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SAFETY DATA SHEET

FOR INDUSTRIAL USE ONLY

EPIKURE

Curing Agent MGS RIMH 937

Section 1. Product and company identification

GHS product identifier : EPIKURE

Curing Agent MGS RIMH 937
MSDS Number : 16S-00151
Product type : Curing Agent
Material uses : Epoxy Resin Systems

Manufacturer/Supplier/Impor
ter
: Hexion Inc.
180 East Broad Street
Columbus, Ohio
43215 USA

Contact person : 4information@hexion.com

Telephone : For additional health and safety or regulatory information, call
1 888 443 9466.

Emergency telephone number : For Emergency Medical Assistance
Call Health & Safety Information Services
1-866-303-6949

For Emergency Transportation Information
CHEMTREC US Domestic (800) 424-9300
CHEMTREC International (703) 527-3887
CANUTEC CA Domestic (613) 996-6666

Section 2. Hazards identification

Classification of the substance or
mixture
: ACUTE TOXICITY:oral – Category 4
ACUTE TOXICITY:dermal – Category 3
ACUTE TOXICITY:inhalation – Category 3
SKIN CORROSION/IRRITATION – Category 1A
SERIOUS EYE DAMAGE/ EYE IRRITATION – Category 1
SKIN SENSITIZATION – Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
[heart, nervous system, respiratory tract, kidneys] – Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) [skin] – Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

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Hazard statements : H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H371 May cause damage to organs (heart, nervous system, respiratory
tract, kidneys)
H372 Causes damage to organs through prolonged or repeated
exposure: (skin)

Precautionary statements

General : Not applicable.

Prevention : Wear protective gloves.
Wear eye or face protection.
Wear protective clothing.
Use only outdoors or in a well-ventilated area.
Do not breathe vapor.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Contaminated work clothing should not be allowed out of the
workplace.

Response : Get medical attention if you feel unwell.
IF exposed or if you feel unwell:
Call a POISON CENTER or physician.
IF INHALED:
Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
Immediately call a POISON CENTER or physician.
IF SWALLOWED:
Immediately call a POISON CENTER or physician.
Rinse mouth.
Do NOT induce vomiting.
IF ON SKIN (or hair):
Take off immediately all contaminated clothing.
Rinse skin with water or shower.
Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or physician.
IF ON SKIN:
Wash with plenty of soap and water.
Call a POISON CENTER or physician if you feel unwell.
If skin irritation or rash occurs:
Get medical attention.
IF IN EYES:
Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local,
regional, national and international regulations.

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Other hazards which do not result
in classification
: None known.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % by weight CAS
number
Cyclohexanamine, 4,4′-methylenebis[2-methyl- 90 – 100 6864-37-5
Isophorone Diamine 10 – 12.5 2855-13-2

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact : Get medical attention immediately. Call a poison center or physician.
Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Chemical burns must be
treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician.
Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing
apparatus. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In
case of inhalation of decomposition products in a fire, symptoms may
be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician.
Wash with plenty of soap and water. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician. In the event
of any complaints or symptoms, avoid further exposure. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician.
Wash out mouth with water. Remove dentures if any. Remove victim
to fresh air and keep at rest in a position comfortable for breathing. If
material has been swallowed and the exposed person is conscious, give
small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed

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to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Chemical burns must
be treated promptly by a physician. Never give anything by mouth to
an unconscious person. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms
may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first aid personnel : No action shall be taken involving any personal risk or without
suitable training. If it is suspected that fumes are still present, the
rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly
with water before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media : None known.

Specific hazards arising from the
chemical
: In a fire or if heated, a pressure increase will occur and the container
may burst.
Hazardous thermal
decomposition products
: Decomposition products may include the following materials:
carbon oxides
nitrogen oxides

Special protective actions for fire-
fighters
: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training.
Special protective equipment for
fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel : No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilled material. Do not breathe vapor or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of
any information in Section 8 on suitable and unsuitable materials. See

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also the information in “For non-emergency personnel”.

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air).

