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Reviet+,ed on 0 I /06/2020
I ldentiJication
Product identifier
Trade name:F100 Medium Blue Polvol
Article number : I 02 2 7 2 9
Application of the substance / the mixture Polyurethane resin
Details of the supplier of the safety datu sheet
Sika Advanced Resins, US
EHS Department
M a nufa ctur e r/S upp lier :
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
a dv an c e dr e s in s. ehs
@us.
s ika. c o m
I nfo rm atio n dep artm e nt : P r o du ct s afety d ep ar t m en t
E m er ge ncy telep hone nam b er :
During normal opening times: + I (248) 588-2270
CHEMTREC 24-hour Emergency: +I (800) 424-9300
2 Hazard.(s) identffication
*
6;’:::::::’:::::^***
Carc. 2 H351 Suspected ofcausing cancer.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. I H304 May befatal if swallowed and enters airways-
Aquatic Acute 3 H402 Harmful to aquatic life.
Aquatic Chronic 3 H4I2 Harmful to aquatic liJb with long lasting elJ’ects-
Label elements
GHS tubet elements The product is clussified und labeled according to the Clobally Harmonized System (GHS).
Hazard pietograms
GHSOS
Signal word Danger
(Contd. on page 2)
US
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P rintin g date 0 I /0 6/2 02 0
*
Trade nume: F|00 Medium Blue PolYol
Hazard-determining components of labeling:
Diis opropyl naphthalene
Blue reactive pigment
Solvent naphtha (petroleum), heavy arom.
ethylbenzene
Hazard statements
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
May befatal if swallowed and enters airways.
Harmful to aquatic life.
Harmful to aquatic life with long lastittg fficts.
Precautionary statem ents
Avoid breathing dus t/fu me/gas /mis t/v ap o rs /spray
Obtain special instructions before use-
D o not bre ath e dus t/fum e/ gas /mis t/v ap ors/s pray.
Avoid release to the environment.
Iy’ear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Do NOT induce vomiting.
IF exposed or concerned: Get medicul udvice/uttentiott.
Get medical advice/attention if you.feel unwell.
Store locked up.
Dispose of coitents/contdinel in accortlurrce with local/regional/national/intemational regulations.
Classification system:
NFPA ratings (scale 0 – 4)
Health:0
Fire : l
Reactivity:0
HMlS-ratings (scale 0 – 4)
Health: 0
Fire: l
Reactittitlt :
0
Other hazards
Resalts of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
C hem ical c haracterizatio n : M ixt u re s
Description: Mixture of the substances listed below with nonhazardous additions.
(Contd. ofpage l)
(Contd. on page 3)
REACTTVTTYE
3 C omposition/inform utio non ingredients
US
BUILOIN6 TRUST
Printing datc 0 I /06/2020
Sa.feA DMe Sheet
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Page 3/1 3
Reviewed on 0l/06/2020
Trade nsme: F100 Medium Blue PolYol
Personal precautions, protective equipment and emergency procedures Mount respiratory protective device.
(Contd. on page 4)
{<
(Contd. ofpage 2)
Dangerous components:
cAS: 38640-62-9 Diis opropyl naphthalene s-t0%
cAS:25214-63-5 Alkoxylated amine
>5-<10t%
CAS:64742-94-5
EINECS:265-198-5
Solvent naphtha (petroleum), heavy arom' r-5%
Blue reactive pigment r-5%
cAS:9t-20-3
EINECS: 202-049-5
naphthalene 4.25-
(Jndetermincd.
290 “C (554’F)
Flammability (solid, gaseous): Not applicable’
D e co mp ositio n temq erstare : Not determined.
Product is not selJigniting
Auto igniting:
Danger of explosion: Product does not present an explosion hazard
Explosion limits
Lower:
Upper:
Not determined.
Not determined.
Not determined.
Vapor pressure:
Density at 20
oC
(68 “I):
Relative density
Vapor density
Evoporotion rate
1.64 g/cm’ (l 3.69 lbJgul)
Not determined.
Not determined.
Not determined.
Soluhility in / Miscibility with
lYater: Not miscible or dfficult to mix.
Partitiott coefficient (n-octanolhuatcr) : Not determined
l/iscosity:
Dynamic: Not determined.
(Contd. on page 7)
TJS
BUILNING TRUST
Pri n t i n.g dn te 0 I /06/2 020
Safe$ Datu Sheet
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Page 7/l 3
Rcvictcd on 0I/06/2020
Trade name: F100 Medium Blue Polyol
(Contd. ofpage 6)
Kinematic: Not determined.
