by | Sep 27, 2025
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 08/24/2016 Revision date: 01/31/2019 Version: M1034-2019a
01/31/2019 EN (English US) Page 1
SECTION 1: Identification
Identification
Product name : PRO-SET M1034 Resin
Product code : M1034, M1034-1, M1034-2, M1034-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Epoxy resin for composites
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Skin Irrit. 2
Eye Irrit. 2A
Skin Sens. 1
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS07
GHS09
Signal word (GHS)
:
Warning
Hazard statements (GHS)
:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects
Precautionary statements (GHS)
:
Avoid breathing dust, fume, gas, mist, vapors, spray. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of
the workplace. Avoid release to the environment. Wear protective gloves, protective clothing, eye protection, face protection. If on skin: Wash with
plenty of soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash it before reuse. Collect spillage. Dispose of contents/container to hazardous or special waste collection point, in accordance with
local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/Information on ingredients
Substances
Not applicable
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/31/2019 EN (English US) 2/6
Mixtures
Name Product identifier HPR %
Bisphenol A-epichlorohydrin polymer
(CAS No) 25068-38-6 80 – 100
Oxirane, methyl-, polymer with oxirane
(CAS No) 9003-11-6 1 – 5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing
and shoes. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical advice/attention.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. If irritation persists, get medical attention.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, phenolics.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/31/2019 EN (English US) 3/6
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE).
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing dust, fume, gas, mist, vapors, spray. Do not
swallow. Handle and open container with care. When using do not eat, drink or smoke. When
mixed with epoxy curing agents this product causes an exothermic reaction, which in large
masses, can produce enough heat to damage or ignite surrounding materials and emit fumes
and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature : 40 F (4 C) – 120 F (49 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Bisphenol A-epichlorohydrin polymer (25068-38-6)
Not applicable
Oxirane, methyl-, polymer with oxirane (9003-11-6)
Not applicable
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear eye/face protection.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Viscous. Cloudy
Colour : White
Odour : Mild.
Odour threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : > 502 F (261 C)
Flash point : > 486 F (252 C)
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Not flammable
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/31/2019 EN (English US) 4/6
Vapour pressure : < 0.03 hPa (< 0.0 mmHg ) @ 25 C / 77 F
Relative vapour density at 20 C : < 1 (Estimated based on ingredient data)
Relative density : No data available
Solubility : Insoluble.
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Other information
Bulk density : 9.74 lb/gal (1.16 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an aliphatic amine will cause irreversible polymerization with significant heat
buildup. Strong acids, bases, amines and mercaptans can cause polymerization.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Strong acids. Bases. Amines. Mercaptans.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, phenolics.
SECTION 11: Toxicological information
Information on toxicological effects
Bisphenol A-epichlorohydrin polymer (25068-38-6)
LD50 oral rat > 15000 mg/kg
LD50 dermal rabbit > 23000 mg/kg
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity single
exposure
: Not classified
Specific target organ toxicity repeated
exposure
: Not classified
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/31/2019 EN (English US) 5/6
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Persistence and degradability
PRO-SET M1034 Resin
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET M1034 Resin
Bioaccumulative potential Not established.
Mobility in soil
PRO-SET M1034 Resin
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name CAS# Ecotoxicity Classification Information
Bisphenol A-epichlorohydrin polymer
25068-38-6 Aquatic Chronic Cat. 2
Oxirane, methyl-, polymer with oxirane
9003-11-6 Not Classified
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
Not regulated
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3082
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O. S. (Epoxy Resin)
Class (IMDG) : 9
Packing group (IMDG) : III
EmS Number : F-A, S-F
Marine pollutant : Yes
Transport by air
In accordance with IATA
UN-No. (IATA) : 3082
Proper Shipping Name (IATA) : Environmentally hazardous substance, liquid, n.o.s. (Epoxy Resin)
Class (IATA) : 9
Packing group (IATA) : III
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory
PRO-SET M1034 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/31/2019 EN (English US) 6/6
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Bisphenol A-epichlorohydrin polymer (25068-38-6)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Oxirane, methyl-, polymer with oxirane (9003-11-6)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
International regulations
No additional information available
US State regulations
California Proposition 65 – This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm
SECTION 16: Other information
Date of issue : 08/24/2016
Revision date : 01/31/2019
Other information : None.
NFPA health hazard : 2
NFPA fire hazard : 1
NFPA reactivity : 1
HMIS III Rating
Health : 2 Moderate Hazard
Flammability : 1 Slight Hazard
Physical : 1 Slight Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 06/01/2015 Revision date: 01/25/2019 Version: M1033-2019a
01/25/2019 EN (English US) Page 1
SECTION 1: Identification
Identification
Product name : PRO-SET M1033 Resin
Product code : M1033, M1033-1, M1033-2, M1033-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Resin for coatings or adhesives
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Skin Irrit. 2
Eye Irrit. 2A
Skin Sens. 1
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS07
GHS09
Signal word (GHS)
:
Warning
Hazard statements (GHS)
:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects
Precautionary statements (GHS)
:
Avoid breathing dust, fume, gas, mist, vapors, spray. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of
the workplace. Avoid release to the environment. Wear protective gloves, protective clothing, eye protection, face protection. If on skin: Wash with
plenty of soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash it before reuse. Collect spillage. Dispose of contents/container to hazardous or special waste collection point, in accordance with
local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/Information on ingredients
Substances
Not applicable
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 2/7
Mixtures
Name Product identifier HPR %
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer
(CAS No) 25085-99-8 65-85
Phenol, polymer with formaldehyde, glycidyl ether
(CAS No) 28064-14-4 10-30
Silica, amorphous, fumed, crystalline-free
(CAS No) 112945-52-5 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing
and shoes. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical advice/attention.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. If irritation persists, get medical attention.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbo, phenolics.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available
For emergency responders
No additional information available
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 3/7
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE).
