SAFETY DATA SHEET
1. Identification
Product identifier
Other means of identification
Product code
Recommended use
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
MR307, MR307SP, MR309, MR315
Industrial use polish.
Workers (and your customers or users in the case of resale) should be informed of the potential
presence of respirable dust and respirable crystalline silica as well as their potential hazards.
Appropriate training in the proper use and handling of this material should be provided as required
under applicable regulations.
Recommended restrictions
Manufacturer/Importer/Supplier/Distributor information
TR Industries a Division of Granitize Products Inc.Company name
11022 Vulcan StreetAddress
South Gate, CA 90280-0893
United States
(562) 923-5438Telephone
CHEMTREC: (800) 424-9300Emergency telephone
CHEMTREC International: 00 1-703-527-3887
2. Hazard(s) identification
Not classified.Physical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2Serious eye damage/eye irritation
Category 1ACarcinogenicity (inhalation)
Category 3 narcotic effectsSpecific target organ toxicity, single exposure
Category 2 (lungs)Specific target organ toxicity, repeated
exposure (inhalation)
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. May
cause cancer by inhalation. May cause damage to organs (lungs) through prolonged or repeated
exposure by inhalation.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after
handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective
clothing/eye protection/face protection.
Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If exposed or concerned: Get medical
advice/attention. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get
medical advice/attention. Take off contaminated clothing and wash it before reuse.
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
classified (HNOC)
None known.
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Supplemental information None.
3. Composition/information on ingredients
Mixtures
7732-18-5 35 – 40Water
CAS number %Chemical name
64742-47-8 30 – 35Petroleum distillates
14808-60-7 15 – 20Quartz
61790-12-3 5 – 10Fatty acids, tall oil
8002-09-3 1 – 5Pine Oil
141-43-5 1 – < 32-Aminoethanol
All concentrations are in percent by weight unless otherwise indicated.Composition comments
4. First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Inhalation
Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get
medical advice/attention. Wash contaminated clothing before reuse.
Skin contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Eye contact
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Get medical attention if
symptoms occur.
Ingestion
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain. Prolonged exposure may cause chronic effects.
Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
Indication of immediate
medical attention and special
treatment needed
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
General information
5. Fire-fighting measures
Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing
media
During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Cool containers exposed to flames with water until well after the fire is out.
Fire fighting
equipment/instructions
Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods
Will burn if involved in a fire.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
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Prevent product from entering drains.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product
recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid release to the environment.Environmental precautions
7. Handling and storage
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep formation of airborne dusts to a minimum. Provide appropriate exhaust
ventilation at places where dust is formed. Do not breathe dust/fume/vapors. Do not get in eyes,
on skin, or on clothing. Avoid prolonged or repeated contact with skin. Should be handled in closed
systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective
equipment. Avoid release to the environment. Observe good industrial hygiene practices.
Precautions for safe handling
Keep away from heat and sources of ignition. Store in tightly closed container. Store away from
incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
ValueComponents Type
TWA 0.05 mg/m3Quartz (CAS 14808-60-7)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 6 mg/m32-Aminoethanol (CAS
141-43-5)
3 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
FormValueComponents Type
TWA 0.1 mg/m3 Respirable.Quartz (CAS 14808-60-7)
2.4 mppcf Respirable.
US. ACGIH Threshold Limit Values
FormValueComponents Type
STEL 6 ppm2-Aminoethanol (CAS 141-43-5)
TWA 3 ppm
TWA 0.025 mg/m3 Respirable fraction.Quartz (CAS 14808-60-7)
US. NIOSH: Pocket Guide to Chemical Hazards
Form
ValueComponents Type
STEL 15 mg/m32-Aminoethanol (CAS
141-43-5)
6 ppm
TWA 8 mg/m3
3 ppm
TWA 100 mg/m3Petroleum distillates (CAS
64742-47-8)
TWA 0.05 mg/m3 Respirable dust.Quartz (CAS 14808-60-7)
No biological exposure limits noted for the ingredient(s).Biological limit values
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Good general ventilation should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. Provide easy access to water
supply and eye wash facilities.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Nitrile or neoprene gloves are recommended. Other suitable gloves
can be recommended by the glove supplier.
Hand protection
Skin protection
Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Check with respiratory protective
equipment suppliers.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
Observe any medical surveillance requirements. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Solid.Physical state
Paste.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH Not applicable.
Melting point/freezing pointNot available.
Initial boiling point and boiling
range
Not available.
Flash point > 140.0 F (> 60.0 C) (Estimated)
Evaporation rate Not applicable.
Will burn if involved in a fire.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit – lower
(%)
Not available.
Flammability limit – upper
(%)
Not available.
Vapor pressure Not applicable.
Vapor density Not applicable.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not applicable.
