PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 06/01/2015 Revision date: 05/12/2017 Version: ADV-273-NC-2017a
05/12/2017 EN (English) Page 1
SECTION 1: Identification
Identification
Product form : Mixtures
Product name : PRO-SET ADV-273-NC HARDENER
Product code : ADV-273-NC, ADV-273-NC-0, ADV-273-NC-2, ADV-273-NC-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy adhesive resins
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Acute Tox. 4 (Oral)
Acute Tox. 4 (Inhalation)
Skin Corr. 1B
Eye Dam. 1
Resp. Sens. 1
Skin Sens. 1
Muta. 2
Repr. 2
STOT SE 3
STOT RE 2
Aquatic Acute 2
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS05
GHS07
GHS08
GHS09
Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma
symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertility
or the unborn child. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long
lasting effects
Precautionary statements (GHS)
:
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust, fume, gas,
mist, vapours, spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-
ventilated area. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves,
protective clothing, eye protection, face protection. [In case of inadequate ventilation] wear respiratory protection. If swallowed: rinse mouth. Do
NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person
to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Immediately call a poison center/doctor. If skin irritation or rash
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 2/10
occurs: Get medical advice/attention. If experiencing respiratory symptoms: Call a poison center/doctor. Take off contaminated clothing and wash it
before reuse. Collect spillage. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container to
hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/information on ingredients
Substance
Not applicable
Mixtures
Name Product identifier %
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol
(CAS No) 32610-77-8 10 – 40
Benzyl alcohol
(CAS No) 100-51-6 10 – 40
Mercaptan-terminated polymer (Non-hazarddous)
(CAS No) Not available 10 – 40
Triethylenetetramine
(CAS No) 112-24-3 1 – 15
Alicylic aliphatic polyamine
(CAS No) Trade Secret 1 – 10
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine)
(CAS No) 57214-10-5 1 – 10
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 1 – 10
1-Piperazineethanamine
(CAS No) 140-31-8 1 – 10
Phenol
(CAS No) 108-95-2 1 – 10
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 1 – 10
Alkyletheramine
(CAS No) Trade Secret 1 – 10
Alkylphenol
(CAS No) Trade Secret 1 – 10
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 1 – 5
Diethylenetriamine
(CAS No) 111-40-0 0.1 – 2
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold. Refer to Section 15 for additional information regarding this CBI claim.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 3/10
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Nitrogen oxides.
Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions.
Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it
can ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA). Use water spray or fog for cooling exposed containers.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or other combustible
absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Do not swallow. Handle and open container with care. Use only outdoors or in a well-ventilated
area. Do not get in eyes, on skin, or on clothing. Do not breathe dust, fume, gas, mist, vapours,
spray. Do not eat, drink or smoke when using this product. Use personal protective equipment
as required. When mixed with epoxy resin this product causes an exothermic reaction, which in
large masses, can produce enough heat to damage or ignite surrounding materials and emit
fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Do not eat, drink or smoke when using this product. Contaminated work clothing should not be
allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep locked up and out of reach of children. Keep container tightly closed. Keep only in the
original container in a cool, well-ventilated place. Protect from moisture. Storage temperature :