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing dust, fume, gas, mist, vapors, spray. Do not
swallow. Handle and open container with care. When using do not eat, drink or smoke. When
mixed with epoxy curing agents this product causes an exothermic reaction, which in large
masses, can produce enough heat to damage or ignite surrounding materials and emit fumes
and vapors that vary widely in composition and toxicity.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature : 40 F (4 C) – 120 F (49 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
Not applicable
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
Not applicable
Silica, amorphous, fumed, crystalline-free (112945-52-5)
ACGIH ACGIH TWA (mg/m ) 10 mg/m (Inhalable)
3 mg/m (Respirable)
OSHA OSHA PEL (TWA) (mg/m ) 6 mg/m Amorphous silica
15 mg/m (Total dus)t
5 mg/m (Respirable fraction)
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear eye/face protection.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Viscous
Colour : Colourless
Odour : Mild.
Odour threshold : No data available
pH : No data available
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 4/7
Melting point : No data available
Freezing point : No data available
Boiling point : > 400 F (204 C)
Flash point : > 200 F (93 C). Estimated based on testing similar product
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : No data available
Relative vapour density at 20 C : Heavier than air. (Estimated based on testing similar product)
Relative density : 1.18
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Other information
Bulk density : 9.9 lb/gal (1.18 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an aliphatic amine will cause irreversible polymerization with significant heat
buildup. Strong acids, bases, amines and mercaptans can cause polymerization.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Strong acids. Bases. Amines. Mercaptans.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, phenolics.
SECTION 11: Toxicological information
Information on toxicological effects
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
LD50 oral rat > 15000 mg/kg
LD50 dermal rabbit > 23000 mg/kg
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
LD50 oral rat > 2000 mg/kg
LD50 dermal rat 2000 mg/kg
Silica, amorphous, fumed, crystalline-free (112945-52-5)
LD50 oral rat > 5000 mg/kg
LD50 dermal rabbit > 2000 mg/kg
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Silica, amorphous, fumed, crystalline-free (112945-52-5)
IARC group 3 – Not classifiable
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 5/7
Reproductive toxicity : Not classified
Specific target organ toxicity single
exposure
: Not classified
Specific target organ toxicity repeated
exposure
: Not classified
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Persistence and degradability
PRO-SET M1033 Resin
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET M1033 Resin
Bioaccumulative potential Not established.
Mobility in soil
PRO-SET M1033 Resin
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name CAS# Ecotoxicity Classification Information
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer
25085-99-8 Aquatic Chronic Cat. 2
Phenol, polymer with formaldehyde, glycidyl ether
28064-14-4 Aquatic Chronic Cat. 2
Silica, amorphous, fumed, crystalline-free
112945-52-5 Not classified
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
Not regulated
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3082
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O. S. (Epoxy Resin)
Class (IMDG) : 9
Packing group (IMDG) : III
EmS Number : F-A, S-F
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 6/7
Marine pollutant : Yes
Transport by air
In accordance with IATA
UN-No. (IATA) : 3082
Proper Shipping Name (IATA) : Environmentally hazardous substance, liquid, n.o.s. (Epoxy Resin)
Class (IATA) : 9
Packing group (IATA) : III
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory .
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Epichlorohydrin (106-89-8)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 100 lb
SARA Section 302 Threshold Planning
Quantity (TPQ)
1000 lb
SARA Section 313 – Emission Reporting 0.1 %
International regulations
No additional information available
US State regulations
California Proposition 65 – This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause
cancer, developmental and/or reproductive harm
Epichlorohydrin (106-89-8)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Male
No significant risk
level (NSRL)
Yes No No Yes 9 g/day
Epichlorohydrin (106-89-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) – Special Hazardous Substances
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 06/01/2015
Revision date : 01/25/2019
Other information : None.
PRO-SET M1033 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 7/7
NFPA health hazard : 2
NFPA fire hazard : 1
NFPA reactivity : 1
HMIS III Rating
Health : 2 Moderate Hazard
Flammability : 1 Slight Hazard
Physical : 1 Slight Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 01JUN15
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT IDENTIFIER: ……………………………… PRO-SET
M1014 Resin
APPLICABLE PRODUCT CODES: ………………. M1014, M1014-1, M1014-2, M1014-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Resin for coatings or adhesives.
PRODUCT USE RESTRICTIONS: ………………… None identified.
SDS VERSION: …………………………………………. M1014-2015a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word
WARNING
Hazard Statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards Not Resulting In Classification
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-100
Benzyl alcohol 100-51-6 10-30
PRO-SET
M1014 Resin
Page 2 of 6 Last Revised: 01JUN15
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 1-10
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as confidential business information (CBI).
Refer to Section 15 for additional information regarding this CBI claim.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ……. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION GUIDELINES: …………………………….. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a
NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
PRO-SET
M1014 Resin
Page 3 of 6 Last Revised: 01JUN15
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C).
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
FLAMMABILITY (solids or gasses) …………………………………………… No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.15
BULK DENSITY………………………………………………………………………. 9.6 lb./gal. (1.15 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. 869.5 mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ………………………………….. Product will not react by itself. A mass of more than one pound of product
mixed with an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can
cause polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Benzyl alcohol
100-51-6
1620 mg/kg
No data
>4.18 mg/l
4 h aerosol
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
PRO-SET
M1014 Resin
Page 4 of 6 Last Revised: 01JUN15
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Diglycidyl ether bisphenol-A in animal mutagenicity studies
were negative. In vitro mutagenicity tests were negative in some cases and positive in others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
PRO-SET
M1014 Resin
Page 5 of 6 Last Revised: 01JUN15
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Immediate.
