BTB
ENTERPRISEs
SAFETY DATA SHEET
WC-753 PART A
Date lssucd : 04/06/2009
SDS No: WC-753 PART A
I)ate Revised: 05/l l/2018
Ro,ision No : 3
r. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: wC-753 PART A
GENERAL USE: Polyu’ethane resin
MANUFACTURER
BJB Entelprises, lnc.
14791 Frrurklin Avenue
Tustin, CA92180
Emergency Phone: (1 1 4) 134-8450
24 HR. EMERGENCY TELEPHONE NIINIBERS
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-388’l CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health;
Acute Toxicity (Inhalation), Category 3
Skin Initation, Category 2
Eye Irritation, Category 2A
Respiratory Sensi tization, Category 1
Skin Sensitization, Category I
Germ Cell Mutagenicity, Category I
Ca cinogenicity, Category I
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Skull zmd
cr-ossbones
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H331 : Toxic if inhaled.
H3 15: Causes skin initation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or bre athing difficulties if inhaled.
H3 17: May cause an alleryic skin reaction.
H340: May cause genetic defects.
H350: May cause cancer.
H335: May cause respiratory in’itation.
H373: May cause damage to organs through prolonged or tepeated expostlrc.
PRECAUTI ONARY STATEMENTS
Prevention:
P201 : Obtain special inshuctions before use.
P202:Do not handle until all safety precautions have been read and understood
P2 60 : Do not breath e dLr st/f u me/gas/mist/vapou rs/splay.
WC.753 PART A
P2’71 : Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264 : Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clottring/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P31l: Call a POISON CENTER/doctor/physician.
P3A+P352: IF ON SICN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention’
P36l +P364: Take off immediately all contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P31 3: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance wittr local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.Vo cAs
Cyclo aliphatic polymer 15 – ,lO Proprietary
Benzene, 1, I’-methylenebisfisocyanato- 15-40 2@,4740-5
Dicyclohexylmethan e-4,4′-diisocyanate l0- 30 5124-30-l
4,4′-Diphenylmethane diisocyanate 10- 30 I 01 -68-8
Propanol, [(1-methyl-1,2-ethanediyl)bis(oxy)]bis-,polymerwith
1,1′-methylenebis[isocyanatobenzene]and
oxybisIpropanol]
t0- 30 68092-58-0
Solvent naphtha (petroleum), light aromatic 0.1 -1 6n42-95-6
Xylene 0.1 -l 1330-20-7
1,2, 4-limethyl ben zen e 0.1 -1 95-63-6
Ethylbenzene 0.1 -t 100-41-4
Cumene
< 0.02 98-82-8
N-Methylpyrrolidone
0.0066 872-504
Phenyl mercuric acetate 0.0017 62-38-4
Toluene
< 0.001 1 08-88-3
Benzene
< 0.0001 7143-2
Naphthalene
< 0.00001 9t-20-3
4. FIRST AID MEAST]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
WC.753 PART A
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrestoccurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGTIISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQTIIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzlx for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPLL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notiff applicable govemment authorities if release is reporable. (See CERCLA in Section 15).
