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1 Identification
Product identifier
Trade name: TCC102 Hardener
Article number:I070102
Application of the substance / the mixtureEpoxy curing agent
Details of the supplier of the safety data sheet
Sika Advanced Resins, US
EHS Department
Manufacturer/Supplier:
Supplier’s Name: Sika Advanced Resins, US
Headquarters:
30800 Stephenson Hwy
Madison Heights, MI 48071
USA
ehs-us@axson.com
Information department:Product safety department
Emergency telephone number:
During normal opening times: +1 (248) 588-2270
CHEMTREC 24-hour Emergency: +1 (800) 424-9300
2 Hazard(s) identification
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carc. 2 H351 Suspected of causing cancer.
Repr. 1B H360 May damage fertility or the unborn child.
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS09 Environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
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GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2′-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Avoid breathing dust/fume/gas/mist/vapors/spray
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
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Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
3
1
0
Health = 3
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
REACTIVITY
*3
1
0
Health = *3
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
CAS: 112-24-3
EINECS: 203-950-6
3,6-diazaoctanethylenediamin 25- 50%
CAS: 84852-15-3
EINECS: 284-325-5
4-nonylphenol, branched 10-20%
CAS: 80-05-7
EINECS: 201-245-8
bisphenol A 10-<20%
CAS: 111-40-0
EINECS: 203-865-4
2,2'-iminodiethylamine 10-<20%
CAS: 2426-08-6
EINECS: 219-376-4
butyl glycidyl ether 0.1-<1%
4 First-aid measures
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
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Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation:
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
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See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
112-24-3 3,6-diazaoctanethylenediamin 3 ppm
84852-15-3 4-nonylphenol, branched 3.9 mg/m
80-05-7 bisphenol A 15 mg/m
111-40-0 2,2'-iminodiethylamine 3 ppm
2426-08-6 butyl glycidyl ether 9 ppm
PAC-2:
112-24-3 3,6-diazaoctanethylenediamin 14 ppm
84852-15-3 4-nonylphenol, branched 43 mg/m
80-05-7 bisphenol A 110 mg/m
111-40-0 2,2'-iminodiethylamine 8.5 ppm
2426-08-6 butyl glycidyl ether 580 ppm
PAC-3:
112-24-3 3,6-diazaoctanethylenediamin 83 ppm
84852-15-3 4-nonylphenol, branched 260 mg/m
80-05-7 bisphenol A 650 mg/m
111-40-0 2,2'-iminodiethylamine 51 ppm
2426-08-6 butyl glycidyl ether 3,500 ppm
7 Handling and storage
Handling:
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Information about protection against explosions and fires:Keep respiratory protective device available.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:Keep receptacle tightly sealed.
Specific end use(s)No further relevant information available.
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8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
112-24-3 3,6-diazaoctanethylenediamin
WEEL Long-term value: 6 mg/m , 1 ppm
Skin
111-40-0 2,2'-iminodiethylamine
REL Long-term value: 4 mg/m , 1 ppm
Skin
TLV Long-term value: 4.2 mg/m , 1 ppm
Skin
2426-08-6 butyl glycidyl ether
PEL Long-term value: 270 mg/m , 50 ppm
REL Ceiling limit value: 30 mg/m , 5.6 ppm
*15-min
TLV Long-term value: 16 mg/m , 3 ppm
Skin; DSEN
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
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Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Amber colored
Odor: Amine-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range:Undetermined.
Boiling point/Boiling range:207.1 C (404.8 F)
Flash point: 122 C (251.6 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 325 C (617 F)
Decomposition temperature: Not determined.
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: 1 Vol %
Upper: 10 Vol %
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Vapor pressure at 20 C (68 F):0.5 hPa (0.4 mm Hg)
Density at 20 C (68 F): 1.02 g/cm (8.51 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
VOC content: 0.00 %
0.0 g/l / 0.00 lb/gal
Solids content: 11.1 %
Other information No further relevant information available.
10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsNo dangerous reactions known.
Conditions to avoidNo further relevant information available.
Incompatible materials:No further relevant information available.
Hazardous decomposition products:
Aldehyde
Carbon monoxide and carbon dioxide
11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
112-24-3 3,6-diazaoctanethylenediamin
Oral LD50 2,000 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rabbit)
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80-05-7 bisphenol A
Oral LD50 3,250 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rabbit)
111-40-0 2,2'-iminodiethylamine
Oral LD50 1,553 mg/kg (rat)
Dermal LD50 1,045 mg/kg (rabbit)
Primary irritant effect:
on the skin:Caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization:Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Toxic
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Ecotoxical effects:
Remark:Toxic for fish
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
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Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
13 Disposal considerations
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
14 Transport information
UN-Number
DOT NA2735
IMDG, IATA UN2735
UN proper shipping name
DOT Amines, liquid, corrosive, n.o.s. (Triethylenetetramine,
Diethylenetriamine)
IMDG A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), MARINE
POLLUTANT
IATA A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE)
Transport hazard class(es)
DOT
Class 8 Corrosive substances
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Label 8
IMDG
Class 8 Corrosive substances
Label 8
IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards: Product contains environmentally hazardous substances: 4-
nonylphenol, branched
Marine pollutant: Yes
Symbol (fish and tree)
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Alkalis
Stowage Category A
Segregation Code SG35 Stow "separated from" SGG1-acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
Remarks: Special marking with the symbol (fish and tree).
IMDG
Limited quantities (LQ) 1L
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Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
UN "Model Regulation": U N 2 7 3 5 A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .
(TRIETHYLENETETRAMINE, DIETHYLENETRIAMINE), 8, II,
ENVIRONMENTALLY HAZARDOUS
15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
84852-15-3 4-nonylphenol, branched
80-05-7 bisphenol A
TSCA (Toxic Substances Control Act):
All components have the value ACTIVE.
Chemicals regulated by TSCA Section 12(b)
None of the ingredients is listed.
Chemical regulated by TSCA 5(a)(2)rule:
None of the ingredients is listed.
Hazardous Air Pollutants
None of the ingredients is listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
80-05-7 bisphenol A
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
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TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
Listed in CWC Regulations
None of the ingredients is listed.
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05GHS06GHS07GHS08GHS09
Signal wordDanger
Hazard-determining components of labeling:
3,6-diazaoctanethylenediamin
2,2'-iminodiethylamine
bisphenol A
4-nonylphenol, branched
butyl glycidyl ether
Hazard statements
Harmful if swallowed.
Toxic if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing cancer.
May damage fertility or the unborn child.
May cause respiratory irritation.
Toxic to aquatic life.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Do not breathe dusts or mists.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Date of preparation / last revision09/11/2018 / 4
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity Category 4
Acute Tox. 3: Acute toxicity Category 3
Skin Corr. 1B: Skin corrosion/irritation Category 1B
Eye Dam. 1: Serious eye damage/eye irritation Category 1
Skin Sens. 1: Skin sensitisation Category 1
Carc. 2: Carcinogenicity Category 2
Repr. 1B: Reproductive toxicity Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2
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