Subject to Section 313 ................................................................ No data available.
Canada WHMIS Confidential Business Information (CBI): .............. The HMIRA number issued for this CBI claim is #9455. The date of filing is
2015-04-09.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ SDS prepared according to the requirements of the US OSHA 1910.1200
HazCom 2012.
PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ June 1, 2015
SUPERSEDES DATE: ........................................................................ March 3, 2014
SDS VERSION: .................................................................................. M1014-2015a
PRO-SET
M1014 Resin
Page 6 of 6 Last Revised: 01JUN15
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
2
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 23AUG16
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
M1007 Resin
APPLICABLE PRODUCT CODE S: ………………. M1007, M1007-1, M1007-2, M1007-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin for glues and adhesives.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. M1007-2016a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-100
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
PRO-SET
M1007 Resin
Page 2 of 6 Last Revised: 23AUG16
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as confidential business information (CBI).
Refer to Section 15 for additional information regarding this CBI claim.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ……. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION GUIDELINES: …………………………….. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a
NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.
This product contains glass oxide, non-fibrous spheres. No significant exposure is expected to occur during use of products in which these
spheres are present in a liquid dispersion or bound to other materials, such as in epoxies. Risk of overexposure by way of inhalation depends on
actual concentration in the formula and duration and level of exposure to airborne particulate generated from sanding or similar machining
operations.
PRO-SET
M1007 Resin
Page 3 of 6 Last Revised: 23AUG16
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 No data available.
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204
C) Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C) Based on ASTM D92 test results from similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.75 lbs./gal. (1.17 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. < 1 mmHg@ 20
C. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data available
WATER SOLUBILITY (% BY WT.) ..................................................... No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data available
KINEMATIC VISCOSITY: ................................................................... > 10000 mm
2
/s
@ 20
C
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8 >15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4
>2000 mg/kg
2000 mg/kg
No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.
PRO-SET
M1007 Resin
Page 4 of 6 Last Revised: 23AUG16
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for germ cell mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Does not meet acute aquatic toxicity requirements.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification
Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 Aquatic Chronic Cat. 2
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 Aquatic Chronic Cat. 2
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
PRO-SET
M1007 Resin
Page 5 of 6 Last Revised: 23AUG16
ICAO/IATA
UN NUMBER: ..................................................................................... UN 3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
IMDG
UN NUMBER: ..................................................................................... UN 3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC All ingredients are listed or otherwise compliant.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Immediate.
Subject to Section 313 ................................................................ No data available.
Canada WHMIS Confidential Business Information (CBI): .............. The HMIRA number issued for this CBI claim is #10304. The date of filing is
2016-08-09.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Sections 3 and 15 to meet Canada WHMIS 2015 requirements.
PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ August 23, 2016
SUPERSEDES DATE: ........................................................................ June 1, 2015
SDS VERSION: .................................................................................. M1007-2016a
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
PRO-SET
M1007 Resin
Page 6 of 6 Last Revised: 23AUG16
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
2
by | Sep 27, 2025
MATERIAL SAFETY DATA SHEET
Pro-Set Inc.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:…………………………………..PRO-SET
M1012 Resin
PRODUCT CODE:……………………………………M1012
CHEMICAL FAMILY:……………………………….Epoxy Resin.
CHEMICAL NAME:………………………………….Epoxy Resin.
FORMULA:……………………………………………..Not applicable.
MANUFACTURER: EMERG ENCY TELEPHONE NUMBERS:
Pro-Set Inc. Transportation
707 Martin Street CHEMTREC:………………800-424-9300 (U.S.)
Bay City, MI 48706-4143, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-671-4079 Non-transportation
www.prosetepoxy.com Poison Hotline:……………800-222-1222
2. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION
Diglycidyl ether of Bisphenol-A 1675-54-3
Bisphenol-F type epoxy resin 28064-14-4
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS Hazard Rating: Health – 2 Flammability – 1 Physical Hazards – 0
CAUTION! Mild eye and skin irritant. May cause allergic reaction and sensitization. Clear, light-yellow liquid with mild odor.
PRIMARY ROUTE(S) OF ENTRY:………………………………………….Skin contact.
POTENTIAL HEALTH EFFECTS:
ACUTE INHALATION:………………………………………………………….Not likely to cause acute effects unless heated to high temperatures. If
product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high
concentrations.
CHRONIC INHALATION:………………………………………………………Not likely to cause chronic effects. Repeated exposure to high vapor
concentrations may cause irritation of pre-existing lung allergies and increase the chance of developing allergy symptoms to this product.
ACUTE SKIN CONTACT:……………………………………………………..May cause allergic skin response in certain individuals. May cause
moderate irritation to the skin such as redness and itching.
CHRONIC SKIN CONTACT:………………………………………………….May cause sensitization in susceptible individuals. May cause
moderate irritation to the skin.
EYE CONTACT:…………………………………………………………………..May cause irritation.
INGESTION:………………………………………………………………………..Low acute oral toxicity.
SYMPTOMS OF OVEREXPOSURE:………………………………………Possible sensitization and subsequent allergic reactions usually seen
as redness and rashes. Repeated exposure is not likely to cause other adverse health effects.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Pre-existing skin and respiratory disorders may be aggravated by exposure to this product. Pre-existing lung and skin allergies may
increase the chance of developing allergic symptoms to this product.
