SAFETY DATA SHEET
Date Issued : 1/4/2007
MSDS No : TC-895 PART A
Date-Revised : 6/27/2013
Revision No : 2
TC-895 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-895 PART A
GENERAL USE: Polyurethane resin
CHEMICAL FAMILY: Aliphatic polyisocyanate
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887
2. HAZARDS IDENTIFICATION
HAZARD DESIGNATION
EEC LABEL SYMBOL AND CLASSIFICATION
“Xn” – Harmful
RISK PHRASES
R20: Harmful by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
R42/43: May cause sensitization by inhalation and skin contact.
SAFETY PHRASES
S1/2: Keep locked up and out of reach of children.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28: After contact with skin, wash immediately with plenty of water and soap.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
GHS CLASSIFICATIONS
Health:
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
GHS LABEL
Health hazardExclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
Page 1 of 6
PRECAUTIONARY STATEMENT(S)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P285: In case of inadequate ventilation wear respiratory protection.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
Response:
P304+P341: IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale yellow viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes and respiratory system. May cause
sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer: repeated inhalation of
vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even
minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for
several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Slightly irritating. May cause tearing, reddening, and swelling.
SKIN: May cause irritation and possible allergic sensitivity with repeated contact.
INGESTION: May cause irritation to the mouth, throat and stomach.
INHALATION: May be harmful if inhaled. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization
and risk of serious damage to the respiratory system.
CHRONIC TOXICITY
CHRONIC EFFECTS: Hot processing of this material releases isocyanate containing vapors. Isocyanates are known to be toxic by
inhalation and can cause skin and respiratory sensitization.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS EINECS
Hexane, 1,6-diisocyanato-, homopolymer >= 9928182-81-2500-060-2
Hexamethylene-1,6-diisocyanate <= 1822-06-0212-485-8
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Consult a physician.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove patient from exposure, keep warm and at rest. Obtain immediate medical attention. Treatment is symptomatic for
primary irritation or bronchospasm. If breathing is labored, oxygen should be administered by qualified personnel. Apply artificial respiration
if breathing has ceased or shows signs of failing.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
Page 2 of 6
TC-895 PART A
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, oxides of nitrogen, HCN: Hydrogen cyanide
(hydrocyanic acid), and isocyanate-containing vapours.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
RELEASE NOTES: US regulations require reporting spills that could reach any surface waters. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a cool, dry place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from
freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Hexane, 1,6-diisocyanato-, homopolymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Hexamethylene-1,6-diisocyanate
TWA NE NE 0.005 0.0350.005
[1]
0.035
[1]
STEL NE NE NE NE NE NE
OSHA TABLE COMMENTS:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
Page 3 of 6
TC-895 PART A
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: 0
FLASHPOINT AND METHOD: 158 C (316 F)
AUTOIGNITION TEMPERATURE: 445 C (833 F)
VAPOR PRESSURE: < 0.03 mmHg at 20 C (68 F)
VAPOR DENSITY: Not Established
BOILING POINT: Decomposes
SOLUBILITY IN WATER: Insoluble, reacts slowly with water
SPECIFIC GRAVITY: 1.16 (water=1) at 25 C (77 F)
VISCOSITY: 1000 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reacts violently with amines (exothermic). Exothermic reactions with acids, alkalis,
powerful oxidants, and alcohols. Reacts with water, whereby carbon dioxide is produced; pressure may build up in closed containers (danger
of bursting).
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, oxides of nitrogen, HCN: Hydrogen cyanide
(hydrocyanic acid), and isocyanate-containing vapours.
INCOMPATIBLE MATERIALS: Amines, water, strong bases, alcohols, and metals.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Hexane, 1,6-diisocyanato-, homopolymer
> 5000 mg/kg > 5000 mg/kg 390 to 453
mg/m3 (4 h)
Hexamethylene-1,6-diisocyanate 746 to 959 mg/kg 599 mg/kg 124 mg/m3 (4 h)
SENSITIZATION: May cause sensitization by inhalation and skin contact.
12. ECOLOGICAL INFORMATION
AQUATIC TOXICITY
96-HOUR LC
50: >= 100 mg/l Brachydanio rerio
48-HOUR EC
50: >= 100 mg/l Daphnia magna
Page 4 of 6
TC-895 PART A
96-HOUR EC50: > 1000 mg/l Scenedesmus subspicatus (72 hours)
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Hexamethylene-1,6-diisocyanate <= 1100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Toxic
Class D-2A: Poisonous and infectious material (Very toxic).
Class D-2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A - Respiratory tract sensitization
D2B - Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
Page 5 of 6
TC-895 PART A
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are included on the Domestic Substances List (DSL) or
the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 1/8/2010 MSDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
TC-895 PART A
SAFETY DATA SHEET
Date Issued : 1/4/2007
MSDS No : TC-895 PART B
Date-Revised : 6/28/2013
Revision No : 2
TC-895 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-895 PART B
GENERAL USE: Polyurethane curative
CHEMICAL FAMILY: Aromatic diamine polyether polyol mixture
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887
2. HAZARDS IDENTIFICATION
HAZARD DESIGNATION
EEC LABEL SYMBOL AND CLASSIFICATION
"Xn" - Harmful
"N" - Dangerous for the environment
RISK PHRASES
R22: Harmful if swallowed.
R43: May cause sensitization by skin contact.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SAFETY PHRASES
S2: Keep out of the reach of children.
S24: Avoid contact with skin.
S37: Wear suitable gloves.
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions/safety data sheets.
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental:
Acute Hazards to the Aquatic Environment, Category 1
Chronic Hazards to the Aquatic Environment, Category 1
GHS LABEL
Page 1 of 6
Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do no eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber liquid with an amine odor.
IMMEDIATE CONCERNS: Harmful if swallowed. Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin
irritation. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause irritation.
SKIN: May cause irritation and possible allergic sensitivity with repeated contact.
INGESTION: Harmful if swallowed.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS EINECS
Di-(methylthio)toluenediamine 50 - 70106264-79-3403-240-8
Polyether polyol mixture 30 - 50ProprietaryProprietary
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Consult a physician.
Page 2 of 6
TC-895 PART B
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash
clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen, sulfur, and highly flammable tetrahydrofuran
may be produced.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
RELEASE NOTES: US regulations require reporting spills that could reach any surface waters. The toll free number for the US Coast Guard
National Response Center is (800) 424-8802.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a cool, dry place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from
freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Di-(methylthio)toluenediamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Page 3 of 6
TC-895 PART B
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.07
FLASHPOINT AND METHOD: 179 C (355 F) Pensky-Martens CC
VAPOR PRESSURE: < 1 mmHg at 25 C (77 F)
VAPOR DENSITY: Not Established
BOILING POINT: > 300 C (572 F) Decomposes
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.16 (water=1) at 25 C (77 F)
VISCOSITY: 650 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 0.900 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen, sulfur, and highly flammable tetrahydrofuran
may be produced.
INCOMPATIBLE MATERIALS: Isocyanates, oxidizing agents, and strong mineral acids.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Di-(methylthio)toluenediamine 1515 mg/kg > 2000 mg/kg Not Established
Polyether polyol mixture Not Established Not Established Not Established
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Avoid release to the environment.
Page 4 of 6
TC-895 PART B
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the MSDS comply with the OSHA Hazard Communication Standard 29 CFR
1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are included on the Domestic Substances List (DSL) or
the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 1/8/2010 MSDS.
Page 5 of 6
TC-895 PART B
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
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TC-895 PART B