80TC1604-F_SDS.pdf

SAFETY DATA SHEET
Date Issued : 3/18/2014
MSDS No : TC-1604 PART A
TC-1604 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1604 PART A
GENERAL USE: Epoxy resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929

CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Mutagenicity, Category 1
Carcinogenicity, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Health hazardEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H340: May cause genetic defects.
H350: May cause cancer.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
Page 1 of 8

P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P321: Specific treatment (see on this label).
P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P391: Collect spillage.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: White viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. Can cause allergic skin
reaction. May be harmful if swallowed. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Phenol, 4,4′-(1-methylethylidene)bis, polymer with (chloromethyl)oxirane 60 – 10025068-38-6
Calcium Carbonate (limestone) 10 – 301317-65-3
2,3-epoxypropyl O-tolyl Ether 5 – 102210-79-9
Furfuryl Alcohol 1 – 5 98-00-0
Titanium oxide (TiO2) 1 – 513463-67-7
Silica, Crystalline < 0.114808-60-7 4. FIRST AID MEASURES EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get immediate medical attention. SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash develops. Wash clothing before reuse. Page 2 of 8 TC-1604 PART A INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person. INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get immediate medical attention. NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide. FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff from fire control methods to sewers or waterways. FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned hose holders or monitor nozzles for fighting large fires. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills with a decontaminant. LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15). ENVIRONMENTAL PRECAUTIONS WATER SPILL: Do not discharge into drains or rivers. GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details. RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors. HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a manner consistent with good industrial/manufacturing techniques and practices. STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. STORAGE TEMPERATURE: 65-80 F (18-27 C) SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 3 of 8 TC-1604 PART A EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV SupplierOEL Chemical Name ppm mg/m 3 ppm mg/m 3 ppm mg/m 3 Phenol, 4,4'-(1-methylethylidene)bis, polymer with (chloromethyl)oxirane TWA NE NE NE NE NE NE STEL NE NE NE NE NE NE Calcium Carbonate (limestone) TWA NE [1] 15T 5R [1] NE 10 NE NE STEL NE NE NE NE NE NE 2,3-epoxypropyl O-tolyl Ether TWA NE NE NE NE NE NE STEL NE NE NE NE NE NE Furfuryl Alcohol TWA 50 200 10 40 10 40 STEL NE NE 15 60 15 60 Titanium oxide (TiO2) TWA NE 15 Total Dust NE 10 NE NE STEL NE NE NE NE NE NE Silica, Crystalline TWA250 mppcf 10 NE 0.025 NE [2] 0.05 [2] STEL NE NE NE NE NE NE OSHA TABLE COMMENTS: 1. T = Total, R = Respirable 2. NIOSH REL ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent. SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection. RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134). PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical Protective Clothing' published by ACGIH. WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate work area should be prohibited. Wash hands before eating. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is important. Follow all label precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Viscous liquid ODOR: Slight COLOR: White pH: Not Established Page 4 of 8 TC-1604 PART A PERCENT VOLATILE: 0.22 FLASHPOINT AND METHOD: > 125 C (257 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Practically insoluble
SPECIFIC GRAVITY: 1.28 (water=1) at 25 C (77 F)
VISCOSITY: 8500 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 2.820 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY STABILITY: This product is stable under normal ambient conditions of temperature and pressure. POLYMERIZATION: Product will not undergo polymerization. CONDITIONS TO AVOID: No data available. POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide. INCOMPATIBLE MATERIALS: Strong oxidizing agents, strong alkalies, and strong acids. 11. TOXICOLOGICAL INFORMATION TOXICITY TO ANIMALS Chemical Name ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC 50 (rat) Phenol, 4,4'-(1-methylethylidene)bis, polymer with (chloromethyl)oxirane 30000 mg/kg > 1200 mg/kg Not Established
Calcium Carbonate (limestone) Not Established Not Established Not Established
2,3-epoxypropyl O-tolyl Ether > 2000 mg/kg Not Established 1220 ppm
Furfuryl Alcohol 177 mg/kg 3825 ml/kg Not Established
Titanium oxide (TiO2) > 10000 mg/kg> 10000 mg/kg > 6.82 mg/l
Silica, Crystalline Not Established Not Established Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Titanium oxide (TiO2) 2B
Silica, Crystalline 1 1
IARC: This product contains substances that are classified as carcinogens to humans.
IRRITATION: Causes eye and skin irritation.
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
Page 5 of 8
TC-1604 PART A

BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
PROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Bisphenol A epoxy resin
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
ERG CODE: 171
LABEL: Class 9 (miscellaneous hazardous materials)
MARINE POLLUTANT #1: Yes
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
AIR (ICAO/IATA)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s. (See Note)
TECHNICAL NAME: Bisphenol A epoxy resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
ERG CODE: 9L
LABEL: Class 9 (miscellaneous hazardous materials)
NOTE: Only regulated for bulk and vessel shipments, per 49CFR171.4 (c) Exceptions. Except when all or part of the transportation is by
vessel, the requirements of this subchapter specific to marine pollutants do not apply to non-bulk packagings transported by motor vehicle,
rail car, or aircraft.
VESSEL (IMO/IMDG)
SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL NAME: Bisphenol A epoxy resin
UN/NA NUMBER: UN3082
PRIMARY HAZARD CLASS/DIVISION: 9
PACKING GROUP: III
EmS: F-A, S-F
MARINE POLLUTANT #1: Yes
LABEL: Class 9 (miscellaneous hazardous materials)
15. REGULATORY INFORMATION
Page 6 of 8
TC-1604 PART A

UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D2A – Carcinogenicity
D2B – Eye irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revised format
Page 7 of 8
TC-1604 PART A

HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES

1
2 0

HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 8 of 8
TC-1604 PART A

SAFETY DATA SHEET
Date Issued : 3/18/2014
MSDS No : TC-1604 PART B
TC-1604 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TC-1604 PART B
GENERAL USE: Epoxy curing agent
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929

CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Acute Toxicity (Dermal), Category 4
Skin Corrosion, Category 1
Eye Corrosion, Category 1
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Reproductive Toxicity, Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
Physical:
Flammable Liquids, Category 4
GHS LABEL
CorrosionHealth hazardEnvironment
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H227: Combustible liquid.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
H361: Suspected of damaging fertility or the unborn child .
PRECAUTIONARY STATEMENT(S)
Page 1 of 8

Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P285: In case of inadequate ventilation wear respiratory protection.
P273: Avoid release to the environment.
Response:
P370+P378: In case of fire: Use alcohol resistant foam, carbon dioxide, dry chemical, dry sand, water spray (fog), or limestone powder
for extinction. Do not use water jet.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P321: Specific treatment (see on this label).
P363: Wash contaminated clothing before reuse.
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P391: Collect spillage.
Storage:
P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber liquid with an ammoniacal odor.
IMMEDIATE CONCERNS: Combustible liquid. Keep away from heat, sparks, and flame. Corrosive to eyes and skin. Causes burns. May
be harmful if absorbed through skin or if swallowed. Irritating to the respiratory system. Do not breathe vapor or mist. Do not ingest. Do
not get in eyes or on skin or clothing. Contains material that may target organ damage, based on animal data. Use only with adequate
ventilation. Keep container tightly closed and sealed untill ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes eye burns. May cause blindness. Severe eye irritation.
SKIN: Causes skin burns, severe irritation and possible allergic reaction.
INGESTION: Harmful if swallowed. If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus
and the stomach.
INHALATION: Irritating to respiratory system.
CARCINOGENICITY: Contains material which may cause cancer, based on animal data. Risk of cancer depends on duration and level of
exposure.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGANS: Contains material which may cause damage to the following organs: kidneys, liver, central nervous system (CNS).
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Page 2 of 8
TC-1604 PART B