4. FIRST AID MEASURES:
FIRST AID FOR EYES:…………………………………………………………Flush immediately with water for at least 15 minutes. Consult a
physician.
FIRST AID FOR SKIN:………………………………………………………….Remove contaminated clothing. Wipe excess from skin. Wash with
soap and water. If irritation occurs, get medical attention.
MSDS #M1012-08a Last Revised: 03JAN08
Pro-Set Inc. Page 2 of 4 PRO-SET
M1012 Resin
FIRST AID FOR INHALATION:……………………………………………..Remove to fresh air and rest if effects occur.
FIRST AID FOR INGESTION:………………………………………………..Seek medical attention if appreciable amounts are ingested.
5. FIRE FIGHTING MEASURES:
FLASH POINT:…………………………………………………………………….> 260 F (PMCC)
EXTINGUISHING MEDIA:……………………………………………………..Water fog, carbon dioxide (CO
2
) or dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES:
Wear complete fire fighting gear and self-contained breathing apparatus. Cool fire-exposed containers with water spray. Material is not
readily combustible unless preheated.
FIRE AND EXPLOSION HAZARDS:………………………………………HAZARDOUS DECOMPOSITION PRODUCTS: During a fire, smoke
may contain the original materials in addition to combustion products of varying composition which may be toxic and/or irritating.
Combustion products may include, but are not limited to: phenolics, carbon monoxide, carbon dioxide.
6. ACCIDENTAL RELEASE MEASURES:
SPILL OR LEAK PROCEDURES: Stop leak without additional risk. Dike and absorb with inert material (e.g., sand) and
collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
7. HANDLING AND STORAGE:
STORAGE TEMPERATURE (MIN./MAX):……………………………….40 F (4 C) / 90 F (32 C)
STORAGE:………………………………………………………………………….Store in tightly closed containers to prevent moisture absorption and
loss of volatiles. Store away from heat and open flame.
HANDLING PRECAUTIONS:…………………………………………………Ventilate work area. Avoid skin contact. Wash skin thoroughly after
handling. Wash contaminated clothing before reuse. Precautionary steps should be taken when curing product in large quantities. When
mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to damage or ignite
surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
EYE PROTECTION REQUIREMENTS:…………………………………..Wear safety glasses with side shields or chemical splash goggles
when exposure is more likely.
SKIN PROTECTION GUIDELINES:………………………………………..Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber,
neoprene, butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION REQUIREMENTS:
Good room ventilation is usually adequate for most operations. Use respirators when exposure to vapors from heated material or mist is
likely, unless determined to be below applicable limits. Use a NIOSH/MSHA approved respirator with organic vapor cartridge.
Note: Pro-Set, Inc. has conducted an air sampling study using this product or similarly formulated products. The results indicate that the
components sampled for (epichlorohydrin) were either so low that they were not detected at all or they were well below OSHA s
permissible exposure levels.
ADDITIONAL PROTECTIVE MEASURES:… Wash thoroughly after handling. Avoid breathing vapors from heated material. Protective
skin cream barriers can be applied to hands in addition to gloves for added protection. Generally speaking, working cleanly and following
basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS:………………………………….Not established for product as whole. Refer to OSHA s Permissible
Exposure Level (PEL) or the ACGIH Guidelines for information on specific ingredients.
9. PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL FORM………………………………………………………………..Liquid.
COLOR……………………………………………………………………………….Clear to pale yellow.
ODOR…………………………………………………………………………………Mild.
BOILING POINT…………………………………………………………………..No data.
MELTING POINT/FREEZE POINT………………………………………….No data.
VISCOSITY………………………………………………………………………….3000 – 6000 cPs.
pH………………………………………………………………………………………No data.
SOLUBILITY IN WATER……………………………………………………….Insoluble.
SPECIFIC GRAVITY…………………………………………………………….1.18
MSDS #M1012-08a Last Revised: 03JAN08
Pro-Set Inc. Page 3 of 4 PRO-SET
M1012 Resin
BULK DENSITY…………………………………………………………………..9.85 pounds/gallon.
VAPOR PRESSURE…………………………………………………………….< 1 mmHg @ 20 mmHg.
VAPOR DENSITY...........................................................................Heavier than air.
% VOLATILE BY WEIGHT.............................................................EPA Method 24, as described in 40 CFR Part 60, was used to
determine the Volatile Matter Content of mixed epoxy resin and hardener. This method states that two-component coating systems
should be tested by mixing the individual components together at the proper ratio. Refer to the hardener's MSDS for information about
the total volatile content of the resin/hardener system.
10. REACTIVITY:
STABILITY:....................................................................................Stable.
HAZARDOUS POLYMERIZATION:...............................................Will not occur by itself, but masses of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with considerable heat buildup.
INCOMPATIBILITIES:....................................................................Strong acids and oxidizing agents.
DECOMPOSITION PRODUCTS:...................................................Carbon monoxide and carbon dioxide may be produced when the
product is heated to decomposition.
11. TOXICOLOGICAL INFORMATION:
No specific oral, inhalation or dermal toxicology data is known for this product.
Oral:................................................................No data.
Inhalation:.......................................................No data.
Dermal:...........................................................No data.
TERATOLOGY: No data.
MUTAGENICITY: No data.
CARCINOGENICITY:
NTP.........................................................................................Product not listed.
IARC.......................................................................................Product not listed.
OSHA......................................................................................Product not listed.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak
evidence of carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that
DGEBPA is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer
(IARC) has concluded that DGEBPA is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce
mutagenic changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer
(IARC) as a probable human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal
evidence sufficient. It has been classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is
unlikely that normal use of this product would result in measurable exposure concentrations to this substance.
12. ECOLOGICAL INFORMATION:
No data.