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Dilute with
water and mop up if water-soluble. Alternatively, or if water-insoluble,
absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach
release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to
local regulations (see section 13 of SDS). Dispose of via a licensed
waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see section 1 of SDS for
emergency contact information and section 13 of SDS for waste
disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see section 8 of
SDS). Persons with a history of skin sensitization problems should not
be employed in any process in which this product is used. Do not get
in eyes or on skin or clothing. Do not breathe vapor or mist. Do not
ingest. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Keep in the original container or an
approved alternative made from a compatible material, kept tightly
closed when not in use. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Advice on general occupational
hygiene
: Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed. Workers should wash hands
and face before eating, drinking and smoking. Remove contaminated
clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage,
including any incompatibilities
: Store in accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials (see section 10 of SDS) and food
and drink. Store locked up. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid
environmental contamination.

Section 8. Exposure controls/personal protection

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Control parameters

Occupational exposure limits

None.

Recommended monitoring
procedures
: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures
and/or the necessity to use respiratory protective equipment. Reference
should be made to appropriate monitoring standards. Reference to
national guidance documents for methods for the determination of
hazardous substances will also be required.
Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local
exhaust ventilation or other engineering controls to keep worker
exposure to airborne contaminants below any recommended or
statutory limits.
Environmental exposure controls : Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Contaminated work
clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations
and safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure to
liquid splashes, mists, gases or dusts. If contact is possible, the
following protection should be worn, unless the assessment indicates a
higher degree of protection: chemical splash goggles and/or face
shield. If inhalation hazards exist, a full-face respirator may be
required instead.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. Considering the
parameters specified by the glove manufacturer, check during use that
the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves
cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures

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should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with
an approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the
selected respirator.

Section 9. Physical and chemical properties

Appearance

Physical state : Liquid
Color : Blue.

Odor : amine.
Odor threshold : Not available
pH : Not available
Melting point/ Freezing point : Not available
Boiling point : 247 C (476.60 F)

Flash point : 110 C (230.00 F)

Burning time : Not available
Burning rate : Not available
Evaporation rate : Not available
Flammability (solid, gas) : Not available
Lower and upper explosive
(flammable) limits
: Lower: Not available
Upper: Not available
Vapor pressure : Not available
Vapor density : Not available
Relative density : Not available
Density : 0.940 g/cm3

Solubility : Not available
Solubility in water : Insoluble

Partition coefficient: n-
octanol/water
: Not available
Auto-ignition temperature : Not available
Decomposition temperature : Not available
SADT : Not available
Viscosity : Dynamic: Not available
Kinematic: Not available

Other information
No additional information.

Section 10. Stability and reactivity

Reactivity : Stable under normal conditions.

Chemical stability : The product is stable.

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Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will
not occur.

Conditions to avoid : Strong oxidizer,

Incompatible materials : No specific data.

Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure
Cyclohexanamine, 4,4′-methylenebis[2-methyl-
LD50 Oral Rat > 320 – 460 mg/kg –
LC50 Inhalation Rat 0.42 mg/l 4 h
LD50 Dermal Rabbit > 200 – 400 mg/kg –
Isophorone Diamine
LD50 Oral Rat 1,030 mg/kg –
Conclusion/Summary : Not available

Irritation/Corrosion

Conclusion/Summary
Skin : Not available
eyes : Not available
Respiratory : Not available

Sensitization

Conclusion/Summary
Skin : Not available
Respiratory : Not available

Mutagenicity

Conclusion/Summary : Not available

Carcinogenicity

Conclusion/Summary : Not available

Reproductive toxicity

Conclusion/Summary : Not available

Teratogenicity

Conclusion/Summary : Not available

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Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
Cyclohexanamine, 4,4′-
methylenebis[2-methyl-
Category 2

respiratory tract
nervous system
kidneys
heart

Isophorone Diamine Category 3

Respiratory tract irritation

Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
Cyclohexanamine, 4,4′-
methylenebis[2-methyl-
Category 2

Category 1

adrenal
kidneys
respiratory tract
liver
heart
blood system
skin

Aspiration hazard
Not available

Information on the likely routes of
exposure
: Not available

Potential acute health effects

Eye contact : Causes serious eye damage.
Inhalation : Toxic if inhaled. May give off gas, vapor or dust that is very irritating
or corrosive to the respiratory system. Exposure to decomposition
products may cause a health hazard. Serious effects may be delayed
following exposure.
Skin contact : Causes severe burns. Toxic in contact with skin. May cause an allergic
skin reaction.
Ingestion : Harmful if swallowed. May cause burns to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure

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Short term exposure

Potential immediate effects : Not available
Potential delayed effects : Not available

Long term exposure

Potential immediate effects : Not available
Potential delayed effects : Not available

