81XR28A-2_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

XR28A Resin
APPLICABLE PRODUCT CODE S: ………………. XR28A, XR28A-1, XR28A-2, XR28A-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Fire retardant resin applications.
PRODUCT RESTRICT IONS: ……………………….. Use product only for intended uses as listed. Export restrictions.
SDS VERSION: …………………………………………. XR28A-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Germ cell mutagenicity, Category 1B
Reproductive toxicity, Category 2
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H340 May cause genetic defects
H361 Suspected of damaging fertility or the unborn child
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 If exposed or concerned: Get medical attention/advice.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.

Other Hazards

PRO-SET

XR28A Resin
Page 2 of 6 Last Revised: 03JAN22
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-100
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
Dimethyl methylphosphonate 756-79-6 1-10
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical advice.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon oxides, phosphorous oxides.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES: …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.

PRO-SET

XR28A Resin
Page 3 of 6 Last Revised: 03JAN22
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Dimethyl methylphosphonate 756-79-6 No data available.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. >400 F (204

C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93

C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.14
BULK DENSITY………………………………………………………………………. 9.49 lbs./gal. (1.14 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20 C. Estimated based on ingredient data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available WATER SOLUBILITY (% BY WT.) ..................................................... No data available PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available KINEMATIC VISCOSITY: ................................................................... 478 mm 2 /s @ 20 C DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system. 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon oxides, phosphorous oxides and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition. 11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-

17557-23-2

4500 mg/kg

>2000 mg/kg

No data
Dimethyl methylphosphonate 756-79-6 >5000 mg/kg 4640 mg/kg >2.59 mg/l 4h

PRO-SET

XR28A Resin
Page 4 of 6 Last Revised: 03JAN22

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.

SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.

REPRODUCTIVE TOXICIT Y: …………………………………………………….. Suspected of damaging fertility or the unborn child. Category 2.

Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth
defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.

Dimethyle methylphosphonate has been shown to cause impairment of fertility in laboratory animal studies. Suspected human reproductive
toxicant. Paternal Effects: Spermatogenesis (including genetic material, sperm morphology, motility, and count). Effects on Fertilitiy: Male fertility
index (Ex. number of males impregnating females per number of males exposed to fertile non-pregnant females).

MUTAGENICITY: …………………………………………………………………….. May cause genetic defects. Category 1B.

Dimethyl methylphosphonate showed mutagenic effects in in vivo testing. The substance was not mutagenic in bacteria. The substance was
mutagenic in a mammalian cell culture test system. The substance was mutagenic in studies with mammals.

Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.

CARCINOGENICITY: ……………………………………………………………….. Suspected of causing cancer. Category 2.

Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.

Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... Excessive inhalation of a high concentration of vapors may cause slight respiratory irritation. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity requirements. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2. PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification PRO-SET XR28A Resin Page 5 of 6 Last Revised: 03JAN22 Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2 Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified. Dimethyl methylphosphonate 756-79-6 Not classified. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME : .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes IMDG UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC All ingredients are listed or otherwise compliant. US EPA TSCA Specific Requirements: ............................................ No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITTLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2. Subject to Section 313 ................................................................ No data available. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. PRO-SET XR28A Resin Page 6 of 6 Last Revised: 03JAN22 COMPONENT NAME /CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1 CA Dimethyl methylphosphonate 756-79-6 PA, NJ 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ January 15, 2019 SDS VERSION: .................................................................................. XR28A-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 2 FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 2 1 1

81XR28A-1_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

XR28A Resin
APPLICABLE PRODUCT CODE S: ………………. XR28A, XR28A-1, XR28A-2, XR28A-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Fire retardant resin applications.
PRODUCT RESTRICT IONS: ……………………….. Use product only for intended uses as listed. Export restrictions.
SDS VERSION: …………………………………………. XR28A-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Germ cell mutagenicity, Category 1B
Reproductive toxicity, Category 2
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H340 May cause genetic defects
H361 Suspected of damaging fertility or the unborn child
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 If exposed or concerned: Get medical attention/advice.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.

Other Hazards

PRO-SET

XR28A Resin
Page 2 of 6 Last Revised: 03JAN22
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-100
Oxirane, 2,2′[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 10-30
Dimethyl methylphosphonate 756-79-6 1-10
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical advice.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon oxides, phosphorous oxides.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES: …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.

PRO-SET

XR28A Resin
Page 3 of 6 Last Revised: 03JAN22
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available.
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-
17557-23-2 No data available.
Dimethyl methylphosphonate 756-79-6 No data available.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. >400 F (204

C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93

C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.14
BULK DENSITY………………………………………………………………………. 9.49 lbs./gal. (1.14 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20 C. Estimated based on ingredient data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available WATER SOLUBILITY (% BY WT.) ..................................................... No data available PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available KINEMATIC VISCOSITY: ................................................................... 478 mm 2 /s @ 20 C DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system. 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon oxides, phosphorous oxides and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition. 11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Oxirane, 2,2′[(2,2-dimethyl-1,3-
propanediyl)bis(oxymethylene)]bis-

17557-23-2

4500 mg/kg

>2000 mg/kg

No data
Dimethyl methylphosphonate 756-79-6 >5000 mg/kg 4640 mg/kg >2.59 mg/l 4h

PRO-SET

XR28A Resin
Page 4 of 6 Last Revised: 03JAN22

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.

SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.

REPRODUCTIVE TOXICIT Y: …………………………………………………….. Suspected of damaging fertility or the unborn child. Category 2.

Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth
defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.

Dimethyle methylphosphonate has been shown to cause impairment of fertility in laboratory animal studies. Suspected human reproductive
toxicant. Paternal Effects: Spermatogenesis (including genetic material, sperm morphology, motility, and count). Effects on Fertilitiy: Male fertility
index (Ex. number of males impregnating females per number of males exposed to fertile non-pregnant females).

MUTAGENICITY: …………………………………………………………………….. May cause genetic defects. Category 1B.

Dimethyl methylphosphonate showed mutagenic effects in in vivo testing. The substance was not mutagenic in bacteria. The substance was
mutagenic in a mammalian cell culture test system. The substance was mutagenic in studies with mammals.

Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.

CARCINOGENICITY: ……………………………………………………………….. Suspected of causing cancer. Category 2.

Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.

Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance. SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... Excessive inhalation of a high concentration of vapors may cause slight respiratory irritation. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity requirements. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2. PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification PRO-SET XR28A Resin Page 5 of 6 Last Revised: 03JAN22 Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2 Oxirane, 2,2'[(2,2-dimethyl-1,3-propanediyl)bis(oxymethylene)]bis- 17557-23-2 Not classified. Dimethyl methylphosphonate 756-79-6 Not classified. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME : .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes IMDG UN NUMBER: ..................................................................................... UN 3082. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS All ingredients are listed or otherwise compliant. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC All ingredients are listed or otherwise compliant. US EPA TSCA Specific Requirements: ............................................ No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITTLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in Section 2. Subject to Section 313 ................................................................ No data available. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. PRO-SET XR28A Resin Page 6 of 6 Last Revised: 03JAN22 COMPONENT NAME /CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1 CA Dimethyl methylphosphonate 756-79-6 PA, NJ 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ January 15, 2019 SDS VERSION: .................................................................................. XR28A-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 2 FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 2 1 1

81TLG625R2_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

TLG-625-R
APPLICABLE PRODUCT CODE S: ………………. TLG-625-R, TLG-625-R-1, TLG-625-R-2, TLG-625-R-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin used for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. TLG-625-R-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers

25085-99-8

60-80

PRO-SET

TLG-625-R
Page 2 of 7 Last Revised: 03JAN22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
Soda lime borosilicate glass 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash hands and skin thoroughly after
handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken
when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can
produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

PRO-SET

TLG-625-R
Page 3 of 7 Last Revised: 03JAN22
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

This product contains glass oxide spheres, amorphous (crystalline-free) silica, and other silicate particulate matter. No significant exposure is
expected to occur during use of products in which the particulate matter is present in a liquid dispersion or bound to other materials, such as in
epoxies. Risk of overexposure by way of inhalation depends on actual concentration in the formula and duration and level of exposure to airborne
particulate generated from sanding or similar machining operations. Consider the use of a respirator suitable for particulate matter if sanding or
machining cured product.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions. Avoid breathing airborne dust generated from sanding or machining cured product.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers

25085-99-8

No data available.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Soda lime borosilicate glass 65997-17-3 10 mg/m
3
(supplier WEEL)
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 ACGIH TWA 10 mg/m
3
total dust; 3 mg/m
3
respirable dust
OSHA PEL 15 mg/m3 total dust; 5 mg/m3
respirable dust

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Paste.
COLOR: ………………………………………………………………………………… Off-white.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204

C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93

C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 0.87
BULK DENSITY………………………………………………………………………. 7.25 lbs./gal. (0.87 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20 C. Estimated based on ingredient data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available WATER SOLUBILITY (% BY WT.) ..................................................... No data available PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available KINEMATIC VISCOSITY: ................................................................... No data mm 2 /s @ 20 C DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system. 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. PRO-SET TLG-625-R Page 4 of 7 Last Revised: 03JAN22 CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition. 11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 <15000 mg/kg <23000 mg/kg No data Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 >2000 mg/kg 2000 mg/kg No data
Soda lime borosilicate glass 65997-17-3 2000 5000 mg/kg >5000 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Sodium potassium aluminum silicate (expanded
perlite)
93763-70-3 No data No data No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.

SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.

Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.

Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.

Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance. This product contains glass oxide spheres. Some positive data exists that indicates glass oxide (CAS# 65997-17-3) may be carcinogenic by route of inhalation to some animal species, but that data is not sufficient for classification. Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic amorphous silica. Trace residual formaldehyde may be present in this product at <0.002%. Formaldehyde is classified by IARC as a Group 1 carcinogenic to humans, by NTP Known to be a human carcinogen, and by OSHA as a specifically regulated carcinogen in 29CFR 1910.1048. This product is not classified as a carcinogen because the concentration of formaldehyde does not exceed the cutoff threshold for classification. Exposure potential is expected to be minimal under normal conditions of use due to the physical characteristics of the product. Trace amounts of crystalline silica (quartz) may be present in this product at <0.003%. Crystalline silica is classified by IARC as a Group 1 carcinogenic to humans, by NTP Known to be a human carcinogen. No significant inhalation exposure is expected to occur during use of products in which crystalline silica is present in a liquid dispersion or when bound to other materials, such as in cured epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of exposure to dust from sanding or similar machining operations of solidified product. When sanding or machining solidified product and creating an airborne dust that may contain crystalline silica, consider the use of appropriate respiratory protection, such as a N95 particulate filter or greater. PRO-SET TLG-625-R Page 5 of 7 Last Revised: 03JAN22 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity requirements. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2. PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2 Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2 Soda lime borosilicate glass 65997-17-3 Not classified. Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Not classified. Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 Not classified. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... UN 3077. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes IMDG UN NUMBER: ..................................................................................... UN 3077. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes PRO-SET TLG-625-R Page 6 of 7 Last Revised: 03JAN22 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Not determined. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC All ingredients are listed or otherwise compliant. US EPA TSCA Requirements: ..................................................... No data available. Canada WHMIS Confidential Business Information (CBI): ........ No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ No data available. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1 CA Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA, Crystalline silica 14808-60-7 <0.003% PA, NJ, MA, 1 CA Formaldehyde 50-00-0 <0.002% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ January 15, 2019 SDS VERSION: .................................................................................. TLG-625-R-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 2 FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe 2 1 1 PRO-SET TLG-625-R Page 7 of 7 Last Revised: 03JAN22 Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data.

81TLG625R1_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

TLG-625-R
APPLICABLE PRODUCT CODE S: ………………. TLG-625-R, TLG-625-R-1, TLG-625-R-2, TLG-625-R-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin used for composites.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. TLG-625-R-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P332 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers

25085-99-8

60-80

PRO-SET

TLG-625-R
Page 2 of 7 Last Revised: 03JAN22
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
Soda lime borosilicate glass 65997-17-3 1-5
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 1-5
Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash hands and skin thoroughly after
handling. Launder contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken
when curing product in large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can
produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

PRO-SET

TLG-625-R
Page 3 of 7 Last Revised: 03JAN22
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

This product contains glass oxide spheres, amorphous (crystalline-free) silica, and other silicate particulate matter. No significant exposure is
expected to occur during use of products in which the particulate matter is present in a liquid dispersion or bound to other materials, such as in
epoxies. Risk of overexposure by way of inhalation depends on actual concentration in the formula and duration and level of exposure to airborne
particulate generated from sanding or similar machining operations. Consider the use of a respirator suitable for particulate matter if sanding or
machining cured product.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions. Avoid breathing airborne dust generated from sanding or machining cured product.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers

25085-99-8

No data available.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
Soda lime borosilicate glass 65997-17-3 10 mg/m
3
(supplier WEEL)
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
,
TWA, Respirable
Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 ACGIH TWA 10 mg/m
3
total dust; 3 mg/m
3
respirable dust
OSHA PEL 15 mg/m3 total dust; 5 mg/m3
respirable dust

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Paste.
COLOR: ………………………………………………………………………………… Off-white.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204

C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93

C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 0.87
BULK DENSITY………………………………………………………………………. 7.25 lbs./gal. (0.87 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20 C. Estimated based on ingredient data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available WATER SOLUBILITY (% BY WT.) ..................................................... No data available PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available KINEMATIC VISCOSITY: ................................................................... No data mm 2 /s @ 20 C DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM D 2369-07 was used to determine the Volatile Content of mixed epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system. 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause polymerization. INCOMPATIBILITIES: ........................................................................ Strong acids, bases, amines and mercaptans can cause polymerization. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. PRO-SET TLG-625-R Page 4 of 7 Last Revised: 03JAN22 CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Carbon monoxide, carbon dioxide and phenolics may be produced during uncontrolled exothermic reactions or when otherwise heated to decomposition. 11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 <15000 mg/kg <23000 mg/kg No data Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 >2000 mg/kg 2000 mg/kg No data
Soda lime borosilicate glass 65997-17-3 2000 5000 mg/kg >5000 mg/kg No data
Synthetic Amorphous, Pyrogenic Silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data
Sodium potassium aluminum silicate (expanded
perlite)
93763-70-3 No data No data No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.

SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.

Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.

Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.

Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product would result in measurable exposure concentrations to this substance. This product contains glass oxide spheres. Some positive data exists that indicates glass oxide (CAS# 65997-17-3) may be carcinogenic by route of inhalation to some animal species, but that data is not sufficient for classification. Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic amorphous silica. Trace residual formaldehyde may be present in this product at <0.002%. Formaldehyde is classified by IARC as a Group 1 carcinogenic to humans, by NTP Known to be a human carcinogen, and by OSHA as a specifically regulated carcinogen in 29CFR 1910.1048. This product is not classified as a carcinogen because the concentration of formaldehyde does not exceed the cutoff threshold for classification. Exposure potential is expected to be minimal under normal conditions of use due to the physical characteristics of the product. Trace amounts of crystalline silica (quartz) may be present in this product at <0.003%. Crystalline silica is classified by IARC as a Group 1 carcinogenic to humans, by NTP Known to be a human carcinogen. No significant inhalation exposure is expected to occur during use of products in which crystalline silica is present in a liquid dispersion or when bound to other materials, such as in cured epoxies. Risk of overexposure depends on actual concentration in the formula and duration and level of exposure to dust from sanding or similar machining operations of solidified product. When sanding or machining solidified product and creating an airborne dust that may contain crystalline silica, consider the use of appropriate respiratory protection, such as a N95 particulate filter or greater. PRO-SET TLG-625-R Page 5 of 7 Last Revised: 03JAN22 SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria. SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity requirements. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Aquatic Chronic Category 2. PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2 Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2 Soda lime borosilicate glass 65997-17-3 Not classified. Synthetic Amorphous, Pyrogenic Silica 112945-52-5 Not classified. Sodium potassium aluminum silicate (expanded perlite) 93763-70-3 Not classified. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... UN 3077. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. MARINE POLLUTANT: ....................................................................... Yes IMDG UN NUMBER: ..................................................................................... UN 3077. SHIPPING NAME: ............................................................................... Environmentally hazardous substance, solid, n.o.s. TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin. HAZARD CLASS: ................................................................................ Class 9. PACKING GROUP: ............................................................................. PG III. EmS Number: .................................................................................... F-A, S-F MARINE POLLUTANT ........................................................................ Yes PRO-SET TLG-625-R Page 6 of 7 Last Revised: 03JAN22 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Not determined. South Korea KECI All ingredients are listed or otherwise compliant. China IECSC All ingredients are listed or otherwise compliant. Philippines PICCS All ingredients are listed or otherwise compliant. New Zealand NZIoC All ingredients are listed or otherwise compliant. US EPA TSCA Requirements: ..................................................... No data available. Canada WHMIS Confidential Business Information (CBI): ........ No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... No data available. Subject to Section 304 (RQ) ........................................................ No data available. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ No data available. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Epichlorohydrin 106-89-8 < 5ppm 1 CA Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA, Crystalline silica 14808-60-7 <0.003% PA, NJ, MA, 1 CA Formaldehyde 50-00-0 <0.002% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ January 15, 2019 SDS VERSION: .................................................................................. TLG-625-R-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 2 FLAMMABILITY: 1 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe 2 1 1 PRO-SET TLG-625-R Page 7 of 7 Last Revised: 03JAN22 Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data.

81TLG625H2_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

TLG-625-H Hardener
APPLICABLE PRODUCT CODE S: ………………. TLG-625-H, TLG-625-H-1, TLG-625-H-2
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. TLG-625-H-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1C
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations

Other Hazards

PRO-SET

TLG-625-H HARDENER
Page 2 of 7 Last Revised: 03JAN22
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty acids and
triethylenetetramine

68082-29-1

30-60

Benzyl alcohol

100-51-6

10-30

Soda lime borosilicate glass

65997-17-3

10-30

Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde

57214-10-5

10-30

Benzene-1,3-dimethanamine

1477-55-0

3-10

Synthetic amorphous, pyrogenic silica

112945-52-5

1-5

Triethylenetetramine

112-24-3

1-5

Polymer of epichlorohydrin / bisphenol A and diethylenetriamine

31326-29-1

1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist or if you feel unwell.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, nitrosamines. When mixed with sawdust, wood chips, or
other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat
is not dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY MEASURES : ……………………………………………………… Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

PRO-SET

TLG-625-H HARDENER
Page 3 of 7 Last Revised: 03JAN22

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).

STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.

HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Fatty acids, C18-unsatd., dimers, polymers with
tall-oil fatty acids and triethylenetetramine

68082-29-1

No data available (reference triethylenetetramine)

Benzyl alcohol

100-51-6

10 ppm TWA (WEEL)

Soda lime borosilicate glass

65997-17-3
Dust and PNOS: ACGIH 10mg/m3, TWA, Inhalable; 3 mg/m3,
TWA, Respirable; OSHA PEL 15 mg/m3, TWA, total dust; 5
mg/m3, TWA, Respirable

Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde

57214-10-5

No data available

Benzene-1,3-dimethanamine

1477-55-0
NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A

Synthetic amorphous, pyrogenic silica

112945-52-5
Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable

Triethylenetetramine

112-24-3

AIHA WEEL: 1 ppm ; 6 mg/m3; SKIN

Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

No data available

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Paste.
COLOR: ………………………………………………………………………………… Light brown.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200

F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.

PRO-SET

TLG-625-H HARDENER
Page 4 of 7 Last Revised: 03JAN22
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data). SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.49 BULK DENSITY.................................................................................. 4.09 lbs./gal. (0.49 kg/L) VAPOR DENSITY (air = 1) ................................................................. No data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data. WATER SOLUBILITY (% BY WT.) ..................................................... No data. PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data. KINEMATIC VISCOSITY: ................................................................... Paste. (mm 2 /s @ 20 C) DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below. VOC Content Resin/Hardener (g/L) (lb/gal) TLG-625-R / TLG-625-H ............................................................. 3.77 0.03 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure. INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, nitrosamines. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty acids and triethylenetetramine 68082-29-1 No data available (reference triethylenetetramine) No data available (reference triethylenetetramine) No data available (reference triethylenetetramine) Benzyl alcohol 100-51-6 1620 mg/kg No data available >4.18 mg/l
4h aerosol

Soda lime borosilicate glass

65997-17-3

No data available

No data available

No data available

Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde

57214-10-5

No data available

No data available

No data available

Benzene-1,3-dimethanamine

1477-55-0

980 mg/kg

2000 mg/kg

1.34 mg/l 4h dust/mist

Synthetic amorphous, pyrogenic silica

112945-52-5

>5000 mg/kg

>2000 mg/kg

No data available

Triethylenetetramine

112-24-3

1716.2 mg/kg

805 mg/kg

No data

Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

1620 mg/kg

No data available

No data available

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data this product does not
meet classification criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.

SKIN CORROSION / IRRITATION: …………………………………………….. Category 1C. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.

SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.

RESPIRATORY SENSITIZATION: ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.

PRO-SET

TLG-625-H HARDENER
Page 5 of 7 Last Revised: 03JAN22

SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.

REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Not classified. Based on available data this product does not meet
classification criteria.

ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.

OTHER HEALTH HAZARD INFORMATION : ……………………………….. None known.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.

CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.

PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.

MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.

ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification Information
Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty
acids and triethylenetetramine

68082-29-1

Chronic Aquatic Cat. 2
Benzyl alcohol 100-51-6 No data available
Soda lime borosilicate glass 65997-17-3 Not classified
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde

57214-10-5

Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Synthetic amorphous, pyrogenic silica 112945-52-5 Not classified
Triethylenetetramine 112-24-3 Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

No data available

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine

PRO-SET

TLG-625-H HARDENER
Page 6 of 7 Last Revised: 03JAN22
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes

ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.

US EPA TSCA Requirements: …………………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): …….. No data available.