13. DISPOSAL CONSIDERATIONS:
WASTE DISPOSAL METHOD:......................................................Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local
regulations.
14. TRANSPORTATION INFORMATION:
DOT SHIPPING NAME:.................................................................Not regulated by DOT.
TECHNICAL SHIPPING NAME:....................................................Not applicable.
DOT HAZARD CLASS:..................................................................Not applicable.
U.N./N.A. NUMBER:.......................................................................Not applicable.
PACKING GROUP:........................................................................Not applicable.
15. REGULATORY INFORMATION:
MSDS #M1012-08a Last Revised: 03JAN08
Pro-Set Inc. Page 4 of 4 PRO-SET
M1012 Resin
OSHA STATUS:.............................................................................Irritant; possible sensitizer.
TSCA STATUS:..............................................................................All components are listed on TSCA Inventory or otherwise comply with
TSCA requirements.
SARA TITLE III:
SECTION 313 TOXIC CHEMICALS.......................................None (deminimus).
STATE REGULATORY INFORMATION:
The following chemicals are specifically listed or otherwise regulated by individual states. For details on your regulatory requirements
you should contact the appropriate agency in your state.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA, MA, PA, RI
1.
These substances are known to the State of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION:
REASON FOR ISSUE:...................................................................Changes in Sections 3, 5, 8, 11 & 15.
PREPARED BY:.............................................................................T. J. Atkinson
APPROVED BY:.............................................................................G. M. House
TITLE:.............................................................................................Health, Safety & Environmental Manager
APPROVAL DATE:........................................................................January 3, 2008
SUPERSEDES DATE:...................................................................January 3, 2005
MSDS NUMBER :............................................................................M1012-08a.
Note: The Hazardous Material Indexing System (HMIS), cited in the Emergency Overview of Section 3, uses the following index to assess
hazard rating: 0 = Minimal; 1 = Slight: 2 = Moderate; 3 = Serious; and 4 = Severe.
This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Pro-Set Inc. The data
on this sheet is related only to the specific material designated herein. Pro-Set Inc. assumes no legal responsibility for use or reliance upon
these data.
MSDS #M1012-08a Last Revised: 03JAN08
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 23AUG16
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT IDENTIFIER: ……………………………… PRO-SET
M1002 Resin
APPLICABLE PRODUCT CODES: ………………. M1002, M1002-0, M1002-00, M1002-1, M1002-2, M1002-3, M1002-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Resin for coatings or adhesives.
PRODUCT USE RESTRICTIONS: ………………… None identified.
SDS VERSION: …………………………………………. M1002-2016b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word
WARNING
Hazard Statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards Not Resulting In Classification
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 70-100
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 10-20
PRO-SET
M1002 Resin
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Benzyl alcohol 100-51-6 1-10
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with
bisphenol A and epichlorohydrin
68610-41-3 1-10
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as confidential business information (CBI).
Refer to Section 15 for additional information regarding this CBI claim.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ……. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION GUIDELINES: …………………………….. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a
NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.
PRO-SET
M1002 Resin
Page 3 of 6 Last Revised: 23AUG16
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and epichlorohydrin
68610-41-3
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C).
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
FLAMMABILITY (solids or gasses) …………………………………………… No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.73 lb./gal. (1.17 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s
@ 20
C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ………………………………….. Product will not react by itself. A mass of more than one pound of product
mixed with an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can
cause polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
Benzyl alcohol
100-51-6
1620 mg/kg
No data
>4.18 mg/l
4 h aerosol
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and
epichlorohydrin
68610-41-3
No data
No data
No data
PRO-SET
M1002 Resin
Page 4 of 6 Last Revised: 23AUG16
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAG E / IRRITATION:…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Diglycidyl ether bisphenol-A in animal mutagenicity studies
were negative. In vitro mutagenicity tests were negative in some cases and positive in others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and
epichlorohydrin
68610-41-3
Aquatic Chronic Cat. 2
13. DISPOSAL CONSIDERATIONS
PRO-SET
M1002 Resin
Page 5 of 6 Last Revised: 23AUG16
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Immediate.
Subject to Section 313 ................................................................ No data available.
Canada WHMIS Confidential Business Information (CBI): .............. The HMIRA number issued for this CBI claim is #10303. The date of filing is
2016-08-09.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
PRO-SET
M1002 Resin
Page 6 of 6 Last Revised: 23AUG16
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Sections 3 and 15 to meet Canada WHMIS 2015 requirements.
PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ August 23, 2016
SUPERSEDES DATE: ........................................................................ May 2, 2016
SDS VERSION: .................................................................................. M1002-2016b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products
Regulations (HPR) WHMIS 2015
Date of issue: 05/02/2016 Revision date: 01/25/2019 Version: M1002-2019a
01/25/2019 EN (English US) Page 1
SECTION 1: Identification
Identification
Product name : PRO-SET M1002 Resin
Product code : M1002, M1002-0, M1002-00, M1002-1, M1002-2, M1002-3, M1002-4
Relevant identified uses of the substance or mixture and uses advised against
Recommended use : Resin for coatings or adhesives
Details of the supplier of the safety data sheet
Manufacturer
Gougeon Brothers, Inc
100 Patterson Ave.
Bay City, MI 48706 – U.S.A.