Potential chronic health effects

Conclusion/Summary : Not available

General : Causes damage to organs through prolonged or repeated exposure:
Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Route ATE value
Oral mg/kg
Route ATE value
Dermal mg/kg
Route ATE value
Inhalation (vapors) mg/l

Section 12. Ecological information

Toxicity

Product/ingredient name Result Species Exposure
2,2′-dimethyl-4,4′-methylenebis(cyclohexylamine)
Acute LC50 31.6 mg/l Fish – Ide, Silver or
Golden Orfe
96 h
Acute EC50 4.6 mg/l Aquatic invertebrates.
Water flea
48 h
Acute EC50 > 5 mg/l Aquatic plants – Green
algae
72 h

Conclusion/Summary : Not available

Persistence/degradability

Conclusion/Summary : Not available

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Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Cyclohexanamine, 4,4′-
methylenebis[2-methyl-
2.3 < 60 <= 6 low Mobility in soil Soil/water partition coefficient (KOC) : Not available Other adverse effects : No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information The data provided in this section is for information only and may not be specific to your package size or mode of transport. You will need to apply the appropriate regulations to properly classify your shipment for transportation. International transport regulations Regulatory information UN/NA number Proper shipping name Classes/*PG Reportable Quantity (RQ) CFR 2922 CORROSIVE LIQUID, TOXIC, N.O.S. (Cyclohexanamine, 4,4'- methylenebis[2-methyl-) Class 8 (6.1) II IMO/IMDG 2922 CORROSIVE LIQUID, TOXIC, N.O.S. (Cyclohexanamine, 4,4'- methylenebis[2-methyl-) Class 8 (6.1) II IATA (Cargo) 2922 CORROSIVE LIQUID, TOXIC, N.O.S. Class 8 (6.1) II EPIKURE Curing Agent MGS RIMH 937 Page:12/13 Version: 4.0 Date of issue/Date of revision: 05/14/2015 Date of previous issue: 05/14/2015 (Cyclohexanamine, 4,4'- methylenebis[2-methyl-) *PG : Packing group Special precautions for user : Transport within user s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Section 15. Regulatory information United States U.S. Federal regulations : United States - TSCA 12(b) - Chemical export notification: None required. United States - TSCA 5(a)2 - Final significant new use rules: Not listed United States - TSCA 5(a)2 - Proposed significant new use rules: Not listed United States - TSCA 5(e) - Substances consent order: Not listed California Prop. 65: : None required. United States inventory (TSCA 8b) : All components are listed or exempted. Canada WHMIS (Canada) : Class D-1A: Material causing immediate and serious toxic effects (Very toxic). Class D-2B: Material causing other toxic effects (Toxic). Class E: Corrosive material Canadian lists Canadian NPRI : None required. CEPA Toxic substances : None required. International regulations International lists : Australia inventory (AICS): All components are listed or exempted. Canada inventory: All components are listed or exempted. Japan inventory: All components are listed or exempted. China inventory (IECSC): All components are listed or exempted. Korea inventory: All components are listed or exempted. New Zealand Inventory (NZIoC): All components are listed or exempted. Philippines inventory (PICCS): All components are listed or exempted. United States inventory (TSCA 8b): All components are listed or exempted. Taiwan inventory (CSNN): All components are listed or exempted. EPIKURE Curing Agent MGS RIMH 937 Page:13/13 Version: 4.0 Date of issue/Date of revision: 05/14/2015 Date of previous issue: 05/14/2015 Section 16. Other information Hazardous Material Information System III (U.S.A.) : Health * 3 Flammability 1 Physical hazards 0 Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Full text of abbreviated H statements : Not applicable. History Date of printing : 09/06/2016 Date of issue/Date of revision : 05/14/2015 Date of previous issue : 05/14/2015 Version : 4.0 Prepared by : Product Safety Stewardship Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail UN = United Nations References : Not available Notice to reader The information provided herein was believed by Hexion Inc. ("Hexion") to be accurate at the time of preparation or prepared from sources believed to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all laws and procedures applicable to the safe handling and use of the product and to determine the suitability of the product for its intended use. All products supplied by Hexion are subject to Hexion's terms and conditions of sale. HEXION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY HEXION, except that the product shall conform to Hexion's specifications. Nothing contained herein constitutes an offer for the sale of any product. and Licensed trademarks of Hexion Inc.