US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in section 2.
Subject to Section 313 ………………………………………………………. No data available.

US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Triethylenetetramine
112-14-3 PA, MA, NJ

16. OTHER INFORMATION

REASON FOR ISSUE:……………………………………………………………… Approval date change.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. January 3, 2022
SUPERSEDES DATE: ……………………………………………………………… January 15, 2019
SDS VERSION: ………………………………………………………………………. TLG-625-H-2022a

OTHER HAZARD INFORMATION AND RATING SYSTEMS:

HMIS RATING NFPA 704 CODES

PRO-SET

TLG-625-H HARDENER
Page 7 of 7 Last Revised: 03JAN22

HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe

Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
2

81TLG625H1_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… PRO-SET

TLG-625-H Hardener
APPLICABLE PRODUCT CODE S: ………………. TLG-625-H, TLG-625-H-1, TLG-625-H-2
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. TLG-625-H-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1C
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H411 Toxic to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations

Other Hazards

PRO-SET

TLG-625-H HARDENER
Page 2 of 7 Last Revised: 03JAN22
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty acids and
triethylenetetramine

68082-29-1

30-60

Benzyl alcohol

100-51-6

10-30

Soda lime borosilicate glass

65997-17-3

10-30

Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde

57214-10-5

10-30

Benzene-1,3-dimethanamine

1477-55-0

3-10

Synthetic amorphous, pyrogenic silica

112945-52-5

1-5

Triethylenetetramine

112-24-3

1-5

Polymer of epichlorohydrin / bisphenol A and diethylenetriamine

31326-29-1

1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist or if you feel unwell.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, nitrosamines. When mixed with sawdust, wood chips, or
other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat
is not dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY MEASURES : ……………………………………………………… Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

PRO-SET

TLG-625-H HARDENER
Page 3 of 7 Last Revised: 03JAN22

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).

STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.

HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Fatty acids, C18-unsatd., dimers, polymers with
tall-oil fatty acids and triethylenetetramine

68082-29-1

No data available (reference triethylenetetramine)

Benzyl alcohol

100-51-6

10 ppm TWA (WEEL)

Soda lime borosilicate glass

65997-17-3
Dust and PNOS: ACGIH 10mg/m3, TWA, Inhalable; 3 mg/m3,
TWA, Respirable; OSHA PEL 15 mg/m3, TWA, total dust; 5
mg/m3, TWA, Respirable

Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde

57214-10-5

No data available

Benzene-1,3-dimethanamine

1477-55-0
NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A

Synthetic amorphous, pyrogenic silica

112945-52-5
Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable

Triethylenetetramine

112-24-3

AIHA WEEL: 1 ppm ; 6 mg/m3; SKIN

Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

No data available

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Paste.
COLOR: ………………………………………………………………………………… Light brown.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200

F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.

PRO-SET

TLG-625-H HARDENER
Page 4 of 7 Last Revised: 03JAN22
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data). SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.49 BULK DENSITY.................................................................................. 4.09 lbs./gal. (0.49 kg/L) VAPOR DENSITY (air = 1) ................................................................. No data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data. WATER SOLUBILITY (% BY WT.) ..................................................... No data. PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data. KINEMATIC VISCOSITY: ................................................................... Paste. (mm 2 /s @ 20 C) DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below. VOC Content Resin/Hardener (g/L) (lb/gal) TLG-625-R / TLG-625-H ............................................................. 3.77 0.03 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure. INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, nitrosamines. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty acids and triethylenetetramine 68082-29-1 No data available (reference triethylenetetramine) No data available (reference triethylenetetramine) No data available (reference triethylenetetramine) Benzyl alcohol 100-51-6 1620 mg/kg No data available >4.18 mg/l
4h aerosol

Soda lime borosilicate glass

65997-17-3

No data available

No data available

No data available

Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde

57214-10-5

No data available

No data available

No data available

Benzene-1,3-dimethanamine

1477-55-0

980 mg/kg

2000 mg/kg

1.34 mg/l 4h dust/mist

Synthetic amorphous, pyrogenic silica

112945-52-5

>5000 mg/kg

>2000 mg/kg

No data available

Triethylenetetramine

112-24-3

1716.2 mg/kg

805 mg/kg

No data

Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

1620 mg/kg

No data available

No data available

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data this product does not
meet classification criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.

SKIN CORROSION / IRRITATION: …………………………………………….. Category 1C. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.

SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.

RESPIRATORY SENSITIZATION: ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.

PRO-SET

TLG-625-H HARDENER
Page 5 of 7 Last Revised: 03JAN22

SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.

REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Not classified. Based on available data this product does not meet
classification criteria.

ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.

OTHER HEALTH HAZARD INFORMATION : ……………………………….. None known.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.

CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.

PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.

MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.

ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification Information
Fatty acids, C18-unsatd., dimers, polymers with tall-oil fatty
acids and triethylenetetramine

68082-29-1

Chronic Aquatic Cat. 2
Benzyl alcohol 100-51-6 No data available
Soda lime borosilicate glass 65997-17-3 Not classified
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde

57214-10-5

Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Synthetic amorphous, pyrogenic silica 112945-52-5 Not classified
Triethylenetetramine 112-24-3 Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine

31326-29-1

No data available

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine

PRO-SET

TLG-625-H HARDENER
Page 6 of 7 Last Revised: 03JAN22
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes

ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.

US EPA TSCA Requirements: …………………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): …….. No data available.

US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in section 2.
Subject to Section 313 ………………………………………………………. No data available.

US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Triethylenetetramine
112-14-3 PA, MA, NJ

16. OTHER INFORMATION

REASON FOR ISSUE:……………………………………………………………… Approval date change.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. January 3, 2022
SUPERSEDES DATE: ……………………………………………………………… January 15, 2019
SDS VERSION: ………………………………………………………………………. TLG-625-H-2022a

OTHER HAZARD INFORMATION AND RATING SYSTEMS:

HMIS RATING NFPA 704 CODES

PRO-SET

TLG-625-H HARDENER
Page 7 of 7 Last Revised: 03JAN22

HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe

Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
2

81SBE460-P_SDS.pdf

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 09/10/2015 Revision date: 01/25/2019 Version: SBE-460 -2019a
`
01/25/2019 EN (English) Page 1

SECTION 1: Identification

Identification
Product form : Mixtures
Product name : PRO-SET SBE-460 Accelerator
Product code : SBE-460, SBE-460-P, SBE-460-PT, SBE-460-G, SBE-460-GAL

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Epoxy system cure accelerator.

Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 888-377-6738 or 989-684-7286
www.prosetepoxy.com

Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr

SECTION 2: Hazard(s) identification

Classification of the substance or mixture
Acute Tox. 4 (Oral)
Acute Tox. 4 (Dermal)
Skin Corr. 1A
Eye Dam. 1
STOT SE 3

Label elements
Hazard pictograms (GHS) :

GHS05

GHS07

Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed or in contact with skin. Causes severe skin burns and eye damage. May cause respiratory irritation
Precautionary statements (GHS)
:
Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use
only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: rinse mouth. Do
NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing
before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/ container to hazardous or special
waste collection point, in accordance with local, regional, national and/or international regulation

Other hazards
No additional information available.
Unknown acute toxicity
No additional information available

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 2/7

SECTION 3: Composition/information on ingredients

Substance
Not applicable
Mixtures

Name Product identifier HPR %
Water

(CAS No) 7732-18-5 80 – 100
Hydrochloric acid

(CAS No) 7647-01-0 10 – 30

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures

Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a poison center or a doctor if you feel unwell.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.

Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause burns or
irritation of the linings of the mouth, throat, and gastrointestinal tract.

Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Water spray. Dry chemical. Alcohol-resistant foam. Carbon dioxide.
Unsuitable extinguishing media : None known.

Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, hydrogen
chloride. Toxic and irritating gases may be released.
Reactivity : No dangerous reaction known under conditions of normal use.

Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 3/7

Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE).
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.

Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage

Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray.
Do not swallow. Handle and open container with care. Use only outdoors or in a well-ventilated
area. Do not eat, drink or smoke when using this product.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.

Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in a dry, cool and well-
ventilated place. Protect from sunlight. Storage temperature : 40 F (4 C) – 77 F (25 C).

SECTION 8: Exposure controls/personal protection

Control parameters

Water (7732-18-5)
Not applicable

Hydrochloric acid (7647-01-0)
ACGIH ACGIH Ceiling (ppm) 2 ppm Ceiling limit C is to be determined by
breathing zone air samples.
OSHA OSHA PEL (Ceiling) (mg/m ) 7 mg/m
OSHA OSHA PEL (Ceiling) (ppm) 5 ppm
IDLH US IDLH (ppm) 50 ppm
NIOSH NIOSH REL (ceiling) (mg/m ) 7 mg/m
NIOSH NIOSH REL (ceiling) (ppm) 5 ppm

Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties
Physical state : Liquid

Appearance : No data available

Colour : Colourless

Odour : Strong, irritating

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 4/7

Odour threshold : No data available

pH : 1.08

Melting point : No data available

Freezing point : No data available

Boiling point : > 200 F (93 C)

Flash point : No data available

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : Non flammable.

Vapour pressure : 253 hPa (190 mmHg) @ 77 F (25 C)

Relative vapour density at 20 C : No data available

Relative density : 1

Solubility : Water: 100 %

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

Other information
VOC content : SBE-160 / SBE-262 / SBE-460: 27.13 g/L (0.23 lbs/gal);
SBE-160 / SBE-265 / SBE-460: 28.16 g/L (0.24 lbs/gal)
Bulk density : 8.3 lb/gal (1.00 kg/L)
SECTION 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Strong oxidizers. Caustics. Alkalis. Cyanides. Metals.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, hydrogen chloride, and hydrogen in
contact with metals, chlorine from oxidizers. Toxic and irritating vapours.
SECTION 11: Toxicological information

Information on toxicological effects

Water (7732-18-5)
LD50 oral rat > 90 ml/kg

Hydrochloric acid (7647-01-0)
LD50 oral rat 900 mg/kg
LD50 dermal rabbit 1449 mg/kg
LC50 inhalation 1108 ppm/1h (mouse); 3124 mg/l 1h (rat)

Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Dermal: Harmful in contact with skin.
Acute toxicity (inhalation) : Not classified.
Skin corrosion/irritation : Causes severe skin burns
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : Not classified.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 5/7

Hydrochloric acid (7647-01-0)
IARC group 3 – Not classifiable

Reproductive toxicity : Not classified.
Specific target organ toxicity (single
exposure)
: May cause respiratory irritation.
Specific target organ toxicity (repeated
exposure)
: Not classified.
Aspiration hazard : Not classified.

Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause burns or
irritation of the linings of the mouth, throat, and gastrointestinal tract.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

Toxicity
Ecology – general : May cause long-term adverse effects in the aquatic environment.

Persistence and degradability
PRO-SET SBE-460 Accelerator
Persistence and degradability Not established.

Bioaccumulative potential
PRO-SET SBE-460 Accelerator
Bioaccumulative potential Not established.

Mobility in soil
No additional information available

Other adverse effects

Effect on the global warming : No known effects from this product.

Ingredient CAS# Ecotoxicity Classification Information
Water 7732-18-5 Does not meet classification criteria.
Hydrochloric acid 7647-01-0 Does not meet classification criteria.

Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information

Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
UN-No.(DOT/TDG) : UN1789
Proper Shipping Name (DOT/TDG) : Hydrochloric acid
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : II

Transport by sea

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 6/7

In accordance with IMDG
UN-No. (IMDG) : 1789
Proper Shipping Name (IMDG) : HYDROCHLORIC ACID
Class (IMDG) : 8
Packing group (IMDG) : II
EmS Number : F-A, S-B
Marine Pollutant : No

Transport by air
In accordance with IATA
UN-No. (IATA) : 1789
Proper Shipping Name (IATA) : Hydrochloric acid
Class (IATA) : 8
Packing group (IATA) : II
Marine Pollutant : No
SECTION 15: Regulatory information

Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.

All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.

Hydrochloric acid (7647-01-0)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 5000 lb
SARA Section 302 Threshold Planning Quantity (TPQ) 500 lb (gas only)
SARA Section 313 – Emission Reporting 1 % (acid aerosols including mists, vapors, gas, fog, and other airborne forms of any
particle size)

International regulations
No additional information available

US State regulations

California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

Hydrochloric acid (7647-01-0)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) List

SECTION 16: Other information

Date of issue : 09/10/2015
Revision date : 01/25/2019
Other information : None.

NFPA health hazard : 3

NFPA fire hazard : 0
NFPA reactivity : 1

PRO-SET SBE-460 Accelerator
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 7/7

HMIS III Rating
Health : 3 Serious Hazard
Flammability : 0 Minimal Hazard
Physical : 1 Slight Hazard

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.

81SBE265-2_SDS.pdf

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 11/03/2016 Revision date: 01/25/2019 Version: SBE-265-2019a

01/25/2019 EN (English) Page 1

SECTION 1: Identification

Identification
Product form : Mixtures
Product name : PRO-SET SBE-265 Hardener
Product code : SBE-265, SBE-265-1, SBE-265-2, SBE-265-4, 265-G

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins

Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com

Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr

SECTION 2: Hazard(s) identification

Classification of the substance or mixture
Acute Tox. 4 (Oral)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
Aquatic Acute 3
Aquatic Chronic 3

Label elements
Hazard pictograms (GHS) :

GHS05

GHS07

Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful to aquatic life. Harmful to aquatic
life with long lasting effects
Precautionary statements (GHS)
:
Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.
Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/
eye protection/face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin
irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store locked up. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation

Other hazards
No additional information available.

Unknown acute toxicity
No additional information available.

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 2/7

SECTION 3: Composition/information on ingredients

Substance
Not applicable
Mixtures

Name Product identifier HPR %
Trimethylhexamethylenediamine

(CAS No) 25620-58-0 10 – 30
Benzyl alcohol

(CAS No) 100-51-6 10 – 30
Isophorone diamine

(CAS No) 2855-13-2 10 – 30
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with
2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine

(CAS No) 111850-23-8 10 – 30
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate

(CAS No) 41556-26-7 0.1 – 1.5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.

SECTION 4: First aid measures

Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Rinse mouth.

Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.

Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.

Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, nitrogen oxides,
amines, ammonia, nitric acid, cyanides, nitrosamines. When mixed with sawdust, wood chips,
or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat
is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can
ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.

Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 3/7

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available

Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or
other combustible absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.

Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage

Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray.
Do not swallow. Handle and open container with care. Do not eat, drink or smoke when using
this product. Use personal protective equipment as required. Use only outdoors or in a well-
ventilated area. When mixed with epoxy resin this product causes an exothermic reaction,
which in large masses, can produce enough heat to damage or ignite surrounding materials
and emit fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.

Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Keep only in the original
container in a cool, well-ventilated place. Protect from moisture. Storage temperature : 40 F
(4 C) – 90 F (32 C).

SECTION 8: Exposure controls/personal protection

Control parameters

Trimethylhexamethylenediamine (25620-58-0)
Not applicable

Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm

Isophorone diamine (2855-13-2)
Not applicable

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
Not applicable

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
ACGIH ACGIH Ceiling (mg/m ) 1 mg/m

Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 4/7

Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties
Physical state : Liquid

Appearance : No data available

Colour : Clear

Odour : Ammonia-like

Odour threshold : No data available

pH : 12.13

Melting point : No data available

Freezing point : No data available

Boiling point : > 400 F (204 C)

Flash point : > 200 F (93 C) Estimated based similar product.

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : Non flammable.

Vapour pressure : No data available

Relative vapour density at 20 C : No data available

Relative density : 0.97

Solubility : No data available

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : 88.6 mm /s @ 22 C (72 F)

Viscosity, dynamic : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

Other information
VOC content : SBE-160 / SBE-265: 3.61 g/L (0.03 lbs/gal); SBE-163 / SBE-265: 8.25 g/L (0.07 lbs/gal); SBE-
166 / SBE-265: 7.82 g/L (0.07 lbs/gal)
Bulk density : 8.14 lb/gal (0.97 kg/L)
SECTION 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, nitrogen oxides, amines, ammonia, nitric
acid, cyanides, nitrosamines.
SECTION 11: Toxicological information

Information on toxicological effects

Trimethylhexamethylenediamine (25620-58-0)
LD50 oral rat 910 mg/kg

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 5/7

Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
LC50 inhalation rat > 4.18 mg/l/4h

Isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat > 5.01 mg/l/4h

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LD50 oral rat 2615 mg/kg

Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Not classified.
Specific target organ toxicity (single
exposure)
: Not classified.
Specific target organ toxicity (repeated
exposure)
: Not classified.
Aspiration hazard : Not classified.

PRO-SET SBE-265 Hardener
Viscosity, kinematic (calculated value) 88.6 mm /s @ 22 C (72 F)

Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

Toxicity
Ecology – general : Harmful to aquatic life with long lasting effects.

Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Isophorone diamine (2855-13-2)
EC50 Daphnia 1 14.6 – 21.5 mg/l (Exposure time: 48 h – Species: Daphnia magna [semi-static])

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LC50 fish 1 0.97 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Persistence and degradability
PRO-SET SBE-265 Hardener
Persistence and degradability Not established.

Bioaccumulative potential
PRO-SET SBE-265 Hardener
Bioaccumulative potential Not established.

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 6/7

Trimethylhexamethylenediamine (25620-58-0)
Partition coefficient n-octanol/water 0.77 (at 23 C)

Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1

Isophorone diamine (2855-13-2)
Partition coefficient n-octanol/water 0.79 (at 23 C)

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
Partition coefficient n-octanol/water 0.37 (at 25 C)

Mobility in soil
PRO-SET SBE-265 Hardener
Ecology – soil No additional information available.

Other adverse effects

Effect on the global warming : No known effects from this product.

Name CAS# Ecotoxicity Classification Information
Trimethylhexamethylenediamine

25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Benzyl alcohol

100-51-6 Not classified
Isophorone diamine

2855-13-2 Chronic Aquatic Cat. 3
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction
products with 2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine

111850-23-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate

41556-26-7 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1

Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

Waste treatment methods
Product/Packaging disposal
recommendations
: This material must be disposed of in accordance with all local, state, provincial, and federal
regulations. The generation of waste should be avoided or minimized wherever possible.
SECTION 14: Transport information

Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (Isophorone diamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : II
Marine pollutant : No

Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Isophorone diamine)
Class (IMDG) : 8
EmS Number : F-A, S-B
Packing group (IMDG) : II
Marine pollutant : No

Transport by air
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (Isophorone diamine)
Class (IATA) : 8
Packing group (IATA) : II
Marine pollutant : No

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 7/7

SECTION 15: Regulatory information

Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
EPA TSCA Regulatory Flag N – N – indicates a polymeric substance containing no free-radical initiator in its Inventory
name but is considered to cover the designated polymer made with any free-radical initiator
regardless of the amount used.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).

International regulations
No additional information available

US State regulations

California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

Trimethylhexamethylenediamine (25620-58-0)
U.S. – New Jersey – Right to Know Hazardous Substance List

Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List

Isophorone diamine (2855-13-2)
U.S. – New Jersey – Right to Know Hazardous Substance List

SECTION 16: Other information

Date of issue : 11/03/2016
Revision date : 01/25/2019
Other information : None.

NFPA health hazard : 3

NFPA fire hazard : 1
NFPA reactivity : 0

HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.

81SBE265-1_SDS.pdf

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 11/03/2016 Revision date: 01/25/2019 Version: SBE-265-2019a

01/25/2019 EN (English) Page 1

SECTION 1: Identification

Identification
Product form : Mixtures
Product name : PRO-SET SBE-265 Hardener
Product code : SBE-265, SBE-265-1, SBE-265-2, SBE-265-4, 265-G

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins

Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com

Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr

SECTION 2: Hazard(s) identification

Classification of the substance or mixture
Acute Tox. 4 (Oral)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
Aquatic Acute 3
Aquatic Chronic 3

Label elements
Hazard pictograms (GHS) :

GHS05

GHS07

Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful to aquatic life. Harmful to aquatic
life with long lasting effects
Precautionary statements (GHS)
:
Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product.
Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/
eye protection/face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin
irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store locked up. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation

Other hazards
No additional information available.

Unknown acute toxicity
No additional information available.

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 2/7

SECTION 3: Composition/information on ingredients

Substance
Not applicable
Mixtures

Name Product identifier HPR %
Trimethylhexamethylenediamine

(CAS No) 25620-58-0 10 – 30
Benzyl alcohol

(CAS No) 100-51-6 10 – 30
Isophorone diamine

(CAS No) 2855-13-2 10 – 30
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with
2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine

(CAS No) 111850-23-8 10 – 30
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate

(CAS No) 41556-26-7 0.1 – 1.5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.

SECTION 4: First aid measures

Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Rinse mouth.

Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.

Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.

Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, nitrogen oxides,
amines, ammonia, nitric acid, cyanides, nitrosamines. When mixed with sawdust, wood chips,
or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat
is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it can
ignite the sawdust.
Reactivity : No dangerous reaction known under conditions of normal use.

Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 3/7

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available

Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.

Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or
other combustible absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.

Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage

Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray.
Do not swallow. Handle and open container with care. Do not eat, drink or smoke when using
this product. Use personal protective equipment as required. Use only outdoors or in a well-
ventilated area. When mixed with epoxy resin this product causes an exothermic reaction,
which in large masses, can produce enough heat to damage or ignite surrounding materials
and emit fumes and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.

Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Keep only in the original
container in a cool, well-ventilated place. Protect from moisture. Storage temperature : 40 F
(4 C) – 90 F (32 C).

SECTION 8: Exposure controls/personal protection

Control parameters

Trimethylhexamethylenediamine (25620-58-0)
Not applicable

Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm

Isophorone diamine (2855-13-2)
Not applicable

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
Not applicable

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
ACGIH ACGIH Ceiling (mg/m ) 1 mg/m

Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 4/7

Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties
Physical state : Liquid

Appearance : No data available

Colour : Clear

Odour : Ammonia-like

Odour threshold : No data available

pH : 12.13

Melting point : No data available

Freezing point : No data available

Boiling point : > 400 F (204 C)

Flash point : > 200 F (93 C) Estimated based similar product.