T 866-937-8797 or 989-684-7286
www.westsystem.com
Emergency telephone number
Emergency number : CHEMTREC 1 (800) 424-9300
CHEMTREC International +1 (703) 527-3887 24 hr
SECTION 2: Hazard(s) identification
Classification of the substance or mixture
Skin Irrit. 2
Eye Irrit. 2A
Skin Sens. 1
Aquatic Chronic 2
Label elements
Hazard pictograms (GHS) :
GHS07
GHS09
Signal word (GHS)
:
Warning
Hazard statements (GHS)
:
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects
Precautionary statements (GHS)
:
Avoid breathing dust, fume, gas, mist, vapors, spray. Wash hands thoroughly after handling. Contaminated work clothing must not be allowed out of
the workplace. Avoid release to the environment. Wear protective gloves, protective clothing, eye protection, face protection. If on skin: Wash with
plenty of soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated
clothing and wash it before reuse. Collect spillage. Dispose of contents/container to hazardous or special waste collection point, in accordance with
local, regional, national and/or international regulation
Other hazards
No additional information available
Unknown acute toxicity
No additional information available
SECTION 3: Composition/Information on ingredients
Substances
Not applicable
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 2/7
Mixtures
Name Product identifier HPR %
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer
(CAS No) 25085-99-8 65 – 85
Phenol, polymer with formaldehyde, glycidyl ether
(CAS No) 28064-14-4 10 – 30
Benzyl alcohol
(CAS No) 100-51-6 5 – 10
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with bisphenol A and epichlorohydrin
(CAS No) 68610-41-3 3 – 7
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information (CBI). Any
ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may be present at a level
below its disclosure threshold.
SECTION 4: First aid measures
Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing
and shoes. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get
medical advice/attention.
First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. If irritation persists, get medical attention.
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media : Do not use a heavy water stream.
Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, phenolics.
Reactivity : No dangerous reaction known under conditions of normal use.
Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For non-emergency personnel
No additional information available.
For emergency responders
No additional information available.
Environmental precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information.
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 3/7
Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE).
Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation.
Reference to other sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing dust, fume, gas, mist, vapors, spray. Do not
swallow. Handle and open container with care. When using do not eat, drink or smoke. When
mixed with epoxy curing agents this product causes an exothermic reaction, which in large
masses, can produce enough heat to damage or ignite surrounding materials and emit fumes
and vapors that vary widely in composition and toxicity.
Hygiene measures : Wash hands before eating, drinking, or smoking. Launder contaminated clothing before reuse.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store in dry, cool, well-
ventilated area. Protect from moisture. Storage temperature : 40 F (4 C) – 120 F (49 C).
SECTION 8: Exposure controls/personal protection
Control parameters
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
Not applicable
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
Not applicable
Benzyl alcohol (100-51-6)
AIHA WEEL TWA (ppm) 10 ppm
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with bisphenol A and epichlorohydrin (68610-41-3)
Not applicable
Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection : Wear chemically resistant protective gloves.
Eye protection : Wear eye/face protection.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Environmental exposure controls : Maintain levels below Community environmental protection thresholds.
Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands
carefully before eating or smoking. Handle according to established industrial hygiene and
safety practices.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Viscous
Colour : Colourless
Odour : Mild.
Odour threshold : No data available
pH : No data available
Melting point : No data available
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 4/7
Freezing point : No data available
Boiling point : > 400 F (204 C)
Flash point : > 200 F (93 C). Estimated based on ingredient data
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : No data available
Relative vapuor density at 20 C : Heavier than air. (Estimated based on ingredient data)
Relative density : 1.17
Solubility : No data available
Partition coefficient n-octanol/water : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Other information
Bulk density : 9.73 lb/gal (1.17 kg/L)
SECTION 10: Stability and reactivity
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal storage conditions.
Possibility of hazardous reactions : No dangerous reaction known under conditions of normal use. A mass of more than one pound
of product plus an aliphatic amine will cause irreversible polymerization with significant heat
buildup. Strong acids, bases, amines and mercaptans can cause polymerization.
Conditions to avoid : Heat. Incompatible materials.
Incompatible materials : Strong acids. Bases. Amines. Mercaptans.
Hazardous decomposition products : May include, and are not limited to: oxides of carbon, phenolics.
SECTION 11: Toxicological information
Information on toxicological effects
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
LD50 oral rat > 15000 mg/kg
LD50 dermal rabbit > 23000 mg/kg
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
LD50 oral rat > 2000 mg/kg
LD50 dermal rat 2000 mg/kg
Benzyl alcohol (100-51-6)
LD50 oral rat 1620 mg/kg
LC50 inhalation rat > 4.18 mg/l/4h
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity single
exposure
: Not classified
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 5/7
Specific target organ toxicity repeated
exposure
: Not classified
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : May cause respiratory tract irritation.
Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking
of the skin. May cause an allergic skin reaction.
Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and
tear production, with marked redness and swelling of the conjunctiva.
Symptoms/injuries after ingestion : May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Other information : Likely routes of exposure: ingestion, inhalation, skin and eye.
SECTION 12: Ecological information
Toxicity
Ecology – general : Toxic to aquatic life with long lasting effects.
Benzyl alcohol (100-51-6)
LC50 fish 1 460 mg/l (Exposure time: 96 h – Species: Pimephales promelas [static])
EC50 Daphnia 1 23 mg/l (Exposure time: 48 h – Species: water flea)
LC50 fish 2 10 mg/l (Exposure time: 96 h – Species: Lepomis macrochirus [static])
Persistence and degradability
PRO-SET M1002 Resin
Persistence and degradability Not established.
Bioaccumulative potential
PRO-SET M1002 Resin
Bioaccumulative potential Not established.
Benzyl alcohol (100-51-6)
Partition coefficient n-octanol/water 1.1
Mobility in soil
PRO-SET M1002 Resin
Ecology – soil No additional information available.
Other adverse effects
Effect on the global warming : No known effects from this product.
