CR30MIQ_SDS.pdf

INDEX

CR30MI
CR30MICG
CR30MICQ
CR30MIF
CR30MIG
CR30MIQ

Composite Resource Marine ISO Laminating Resin
Safety Data SheetCR30MIMarine ISO
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue:11/11/2014 Revision date: Supersedes: Version:1.0
11/11/2014 EN(English) SDS ID:CR30MI Page 1
SECTION 1:Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form :Mixture liquidresin
Trade name :Composite Resource Marine ISO Laminating Resin
CAS No :Mixture
Product code :CR30MICP,CR30MICQ,CR30MIG, CR30MIF
Other means of identification :DISTRIBUTED BY REVCHEM COMPOSITES, INC.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :Marine ISO Laminating Resin
1.3. Details of the supplier of the safetydata sheet
Composite Resources is supplied by Revchem Composites. 2720 South Willow Ave., Bloomington, CA 92316 1-800-281-4975
1.4. Emergency telephone number
Emergency number :800.424.9300
CHEMTREC: 1-800-424-9300
SECTION 2:Hazards identification
2.1. Classification of the substance or mixture
GHS-US classification
Flam. Liq. 1H224
2.2. Label elements
GHS-US labelling
Hazard pictograms (GHS-US) :
GHS02
Signal word (GHS-US) :Danger
Hazard statements (GHS-US) :H224-Extremely flammable liquid and vapour
Precautionary statements (GHS-US) :P210-Keep away from sparks.-No smoking
P233-Keep container tightly closed
P240-Ground/bond container and receiving equipment
P241-Use explosion-proof electrical equipment
P242-Use onlynon-sparking tools
P243-Take precautionary measures against static discharge
P280-Wear protective clothing
P303+P361+P353-IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P370+P378-In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam for
extinction
P403+P235-Store in a well-ventilated place. Keep cool
P501-Dispose of contents/container to …
2.3. Other hazards
No additional information available
2.4. Unknown acute toxicity (GHS-US)
No data available
SECTION 3:Composition/information on ingredients
3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture

Composite Resource Marine ISO Laminating Resin
Safety Data SheetCR30MIMarine ISO
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2014 EN(English) SDS ID:CR30MI 2/7
Name Product identifier % GHS-US classification
Unsaturated Polyester Resin (CAS No)TRADE SECRET 53.5-53.5 Not classified
Styrene, inhibited (CAS No)100-42-5 <= 46.9 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation:vapour), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Carc. 2, H351 SECTION 4:First aid measures 4.1. Description of first aid measures First-aid measures general :Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation :Assure fresh air breathing. Allow the victim torest. First-aid measures after skin contact :Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact :Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion :Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries :Not expectedto present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5:Firefighting measures 5.1. Extinguishing media Suitable extinguishing media :Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media :Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions :Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting :Do not enterfire area without proper protective equipment, including respiratory protection. SECTION 6:Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1.For non-emergency personnel Emergency procedures :Evacuate unnecessary personnel. 6.1.2.For emergency responders Protective equipment :Equip cleanup crew with proper protection. Emergency procedures :Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up :Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7:Handling and storage 7.1. Precautions for safe handling Precautions for safe handling :Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Composite Resource Marine ISO Laminating Resin Safety Data SheetCR30MIMarine ISO according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN(English) SDS ID:CR30MI 3/7 7.2. Conditions for safe storage, including any incompatibilities Storage conditions :Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. Incompatible products :Strong bases. strong acids. Incompatible materials :Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8:Exposure controls/personal protection 8.1. Control parameters styrene, inhibited (100-42-5) USA ACGIH ACGIH TWA (ppm) 20 ppm USA ACGIH ACGIH STEL (ppm) 40 ppm 8.2. Exposure controls Personal protective equipment :Avoid all unnecessary exposure. Hand protection :Wear protective gloves. Eye protection :Chemical goggles or safety glasses. Respiratory protection :Wear approved mask. Other information :When using, do not eat, drink or smoke. SECTION 9:Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state :Liquid Appearance :Clear, colorless liquid Colour :Clear Odour :Characteristic Odour threshold :No data available pH :No dataavailable Relative evaporation rate (butylacetate=1):No data available Relative evaporation rate (ether=1) :< 1 slower than ether Melting point :No data available Freezing point :No data available Boiling point :145.22 CInitial BoilingPoint for Styrene @ 760.00 mm HG(293.4 F) Flash point :31.1 CFor Volatile Component (88 F) Auto-ignition temperature :No data available Decomposition temperature :No data available Flammability (solid, gas) :No data available Vapour pressure :4.3 mm HgVapor pressurefor Styrene20 C(68 F) Relative vapour density at 20 C :3.6 (Air = 1) Relative density :1.01-1.30Relative Density @25 C(77 F) Solubility :No data available Log Pow :No data available Log Kow :No data available Viscosity, kinematic :No data available Viscosity, dynamic :No data available Explosive properties :No data available Oxidising properties :No data available Explosive limits :No data available 9.2. Other information No additional information available Composite Resource Marine ISO Laminating Resin Safety Data SheetCR30MIMarine ISO according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN(English) SDS ID:CR30MI 4/7 SECTION 10:Stability and reactivity 10.1.Reactivity No additional information available 10.2.Chemical stability Stable under normal conditions. Not established. 10.3.Possibility of hazardous reactions Not established. 10.4.Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5.Incompatible materials strong acids. Strong bases. 10.6.Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11:Toxicological information 11.1.Information on toxicological effects Acute toxicity :Not classified styrene, inhibited (100-42-5) LD50 oral rat 5000 mg/kg (>6000 mg/kg bodyweight; Rat; Rat)
LD50 dermal rat 2820 mg/kg (>2000 mg/kg bodyweight; Rat; Rat; Experimental value)
LD50 dermal rabbit 5010 mg/kg (Rabbit)
LC50 inhalation rat (mg/l) 12 mg/l/4h (Rat)
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat)
ATE CLP (oral) 5000.000 mg/kg bodyweight
ATE CLP (dermal) 2820.000 mg/kg bodyweight
ATE CLP (gases) 2770.000 ppmv/4h
ATE CLP (vapours) 12.000 mg/l/4h
ATE CLP (dust,mist) 12.000 mg/l/4h
Skin corrosion/irritation :Not classified
Serious eye damage/irritation :Not classified
Respiratory or skin sensitisation :Not classified
Germ cell mutagenicity :Notclassified
Based on available data, the classification criteria are not met
Carcinogenicity :Not classified
styrene, inhibited (100-42-5)
IARC group 2B-Possibly Carcinogenic to Humans
Reproductive toxicity :Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure):Not classified
Specific target organ toxicity (repeated
exposure)
:Not classified
Based on available data, the classification criteria are not met
Aspiration hazard :Not classified
Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
:Based on available data, the classification criteria are not met.
Likely routes of exposure :Inhalation
SECTION 12:Ecological information
12.1.Toxicity