ENVIRONMET{ TAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GEIERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLINGANDSTORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away flom excessive heat, in original or similar container. Avoid unnecessary contacL
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATLJRE: 65-80'F (l 8-27 "C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
osrrA HAZARDOUS COMPONENTS (29 CFRr910.1200)
EXPOSTJRE LIMITS
Chemical Name Type ppm mdm3
Cycloaliphatic polymer
OSHA PEL
TWA
STEL
ACGIH
TLV
TWA
STEL
NIOSH
REL
TWA
STEL
WC.753 PART A
Benzene, 1, l'-methylenebi sI isocyanato-
TWA
OSHA PEL
STEL
TWA
ACGIH
TI;V
STEL
NIOSH
REL
TWA
TWA
STELOSHA PEL
c 0.01 trl0ll
rrl
TWA 0.005
ACGIH
TLV
STEL
TWA
STEL
NIOSH
REI,
c 0.01 0.11
Dicyclohexylmethan e- 4,4'-di isocyanate
TWA
STEL
0.m 0.2
OSHA PEL
c
TWA 0.005
ACGIH
TLV
STEL
TWA 0.005 0.05
STEL
NIOSH
REL
c
g.g2tztg.2tz)
4,4 -Diphenylmethane diisocyanate
TWA
OSIIA PEL
STEL
TWA
sTEL
ACGIH
TLV
TWA
NIOSH
REL
STEL
Propanol, [(
I -methyl - 1,2 -eth anedi yl )bis
(oxy)] bi s-, polymer with I, l' -
methylenebi sI is ocyanatobenzene] and ox ybi s[propanol]
TWA
OSIIA PEL
STEL
TWA
ACGIH
TLV
STEL
TWA
NIOSH
REL
STEL
Solvent naphtha (petroleum), light aromatic
435TWA r00
OSHA PEL
STEL
TWA 100
ACGIH
TLV
STEL 150
Xylene
WC.753 PART A
STEL 150 655
TWA
STEL
OSHA PEL
TWA 25 123
STEL
ACGIH
TLV
TWA 25 125
NIOSH
REL
STEL
1,2,4-trimethylbenzene
TWA 100 435
OSHA PEL
STFI
TWA 100
ACGIH
TLV
STEL 125
100 435TWA
NIOSH
REL
STEL 125 545
Ethylbenzene
245 ttlTWA 50 tll
STEL
OSIIA PEL
TWA 50
STEL
ACGIH
TLV
TWA 50lrl245 ttt
NIOSH
REL
STEL
Cumene
TWA
OSIH PEL
STEL
TWA
ACGIH
TLV
STEL
TWA
NIOSH
REL
STEL
N-Mettrylpyrrolidone
TWA
OSHA PEL
STEL
TWA - tll
0.1 as
Hg
ttJACGIH
TLV
STEL
TWA 0.05
STEL
0.1
NIOSH
REL
C
Ph enyl mercuri c acetate
TWA zffi
STELOSIIA PEL
C 300
NIOSH
REI,
TWA 100 435
WC.753 PART A
Toluene ACGIH
TI.V
TWA
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTEC TTVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cmtridge or fresh air supplied respirator (MOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGENIC PRACTICES: Contaminated clothing should be changed and washedbefore reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Trainingis important. Follow all label precautions.
STEL
TWA 100 375
NIOSH
REL
STEL 150 560
1TWA
OSHA PEL
STEL 5
TWA 0.5
ACGIH
TLV
STEL 2.5
TWA 0.1 0.319
I 3.19
NIOSH
REL
STEL
Benzene
TWA l0 50
OSIIA PEL
STEL
TWA l0 52
ACGIH
TLV
STEL 15 19
TWA 10 50
NIOSH
REL
STEL l5 75
Naphthalene
Footnotes:
1. Skin
2. 1O-minute
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 1.55
FLASH POINT AID METHOD: 96.I'C (205"D Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
WC.753 PART A
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts with water
SPECIFIC GRAVITY: 1.12 (water=1) at25"C (11"D
USCOSITY #1:4150 Centipoise at25"C (T"n
(VOC): < 17 .4 gll Calculated. Thmretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with waterproduces carbon dioxide. Exothermic reaction with materials
containing active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the
miscibility of the reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than
water and sinks to the bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by
liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, strong bases, strong acids, strong oxidizing agents, alcohols, and amines.
1 1. TOXICOLOGICAL INFORMATION
ACUTE TO)ilCITY
WC.753 PART A
Chemical Name ORAL LDsO
DERMAL
LDso
INHALATIONLCSO
Cyclo al iph ati c polymer
No data
available
No data
available
No data available
Benzene, 1, 1'-methylenebis[isocyanato-
No data
available
No data
available
No data available
Dicyclohex ylmethan e-4,4'-diisocyanate
l 8200
mg/kg Rat
> 7000 mg/kg
Rat
0.33 mg/l Rat (4 h,
dust/mist)
4,4′-Diphenylmethane diisocyanate
> 10000
mg/kg Rat
> 9400 mg/kg
Rabbit
490mglm3 Rat (4 h)
Propanol, [(
I -methyl – 1,2-ethanediyl)bis (oxy)] bi s-, polymer with 1, 1′ –
methylenebis[isocyanatobenzene] and oxybis[propanol]
No data
available
No data
available
No data available
Solvent naphtha (petroleum), light aromatic
> 3492 m{kg
Rat
> 3160 mg/kg
Rabbit
> 6193 m{m3 Rat (4h)
Xylene
3523 mglks
Rat
12126mglkg
Rabbit
5000 ppm Rat (4 h)
1,2, 4-tri methylbenzene
> 344O m{kg
Rat
No data
available
l8 mg/l Rat (4 h)
Ethylbenzene
3500 mglkg
Rat
15400 mg/kg
Rabbit
4000 ppm Rat (4 h)
Cumene
2260 m{kg
Rat
No data
available
No data available
N-Methylpyrrolidone
3914 m{kg
Rat
8000 mg/kg
Rabbit
> 5100 ppm Rat (4 h)
Phenyl mercuric acetate
4l mg/kg
Rat
No data
available
No data available
Toluene
> 5580 mg/kg
Rat
12196mglkg
Rabbit
12500 to 28800 mgim3
Rat (4h)
Benzene
> 5960 mg/kg
Rat
8263 m{kg
Rabbit
43,7 mll Rat (4 h)
Naphthalene
490mglkg
Rat
20000 mg/kg
Rabbit
> 0.4mgt Rat(4h)
SKIN CORROSION/IRRITATION: Causes skin initation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MIJ”TAGENICITY: May cause genetic defects.
