SAFETY DATA SHEET
Date Issued : 12/2/2011
MSDS No : TC-885 FR REV 1 PART A
Date-Revised : 12/16/2013
Revision No : 1
TC-885 FR REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-885 FR REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer .
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure .
PRECAUTIONARY STATEMENT(S)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
Page 1 of 7
P285: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see on this label).
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P304+P341: IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P308+P313: IF exposed or concerned: Get medical advice/attention.
Storage:
P405: Store locked up.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale yellow liquid with a slight musty odor.
IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes, skin, and respiratory system. May cause
sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of
vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even
minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for
several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: Harmful if inhaled. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization and risk
of serious damage to the respiratory system.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin and respiratory reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
4,4′-Diphenylmethane diisocyanate 40 – 50101-68-8
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 4068515-49-1
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 10 – 2025686-28-6
4. FIRST AID MEASURES
Page 2 of 7
TC-885 FR REV 1 PART A
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical
attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water fog, dry chemical, foam, or carbon dioxide.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons and HCN.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
TC-885 FR REV 1 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
TWA 0.02 0.2 0.005 0.05 0.005
[1]
0.05
[1]
STEL NE NE NE NE NE NE
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slightly musty
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: 0.03
FLASHPOINT AND METHOD: 207 C (405 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F) Decomposes
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.1 (water=1) at 25 C (77 F)
VISCOSITY: 75 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 0.330 g/l Calculated. Theoretical VOC minus water and exempt solvents.
Page 4 of 7
TC-885 FR REV 1 PART A
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: May occur when exposed to heat in the presence of moisture, alkalies, tertiary amines, metal compounds.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbon and HCN.
INCOMPATIBLE MATERIALS: Avoid contact with any materials containing active hydrogens such as water, alcohol, amines, bases, and
acids.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
4,4'-Diphenylmethane diisocyanate > 10000 mg/kg > 9400 mg/kg 0.49 mg/l (4 h)
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer Not Established Not Established Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
4,4′-Diphenylmethane diisocyanate 3
IARC: This product contains substances that are not classifiable as carcinogens to humans.
IRRITATION: Causes eye and skin irritation.
SENSITIZATION: May cause sensitization by inhalation and skin contact.
TARGET ORGANS: Contains material which causes damage to the following organs: upper respiratory tract.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
Page 5 of 7
TC-885 FR REV 1 PART A
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 40 – 50101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
4,4′-Diphenylmethane diisocyanate 40 – 505,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 40Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Page 6 of 7
TC-885 FR REV 1 PART A
D1A – Very
Toxic
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D1A: Poisonous and infectious material (Very toxic).
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D1A – Acute lethality
D2A – Respiratory tract sensitization
D2B – Skin irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: The D1A classification applies for this material in aerosol or mist form.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
2 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 7 of 7
TC-885 FR REV 1 PART A
SAFETY DATA SHEET
Date Issued : 12/2/2011
MSDS No : TC-885 FR REV 1 PART B
Date-Revised : 12/16/2013
Revision No : 1
TC-885 FR REV 1 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-885 FR REV 1 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Carcinogenicity, Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H351: Suspected of causing cancer .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P281: Use personal protective equipment as required.
P273: Avoid release to the environment.
Response:
P308+P313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
Page 1 of 8
PHYSICAL APPEARANCE AND ODOR: White viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause irritation.
SKIN: May cause irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled.
CARCINOGENICITY: This product contains ingredients that are considered to be probable or suspected human carcinogens.
MEDICAL CONDITIONS AGGRAVATED: No data available.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol 60 – 70Proprietary
Decabromodiphenylethane 10 – 2084852-53-9
Zinc borate 5 – 101332-07-6
Antimony trioxide 5 – 101309-64-4
Silica, Amorphous 1 – 57631-86-9
Aluminum Oxide (non-fibrous form) 0.1 – 1.51344-28-1
Arsenic < 0.00657440-38-2
Lead < 0.00657439-92-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation persists.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen bromide, bromine, and oxides of antimony.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
Page 2 of 8
TC-885 FR REV 1 PART B
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
TC-885 FR REV 1 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Decabromodiphenylethane
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Zinc borate
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Antimony trioxide
TWA NE NE NE 0.5 as Sb NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous
TWA
20
mppcf
[1]
80
%SiO2
[1]
NE
10 Total
Dust
NE
[2]
6
[2]
STEL NE NE NE NE NE NE
Aluminum Oxide (non-fibrous form)
TWA NE
[3]
15T,5R
[3]
NE NE NE NE
STEL NE NE NE NE NE NE
Arsenic
TWA NE 0.01 NE 0.01 NE
[2]
0.002
[2]
STEL NE NE NE NE NE NE
Lead
TWA NE 0.050 NE 0.05 NE
[2]
0.05
[2]
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. Mineral Dusts
2. NIOSH REL
3. T = Total, R = Respirable
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
Page 4 of 8
TC-885 FR REV 1 PART B
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: White
pH: Not Established
PERCENT VOLATILE: 0.03
FLASHPOINT AND METHOD: 171 C (340 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.38 (water=1) at 25 C (77 F)
VISCOSITY: 3200 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 0.420 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, hydrogen bromide, bromine, and oxides of antimony.
INCOMPATIBLE MATERIALS: Isocyanates, strong bases, strong acids, and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol Not Established Not Established Not Established
Decabromodiphenylethane > 5000 mg/kg > 2000 mg/kg Not Established
Zinc borate > 10000 mg/kg> 10000 mg/kg Not Established
Antimony trioxide > 34600 mg/kg > 2000 mg/kg Not Established
Silica, Amorphous Not Established Not Established Not Established
Aluminum Oxide (non-fibrous form) Not Established Not Established Not Established
Arsenic 763 mg/kg Not Established Not Established
Lead Not Established Not Established Not Established
CARCINOGENICITY
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TC-885 FR REV 1 PART B
Chemical Name NTP Status
IARC
Status
OSHA
Status
Antimony trioxide 2B
Silica, Amorphous 3
Arsenic 1 1 X
Lead 2 2B X
IARC: This product contains substances that are classified as carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Zinc borate 5 – 101332-07-6Zinc Compounds (Category Code N982)
Antimony trioxide 5 – 101309-64-4Antimony Compounds (Category Code N020)
Lead < 0.00657439-92-1Lead Compounds (Category Code N420)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
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TC-885 FR REV 1 PART B
Chemical Name Wt.%
CERCLA
RQ
Zinc borate 5 - 101,000 lbs.
Antimony trioxide 5 - 101,000 lbs.
Arsenic < 0.00651 lbs.
Lead < 0.006510 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Antimony trioxide 5 - 10 Cancer
Arsenic < 0.0065 Cancer
Lead < 0.0065
Cancer
Developmental Toxicity
Female Reproductive
Male Reproductive
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 12/2/2011 MSDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
2 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
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TC-885 FR REV 1 PART B
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TC-885 FR REV 1 PART B