Safety Data Sheet
N,N-dimethylacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name N.N-dimethylacetoacetamide 80%
Recommended use of the chemical and restrictions on use
Recommended use
Manufacturer or supplier’s details
Company
Address
Chemical intermediate
Nexeo Solutions, LLC.
3 Waterway Square Place Suite 1000
The Woodlands, TX. 77380
United States of America
Emergency telephone number:
Health North America: 1-855-NEXE04U (1-855-639-3648)
Health International: 1-855-NEXE04U (1-855-639-3648)
Transport North America: CHEMTREC (1-800-424-9300)
Additional information: : Responsible Party: Product Safety Group
E-Mail: msds@nexeosolutions.com
SDS Requests: 1-855-429-2661
SDS Requests Fax: 1-281-500-2370
Website: www.nexeosolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Not a hazardous substance or mixture.
GHS Label element
Not a hazardous substance or mixture.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
No hazardous ingredients
SECTION 4. FIRST AID MEASURES
General advice :
If inhaled :
In case of skin contact
In case of eye contact
Do not ieave the victim unattended.
If unconscious place in recovery position and seek medical
advice.
!f symptoms persist, call a physician.
[f skin irritation persists, call a physician.
If on skin, rinse well with water.
If on clothes, remove clothes.
Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
SDS Number: 100000027592 1 / 7 N,N-dimethylacetoacetamide 80%
Safety Data Sheet
N,N”dimethylacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
If swallowed
If eye irritation persists, consult a specialist.
Keep respiratory tract clear.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Do not induce vomiting without medical advice,
SECTION 5. F1REF1GHT1NG MEASURES
Suitable extinguishing media
Unsuitable extinguishing
media
Hazardous combustion prod-
ucts
Further information
Special protective equipment
for firefighters
Water spray
Dry chemical
Carbon dioxide (C02)
Foam
High volume water jet
No hazardous combustion products are known
Standard procedure for chemical fires.
Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Wear self-contained breathing apparatus for firefighting if nec-
essary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Persona! precautions, protec”
tive equipment and emer-
gency procedures
Environmental precautions
Methods and materials for
containment and cleaning up
Use personal protective equipment.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Wipe up with absorbent material (e.g. doth, fleece).
Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Normal measures for preventive fire protection.Advice on protection against
fire and explosion
Advice on safe handling
Conditions for safe storage
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Dispose of rinse water in accordance with local and national
regulations.
Keep container tightiy closed in a dry and weil-ventilated
place.
Electrical installations / working materials must comply with
SDS Number: 100000027592 2 / 7 N,N-dimethylacetoacetamide 80%
Safety Data Sheet
N,N-dimethylacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
the technoiogica! safety standards.
SECTiON 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection
Filter type
Hand protection
Remarks
Eye protection
Skin and body protection
Hygiene measures
Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines,
Organic vapour type
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye wash bottle with pure water
Tightly fitting safety goggles
Impervious clothing
Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
When using do not eat or drink.
When using do not smoke,
Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colour
Odour
Odour Threshold
PH
Freezing Point
Boiling Point (Boiling
point/boiiing range)
Flash point
Evaporation rate
Fiammability (solid, gas)
Upper explosion limit
Lower explosion limit
Vapour pressure
Relative vapour density
Relative density
Density
Solubility(Jes)
Water soiubiiity
Solubility in other solvents
liquid
yellow
ammoniacal
No data available
No data available
No data available
100 C(212 F)
122 C(252 F)
Method: Cleveland open cup
No data available
No data available
No data available
No data available
No data available
No data avaiiabie
1.06@24 C(75aF)
No data available
solubie
No data available
SDS Number: 100000027592 3/7 N,N-dEmethylacetoacetamide80%
Safety Data Sheet
N,N-dimethylacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
Partition coefficient: n-
octanoi/water
Auto-ignition temperature
Thermal decomposition
Paw: 0.27
log Row: -0.58
338 C
No data available
SECTION 10. STABILITY AND REACTMTY
ReactEvity
Chemical stability
Possibility of hazardous reac”
tions
Conditions to avoid
Incompatible materials
Hazardous decomposJtion
products
No dangerous reaction known under conditions of normal use.
Stable under normal conditions.
No hazards to be specially mentioned.
Keep away from heat, flame, sparks and other ignition
sources.