40 F (4 C) – 90 F (32 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol (32610-77-8)
Not applicable
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 4/10
Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm
Mercaptan-terminated polymer (Non-hazarddous) (Not available)
Not applicable
Triethylenetetramine (112-24-3)
AIHA WEEL TWA (mg/m ) 6 mg/m (Absorbed via skin)
AIHA WEEL TWA (ppm) 1 ppm
Alicylic aliphatic polyamine (Trade Secret)
Not applicable
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
Not applicable
Silica, amorphous, fumed, crystalline-free (112945-52-5)
ACGIH ACGIH TWA (mg/m ) 10 mg/m (Inhalable)
3 mg/m (Respirable)
OSHA OSHA PEL (TWA) (mg/m ) 6 mg/m (Amorphous silica)
15 mg/m (Total dust)
5 mg/m (Respirable)
1-Piperazineethanamine (140-31-8)
Not applicable
Phenol (108-95-2)
ACGIH ACGIH TWA (mg/m ) 19 mg/m
ACGIH ACGIH TWA (ppm) 5 ppm
OSHA OSHA PEL (TWA) (mg/m ) 19 mg/m
OSHA OSHA PEL (TWA) (ppm) 5 ppm
IDLH US IDLH (ppm) 250 ppm
NIOSH NIOSH REL (TWA) (mg/m ) 19 mg/m
NIOSH NIOSH REL (TWA) (ppm) 5 ppm
NIOSH NIOSH REL (ceiling) (mg/m ) 60 mg/m
NIOSH NIOSH REL (ceiling) (ppm) 15.6 ppm
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
Not applicable
Alkyletheramine (Trade Secret)
Not applicable
Alkylphenol (Trade Secret)
Not applicable
1,3-Benzenedimethanamine (1477-55-0)
ACGIH ACGIH Ceiling (mg/m ) 0.1 mg/m
NIOSH NIOSH REL (ceiling) (mg/m ) 0.1 mg/m
Diethylenetriamine (111-40-0)
ACGIH ACGIH TWA (ppm) 1 ppm
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 5/10
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Gel
Colour : Colourless
Odour : Ammonia
Odour threshold : No data available
pH : 11.2
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C) (estimated based on similar product)
Flash point : > 200 F (93 C) (estimated based similar product)
)
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : < 1 mm Hg (estimated based on ingredient data) Relative vapour density at 20 C : No data available Relative density : 1.05 Solubility : No data available Partition coefficient n-octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available Other information VOC content : 8.65 g/l (0.07 lb/gal) Bulk density : 8.75 lb/gal (1.05kg/L) SECTION 10: Stability and reactivity Reactivity : No dangerous reaction known under conditions of normal use. Chemical stability : Stable under normal storage conditions. Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure. Conditions to avoid : Heat. Incompatible materials. Incompatible materials : Acids. Oxidizing materials. Halogenated compounds. Hazardous decomposition products : May include, and are not limited to: oxides of carbon. Nitrogen oxides. Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. SECTION 11: Toxicological information Information on toxicological effects Benzyl alcohol (100-51-6) LD50 oral rat 1620 mg/kg PRO-SET ADV-273-NC HARDENER Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 05/12/2017 EN (English) 6/10 Benzyl alcohol (100-51-6) LC50 inhalation rat > 4.18 mg/l/4h
Triethylenetetramine (112-24-3)
LD50 oral rat 1716 mg/kg
LD50 dermal rabbit 1465 mg/kg
Silica, amorphous, fumed, crystalline-free (112945-52-5)
LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 2000 mg/kg
1-Piperazineethanamine (140-31-8)
LD50 oral rat 2097 mg/kg
LD50 dermal rabbit 866 mg/kg
Phenol (108-95-2)
LD50 oral rat 317 mg/kg
LD50 dermal rabbit 630 mg/kg (Solid)
LC50 inhalation rat 0.9 mg/l/8h (Solid)
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
LD50 oral rat 1620 mg/kg
1,3-Benzenedimethanamine (1477-55-0)
LD50 oral rat 980 mg/kg
LD50 dermal rabbit 2000 mg/kg
LC50 inhalation rat 1.34 mg/l/4h
Diethylenetriamine (111-40-0)
LD50 oral rat 1080 mg/kg
LD50 dermal rabbit 1090 mg/kg
LC50 inhalation rat 0.07 – 0.3 mg/l/4h
Acute toxicity (oral) : Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Harmful if inhaled.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified.
Silica, amorphous, fumed, crystalline-free (112945-52-5)
IARC group 3 – Not classifiable
Phenol (108-95-2)
IARC group 3 – Not classifiable
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified.
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Harmful if swallowed.
