TOXICOLOGICAL INFORMATION TOXICITY TO ANIMALS Page 4 of 6 TC-879 PART B Chemical Name ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC 50 (rat) Polyether polyol mixture Not Established Not Established Not Established Hydroxy terminated poly(oxyalkylated) polyol 3280 mg/kg > 2000 mg/kg Not Established
aspartic acid, n,n’-(methylenedi-4,1-cyclohexanediyl)bis-, 1,1′,4,4′-
tetraethyl ester
> 2000 mg/kg > 2000 mg/kg> 4224 mg/m3 (4
h)
Phenyl mercuric neodecanoate (35% as Hg) 25 to 200 mg/kg Not Established Not Established
IRRITATION: Causes eye irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
GENERAL COMMENTS: No data available
COMMENTS: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Phenyl mercuric neodecanoate (35% as Hg) 0.57326545-49-3Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
Page 5 of 6
TC-879 PART B

TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Phenyl mercuric neodecanoate (35% as Hg) 0.573Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2A – Very
Toxic
WHMIS CLASSIFICATION
Class D2A: Poisonous and infectious material (Very toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A – Chronic toxicity
D2A – Teratogenicity and embryotoxicity
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 1/8/2009 MSDS.
HMIS RATING
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES

1
2 0

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