Strong oxidizing agents
Carbon oxides
Nitrogen oxides (NOx)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute dermal toxicity : Acute toxidty estimate: 2,000 mg/kg
Further information
Product:
Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradabiiity
No data available
Bioaccumulafive potential
No data available
Mobility in soil
No data available
SDS Number: 100000027592 4 / 7 N.N-dimethylacetoacetsmide 80%
Qnu iTinno
OLHUUUE
Safety Data Sheet
N,N-dimethylacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
Other adverse effects
Product:
Additional ecoiogical infor- : No data available
mation
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
TDG (Transportation of Dangerous Goods): Not regulated as a dangerous good
IATA (International Air Transport Association): Not regulated as a dangerous good
IMDG-Code: Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
WHMiS Classification : : Not controlled.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR.
The components of this product are reported in the following inventories:
TSCA : On TSCA Inventory
DSL : Ail components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory
NZloC : On the inventory, or in compliance with the inventory
ENCS : On the inventory, or in compiiance with the inventory
KECI : On the inventory, or in compliance with the inventory
PHIL : On the inventory, or in compliance with the inventory
IECSC : On the inventory, or in compiiance with the inventory
SDS Number 100000027592 5 / 7 N,N-dimethyiacetoacetamide 80%
Safety Data Sheet
N,N~dimethyIacetoacetamide 80%
Version 1.0 Revision Date: 02/08/2017
SECTION 16. OTHER INFORMATION
The information accumulated is based on the data of which we are aware and is believed to be correct as
of the date hereof. Since this information may be applied under conditions beyond our control and with
which we may be unfamiliar and since data made become available subsequently to the date hereof, we
do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance
of need that the information is current, applicable, and suitable to their circumstances. This MSDS has
been prepared by NEXEO Solutions EHS Product Safety Department (1-855-429-2661)
MSDS@nexeosolutions.com.
Revision Date
Legacy SDS:
Material number:
70694,640565,52816
02/08/2017
100000015576
Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH
AICS
DSL
NDSL
CNS
GAS
EC50
EC50
EGEST
EOSCA
EINECS
MAK
GHS
>=
IC50
IARC
IECSC
ENCS
KECI
<=
American Conference of Qov-
ernment Industrial Hygienists
Australia, Inventory of Chemical
Substances
Canada, Domestic Substances
List
Canada, Non-Domestic Subs-
tances List
Central Nervous System
Chemical Abstract Service
Effective Concentration
Effective Concentration 50%
EOSCA Generic Exposure Sce-
nario Tool
European Oiifieid Specialty
Chemicals Association
European inventory of Existing
Chemical Substances
Germany Maximum Concentra-
tion Values
Globally Harmonized System^
Greater Than or Equal To
inhibition Concentration 50%
International Agency for Research
on Cancer
Inventory of Existing Chemical
Substances in China
Japan, Inventory of Existing and
New Chemical Substances
Korea, Existing Chemical Invento-
ry
Less Than or EgyalTo
LD50
LOAEL
NFPA
NiOSH
NTP
NZIoC
NOAEL
NOEC
OSHA
PEL
PICCS
PRNT
RCRA
STEL
SARA
TLV
TWA
TSCA
UVCB
WHMIS
Lethal Dose 50%
Lowest Obsen/ed Adverse Effect Level
Nationai Fire Protection Agency
NatEonai Institute for Occupational Safety
& Health
National Toxicology Program
New Zealand Inventory ofChemicais
No Observable Adverse Effect Level
No Obsen/ed Effect Concentration
Occupational Safety & Health Administra-
tion
Permissible Exposure Limit
Philippines inventory of Commercial
Chemical Substances
Presumed Not Toxic
Resource Consen/ation Recovery Act
Short-term Exposure Limit
Superfund Amendments and Reauthori-
zation Act.
Threshold Limit Value
Time Weighted Average
Toxic Substance Control Act
Unknown or Variable Composition, Com-
plex Reaction Products, and BEologicai
Materials
Workplace Hazardous Materials Infor-
SDS Number: 100000027592 6 / 7 N,N-dimethy(acetoacetamide 80%
Safety Data Sheet
N,N"dimethylacetoacetamJde 80%
Version 1.0 Revision Date: 02/08/2017
LC50
matjon System
Lethal Concentration 50%
SDS Number: 100000027592 7 / 7 N,N-dimethy!acetoacetamide 80%