Other information
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
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10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
Contact with incompatible materials.Conditions to avoid
Strong oxidizers, strong acids, and strong bases. Chlorine.Incompatible materials
Thermal decomposition of this product can generate carbon monoxide and carbon dioxide.
Nitrogen oxides. Silicon oxide fumes.
Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause
drowsiness and dizziness. May cause cancer by inhalation.
Skin contact Causes skin irritation. May be absorbed through the skin.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Eye contac
t Causes serious eye irritation.
Ingestion May cause discomfort if swallowed.
Symptoms related to the
physical, chemical and
toxicological characteristics
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain. Prolonged exposure may cause chronic effects.
Information on toxicological effects
Acute toxicit
y Not expected to be acutely toxic.
Test ResultsComponents Species
2-Aminoethanol (CAS 141-43-5)
Dermal
Acute
LD50 Rabbit 1025 mg/kg
Oral
LD50 Rat 1089 mg/kg
Quartz (CAS 14808-60-7)
Inhalation
Chronic
LOEC Human 0.0563 mg/m3
Causes skin irritation.Skin corrosion/irritation
Causes serious eye irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitizationNot a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity May cause cancer.
Occupational exposure to respirable dust and respirable crystalline silica should be monitored and
controlled.
IARC Monographs. Overall Evaluation of Carcinogenicity
Quartz (CAS 14808-60-7) 1 Carcinogenic to humans.
NTP Report on Carcinogens
Quartz (CAS 14808-60-7) Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
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This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity –
single exposure
May cause drowsiness and dizziness.
Specific target organ toxicity –
repeated exposure
May cause damage to organs (lungs) through prolonged or repeated exposure by inhalation.
Aspiration hazard Not an aspiration hazard.
Chronic effects May cause damage to organs through prolonged or repeated exposure. May be harmful if
absorbed through skin. Prolonged exposure may cause chronic effects.
Prolonged or repeated exposure may cause liver and kidney damage. These effects have not
been observed in humans.
Further information Symptoms may be delayed.
12. Ecological information
Not expected to be harmful to aquatic organisms.Ecotoxicity
Components Test ResultsSpecies
2-Aminoethanol (CAS 141-43-5)
Aquatic
Acute
EC50Algae 2.8 mg/l, 72 HoursPseudokirchnerella subcapitata
EC50Crustacea 32.6 mg/l, 48 HoursDaphnia magna
LC50Fish 150 mg/l, 96 HoursOncorhynchus mykiss
Chronic
EC50Crustacea 2.52 mg/l, 21 daysDaphnia magna
Petroleum distillates (CAS 64742-47-8)
Aquatic
Acute
LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss)
No data is available on the degradability of this product.Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Aminoethanol (CAS 141-43-5) -1.31
No data available for this product.Mobility in soil
Other adverse effects The product contains volatile organic compounds which have a photochemical ozone creation
potential.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not allow this material to drain
into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used
container. Dispose of contents/container in accordance with local/regional/national/international
regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner.
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
Contaminated packaging
14. Transport information
DOT
Not regulated as dangerous goods.
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IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
This product is a “Hazardous Chemical” as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Quartz (CAS 14808-60-7) Cancer
lung effects
immune system effects
kidney effects
Toxic Substances Control Act (TSCA) All components of the mixture on the TSCA 8(b) inventory are designated
active .
SARA 302 Extremely hazardous substance
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Not listed.
YesSARA 311/312 Hazardous
chemical
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
Classified hazard
categories
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. Massachusetts RTK – Substance List
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
US. New Jersey Worker and Community Right-to-Know Act
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Pine Oil (CAS 8002-09-3)
Quartz (CAS 14808-60-7)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
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US. Rhode Island RTK
2-Aminoethanol (CAS 141-43-5)
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
California Proposition 65
This product can expose you to Quartz, which is known to the State of California to cause cancer.
For more information go to www.P65Warnings.ca.gov.
WARNING:
California Proposition 65 – CRT: Listed date/Carcinogenic substance
Quartz (CAS 14808-60-7) Listed: October 1, 1988
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
Petroleum distillates (CAS 64742-47-8)
Quartz (CAS 14808-60-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesPhilippines
Taiwan Chemical Substance Inventory (TCSI) YesTaiwan
*A “Yes” indicates this product complies with the inventory requirements administered by the governing country(s).
A “No” indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
17-December-2014
15-September-2022
08
NFPA ratings
02
1
TR Industries cannot anticipate all conditions under which this information and its product, or the
products of other manufacturers in combination with its product, may be used. It is the user s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information in the
sheet was written based on the best knowledge and experience currently available.
Disclaimer
SDS US
TR-307, TR-307SP, TR-309, TR-315 Rubbing Compound
3627 Version #: 08 Revision date: – 15-September-2022 Is
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