CARCINOGENICITY
WC.753 PART A
Chemical Name NTP Status IARC Status
4,4′-Diphenylmethane dii socyanate
3
Xylene
3
Ethylbenzene 28
Cumene 2B
Toluene J
Benzene
1 1
Naphthalene ) 28
REPRODUCTM TOKCITY: No data available
STOT-SINGLE E)POSURE: Inhalation – May cause respiratory irritation. – Respiratory system
STOT-REPEATED EXPOSURE: Inhalation – May cause damage to organs through prolonged or repeated exposure. – Respiratory system
ASPIRATION HAZARD: No data available
12. ECOLOGICAL IMORMATION
EITVIRONMENTAL DATA: No data available
ECOTO)ilCOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
B IOACC UMU LA TION/A CCU MIILATION: No d ata avai lab le
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authorityrequirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGT]LATORY INFORMATION
TJNITEDSTATES
SARA TITLE Iu (SUPERFUID AMENDMENTS AND REAUTHORIZATION ACT)
3IIBI2IIAZARD CATEGORIES: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
3 13 of Title III of the Superfund Amendments and Reauthorization Act of 1 986 and 40 CFR Part 372:
Chernical Nanre Y,,lt.VoCAS Comments
Dicycbhcx yhllethane-4.4′-di isocyanate r0- 305124-30-rDiisocyarrate Compounds (Category Code Nl20)
4.4′-Diphcnyl rnelharrc d ii soc1,1v1x19 10- 30 r 01 -68-8Diisocyanate Compounds (Category Code N 120)
Ethylbenz.ene 0.1-1tffi-41-4
Phenyl rnelcu ric ccetate 0.0017 62-38-4Mercury Compounds (Category Code N458)
WC.753 PART A
EPCRA SI’CTION 313 SUPPI,IEIi NOTIFICATION
CERCLA (COMPREHENSIVE ENVIRONMENTAL RFSPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA IUIGUI.ATORY: Fol this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 2A-426-2675):
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGUI,ATORY:
‘Ihis
product does not contain any substances subject to TSCA Section l2(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt fiom the TSCA inventory requilernents.
OCC I]PATIONA L S AFE’IY AND HEA LTH A DMINISTRATION (OSHA
)
29 CFR1910.1I9-.-PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICAI-S: None of the clremicals in
this product ale consideled highly hazzu dous by OSHA.
CALIFORMA PROPOSITION 65: A WARNING: This product can expose you to chemicals including Isee table belowl, which are
known to the State of California to cause cancer and birth defects or other reproductive harm. For more inforrnation, go to
www.P6-5Warnin gs.ca.gov.
Chemical Name
‘V{t.Vo
Listed
Ethylbenzene 0.1 -l Cancer
Cumene < 0.02 Cancer
N-Methylpyrlolidone 0.0066 Develop mental Tox icity
Phenyl mercuric acetate 0.0017 Devel opmental Toxici ry
Toluene < 0.001 Developmental Toxicity
Benzene < 0.0001
o Cancer
o Developrnental Toxicity
o Male Reproductive
Naphthalene < 0.00001 Cancer
OSHA HAZARD COMM. RUI,E: The conrents of the SDS comply with the OSHA Hazard Comrnunication Standad 29 CFR 1910.1200.