Chemical Name Wt.% CAS
Tetraethylenepentamine 60 – 100112-57-2
Triethanolamine 10 – 30102-71-6
Piperazine 3 – 7 110-85-0
2-piperazin-1-ylethylamine 1 – 5 140-31-8
Ethanol, 2, 2′-iminobis- < 0.1 111-42-2 4. FIRST AID MEASURES EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get immediate medical attention. SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention immediately. Wash clothing before reuse. INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person. INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get immediate medical attention. CHRONIC TOXICITY CHRONIC EFFECTS: Prolonged contact may result in chemical burns and permanent damage. May cause allergic skin reaction. NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours. 5. FIRE FIGHTING MEASURES GENERAL HAZARD: May generate ammonia gas. May generate nitrogen oxide gases. Incomplete combustion may form carbon monoxide. Downwind personnel must be evacuated. Burning of material produces obnoxious and toxic fumes. EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, water spray (fog), or limestone powder. Do not use water jet. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, and nitrosamine. EXPLOSION HAZARDS: Temperatures at or above the flash point could generate combustible mixtures. Avoid all ignition sources. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FL AME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES O F IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEAT H. Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of. FIRE FIGHTING PROCEDURES: Remove containers from the fire area if possible. Do not release runoff from fire control methods to sewers or waterways. FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned hose holders or monitor nozzles for fighting large fires. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills with a decontaminant. LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use combustible materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15). ENVIRONMENTAL PRECAUTIONS WATER SPILL: Do not discharge into drains or rivers. Page 3 of 8 TC-1604 PART B GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details. RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Combustible liquid. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors. HANDLING: Do not use sodium nitrite or other nitorsating agents in formulations containing this product. Suspected cancer causing nitrosamines could be formed. Use appropriate personal protective equipment as specified in Section 8. Handle in a well ventilated area. Handle and use in a manner consistent with good industrial/manufacturing techniques and practices. STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition and incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid unnecessary contact. STORAGE TEMPERATURE: 65-80 F (18-27 C) SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV SupplierOEL Chemical Name ppm mg/m 3 ppm mg/m 3 ppm mg/m 3 Tetraethylenepentamine TWA NE NE NE NE NE NE STEL NE NE NE NE NE NE Triethanolamine TWA NE NE NE 5 NE NE STEL NE NE NE NE NE NE Piperazine TWA NE NE NE NE NE NE STEL NE NE NE NE NE NE 2-piperazin-1-ylethylamine TWA NE NE NE NE NE NE STEL NE NE NE NE NE NE Ethanol, 2, 2'-iminobis- TWA NE NE NE NE 3 [1] 15 [1] STEL NE NE NE NE NE NE OSHA TABLE COMMENTS: 1. NIOSH REL ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent. SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection. RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134). Page 4 of 8 TC-1604 PART B PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical Protective Clothing' published by ACGIH. WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate work area should be prohibited. Wash hands before eating. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is important. Follow all label precautions. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Ammoniacal COLOR: Amber pH: Alkaline PERCENT VOLATILE: 6.93 FLASHPOINT AND METHOD: > 90 C (194 F) Closed Cup
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Soluble
SPECIFIC GRAVITY: 1.02 (water=1) at 25 C (77 F)
VISCOSITY: Not Established
VOC (Volatile Organic Compound): < 70.700 g/l Calculated. Theoretical VOC minus water and exempt solvents. 10. STABILITY AND REACTIVITY STABILITY: This product is stable under normal ambient conditions of temperature and pressure. POLYMERIZATION: Product will not undergo polymerization. CONDITIONS TO AVOID: High temperatures and sources of ignition. POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with peroxide may resulting violent decomposition of peroxide possibly creating an explosion. CAUTION! N-Nitrosamines, many of which are known to be potent carcinogens, may be formed when the product comes in contact with nitrous acid, nitrites or atmospheres with high nitrous oxide concentrations HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, nitric acid, ammonia, and nitrosamine. INCOMPATIBLE MATERIALS: Sodium hypochlorite, organic acids, mineral acids, peroxides, oxidizing agents, nitrous acid, and other nitrosating agents. 11. TOXICOLOGICAL INFORMATION TOXICITY TO ANIMALS Chemical Name ORAL LD50 (rat) DERMAL LD50 (rabbit) INHALATION LC 50 (rat) Tetraethylenepentamine 2140 mg/kg > 660 mg/kg Not Established
Triethanolamine Not Established Not Established Not Established
Piperazine Not Established Not Established Not Established
2-piperazin-1-ylethylamine Not Established Not Established Not Established
Ethanol, 2, 2′-iminobis-
700 to 2800
mg/kg
> 5000 mg/kg Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
Page 5 of 8
TC-1604 PART B

subsequently exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
Triethanolamine 3
Ethanol, 2, 2′-iminobis- 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
IRRITATION: Causes severe eye and skin irritation.
CORROSIVITY: Corrosive to the eyes and skin.
SENSITIZATION: May cause sensitization by skin contact.
REPRODUCTIVE EFFECTS: Suspected of damaging fertility. Suspected of damaging the unborn child.
TARGET ORGANS: Contains material which may cause damage to the following organs: kidneys, liver, central nervous system (CNS).
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND
PROPER SHIPPING NAME: Corrosive liquids, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: UN1760
PACKING GROUP: III
ERG CODE: 154
LABEL: Corrosive
AIR (ICAO/IATA)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
ERG CODE: 8L
LABEL: Corrosive
Page 6 of 8
TC-1604 PART B

VESSEL (IMO/IMDG)
SHIPPING NAME: Corrosive liquid, n.o.s.
TECHNICAL NAME: (tetraethylenepentamine solution)
UN/NA NUMBER: UN1760
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
EmS: F-A, S-B
MARINE POLLUTANT #1: Yes
LABEL: Corrosive
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Ethanol, 2, 2′-iminobis- < 0.1100 lbs. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification: None TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA ) 29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this product are considered highly hazardous by OSHA. CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Chemical Name Wt.% Listed Ethanol, 2, 2'-iminobis- < 0.1 Cancer OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. CANADA WHMIS HAZARD SYMBOL AND CLASSIFICATION Combustible Liquid WHMIS CLASSIFICATION Class B3: Combustible liquid Page 7 of 8 TC-1604 PART B WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL). 16. OTHER INFORMATION REASON FOR ISSUE: Revised format HMIS RATING HEALTH * 3 FLAMMABILITY 2 PHYSICAL HAZARD 1 PERSONAL PROTECTION X NFPA CODES 2 3 1 HMIS RATINGS NOTES: Personal Protection: See Section 8 MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal responsibility for use or reliance upon this data. Page 8 of 8 TC-1604 PART B