Composite Resource Marine ISO Laminating Resin
Safety Data SheetCR30MIMarine ISO
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/11/2014 EN(English) SDS ID:CR30MI 5/7
styrene, inhibited (100-42-5)
LC50 fishes 1 25 mg/l (96 h; Lepomis macrochirus)
LC50 other aquatic organisms 1 10-100 mg/l (96 h)
EC50 Daphnia 1 23 mg/l (48 h; Daphnia magna; LOCOMOTOR EFFECT)
LC50 fish 2 32 mg/l (96 h; Pimephales promelas)
EC50 Daphnia 2 27 mg/l (24 h; Daphnia magna)
TLM fish 1 25.1 mg/l (96 h; Lepomis macrochirus; SOFT WATER)
TLM fish 2 46.4 mg/l (96 h; Pimephales promelas; SOFT WATER)
TLM other aquatic organisms 1 10-100,96 h
Threshold limit other aquatic organisms 110-100,96 h; Pseudomonas putida
Threshold limit other aquatic organisms 272 mg/l
Threshold limit algae 1 > 200 mg/l (192 h; Scenedesmus quadricauda; INHIBITORY)
Threshold limit algae 2 67 mg/l (Microcystis aeruginosa; INHIBITORY)
12.2.Persistence and degradability
Composite Resource Marine ISO Laminating Resin(Mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Readily biodegradable in water. Not readily biodegradable in water. Forming sediments in
water. Non degradable in the soil. Adsorbs into the soil. Photodegradation in the air. Not
established.
Chemical oxygen demand (COD) 2.80 g O /g substance
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 % ThOD
Unsaturated Polyester Resin (TRADE SECRET)
Persistence and degradability Not established.
12.3.Bioaccumulative potential
Composite Resource Marine ISO Laminating Resin(Mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 12-77 (QSAR)
BCF fish 2 35.5 (Carassius auratus)
Log Pow 2.95-3.16 (Experimental value)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established. Unsaturated PolyesterResin (TRADE SECRET) Bioaccumulative potential Not established. 12.4.Mobility in soil styrene, inhibited (100-42-5) Surface tension 0.032 N/m (19 C) 12.5.Other adverse effects Other information :Avoid release to the environment. SECTION 13:Disposal considerations 13.1.Waste treatment methods Waste disposal recommendations :Dispose in a safe manner in accordance with local/national regulations. Ecology-waste materials :Avoid release to the environment. SECTION 14:Transport information In accordance with DOT UN-No.(DOT) :UN1866 DOT Proper Shipping Name :RESIN SOLUTION Department of Transportation (DOT) Hazard Classes :3-Class 3-Flammable and combustible liquid 49 CFR 173.120 Composite Resource Marine ISO Laminating Resin Safety Data SheetCR30MIMarine ISO according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN(English) SDS ID:CR30MI 6/7 Hazard labels (DOT) :3-Flammable liquid Packing group (DOT) :III-Minor Danger Additional information Other information :No supplementary information available. ADR Transport document description :UN UN1866 RESIN SOLUTION, III Packing group (ADR) :III Transport by sea No additional information available Air transport No additional information available SECTION 15:Regulatory information 15.1. US Federal regulations Composite Resource Marine ISO Laminating Resin (Mixture) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 1000 lb styrene, inhibited (100-42-5) RQ (Reportable quantity, section 304 of EPA's List of Lists) : 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Reactive hazard Fire hazard Delayed (chronic) health hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2.National regulations styrene, inhibited (100-42-5) Listed on EPA's Hazardous Air Pollutants (HAPS) 15.3. US State regulations styrene, inhibited (100-42-5) U.S.-California- Proposition 65- Carcinogens List U.S.-California- Proposition 65- Developmental Toxicity U.S.-California- Proposition 65- Reproductive Toxicity- U.S.-California- Proposition 65- Reproductive Toxicity-Male No significance risk level (NSRL) Composite Resource Marine ISO Laminating Resin Safety Data SheetCR30MIMarine ISO according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 11/11/2014 EN(English) SDS ID:CR30MI 7/7 styrene, inhibited (100-42-5) Female styrene, inhibited (100-42-5) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK (Right to Know)-Environmental Hazard List SECTION 16:Other information Data sources :REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information :None. Full text of H-phrases: see section 16: ------Acute Tox. 4 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 4 ------Carc. 2 Carcinogenicity, Category 2 ------Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------Flam. Liq. 1 Flammable liquids, Category 1 ------Flam. Liq. 3 Flammable liquids, Category 3 ------Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------H224 Extremely flammable liquid and vapour ------H226 Flammable liquid and vapour ------H315 Causes skin irritation ------H319 Causes serious eye irritation ------H332 Harmful if inhaled ------H351 Suspected of causing cancer SDS US (GHS HazCom 2012) To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.