CANADA
WHMIS (WORKPI.ACE HAZARDOUS MATERJAI-S INFORMATION SYSTEM): This product has been classified accordin-q to the
hazad criteria ol tlre CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted frorn the Dornestic
Substances List tDSL) or the Non-Domestic Substances List (NDSL).
Chemical Narne Wt.Vo CERCLA RQ
4,4' -Diphenyl rneth ane d ii socyan ate l0- 30 5,000 lbs.
Xylene 0.1 -1 I 00 lbs.
Ethylbenzene 0.1 -l 1,000 lbs.
Cur-nene < 0.02 5,000
Phenyl mercudc acetate 0.0017 1 00 lbs.
Toluene < 0.001 1,000 lbs.
Benzene < 0.0001 l0 lbs.
Naphthalene < 0.00001 100 lbs
WC-753 PART A
GENERAL COMMENTS: No data available
16. OTTIER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 05/l 1/2018
REVISION S UMMARY : This SDS replaces the 05 / 12D015 SDS.
HMISRATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection; See Section 8
MANIIFACTURER DISCLAIMER: This information is furnished without wamnty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumqs no legal responsibility for use or reliance upon ttris data.
PERSONAL PROTECTION
BTB
ENTERPR'585
SAFETY DATA SHEET
WC-753 PART B
Date Issued : 04/06/2009
SDS No: WC-753 PART B
Date Revised: 05/l l/20llJ
Revision No : 3
r. PRODUCT AND COMPANY IDENTI}'ICATION
PnODUCT NAME: wC-753 PART B
GENERAL USE: Polyulethane culative
MANUFACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA92780
Emergency Phone: (7 1 4) 734-8450
24 HR. EMERGENCY TELEPHONE NTJMBERS
CHEMTREC (USA & Canada): (800) 424-9300
oL (703) 527-3881 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Reproductive Toxicity, Category 1
Environmental:
Chronic Hazads to the Aquatic Envitontnent, Category 3
GHS LABEL
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H360: May damage fertility or the unborn child.
H412: Harmful to aquatic life with long leuting effects.
PRECAUTI ONARY STATEMENTS
Prevention:
P201 : Obtain special instr'uctions before use.
P2A: Do not handle until all safety precautions have been read and understood.
P2 80 : Wear pl otective gl oves /protective cl o th i ngleye protecti on/face pro tecti on.
P273: Avoid release to the environment.
Response:
P308+P31 3: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/intelnational regulations
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.Vo CAS
WC-753 PART B
Polyether polyol mixture 60- 100Proprietary
0.54 2654549-3Phenyl mercuric neodecanoate
Naphthalene < 0.001 9r-20-3
4. FIRST AID MEASURF^S
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if initation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHAI-ATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGIIISHING MEDIA: Water spray, carbon dioxidq dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogenoxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQTIIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consideruse of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wem
full protective clottring including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notiff applicable govemment authorities if release is reportable. (See CERCLA in Section l5).
EIWIRONMENTAL PRECAUTIONS
WATERSPILL: Do not discharge into drains orrivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AID STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaUmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80'F 0
8 -n' C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
WC-753 PART B
EXPOSURE GI.IIDELINES
osHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mdm3
Pol yether polyol mixture
OSIIA PEL
TWA
STEL
ACGIH TLV
TWA
STEL
NIOSH REL
TWA
STEL
Phenyl mercuric neodecanoate
OSIIA PEL
TWA
STEL
ACGIH TLV
TWA
_ tll 0.1 as Hg
ttJ
STEL
NIOSH REL
TWA
STEL
Naphthalene
OSHA PEL
TWA 10 50
STEL
ACGIH TI,V
TWA 10 52
STEL l5 19
NIOSH REL
TWA l0 50
STEL 15 75
Footnotes
1. Skin
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels
below recommended exposure limits.
PERSONAL PROTEC TIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTM CLOTHING: Protective clothing should be selected and used in accordance with'Guidelines for the Selection of Chemical
Protective Clothin g' published by ACGIH.