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : Non flammable.

Vapour pressure : No data available

Relative vapour density at 20 C : No data available

Relative density : 0.97

Solubility : No data available

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : 88.6 mm /s @ 22 C (72 F)

Viscosity, dynamic : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

Other information
VOC content : SBE-160 / SBE-265: 3.61 g/L (0.03 lbs/gal); SBE-163 / SBE-265: 8.25 g/L (0.07 lbs/gal); SBE-
166 / SBE-265: 7.82 g/L (0.07 lbs/gal)
Bulk density : 8.14 lb/gal (0.97 kg/L)
SECTION 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, nitrogen oxides, amines, ammonia, nitric
acid, cyanides, nitrosamines.
SECTION 11: Toxicological information

Information on toxicological effects

Trimethylhexamethylenediamine (25620-58-0)
LD50 oral rat 910 mg/kg

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 5/7

Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
LC50 inhalation rat > 4.18 mg/l/4h

Isophorone diamine (2855-13-2)
LD50 oral rat 1030 mg/kg
LD50 dermal rabbit > 2000 mg/kg
LC50 inhalation rat > 5.01 mg/l/4h

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LD50 oral rat 2615 mg/kg

Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Not classified.
Specific target organ toxicity (single
exposure)
: Not classified.
Specific target organ toxicity (repeated
exposure)
: Not classified.
Aspiration hazard : Not classified.

PRO-SET SBE-265 Hardener
Viscosity, kinematic (calculated value) 88.6 mm /s @ 22 C (72 F)

Symptoms/injuries after inhalation : May cause respiratory irritation.
Symptoms/injuries after skin contact : Causes severe burns. Symptoms may include redness, pain, blisters. May cause an allergic
skin reaction.
Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/injuries after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

Toxicity
Ecology – general : Harmful to aquatic life with long lasting effects.

Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Isophorone diamine (2855-13-2)
EC50 Daphnia 1 14.6 – 21.5 mg/l (Exposure time: 48 h – Species: Daphnia magna [semi-static])

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LC50 fish 1 0.97 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Persistence and degradability
PRO-SET SBE-265 Hardener
Persistence and degradability Not established.

Bioaccumulative potential
PRO-SET SBE-265 Hardener
Bioaccumulative potential Not established.

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 6/7

Trimethylhexamethylenediamine (25620-58-0)
Partition coefficient n-octanol/water 0.77 (at 23 C)

Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1

Isophorone diamine (2855-13-2)
Partition coefficient n-octanol/water 0.79 (at 23 C)

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
Partition coefficient n-octanol/water 0.37 (at 25 C)

Mobility in soil
PRO-SET SBE-265 Hardener
Ecology – soil No additional information available.

Other adverse effects

Effect on the global warming : No known effects from this product.

Name CAS# Ecotoxicity Classification Information
Trimethylhexamethylenediamine

25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Benzyl alcohol

100-51-6 Not classified
Isophorone diamine

2855-13-2 Chronic Aquatic Cat. 3
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction
products with 2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine

111850-23-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate

41556-26-7 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1

Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

Waste treatment methods
Product/Packaging disposal
recommendations
: This material must be disposed of in accordance with all local, state, provincial, and federal
regulations. The generation of waste should be avoided or minimized wherever possible.
SECTION 14: Transport information

Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (Isophorone diamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : II
Marine pollutant : No

Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Isophorone diamine)
Class (IMDG) : 8
EmS Number : F-A, S-B
Packing group (IMDG) : II
Marine pollutant : No

Transport by air
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (Isophorone diamine)
Class (IATA) : 8
Packing group (IATA) : II
Marine pollutant : No

PRO-SET SBE-265 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 7/7

SECTION 15: Regulatory information

Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
EPA TSCA Regulatory Flag N – N – indicates a polymeric substance containing no free-radical initiator in its Inventory
name but is considered to cover the designated polymer made with any free-radical initiator
regardless of the amount used.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).

International regulations
No additional information available

US State regulations

California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

Trimethylhexamethylenediamine (25620-58-0)
U.S. – New Jersey – Right to Know Hazardous Substance List

Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List

Isophorone diamine (2855-13-2)
U.S. – New Jersey – Right to Know Hazardous Substance List

SECTION 16: Other information

Date of issue : 11/03/2016
Revision date : 01/25/2019
Other information : None.

NFPA health hazard : 3

NFPA fire hazard : 1
NFPA reactivity : 0

HMIS III Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.

81SBE262-4_SDS.pdf

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 12/05/2016 Revision date: 01/25/2019 Version: SBE-262-2019a

01/25/2019 EN (English) Page 1

SECTION 1: Identification

Identification
Product form : Mixture
Product name : PRO-SET SBE-262 Hardener
Product code : SBE-262, SBE-262-1, SBE-262-2, SBE-262-4, SBE-262-G

Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Curing agent for epoxy resins

Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com

Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr

SECTION 2: Hazard(s) identification

Classification of the substance or mixture
Acute Tox. 4 (Oral)
Skin Corr. 1B
Eye Dam. 1
Skin Sens. 1
Aquatic Acute 3
Aquatic Chronic 3

Label elements
Hazard pictograms (GHS) :

GHS05

GHS07

Signal word (GHS)
:
Danger
Hazard statements (GHS)
:
Harmful if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful to aquatic life with long lasting
effects.
Precautionary statements (GHS)
:
Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective
gloves/protective clothing/eye protection/face protection. If swallowed: rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Store locked up.
Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international
regulation.

Other hazards
No additional information available.

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 2/8

Unknown acute toxicity
No additional information available.
SECTION 3: Composition/information on ingredients

Substances
Not applicable
Mixtures

Name Product identifier HPR %
Trimethylhexamethylenediamine

(CAS-No.) 25620-58-0 10 – 30
Benzyl alcohol

(CAS-No.) 100-51-6 10 – 30
1,3-Cyclohexanedimethanamine

(CAS-No.) 2579-20-6 10 – 30
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-
cyclohexanedimethanamine

(CAS-No.) 60112-98-3 10 – 30
Diethylene glycol bis(3-aminopropyl) ether

(CAS-No.) 4246-51-9 1 – 5
Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with
2,2,4(or 2,4,4)-trimethyl-1,6-hexanediamine

(CAS-No.) 111850-23-8 3 – 7
Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate

(CAS-No.) 41556-26-7 0.1 – 1.5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.

SECTION 4: First aid measures

Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER
or doctor/physician.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.

Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory tract irritation.
Symptoms/effects after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/effects after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.

Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures

Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.

Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. Nitrogen oxides.
Amines. Ammonia. Nitric acid. Aldehydes. Nitrosamines. Phenolics. When mixed with sawdust,
wood chips, or other cellulosic material, spontaneous combustion can occur under certain
conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
Reactivity : No dangerous reactions known under normal conditions of use.

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 3/8

Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available

Environmental precautions
No additional information available

Methods and material for containment and cleaning up
For containment : Stop leak if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite),
then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use
appropriate Personal Protective Equipment (PPE). Do not absorb in sawdust, paper, cloth or
other combustible absorbents.
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.

Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage

Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray.
Do not swallow. Handle and open container with care. Do not eat, drink or smoke when using
this product. Use personal protective equipment as required. When mixed with epoxy resin this
product causes an exothermic reaction, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in
composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.

Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature: 40 F (4 C) – 90 F (32 C).

SECTION 8: Exposure controls/personal protection

Control parameters

Trimethylhexamethylenediamine (25620-58-0)
Not applicable

Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm

1,3-Cyclohexanedimethanamine (2579-20-6)
Not applicable

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
Not applicable

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
ACGIH ACGIH Ceiling (mg/m ) 1 mg/m

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
Not applicable

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 4/8

Diethylene glycol bis(3-aminopropyl) ether (4246-51-9)
Not applicable

Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles)
and face protection (face shield).
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle in accordance with good industrial hygiene and
safety procedures.
SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties
Physical state : Liquid

Appearance : No data available

Colour : Clear

Odour : Ammonia-like

Odour threshold : No data available

pH : 12.28

Melting point : No data available

Freezing point : No data available

Boiling point : > 400 F (204 C)

Flash point : > 200 F (93 C) Estimated based similar product.

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : No data available

Vapour pressure : No data available

Relative vapour density at 20 C : No data available

Relative density : 0.99

Solubility : No data available

Partition coefficient n-octanol/water : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : 108 mm /s @ 68 F (20 C)

Viscosity, dynamic : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

Other information
VOC content : SBE-160 / SBE-262: 10.38 g/L (0.09 lbs/gal)
SBE-163 / SBE-262: 10.38 g/L (0.09 lbs/gal)
SBE-166 / SBE-262: 11.03 g/L (0.09 lbs/gal)
Bulk density : 825 lb/gal (0.99 kg/L)
SECTION 10: Stability and reactivity

Reactivity : No dangerous reactions known under normal conditions of use.
Chemical stability : Stable under normal conditions.

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 5/8

Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an epoxy resin will cause irreversible polymerization with significant heat
buildup and pressure.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Acids. Oxidizing materials. Halogenated compounds.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon. Nitrogen oxides. Amines. Ammonia. Nitric
acid. Aldehydes. Nitrosamines. Phenolics.
SECTION 11: Toxicological information

Information on toxicological effects

Trimethylhexamethylenediamine (25620-58-0)
LD50 oral rat 910 mg/kg

Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
LC50 inhalation rat > 4.18 mg/l/4h

1,3-Cyclohexanedimethanamine (2579-20-6)
LD50 oral rat 700 – 780 mg/kg
LD50 dermal rabbit 1700 mg/kg

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
LD50 oral rat 700 – 780 mg/kg
LD50 dermal rabbit 1700 mg/kg

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LD50 oral rat 2615 mg/kg

Diethylene glycol bis(3-aminopropyl) ether (4246-51-9)
LD50 oral rat 4290 mg/kg

Acute toxicity (oral) : Oral: Harmful if swallowed.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation) : Not classified.
Skin corrosion/irritation : Causes severe skin burns.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified.
Carcinogenicity : Not classified.
Reproductive toxicity : Not classified.
STOT-single exposure : Not classified.
STOT-repeated exposure : Not classified.
Aspiration hazard : Not classified.

PRO-SET SBE-262 Hardener
Viscosity, kinematic (calculated value) (40 C) 108 mm /s @ 68 F (20 C)

Symptoms/effects after inhalation : May cause respiratory tract irritation.
Symptoms/effects after skin contact : Harmful in contact with skin. Causes severe burns. Symptoms may include redness, pain,
blisters. Repeated exposure to this material can result in absorption through skin causing
significant health hazard. May cause an allergic skin reaction.
Symptoms/effects after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva. May cause burns.
Symptoms/effects after ingestion : Harmful if swallowed. May cause burns or irritation of the linings of the mouth, throat, and
gastrointestinal tract. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

Toxicity
Ecology – general : Harmful to aquatic life with long lasting effects.

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 6/8

Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
LC50 fish 1 0.97 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])

Persistence and degradability
PRO-SET SBE-262 Hardener
Persistence and degradability Not established.

Bioaccumulative potential
PRO-SET SBE-262 Hardener
Bioaccumulative potential Not established.

Trimethylhexamethylenediamine (25620-58-0)
Partition coefficient n-octanol/water 0.77 (at 23 C)

Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1

Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate (41556-26-7)
Partition coefficient n-octanol/water 0.37 (at 25 C)

Mobility in soil
PRO-SET SBE-262 Hardener
Ecology – soil No additional information available.

Other adverse effects

Effect on the global warming : No known effects from this product.

Name CAS# Ecotoxicity Classification Information
Trimethylhexane-1,6-diamine 25620-58-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Benzyl alcohol 100-51-6 Not classified
1,3-cyclohexanedimethanamine 2579-20-6 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Phenol, 4,4′-(1-methylethylidene) bis-, polymer with 2-
(chromethyl) oxirane and 1,3-cyclohexanedimethanamine
60112-98-3 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin, bisphenol A, and
trimethylhexane-1,6-diamine
111850-23-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
3,3′-(Oxybis(2,1-ethane-diyloxy))bis-1-propanamine 4246-51-9 No data available
Decanedioic acid, 1, 10-bis(1,2,2,6,6-pentamethyl-4-
piperidinyl) ester
41556-26-7 No data available

Other information : Avoid release to the environment.
SECTION 13: Disposal considerations

Waste treatment methods
Product/Packaging disposal
recommendations
: This material must be disposed of in accordance with all local, state, provincial, and federal
regulations. The generation of waste should be avoided or minimized wherever possible.
SECTION 14: Transport information

Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
UN-No.(DOT/TDG) : UN2735
Proper Shipping Name (DOT/TDG) : Polyamines, liquid, corrosive, n.o.s. (1,3-cyclohexanedimethanamine)
Class (DOT/TDG) : 8
Packing group (DOT/TDG) : III
Marine Pollutant No

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 7/8

Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 2735
Proper Shipping Name (IMDG) : POLYAMINES, LIQUID, CORROSIVE, N.O.S. (1,3-cyclohexanedimethanamine)
Class (IMDG) : 8
EmS Number : F-A, S-B
Packing group (IMDG) : III
Marine Pollutant No

Transport by air
In accordance with IATA
UN-No. (IATA) : 2735
Proper Shipping Name (IATA) : Polyamines, liquid, corrosive, n.o.s. (1,3-cyclohexanedimethanamine)
Class (IATA) : 8
Packing group (IATA) : III
Marine Pollutant No
SECTION 15: Regulatory information

Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.

All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane, reaction products with 2,2,4(or 2,4,4)-trimethyl-1,6-
hexanediamine (111850-23-8)
EPA TSCA Regulatory Flag N – N – indicates a polymeric substance containing no free-radical initiator in its Inventory
name but is considered to cover the designated polymer made with any free-radical initiator
regardless of the amount used.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).

Phenol, 4,4′-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane and 1,3-cyclohexanedimethanamine (60112-98-3)
EPA TSCA Regulatory Flag P – P – indicates a commenced PMN substance.
XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).

International regulations
No additional information available

US State regulations

California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

Trimethylhexamethylenediamine (25620-58-0)
U.S. – New Jersey – Right to Know Hazardous Substance List

Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List

SECTION 16: Other information

Date of issue : 12/05/2016
Revision date : 01/25/2019
Other information : None.

PRO-SET SBE-262 Hardener
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

01/25/2019 EN (English) 8/8

NFPA health hazard : 3

NFPA fire hazard : 1
NFPA reactivity : 0

Hazard Rating
Health : 3 Serious Hazard
Flammability : 1 Slight Hazard
Physical : 0 Minimal Hazard

Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.