Solvent content:
Organic solvents:
VOC content:
0.6 %
0.59 %
9.7 g/l / 0.08 lb/gal
Solids content:
Other information
66.0 %
No further
relevant information available.
10 Stability and renctivity
Reactivity No further
relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications
Possibility of hazardous reactions No dangerous reactions knowtt.
Conditions to avoid No.further relevant information available.
Incompatible materials: No further
relevant information available.
Hazardous decomposition products: Carbon monoxide and carbort dioxide
*
I nfo rm ation on toxico logic al effe cts
Acute toxicity:
I 1 Toxicological information
LD/LC|| values that are relevantfor classiJication
Oral LD5O 743 mg/kg (rat)
Primary irritant
on the skin: No ititant effect.
on the eye: No irritating ffict.
Sensitization: No sensitizing effects htown.
A dditio nal toxic olo gic al inform atio n :
The product shows the following dangers according to internally approved calculation -rrroit to,
(;:{r:.rr!r!ru!^!!’r,
3 8 64 0- 6 2-9 Diisopropyl n ap hth ale n e
Oral
Dermal
Inhalative
LD5O
LD5O
LC50/6 h (dynamic)
>4,000 mg/kg (rat)
>5.6 mg/l (ra) (Test Guideline 402)
000 mg/kg (mouse)
91-20-3 naphlhulene
LD5O
LD5O
490 mg/kg (ra)
5,000 mg/kg (ra)
Oral
Dermal
US
BUILIIING TRUST
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Page 8/l 3
Rcviavcd on 0l/06/2020
*
Trade name: FI00 Medium Blue Polyol
Waste trcatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
(Contd. on page 9)
(Contd. of page 7)
Carcinogenic calegories
NTP (National Toxicology Program)
9 I -20-3naphthalene R
OSHA-Ca (Occupational Safety & Health Administration)
7 I -43-2benzene
IARC (International Agency for
Research on Cancer)
Zeo lit e (Crystal lin e a I umin o s ilic at e) 3
9 I -20-3naphthalene 2B
I 330-20-7xylene 3
I 2 E cological information
Aqaatic toxicity:
48ECsO
96 hr LC50
72 or 96 hr ErC50
3 naphthalene
mg/l (daphnia)
0.5 mg/l (Fish)
0.15 mg/l (Algea)
Toxicity
Persistence and degradability No rel ev ant information av ailab le.
Behavior in environmental systems :
B i o ac cu mul ativ e p ote n ti al N o
fu
r t h e r r e I e v a n t i nfo rmation av ail ab I e’
Mobiliry in soil No further
relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
A d ditional e c olo gic al info r m ati o n :
General notes:
llater hazard class 2 (Self-asses.sment): hazardous for water
Do not allow product to rcuch ground water, wdter coutse ot sewage systent.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further
relevant information available.
I 3 Disposal conslderatlons
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BUILDIiIC TRUST
Softty Duta Sheet
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Reviewed on 0l/06/2020
P t i n ti n g date 0 I /06/2020
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage 8)
Uncleaned packagings:
Recommeidation: Disposal must be made according to official regulations.
*
1 4 Tr an sp ort inform atio n
UN-Number
DOT
IMDG,IATA
not regulated
uN3082
not regulated
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N. O. S. (Diis opropyl naph thal en e), MA N N E P O LLUTA NT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID’
N. O. S. (Diis opropyl naphthalene)
IATA
UN proper shipping name
DOT
IMDG
not regulated
IMDG,IATA
CIass
Label
9 Miscellaneous dangerous substances and articles
9
Transport hazard class(es)
DOT
Class
Packing group
DOT
IMDG,IATA
not regulated
III
Environmental hazards :
hlarine pollutant:
Special marking (IATA)
Product contains environmentally hazardous substances
D ii s op r o py I n aph th al en e
Yes
Symbol (fish and tree)
Symbol (/ish and tree)
Speciol precautions for
user
EMS Number:
Stowage Category
Warning : Miscellaneous dangerous substances and articles
F-A,S-F
A
Tronsport in bulk according to Annex II of
MARPOLT3/78 antl the IBC Code Not applicable.
(Contd. on pagc l0)
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BUILNIN6 TRUST
Safe$ Datu Sheet
acc. to OSHA HC,S
Page l0/13
Reviewed on 01/06/2020
P rinting datc 0 I /0 6/2 02 0
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage 9)
5L
Code: El
Maximum net quantity per inner packaging: j0
ml
Maximum net quantity per outer packaging: 1000 ml
T r an sp o t/A ddit io nal info r m at i o n :
IMDG
Limited quantities (LQ)
Excepted quantities (EQ)
UN 3OS2 ENVIRONMENTALLY HAZARDOUS SUBSTANCE’
LrQUrD, N.O.S. (DIISOPROPYL NAPHTHALENE), 9, III
UN “Model Regulation”:
I 5 Re ga lat o ry info rm atio n
*
Safety, health and environnrental regulations/legislation speciiic for
the substance or mkture
Sara
xylene
A
TSCA (Toxic SabstancesControl Act):
CalciumI37-65-3
A
Fibrous6s997-1 7-3
ACTII/E
Polyether35176-
CTIVE
Diisopropyl38640-62-9
ACTIVE
amme2s2 r 4-63-5
ACTIVE
64742-94-5 naphtha arom.
ACTIVE
e
CTIVE
Blue reactive pigmenl
naplfihalene9 I-20-3
A
I acid, l ester
ACTIYE
CTIYE
xyleneI 330-20-7
CTIVE
t I 1-46-62,
ACTIVE
I 47- I 4-8 ocyanine Blue
Section 355 (extremelY hazardoussubstances):
ingredients isNone
Section 313 (SpeciJic toxicchemical listings):
naphthalene91 -20-s
I 3i0-20-7
C’hemicals regulated by TSCA Section I2(b)
ingredients is listed.None
(Contd. on page
US
BUILDING TRUST
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Printing datc 0 I /06/2 02 0
Chemical regulated by TSCA 5(a)(2)rule:
ingredients is listed.None
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage l0)
Proposition 65
Carcino genic categories
NIOSH-Ca Institute for Occupational Sofnty and Health)
GHS label elements The Product
is
Hazard pictograms
(GHS)
@
(Contd. on page 12)
Hazardous Air Pollutants
naphthalene9I
xyleneI s30-20-7
I 00-4 I -4 e
Chemicals known to cause cancer:
r 3 I 7-65-3 Carbonate
9 r -20-3
I 4808-60-7Quartz
100-41-4ethylbenzene
98-82-8cumene
benzene7-43-2
icals known to cause reproductive toxicity for fem
ales:
None of the ingredients is
Chcmicals known to csuse reprotluctive. toxicity for
males:
I -43-2benzene
Chemicals known to cuuse developmental toxicity:
7 1 -43-2benzene
I 08-88-3toluene
EPA (Environmental Protection Agency)
CBD
9 I -20-3
9 I -20-3
TLV (Threshold Limit Value established byACGIH)
e ingredients is listedNone
None ingredients is
Listed in CIYC Regulations
GHSOS
and to the Globally Harmon
rts
.:,
BUILDI’U6 TftU5T
Printing datc 0 I /06/2 02 0
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Page l2/13
Reviewed on UIi06/2020
Trade name: FI00 Medium Blue PolYol
(Contd. ofpage I l)
Signal word Danger
H azar d-d eterm i ning c o mp o nents of I ab elin g :
Diis opropy I naphthalene
Blue reactive pigment
Solvent naphtha (petroleum), heavy arom.
ethylbenzene
Hazard statements
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
May befatal if swallowed and enters airways.
Harmful to aquatic life.
Harmful to aquatic life with long lasting fficts.
Precautionary statements
Obtain special instructions before use.
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid release to the environment.
Ll/ear protective gloves/protective clothing/eye protection/fuce protection.
If swallowed: Immediately call a poison center/doctor.
Do NOT induce vomiting.
IF exposed ur cuncerned: Get medical advice/attentiott.
Get medical advice/attention if youfeel unwell’
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regttlatiotts
Chimical safety assessn ent: A Chemical Safety lsscssment has not been canied ottt.
16 Other information
This information is based on our present lcnowledge. However, this shall not constitute a guarantee
specffii productfeatures and shall not establish a legally valid contractual relationship.
Date ofpreparation / last revision 0l/06/2020 / 5
Ab breviation s an d acr o ny m s :
II(DG : Internalional Arsritime Code for
r-lon gerous Gnnd s
DOT: US Department of Transporlation
I AT,4 : Intarnational,4ir Transport .Association
ACGIH : American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercisl Chemical Substances
ELINCS: European List ofNotified Chemical Substances
CAS: Chemical Abstracts Serttice (division ofthe American Chemical Society)
NFPA: National I’ire Protection Association (USA)
HMIS: Hazardous Mateials Identification System (USA)
VOC: Volatile Organic Compounds (USA, !)U)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose. 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSII: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
for
any
(Contd. on page 13)
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Pinting date 0 I /06/2020
Reviewed on 01/06/2020
Trade nume: F100 Medium Blue PolYol
(Contd. ofpage 12)
PEL: Permissible Exposure Limit
Carc. 2 : Carcinogenicity – Category 2
STOT RE 2: SpeciJic target organ toxicity (repeated atposure) – Category 2
Asp. Tox. 1: Aspiration hazard –
Category I
Aquatic Acute 3: Hazardous to the aquatic environmenl – acute aquatic hazard – Calegory 3
Aquatic Chronic 3: Hazardous to thi aquatic environment – Iong-term aquatic hazard –
Category 3
*
Data compared to the previous version altered.
BUILDING TRUSTA
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I ldenffication
Product identifier
Trade name: Fl00 Part B ISO
Article number: 102 I 125
Application of the substance / the mkture Polyurethane resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
M anufactu r e r/S upp I i e r :
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 4807 l
USA
ehs-us@axson.com
I nfo rm ati o n d ep artm e n t : P r o du ct s afety d ep ar tm e n t
Em ergency telep hone num b er :
During normal opening times: + I (248) 588-2270
CHEMTREC 24-hour Emergencv: *l (800) 424-9300
2 Hazard.(s) idenffication
Classification of the substonce or mkture
@
GHS’B Heatth hazard
Resp. Sens. I
Carc. 2
STOT RE 2
H334 May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
H35l Suspected ofcausing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
CHSOT
Acute Tox. 4 H332 Harnlful if inhaled.
Skin lrrit. 2 II3I5 Causes skin irritation.
Eye lrrit. 2A H3l9 Causes serious eye irritation.
Skin Sens. I H3 17 May cause an allergic skin reaction.
STOT SE 3 H3 j5
May cause rcspiratory irritation
Aquattc Acute 3 H402 Hurmful to uquatic life.
Label elements
GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
I
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BUITDING TRUST
Printing date 0I /06/2020
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Reviewed on 0l /06/21)20
!
‘I’rade
name: h’|00 Part B ISO
(Contd. ofpage l)
Hozard pictograms
GHSOT GHSO8
Signal word Danger
H azard-determining components of labeling:
diph enylmethane diis o cy anate,is omeres and homo lo gue s
4, 4′ – me thy lene dip heny I diis o cyana te
Diisopropyl naphthalene
Hazard statements
Harmful if inhaled.
Causes skin initation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cdncer.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Harm.ful to aquatic life.
Precautionary statem ents
Avoi d b re athin g dus t/fume/gas/mis thaporshpray
D o n o t b r e at h e du s t/fum e/ gas /mis t/v ap o rs /sp r ay.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case ofinadequate ventilationJ wear respiratory protection.
IF INHALED: Remove person tofresh air and keep comfortablefor breathing.
If in eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poison center/doctor if youfeel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
ILrash contanrinated clotldtrg before reuse.
Store locked up.
Dispose ofcontents/container in accordance with local/regional/national/international regulations.
ClassiJic ation system :
NFPA rutings (scale 0 – 4)
Health: 2
Fire : I
Reactivity :
0
HMlS-ratings (scale 0 – 4)
Health:
*2
Fire : I
Reactivity – 0
(Contd. on page 3)
REACTIVITY
HEALTH
FIRE
US
BUILDING TRUST
Printing date 0 I /06/2020
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Page 3/14
Reviewed on 0I/06/2020
*
Trade name: F100 Part B ISO
(Contd. ofpage 2)
Other hazards
Resalts of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemicul characterization : Mixtures
Description: Mixture of the substances listed below with nonhazardous additions
Dangerous components:
CAS:9016-87-9 dipheny lmethanediis o cy an ate,is omeres an d homo lo gues 10-20%
CAS: 101-68-8
EINECS: 202-966-0
4, 4′-methy I enedip heny I diis o cyanat e I0-20%
CAS: 38640-62-9 Diis opropyl naphthalene 5-10%
CAS: 64742-47-8
EINECS: 265-149-8
Kerosine – unspecified t-5%
CAS: 100-41-4
EINECS: 202-849-4
ethylbenzene 0.1-I%
Description oflirst aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical obsemation for at least 48 hours
after the accident.
After inhalation:
Supplyfresh air and to be sure callfor a doctor.
In case ofunconsciousness place patient stably in side positionfor transportation.
Afier skln corrtact: Immediutely wush with water and soap and rinse thoroughly.
After eve contact:
Rinse opened eye for
several minutes under running water. lf symptoms persist, consult a doctor.
After swallowing: If symptoms persist consult doctor.
I nform ation fo r do cto r :
triost important symp16^t ond effects, both ocutc and delayed No further
relevant information available.
Indication of any immediate medical attention anil special tteatment needed
No further
relevant information available.
US
4 First-aid measures
(Contd. on page 4)
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Puge 4/l 4
Revieu,ed on 0 I /06/202 0
*
Trade name: F|00 Part B ISO
(Contd. ofpage 3)
Personal precautions, protcctivc cqaipment and emergency procedures Mount respi.ra.tory prote.ctive device.
E nv ir o n m e ntal p re cautio ns :
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case ofseepage into water course or sewage syste/n.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with tiquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item I 3.
Ensure adequ ate v entilati on.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section I j
Jbr
disposal information.
Protcctivo ,4ction Criteria for Chemicsls
5 Fire-Jighting measures
Extinguishing media
S uitable exting uis hin g age nts :
CO2, extinguishing powder or water spray. Fight largerfires with water spray.
Use fire fighting
measures that suit the environment.
Special hazards arisingfrom the suhstance or mixture
During heating or in case offire poisonous gases are produced.
Nitrogen oxides Q,{Ox)
Hydrogen cyanide (HCN)
Advice for fireftghters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional inform ation
Dispose offire debris and contaminated fire fighting
water in accordance with official regulations.
6 Accidental release ,neasures
PAC-|:
90r 6-87-9diphenylmethan ediis o cy anate,is omeres and homolo gu es 0.15 mg/m3
I 0 r -68-84, 4′ -methylenediphery I diis o qt anat e 0.45
38640-62-9Diisopropy I naphtha lene 5.6 mg/m’
100-41-4ethylbenzene 3j ppm
PAC-2:
e0 I 6-87-9diphenylmethan ediis o cy ana t e, is omeres and homo logues 3.6 mg/m’
I 0 1 -68-84, 4′ -methyl enedipheny I diis o cyanate 5 mg/m3
38640-62-9Diisopropyl naphthalene 61 mg/m3
on page
tts
ri
BUILDIN6 TRUST
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Sofrty Data Sheet
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Pagc 5/14
Rewewed on 0lt’06/2020
,k
Trade name: h’|00 Part B ISO
of 4
I I 00* ppm
ethylbenzeneI 00-4 I -4
PAC-3:
22 mg/m’
dip henylmethan ediis o cy ana te, is omeres and homo lo gues901 6-87-9
55 mg/m’
r 0 I -68-84, 4′ -methyl enedipheny I diis o cy anat e
370 mg/m’
38640-62-9D ii s o p r o py I n aphth al en e
I 800* ppm
I 00-4 I -4ethylbenzene
Additional information about design of technical systems: Nofurther data; see item 7.
Control parameters
Components htith limit values that require monitoring at the workplace:
The foltowing
constituents are the only constituents of the product which have a P EL, TLV or other recommended
exposln’e linit.
At this time, the other constituents have no lorcwn exposure limits.
I 0 1 – 6 8- 8 4,4′ -m ethylene dip henyl diis o cy an ate
7 Handling and storage
Handling:
Precautions for
safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation
of aerosols.
Information about protection against explosions and fires:
Keep respiratory protective device available.
Conditions for
safe storage, including any incompatibilities
Storage:
Requirements to be met by Storerooms and receptacles: No special requirements.
Informatiort about storage in one contnton storagefacility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Spectfic end use(s) No further
relevant information available.
8 Exposure controls/persona,l protection
TLI/
PEL
REL
Ceiling limit value: 0.2 mg/m3, 0.02 ppm
Long-term value: 0.05 mg/m3, 0.005 ppm
Ceiling limit value: 0.2* mg/m3, 0.02* ppm
*10-min
Long-term value: 0.05 I mg/m3, 0.005 ppm
100-41-4 ethylbenzene
PELLong-term value: 435 mg/m3, 100 ppm
on page
lIs
BUILDIf,I6 TRUST
Printirtg date 0 I /06/2 02 0
Sofrty Data Sheet
acc. to OSH.4 HCS
Page 6/14
Reviewed on U l/Ub/2020
Trade name: FI00 Part B ISO
Additional information: The lists that were during the creation were as basis
Exposure contrcls
P erso nal protective equip m ent :
General protective and hygienic measures:
Ke ep aw ay
fr”onr fo
o d s tuffs, b ev cr a g c s an d
fe
e d.
Immediately remove ull soiled and contaninated clotlting.
Wash hands before breal 140 “C (>284 “F)
(Jndetermined.
t90 “c (374 “F)
Not applicable.
400 “c (752’F)
Flantm ab ility (s oli tl, g as e o u s) :
Ignition temperature:
D e c o mp o sitio n te mp e r ature Not determined.
Auto igniting: Product is not seffigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower:
Upper:
0.4 Vol %
Not determined.
Vapor pressure at 20 “C
(68 oF):
U hPa
Density at 20
oC
(68
“F):
Relative density
Vapor density
Evaporation rate
I .73 g/cm3 (1a.a4 lbs/gal)
Not determined.
Nut leternined.
Not determined.
Solubility in / Miscibility with
ll/ater: Not miscihle or dfficult to mix.
Partition c oeffi cient ( n -octanol/water) : Not determined.
(Contd. on page 8)
US
tt
BUILIIING TRUST
Printing date 0 1 /06/2 02 0
Sof”A Datu Sheet
acc. to OSH,4 HCS
Page 8/l 4
Reviev,ed on 0 I /06/2020
Trade name: Fl00 Part B ISO
I nform ation on toxicological effe cts
Acute toxicity:
Primary iwitant effect:
on the skin: Irritant to skin and mucous membranes.
(Contd. on page 9)
(Contd. ofpage 7)
Viseosity:
Dynamic at 20
oC
(68 “F):
Kinematic at 40 “C
(104 “F):
200 mPas
100 mm’z/s
Solvent content:
Organic solvents:
VOC content:
0.6 %
0.57 %
9.9 g/l / 0.08 lb/gal
Solids content:
Other information
89.9 %
No further
relevant information available.
10 Stability and reaetivity
Reactivity No further
relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
P o ssibility of h azardo u s re actio ns
Violent reactions with -NHx, -OH and -SH- groups.
In the presence of water or humidity gas (CO2) is porduced and/or uncontrolled polymerization, possibly leading
to internal pressure rises and conscqucnt risk ofcontainer breach.
Conditions to avoid Nofurther relevant infonnation available.
Incompatible materials: No further
relevant information available.
H azar do us de c o mp o siti on pro du cts :
Nitrogen oxides
Carbon monoxide and carbon dioxide
(possible HCN)
I 1 Toxicolo gical inform atio n
LD/LC|| vulues thul are rclcvanlfor classiJicatiort:
I 0 1 – 6 8 – 8 4,4′-m ethylene dip henyl dii so cy an ate
Oral
Dermul
LD5O
LD5O
2,200 mg/kg (mouse)
>9,400 mg/kg (rabbit)
3 8 6 4 0- 6 2 -g Di isopropyl n ap hth ale ne
Oral
Dennal
Inhalative
LD5O
LD5O
LC50/6 h (dynamic)
>4,000 mg/kg (mouse)
>4,000 mg/kg (rat)
>5.6 mg/l (rat) (Test Guideline 402)
US
BUILUIN6 TRUST
Printing date 0 I /06/2020
SafeA Datu Sheet
acc. to OSHA HCS
Puge 9/14
Revi euted on 0 I /06/2 02 0
Trade name: Fl00 Part B ISO
(Contd. ofpage 8)
on the eye: Irritating effect.
Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
Additional toxicological inform ation:
The product shows thefollowing dangers according to internally approved calculation methods for
preparations
Harmful
Irritant
Carcinogenic categories
NTP (National Toxicology Program)
None of the ingredients is
OSHA-Ca (Occupational Sqfety & Health Administration)
7 I -43-2benzene
IARC (International Agency for
Research on Cancer)
901 6-87-9 is omeres and homologues 3
r 0 I -68-84, 4′ -methylenedipheny I di is o cy an a t e 3
Zeolite (Crystalline aluminosilicate) 3
I 3463-67-7titanium dioxide 2B
I 330-20-7xylene
3
I 00-4 I -4ethylbenzene
2B
I 2 Ecological information
,t
Toxicity
Persistence and degradability relevant information avai
Behavior in environm ental systems :
Bioaccumulative potential No.further relevant information available.
Mobility in soil No further
relevant information available.
Additio nal eco logic al info rm atio n :
General notes:
Water hazard class I (Self-a,s,ses,sment): ‘slightly
hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water cou/se or sewage system.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
(Contd. on page l0)
Aquatic toxicity:
3 8 6 4 0- 6 2-9 Diisopropyl n ap hth ale ne
48 hr EC50
96 hr LC50
72 ur 96 hr ErC50
0.16 mg/l (daphnia)
0.5 mg/l (Fish)
0.15 rng/l (Algea)
US
BUILOINC TRUST
Printing date 0 I /06/2020
Snfety Dote Sheet
acc. to OSHA HCS
Page l0/14
Revie.wcrl on 0 I /06/202 0
Trade name: F|00 Part B ISO
(Contd. ofpage 9)
Other adverse effects No further
relevant information available.
1 3 Disposal considerations
ll/aste treatment m ethods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to fficial
regulations.
:t
I 4 Transport inform ation
UN-Number
DOT
IMDG,IATA
not regulated
uN3082
UN proper shipping name
DOT
IMDG
not regulated
ENVIRONMENT’ALLY HAZARDO US SUBSTANCE, LIQU]D,
N. O. S. (Diisopropyl naphthalene), MANNE POLLUTANT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, L]QLUD,
N. O. S. (Diis opropyl naphthalen e)
IATA
Transport hazard class(es)
DOT
Class not regulated
IMDG,IATA
CIttss
Label
9 Miscellaneous dangerous substances and articles
9
Packing group
DOT
IMDG,IATA
not regulated
ilI
Environmental hazards :
Marine pollutant:
Special marking (IATA) :
Product contains environmentally hazardous substances
Diisopropyl naphthalene
Yes
Symbol (fish and tee)
Symbol (fish and tree)
(Contd. on page I I )
US
BL’ILilII’Jfi TRUST
P rinting date 0 I /0 6/2 0 2 0
Safe$ I)ats Sheet
scc- to OSHA HCS
Page I l/14
Hewewed on 0l/06/’2020
Trade name: FI00 Part B ISO
(Contd. ofpage l0)
Special prccautions for user
Danger code (Kemler):
EMS Number:
Stowage Category
Warning: Miscellaneous dangerous subslances and article.g
90
F-A,S-F
A
Transport in bulk according to Annex II of
MARPOLT3/78 and the IBC Code Not applicable
Tr an sp ort/A ddition al inform atio n :
IMDG
Limited quantities (LQ)
Excepted quantities (EQ)
5L
Code: EI
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN “Model Regulationt’ UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LrQUrD, N.O.S. (DIISOPROPYL NAPHTHALENE), 9, III
1 5 Regulatory inform atio n
i.
Safety, health snd environmental regulations/legislation speciJic for
the suhstance or mixture
Sara
Section 3 5 5 (extremely hazardous substances) :
None of the ingredients is listed.
on page I 2)
Section 313 (Specific toxic chemical listings):
90 r 6-87-9dip heny lmeth an ediis o cy anate, i s omeres and homolo gue s
I 0r -68-84, 4′ -methyl en ediphenyl diis o cy an ate
I 330-20-7xylene
I 00-4 I -4ethylbenzene
TSCA (Toxic Strbstsnces Control Act):
65997- I 7-3Fibrous Glass
diphenylm ethan ediis o cy anate,is om eres and homo I o gu es
ACTIVE
901 6-87-9 ACTIVE
I 0 r -68-84, 4′ -methylenedipheny I diis o cy anate ACTIVE
38640-62-9Diis opropyl naphthalene ACTIVE
Zeolite (Crystalline aluminosilicate) ACTIVE
64742-47-8Kerosine – unspecified ACTIVE
I 3463-67-7titanium dioxide ACTIVE
64742-94-5Solvent naphtha (petroleum), heavy arom. ACTIVE
6861 I-44-9Silane, dichlorodimet hy l-, reaction products with silic a ACTIVE
I 3 30-20-7xylene ACT]VE
US
BUILNING TRUST&
Printing date. 0 I /06/2020
Sofety Data Sheet
scc. to OSHA HCS
Page I2/14
Rcviewed on 0I/06/2020
Trade name: F100 Part B ISO
of
P o lyme thy I a I lry I s i I ox an e ACTIVE
I 00-4 I -4ethylbenzene ACTIVE
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule
None oJ’the ingredients is listed.
Hazardoas Air Pollutants
I 0 I -68-84, 4′-methylened iphenyl d i is ocya na t e
I 330-20-7xylene
I 00-4 I -4ethylbenzene
9 I -20-3naphthalene
Proposition 65
Chemicals known to cause csncer:
I 3463-67-7titanium dioxide
I 00-4 I -4ethylbenzene
9 r -20-3naphthalene
7 I -43-2benzene
Chemicals known lo cause rcproiluclive loxicity for femules:
None of the ingredients i.s listed.
Chemicals known to csuse reproductive toxicity for
males
7 I -43-2benzene
Chemiculs known to cause developmental toxicity:
7 I -43-2benzene
r 08-88-3toluene
Carcinogenic categories
EPA (Environm ental Protection Agency)
90r 6-87-9diphenylmethanediisocyanulc,isunrcrcs und lnrtulugucs CBD
I 01 -68-84, 4′ -methyl enediph eny I diis o cy an ate D, CBD
100-41-4ethylbenzene D
TLV (Threshold Limit Value established by ACGIH)
I 00-4 r -4ethylbenzene A3
NIOSH-Ca (National Institute for Occuputional Safety and Health)
I 3463-67-7titanium dioxide
is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page l3)
Listed in CIYC Regulations
None of the ingredients is listed
GHS label elements
US
BUILDINC TRUST
Printing date u I /u 6/2 u 2 u
So.fety Data Shee.t
occ. to OSHA HCS
Page I 3/14
R eviewerl. on
(
) I /0 6/ 2 0 2.
(
)
Trade name: F|00 Part B ISO
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specifc productfeatures and shall not establish a legally valid contractual relationship.
Date. ofpreporstion / lssl revision 0l /06/2020 / 5
Ab breviatio tts an d ac rony ms :
IMDG: hternational Maritine Codefor Dangetous Goods
DOT: US Department of Transporlation
IATA: International Air Transport Association
ACGIH: Arnerican Conference of Governmental Industrial Hygienists
(Contd. on page l4)
t
(Contd. ofpage 12)
Hazard pictograms
GHSOT GHSO8
Signal word Danger
Hazard-determining components of Iabeling:
dip h eny lm et hane dii s o cy anat e, is o meres and homo lo gues
4, 4′ -me t hy I e n e dip he ny I d iis o cy anate
Diis opropy I n aphthalene
Hazard statements
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing dfficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause rcspirator,, iftitation.
May cause damage to organs through prolonged or repeated exposure.
HarmJill to aquatic liJb.
Pre caution ary statem ents
D o n o t b r e a t h e d u s t /fr.m e /g a s /mi s t/v ap o rs /s pr ay.
Wear protective gloves/protective clothing/eye protection/face protection.
fin case of inadequate verxtilation| wear respiratory protection.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiottsly with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a poisott center/doctor if you feel unwell.
If experiencing respiratory symptoms: Call a poison center/doctor.
LYash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical saJety assessment: A Chemical Sajbty Assessment has not been carried out.
16 Other information
US
BUILDING TRUST
Printing date. 0 I /06/2020
Safety Data Sheet
ncc, to OSHA HCS
Page I4/14
Rewewed on 01/06/2020
Trade name: Fl00 Part B ISO
EINECS: European Inventory of Existing Commercial Chemical Substances
(Contd. ofpage 13)
CAS: Abstracts Service (division ofthe American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials ldentiJication System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NI OSH : National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
kEL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Acute Tox. 4: Acute toxicity –
Category 4
Skin lrrit, 2: Skin corrosion/irritation –
Category 2
Eye lrrit. 2A: Sertous eye damageleye irritation –
Category 2A
Resp. Sens, 1 : Respiratory sensitisation –
Category I
Skin Sens. I : Skin sensitisation –
Category I
Carc. 2: Carcinogenicily –
Category 2
STOT SE 3: SpeciJic target organ toxicity (single acposure) – Category 3
STOT RE 2: Specifc target organ toxicity (repeated exposure) –
Category 2
Aquatic Acute j:
Hazardous to the oquetic enrironment – acute dquatic hazard –
Category 3
*
Data compared to the prcvious version sltercd.
US