SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Recommended use
Recommended restrictions
TR
-212 H.O.T. Liquid Release
MR212
Industrial use.
None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier TR Industries a Division of Granitize Products Inc.
Address 11022 Vulcan Street
South Gate, CA 90280-0893 United States
Telephone: (562) 923-5438
Emergency CHEMTREC: (800) 424-9300
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Category 2Flammable liquidsPhysical hazards
Category 2Serious eye damage/eye irritationHealth hazards
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 1Hazardous to the ozone layerEnvironmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or
dizziness. Harms public health and the environment by destroying ozone in the upper
atmosphere.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist or vapor. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye
protection/face protection.
Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get
medical advice/attention.
Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
3. Composition/information on ingredients
Mixtures
67-63-0 82-88Isopropanol
CAS number %Chemical name
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1717-00-6 10-131,1-Dichloro-1-fluoroethane
65530-85-0 2-4Poly TFE
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON
CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical
attention if irritation develops and persists.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the
material(s) involved, and take precautions to protect themselves. Wash contaminated clothing
before reuse.
5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for
containment and cleaning up
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles
(wood, paper, oil, etc.) away from spilled material.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid
discharge into drains, water courses or onto the ground. Inform appropriate managerial or
supervisory personnel of all environmental releases.
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7. Handling and storage
Precautions for safe handlingDo not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Wear
appropriate personal protective equipment. Avoid release to the environment. Observe good
industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an
area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the
SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 980 mg/m3Isopropanol (CAS 67-63-0)
400 ppm
US. ACGIH Threshold Limit Values
ValueTypeComponents
STEL 400 ppmIsopropanol (CAS 67-63-0)
TWA 200 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
ValueTypeComponents
STEL 1225 mg/m3Isopropanol (CAS 67-63-0)
500 ppm
TWA 980 mg/m3
400 ppm
US. Workplace Environmental Exposure Level (WEEL) Guides
ValueTypeComponents
STEL 14220 mg/m31,1-Dichloro-1-fluoroethane (CAS 1717-00-6)
3000 ppm
TWA 2370 mg/m3
500 ppm
Biological limit values
ACGIH Biological Exposure Indices
Value Sampling TimeDeterminant SpecimenComponents
40 mg/l Acetone Urine *Isopropanol (CAS 67-63-0)
* – For sampling details, please see the source document.
Appropriate engineering
controls
Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide easy access to water supply
and eye wash facilities.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Rubber gloves are recommended. Be aware that the
liquid may penetrate the gloves. Frequent change is advisable. Suitable gloves can be
recommended by the glove supplier.
Other Wear suitable protective clothing. Use of an impervious apron is recommended.
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Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with
organic vapor cartridge and full facepiece.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state Liquid.
Form Clear liquid.
Color Colorless.
Odor Alcohol-like.
Odor threshold Not available.
pH Not available.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
160 – 190 F (71.11 – 87.78 C)
Flash point 53.0 F (11.7 C)
Evaporation rate 1.7 (Butyl Acetate = 1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Explosive limit – lower (%)Not available.
Explosive limit – upper (%)Not available.
Vapor pressure Not available.
Vapor density 2.1 (air= 1)
Relative density 0.78 (Water= 1)
Solubility(ies)
Solubility (water) Completely soluble in water.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Percent volatile 95 – 98
Pounds per gallon 7.25
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Acids. Strong oxidizing agents. Isocyanates. Chlorine.
Hazardous decomposition
products
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
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11. Toxicological information
Information on likely routes of exposure
Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
Isopropanol (CAS 67-63-0)
LD50 Rabbit
Dermal
Acute
12800 mg/kg
LD50 Rat
Oral
4.7 g/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity Harms public health and the environment by destroying ozone in the upper atmosphere.
Components Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
Isopropanol (CAS 67-63-0)
Aquatic
LC50Fish > 1400 mg/l, 96 hoursBluegill (Lepomis macrochirus)
Persistence and degradabilityNo data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
1,1-Dichloro-1-fluoroethane (CAS 1717-00-6) 2.3
Isopropanol (CAS 67-63-0) 0.05
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Mobility in soil This product is water soluble and may disperse in soil.
Other adverse effects Dangerous for the environment: May damage the ozone layer.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN1219UN number
IsopropanolUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IB2, T4, TP1Special provisions
4b, 150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1219UN number
IsopropanolUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
NoEnvironmental hazards
3LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
IMDG
UN1219UN number
ISOPROPANOLUN proper shipping name
3Class
Transport hazard class(es)
-Subsidiary risk
3Label(s)
IIPacking group
NoMarine pollutant
Environmental hazards
F-E, S-DEmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
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15. Regulatory information
US federal regulations This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Isopropanol (CAS 67-63-0) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard – Yes
Delayed Hazard – No
Fire Hazard – Yes
Pressure Hazard – No
Reactivity Hazard – No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
Isopropanol 67-63-0 82-88
1,1-Dichloro-1-fluoroethane 1717-00-6 10-13
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act (SDWA)
Not regulated.
US state regulations
US. Massachusetts RTK – Substance List
Isopropanol (CAS 67-63-0)
US. New Jersey Worker and Community Right-to-Know Act
1,1-Dichloro-1-fluoroethane (CAS 1717-00-6)
Isopropanol (CAS 67-63-0)
US. Pennsylvania Worker and Community Right-to-Know Law
Isopropanol (CAS 67-63-0)
US. Rhode Island RTK
1,1-Dichloro-1-fluoroethane (CAS 1717-00-6)
Isopropanol (CAS 67-63-0)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
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Country(s) or region Inventory name On inventory (yes/no)*
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
NoPhilippines
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date 18-February-2015
Revision date –
Version # 01
NFPA ratings
02
3
Disclaimer TR Industries cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available.
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