Symptoms/injuries after inhalation : Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 7/10
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])
Triethylenetetramine (112-24-3)
LC50 fish 1 570 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
EC50 Daphnia 1 31.1 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 495 mg/l (Exposure time: 96 h – Species: Pimephales promelas)
1-Piperazineethanamine (140-31-8)
LC50 fish 1 1950 – 2460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 32 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 > 1000 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
Phenol (108-95-2)
LC50 fish 1 11.9 – 50.5 mg/l (Exposure time: 96 h – Species: Pimephales promelas [flow-through])
EC50 Daphnia 1 4.24 – 10.7 mg/l (Exposure time: 48 h – Species: Daphnia magna [Static])
LC50 fish 2 20.5 – 25.6 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 2 10.2 – 15.5 mg/l (Exposure time: 48 h – Species: Daphnia magna)
Diethylenetriamine (111-40-0)
LC50 fish 1 248 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [static])
EC50 Daphnia 1 16 mg/l (Exposure time: 48 h – Species: Daphnia magna)
LC50 fish 2 1014 mg/l (Exposure time: 96 h – Species: Poecilia reticulata [semi-static])
Persistence and degradability
PRO-SET ADV-273-NC HARDENER
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET ADV-273-NC HARDENER
Bioaccumulative potential Not established.
Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1
Triethylenetetramine (112-24-3)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.4
1-Piperazineethanamine (140-31-8)
BCF fish 1 (no bioaccumulation expected)
Partition coefficient n-octanol/water -1.48
Phenol (108-95-2)
BCF fish 1 (no significant bioaccumulation)
Partition coefficient n-octanol/water 1.5
Diethylenetriamine (111-40-0)
BCF fish 1 0.3 – 1.7
Partition coefficient n-octanol/water -1.3
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 8/10
Mobility in soil
PRO-SET ADV-273-NC HARDENER
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name Product identifier Ecotoxicity Classification Information
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol
(CAS No) 32610-77-8 Aquatic Chronic Cat. 3
Benzyl alcohol
(CAS No) 100-51-6 No data available
Mercaptan-terminated polymer (Non-hazarddous)
(CAS No) Trade Secret No data available
Triethylenetetramine
(CAS No) 112-24-3 Aquatic Chronic Cat. 3
Alicylic aliphatic polyamine
(CAS No) Trade Secret No data available
Formaldehyde, oligomeric reaction products with phenol and m-
phenylenebis(methylamine)
(CAS No) 57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 No data available
1-Piperazineethanamine
(CAS No) 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Phenol
(CAS No) 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Diethylenetriamine-bisphenol A-epichlorohydrin polymer
(CAS No) 31326-29-1 No data available
Alkyletheramine
(CAS No) Trade Secret No data available
Alkylphenol
(CAS No) Trade Secret Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
1,3-Benzenedimethanamine
(CAS No) 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Diethylenetriamine
(CAS No) 111-40-0 No data available
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT and TDG
UN-No.(DOT/TDG) : UN3259
Proper Shipping Name (DOT/TDG) : Polyamines, solid, corrosive n.o.s. (Triethylenetetramine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : III
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3259
Proper Shipping Name (IMDG) : POLYAMINES, SOLID, CORROSIVE, N.O.S . (Triethylenetetramine)
Class (IMDG) : 8
Packing group (IMDG) : III
EmS Number : F-A, S-B
Marine pollutant : Yes
Transport by air
In accordance with IATA
UN-No. (IATA) : 3259
Proper Shipping Name (IATA) : Polyamines, solid, corrosive, n.o.s. (Triethylenetetramine)
Class (IATA) : 8
Packing group (IATA) : III
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 9/10
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Formaldehyde, polymer with N,N’-bis(2-aminoethyl)-1,2-ethanediamine and phenol (32610-77-8)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Formaldehyde, oligomeric reaction products with phenol and m-phenylenebis(methylamine) (57214-10-5)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol (108-95-2)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 1000 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
500 – 10000 lb
SARA Section 313 – Emission Reporting 1 %
Diethylenetriamine-bisphenol A-epichlorohydrin polymer (31326-29-1)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Canada WHMIS Confidential Business Information (CBI): The HMIRA number issued for this CBI claim is #11231. The date of filing is 2017-04-26
International regulations
No additional information available
US State regulations
California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List
Triethylenetetramine (112-24-3)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
1-Piperazineethanamine (140-31-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
Phenol (108-95-2)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) List
1,3-Benzenedimethanamine (1477-55-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
PRO-SET ADV-273-NC HARDENER
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
05/12/2017 EN (English) 10/10
Diethylenetriamine (111-40-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 06/01/2015
Revision date : 05/12/2017
Other information : None.
NFPA health hazard : 3
NFPA fire hazard : 1
NFPA reactivity : 0
HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard
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