WORK HYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEIVIICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
WC.753 PART B
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: 0.07
FLASH POINT AND METHOD: > 148.9″C (300’F) Pensky-Matens CC
VAPORPRESSURE: No data available
VAPORDENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.04 (water=1) at25″C (77″F)
VISCOSITY #1: 800 Centipoise at25’C (17″n
(VOC): < 0.8 gl Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AID REACTTVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF IIAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogenoxides
INCOMPATIBLE MATERIALS: Isocyanates, strong bases, strong acids, and strong oxidizing agents.
1 1. TOXICOLOGICAL INFORMATION
ACUTE TO)ilCITY
Chemical Name ORAL LDso DERMAL LDsO INHALATIONLCsO
Polyether polyol mixture No data available No data available No data available
Phenyl mercuric neodecanoate 25 to 200 mg&g Rat No data available No data available
Naphthalene 490 mg/kg Rat 20000 mg/kg Rabbit > 0.4 mg/l Rat (4 h)
SKIN CORROSIONIIRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status IARC Status
Naphthalene 2 2B
REPRODUCTM TO)ilCITY: May damage fertility orthe unbom child.
STOT-SINGLE E)GOSURE: No data available
STOT-REPEATED E)POSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
EI{VIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACC LIMULATION/A CCUMLILATION: No d ata avai lab le
DISTRIBUTION: No data available
WC.753 PART ts
CHIIMICAL I,-ATII INI’ORMA’I’ION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL MIITHOD: Tlre generation of waste should be avoided or minirnized whercver possible. E,mpty containers or liners may retain
sonre procluct resiclues. l’his nraterial iurd its containel’must be disposed of in a safe way. Dispose of snrplus ancl non-rccyclable producs via
a licensed waste disposal contractor. Disposal of this procluct, solutions and any by-products shotrld at all tinres conrply with tlre lequiren’)ents
of envilonr.nental protections and waste disposal legislation and any regional loczrl autholityrequirements. Avoid dispersal of spilled material
ancl runoff and contact with soil. waterways, drains and sewers.
I4. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR 0CAO/IATA): Not Regulated
VESSBL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
TJNITED S’fA1’I]S
SARA TITLE III (SUPERFUND A MENDMENTS AND REAUTHORI ZATION A CT)
311 Rlz HA ZARD CA l-E GORIES: Chron ic H eal th H azard
3f3 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
3 l3 of Title III ol’the Superfund Amendrrents and Reauthorization Act of 1986 and 40 CFR Part 312:
EPCRA SI’CTI ON 3I3 SUPPLIER NOTIFI CATION
Chemical Narne Wt.Vo CAS Comments
Phenyl mercuric neodecanoate 0.5426545-49-3Mercury Compounds (Category Code N458)
CERCLA (COMPRtrHENSIVE ENVIRONMENTAI, RFSPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGTTLATORY: For this/these chemicals, rclease of more than the Repor-table Quantity to the environnrent in a 24-hour
period reqnires notification to the National Response Center (800-424-8802 or 202-426-2615):
Chemical Name WtTo CERCI,A RQ
Naphthalene < 0.001 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA IIEGUI-ATORY: This product does not contain any substances subject to TSCA Section l2(b) export notification.
TSCA STA'ruS: This product or its conponents arc listed in or exempt from the TSCA inventory requirements.
OCC UPATI ONA I- S AFE'IY AND HEA LTH A DMIN ISTRATION (OSHA
)
29 CFRl9r0.r I9---PROCFSS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICAIS: None of ille chernicals in
this ploduct are consideled highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: A WARNING: This product can expose you to chemicals including [see table below], which are
known to the State of California to cause cancer and birth defects or other reproductive harrn. For morc information, go to
wrvw.P65Warni n gs.ca.gov.
Chemical Name WtTo Listed
Phenyl mercu ri c neodecanoate 0.s4 Developmental Toxiciry
Naphthalene < 0.001 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910. 1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERJAI-S INFORMATION SYSTEM): This product has been classified according to the
hazard critcria ol'the CPR and the SDS contains all the information required by the CPR.
DOMF-STIC SUIISTANCIt LIST (INVENTORY): All components in this product are listed in or exernpted fronr the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
WC.753 PART B
GBNERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSIIE: Revision
Date Revised: 051 | 112018
REVISION SIJMMARY: This SDS replaces he 05/12D015 SDS.
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is fumished without wamnty, expressed orimplied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on *ris sheet rclates only to the specific material designated herein. BJB Enterprises, Inc.
assurnes no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION