BUILDIN6 TRUSTA
Printing date I 0/26/201 9
Safe$ Datu Sheet
acc. to OSHA HCS
Page l/l I
Reviewed on 10/26/2019
l ldenffication
Product identiJier
Trade name: ESG 215 Resin
Article number: 12 I 5 I 88
Application of the substance / the mixture Epoxy resin
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
M a n ufa c t u r e r/S u pp I i e r :
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 4807 I
USA
ehs-us@axson.com
Inform ation departm ent: Product s afety department
Emergency telephone number:
During normal opening times: + I (248) 588-2270
CHEMTREC 24-hour Emergency: +I (800) 424-9300
2 H azard(s) identiJicatio n
of the substance or mixture
GHS09 Environment
Aquatic Chronic 2 H41 I Toxic to aquatic life with long lasting fficts.
GHSOT
Acute Tox. 4
Acute Tox. 4
Skin lrit. 2
Skin Sens. l
Hj02 Harmful if swallowed.
H3l2 Harmful in contact with skin.
H3I 5 Causes skin irritation.
H3l7 May cause an allergic skin reaction.
Eye Inil. 28 H320 Causes eye irritation.
Lahel elements
GHS labet elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2)
I
o
BUILTIING TRUSTA
Printing date I 0/26/20 I 9
Safe$ Datu Sheet
acc. to OSHA HCS
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t
a
Trade name: ESG 215 Resin
(Contd. ofpage l)
Hazard pictograms
GHSOT GHSO9
Signal word Ll/arning
Hazard-determining components of labeling:
Reaction Product ofBisphenol A and Epichlorohydrin
Hy droxypheny lethane Triglycidyl E ther
I, 3 -bis (2, j
-epoxypropoxy) – 2, 2 -dimethylpropane
Hazard statements
Harmful if swallowed or in contact with sHn.
Causes skin and eye ititation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting fficts.
Precautio nary statem ents
Av oid breathing dus ffime/gas
/mis thap ors/spray
Av oid breathing dust/fume/gas /mis thap ors/spray
Avoid release to the environment.
Wear protective gloves / protective clothing.
If swallowed: Call a poison center/doctor if you
feel
unwell.
Rinse mouth.
If in eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If eye initation persists: Get medical advice/attention.
IMash contaminated clothing before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system :
NFPA ratings (scale 0 – 4)
Health = I
Fire: l
Reactivity :
0
HMlS-ratings (scale 0 – 4)
Health: I
Fire : I
Reactivity :
0
Other hazards
Results of PBT and vPvB sssessment
PBT: Not applicable.
(Contd. on page 3)
REACT|VITYE
lrs
BUILDII{G TRUST
Printing date I 0/26/20 I 9
Safe$ Datu Sheet
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*
Trade name: ESG 215 Resin
(Contd. ofpage 2)
vPvB: Not applicable.
3 Composition/information on ingredients
Description: Mixture of the substances listed below with nonhazardous additions
Dangerous components:
CAS: 25068-38-6
NLP: 500-033-5
Reaction Product of Bisphenol A and Epichlorohydrin >25-<50%
CAS:87093-13-8 Hydroxyp henylethane Triglycidyl E ther >20-<25%
CAS: 17557-23-2
EINECS: 241-536-7
1, 3 -bis (2, 3 - epoxyprop oxy) - 2, 2 - dimethy lprop an e >5-<10%
4 First-aid meflsures
Description ofjlrst aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms ofpoisoning may even occur after several hours; therefore medical observationfor at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for
a doctor.
In case ofunconsciousness place patient stably in side positionfor transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eyefor several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: Immediately call a doctor.
Inform ation for
do ctor :
Most important symptoms and effects, both acute and delayed No further
relevant information available.
Indication of any immediate medical attention und special treatment needed
No further
relevant information available.
Extinguishing media
Suitable extinguishing agents :
CO2, extinguishing powder or water spray. Fight largerfires with water spray or alcohol resistantfoam.
Special hazards arisingfrom the substance or mixture Nofurther relevant information available.
A dvice for Jirejighters
Protective equipm ent: Wear self-contained respiratory protective device.
(Contd. on page 4)
t
5 Fire-lighting measures
US
BUILOING TRUSTA
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Trade name: ESG 215 Resin
(Contd. ofpage 3)
A ddition al info rm atio n
Dispose offire debris and contaminated fire fighting
water in accordance with official regulations.
)F
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures Not required.
E nviro nm e nta I p r e c a utio n s :
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and materialfor containment snd cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust)
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section Sfor information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for
Chemicals
PAC-I:
25068-38-6Reaction Product ofBisphenol A and Epichlorohydrin 90 mg/m3
PAC-2:
25068-38-6Reaction Product ofBisphenol A and Epichlorohydrin 990 mg/m3
PAC-3:
2s068-38-6Reaction Product of Bisphenol A and Epichlorohydrin 5,900 mg/m'
7 Handling and storage
*
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the worlElace.
Prevent formation
of aerosols.
Information about protection against explosions andlires: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Reqairements to be met by storerooms and receptacles: No special requirements.
Information ahout storage in one common storuge facility:
Not required-
Further information about storage conditions: Keep receptacle tightly sealed.
Speciftc end use(s) No further
relevant information available'
US
(Contd, on page 5)
BUILDING TRUSTtu
Printing date I 0/26/20 I 9
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8 Exposure controls/personal protection
*
Trade name: ESG 215 Resin
(Contd. ofpage 4)
'Additional information about design of technical systems: Nofurther data; see item 7.
' Control parameters
' Components with limit valaes that reqaire monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the worlElace.
' Additional information: The lists that were valid during the creation were used as basis.
'Exposare controls
' Personal protective equipment:
' General protective and hygienic measures:
Ke ep aw ay from fo
o ds tuffs, b ev er a ges an d
fe
e d.
Immediately remove all soiled and contaminated clothing.
Wash hands before breal2,000 mg/kg (rat)
6 1 6-4 7- 7 I -m ethylimid azo le
OralLD5O1,400 mg/kg (mouse)
I nform ation o n t oxic o I o gic al effe cts
Acate toxicity:
Primary irritant effect :
on the skin: Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic elfect.
Strong irritant with the danger of severe eye injury.
Sensitization : Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following
dangers according to internally approved calculation methods for preparalions:
Toxic
Harmful
Corrosive
Irritant
Very toxic
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
Toxicity
Aquatic toxicity: No further
relevant information available.
(Contd. on page 9)
12 Ecological
US
BUILI}INI TRUST
Printing date 0 3/03/2020
SafeA Datu Sheet
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Page 9/1 3
Reviewed on 03/03/2020
Trade name: ESG 215 T Hurdener
(Contd, ofpage 8)
Persistence and degradability No further
relevant information available.
Behuvior in environmental systems :
B i o ac c u mu I ativ e p ot enti al N o fur
th er r e I ev ant inform ati o n av ai I a b I e.
Mobility in soil No further
relevant information available.
A dditio nal ec ological inform ation :
General notes:
W’ater hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies ofwater or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further
relevant information available.
1 3 Disposal considerufions
Vl/aste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to fficial
regulations.
*
I 4 Transport information
UN-Number
DOT
IMDG,IATA
NA273s
uN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Diethylenetriamine, m-
p h eny I en ebis (m e t hy I amin e) )
AMINES, LIQUTD, CORROSIVE, N.O.,S.
(D I ETHYL E N E TRI A M I N E, m -p h eny I en ebis (m ethyl amine) ),
MANNE POLLUTANT
AMTNES, LISUID, CORROSTVE, N.O.S.
(D I E THYL E NE T M A MI N E, m-p h eny I en e bi s (m et hy I amin e) )
IMDG
IATA
(Contd. on page l0)
US
BUILDING TRUSTA
Printing date 0 3/03 /2 020
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Reviewed on 03/03/2020
Trade name: ESG 215 T Hardener
(Contd. ofpage 9)
‘ Transport hazard class(es)
.DOT
/>’.
v
CIass
Label
IMDG
8 Corrosive substances
8
A
V
Class
Label
8 Corrosive substances
8
IATA
Zs”.
V
CIass
Label
8 Corrosive substances
8
Packing group
DOT,IMDG,IATA II
Environmental hazards
Marine pollutant:
Product contains environmentally hazardous substances
diethylmethylb enzenediamine, Ep oxy phenol nov o lac resin
Yes
Symbol (/ish and tree)
Special precautions for user
Danger code (Kemler):
EMS Number:
Segregation groups
Stowage Category
Segregation Code
Warning: Corrosive substances
80
F-A,S-B
Alkalis
A
SG3 5 Stow “separated from”
SGG I -acids
Transport in bulk according to Annex II of
MARPOLT3/78 and the IBC Code Not applicable.
(Contd. on page I 1)
US
.$
BUILOING TRUST
Printing date 0 3/0 3/20 20
Sof”ty Duta Sheet
acc, to OSHA HCS
Page I l/13
Reviewed on 03/03/2020
Trade name: ESG 215 T Hardener
(Contd. ofpage l0)
Transp ort/A ddition al inform ati on :
DOT
Quantity limitations
Remarks
On passenger aircraft/rail: I L
On cargo aircraft only: 30 L
Special markingwith the symbol (ish and tree).
IMDG
Limited quantities (LQ)
Excepted quantities (EQ)
1L
Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN’tModel Regulation” : uN 27 3 5 AMTNES, LTQUID, CORROSIVE, N. O.,S.
(DIETHYLENETRIAMINE, M-
P HE|,IYLENEB IS (METHYLAMINE)), 8, II, ENVI RONMENTALLY
HAZARDOUS
1 5 Regulatory information
*
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 3 5 5 (extremely hazardous substances) :
None of the ingredients is listed.
Section 313 (SpeciJic toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Sabstances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA S(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None the t.t
Chemicals known to couse cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Proposition 65
on page
TJS
BU!LNINfi TRUST
Printing date 0 3/0 3 /2 0 20
Sofrty Datu Sheet
ncc. to OSHA HCS
Page 12/13
Reviewed on 03/03/2020
Trade name: ESG 215 T Hardener
(Contd. ofpage I 1)
Chemicals known to cause reproductive toxicity for
males
I
NonA;f ihiinii;AiAnili ilii,d.
”
I
‘ Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
Listed in CII/C Regulations
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
None of the ingredients is listed.
GHS label elentents The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
c@o@
GHSO5 GHSO6 GHSOT GHSO8
Signal word Danger
Huzurd-determining components of labeling :
2, 2’ – imi n o di e t hy I amin e
di e thy lm e t hy I b enzen e di am in e
l -methylimidazole
m-p he ny I en e bis (m e t hyl amin e)
Hazurd statements
Harmful if swallowed or in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs throughprolonged or repeated exposure.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
fin case of inadequate ventilationJ wear respiratory protection.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with waterfor several minutes. Ilemove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
(Contd. on page l3)
US
BUILOING TRUST,A
Printing date 0 3/0 3 /2 020
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Reviewed on 03/03/2020
Trade name: ESG 215 T Hardener
(Contd. ofpage l2)
Specific treatment is urgent (see ott this label).
Take of contaminated clothing and wash it before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations
Chemical safely assessment: A Chemical Safety Assessment has not been carried ouL
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any
speci/ic productfeatures and shall not establish a legally valid contractual relationship.
Date ofpreparation /Iast revision 03/03/2020 / 5
Abbreviations and acronyms :
IMDG: International Maritime Codefor Dangerous Goods
DOT: US Department of Transportation
IATA : International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Sentice (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identifcation Systen (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentrotion, 50 percenl
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persislent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute loxicity – Categoty 4
Acute Tox. 2: Acute toxicity –
Category 2
Skin Corr. 1B: Skin corrosion/irritation –
Category I B
Eye Dam. l: Serious eye damage/eye irritaliott – Category I
Skin Sens. l: Skin sensitisalion – Category I
STOT SE 3: Specifrc target organ toxicity (single exposure) –
Category i
STOT EE 2: Specific target organ toxicity (repeated exposure) –
Category 2
*
Data compared to the previous version altered.
US
16 Other information