Name CAS# Ecotoxicity Classification Information
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer
25085-99-8 Aquatic Chronic Cat. 2
Phenol, polymer with formaldehyde, glycidyl ether
28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol
100-51-6 Not classified
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with bisphenol A
and epichlorohydrin
68610-41-3 Aquatic Chronic Cat. 2
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
Waste treatment methods
Product/Packaging disposal
recommendations
: Avoid release to the environment. This material must be disposed of in accordance with all
local, state, provincial, and federal regulations. The generation of waste should be avoided or
minimized wherever possible.
SECTION 14: Transport information
Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG)
In accordance with DOT/TDG
Not regulated
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 6/7
Transport by sea
In accordance with IMDG
UN-No. (IMDG) : 3082
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O. S. (Epoxy Resin)
Class (IMDG) : 9
Packing group (IMDG) : III
EmS Number : F-A, S-F
Marine pollutant : Yes
Transport by air
In accordance with IATA
UN-No. (IATA) : 3082
Proper Shipping Name (IATA) : Environmentally hazardous substance, liquid, n.o.s. (Epoxy Resin)
Class (IATA) : 9
Packing group (IATA) : III
Marine pollutant : Yes
SECTION 15: Regulatory information
Federal regulations
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory
All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic
Substances List) inventories.
Oxirane, 2,2′-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, homopolymer (25085-99-8)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Phenol, polymer with formaldehyde, glycidyl ether (28064-14-4)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with bisphenol A and epichlorohydrin (68610-41-3)
EPA TSCA Regulatory Flag XU – XU – indicates a substance exempt from reporting under the Inventory Update Reporting
Rule, i.e, Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40
CFR 710(C)).
Epichlorohydrin (106-89-8)
Listed on the United States SARA Section 302
Subject to reporting requirements of United States SARA Section 313
CERCLA RQ 100 lb
SARA Section 302 Threshold Planning Quantity (TPQ) 1000 lb
SARA Section 313 – Emission Reporting 0.1 %
International regulations
No additional information available
US State regulations
California Proposition 65 – This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause
cancer, developmental and/or reproductive harm
Epichlorohydrin (106-89-8)
U.S. – California –
Proposition 65 –
Carcinogens List
U.S. – California –
Proposition 65 –
Developmental Toxicity
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Female
U.S. – California –
Proposition 65 –
Reproductive Toxicity –
Male
No significant risk
level (NSRL)
Yes No No Yes 9 g/day
Benzyl alcohol (100-51-6)
U.S. – Pennsylvania – RTK (Right to Know) List
PRO-SET M1002 Resin
Safety Data Sheet
According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015
01/25/2019 EN (English US) 7/7
Epichlorohydrin (106-89-8)
U.S. – New Jersey – Right to Know Hazardous Substance List
U.S. – Pennsylvania – RTK (Right to Know) – Environmental Hazard List
U.S. – Pennsylvania – RTK (Right to Know) – Special Hazardous Substances
U.S. – Pennsylvania – RTK (Right to Know) List
SECTION 16: Other information
Date of issue : 05/02/2016
Revision date : 01/25/2019
Other information : None.
NFPA health hazard : 2
NFPA fire hazard : 1
NFPA reactivity : 1
HMIS III Rating
Health : 2 Moderate Hazard
Flammability : 1 Slight Hazard
Physical : 1 Slight Hazard
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained
in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the
suitability and completeness of this information for the user s own particular use.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 23AUG16
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT IDENTIFIER: ……………………………… PRO-SET
M1002 Resin
APPLICABLE PRODUCT CODES: ………………. M1002, M1002-0, M1002-00, M1002-1, M1002-2, M1002-3, M1002-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Resin for coatings or adhesives.
PRODUCT USE RESTRICTIONS: ………………… None identified.
SDS VERSION: …………………………………………. M1002-2016b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word
WARNING
Hazard Statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards Not Resulting In Classification
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 70-100
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 10-20
PRO-SET
M1002 Resin
Page 2 of 6 Last Revised: 23AUG16
Benzyl alcohol 100-51-6 1-10
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-terminated, polymers with
bisphenol A and epichlorohydrin
68610-41-3 1-10
The exact chemical identity and/or exact percentage (concentration) of each ingredient has been held as confidential business information (CBI).
Refer to Section 15 for additional information regarding this CBI claim.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS AND PROTECTIVE EQUIPMENT: ……. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid all skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY/VENTILATION GUIDELINES: …………………………….. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits. When ventilation cannot be made adequate enough to keep exposures below established limits, use a
NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.
PRO-SET
M1002 Resin
Page 3 of 6 Last Revised: 23AUG16
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and epichlorohydrin
68610-41-3
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Viscous liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C).
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
FLAMMABILITY (solids or gasses) …………………………………………… No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.73 lb./gal. (1.17 kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s
@ 20
C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ………………………………….. Product will not react by itself. A mass of more than one pound of product
mixed with an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can
cause polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
Benzyl alcohol
100-51-6
1620 mg/kg
No data
>4.18 mg/l
4 h aerosol
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and
epichlorohydrin
68610-41-3
No data
No data
No data
PRO-SET
M1002 Resin
Page 4 of 6 Last Revised: 23AUG16
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria. If product is
heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation Category 2.
SERIOUS EYE DAMAG E / IRRITATION:…………………………………….. Causes serious eye irritation. Category 2A.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.
Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase the chance of
developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. May cause allergic skin reaction. Category 1.
REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Diglycidyl ether bisphenol-A, in animal studies, has been
shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth defects or other adverse effects on the fetus when
pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Diglycidyl ether bisphenol-A in animal mutagenicity studies
were negative. In vitro mutagenicity tests were negative in some cases and positive in others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. No ingredient of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY: ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
2-Propenenitrile, polymer with 1,3-butadiene, carboxy-
terminated, polymers with bisphenol A and
epichlorohydrin
68610-41-3
Aquatic Chronic Cat. 2
13. DISPOSAL CONSIDERATIONS
PRO-SET
M1002 Resin
Page 5 of 6 Last Revised: 23AUG16
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
U.N./N.A. NUMBER:............................................................................ Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
U.N. NUMBER: ................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Immediate.
Subject to Section 313 ................................................................ No data available.
Canada WHMIS Confidential Business Information (CBI): .............. The HMIRA number issued for this CBI claim is #10303. The date of filing is
2016-08-09.
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
PRO-SET
M1002 Resin
Page 6 of 6 Last Revised: 23AUG16
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Sections 3 and 15 to meet Canada WHMIS 2015 requirements.
PREPARED BY: ................................................................................. G. M. House
APPROVED BY: ................................................................................. G. M. House
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ August 23, 2016
SUPERSEDES DATE: ........................................................................ May 2, 2016
SDS VERSION: .................................................................................. M1002-2016b
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 03JAN22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
LAM-251-HT Hardener
APPLICABLE PRODUCT CODES: ………………. LAM-251-HT, LAM-251-HT-2, LAM-251-HT-4
CHEMICAL FAMILY: ………………………………….. Polyamine-imidazole mixture.
INTENDED PRODUCT USES: ……………………… High-temperature curing agent for laminating epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. LAM-251-HT-2022a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity, Oral, Category 4
Acute toxicity, Dermal, Category 3
Acute toxicity, Inhalation, Category 2
Skin corrosion/irritation, Category 1A
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Carcinogenicity, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H311 Toxic in contact with skin
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H351 Suspected of causing cancer
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
PRO-SET
LAM-251-HT Hardener
Page 2 of 6 Last Revised: 03JAN22
P308 + P313 IF exposed or concerned: Get medical attention/advice
P310 Immediately call POISON CONTROL CENTER or doctor.
P313 + P333 If irritation or rash occurs: Get medical attention/advice
P362 + P364 Take of contaminated clothing and wash it before reuse
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HA ZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 80-100
Isophoronediamine 2855-13-2 10-30
2-ethyl-4-methylimidazole 931-36-2 1-10
4-Methylimidazole 822-36-6 0.1-1
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Toxic in contact with skin. Causes severe skin burns, redness
and irritation. May cause allergic skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a
POISON CONTROL CENTER or doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Fatal if inhaled. Can cause respiratory irritation, shortness of
breath or cough. Effects can be immediate or delayed. In the case of inhalation of thermal decomposition products, the exposed person may need
to be kept under medical surveillance for 48 hours. RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing.
Immediately call a POISON CONTROL CENTER or doctor.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. If vomiting occurs, the head should be kept low to prevent vomitus from entering lungs. RESPONSE:
Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway clear. Immediately call POISON CONTROL CENTER or
doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS : ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia. When mixed with sawdust, wood chips, or other cellulosic material,
spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary, untrained, and unprotected personnel from entering
area. Use appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand, limestone powder) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to
absorb the spill, as the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
PRO-SET
LAM-251-HT Hardener
Page 3 of 6 Last Revised: 03JAN22
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Store in
a well-ventilated area, away from incompatible materials listed in Section 10. Keep container tightly closed. Store in a secure location with
restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation or respiratory protection. Use PPE as
described in Section 8. Do not breathe vapors, aerosols or mists from material. Prevent all skin and eye contact. Wash thoroughly after handling.
When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite
surrounding materials and emit fumes and vapors that vary widely in composition and toxicity. Do not breathe vapors or fumes from uncontrolled
exotherming masses.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, butyl
rubber or ethyl vinyl alcohol laminate EVAL) and full body protective clothing. Consider the parameters specified by the glove manufacturer and
check during use to ensure that gloves are still retaining their protective properties.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 No data available
Isophoronediamine 2855-13-2 No data available
2-ethyl-4-methylimidazole 931-36-2 No data available
4-Methylimidazole 822-36-6 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Amber
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.0 11.6 (estimated based on ingredient data).
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 300 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.94
BULK DENSITY.................................................................................. 7.83 lbs./gal. (0.94 kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... 42.5 (mm
2
/s @ 22
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
PRO-SET
LAM-251-HT Hardener
Page 4 of 6 Last Revised: 03JAN22
Resin/Hardener (g/L) (lb/gal)
LAM-151-HT / LAM-251-HT ........................................................ 0.01 0.00
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY / HAZARDOUS REACTIONS: ....................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Strong exothermic reaction with acids. Avoid organic and mineral acids,
oxidizing materials, halogenated organic compounds (e.g., methylene chloride), nitrosating agents, sodium hyprochlorite, acid chlorides and acid
anhydrides. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in
a drum, the drum could expand and rupture violently. Can have corrosive effects on some metals.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
2,2'-Dimethyl-4,4'-methylenebis(cyclohexylamine) 6864-37-5 320-460 mg/kg >200 mg/kg 0.42 mg/L; 4h
(aerosol/mist)
Isophoronediamine 2855-13-2 1030 mg/kg >2000 >5.01 mg/l 4h mist
2-ethyl-4-methylimidazole 931-36-2 731-1000 mg/kg >400 mg/kg No data
4-Methylimidazole 822-36-6 350-751 mg/kg 440 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed . May cause gastrointestinal
irritation or ulceration. May cause burns of the mouth and throat.
Dermal: …………………………………………………………………… Category 3. Toxic in contact with skin.
Inhalation:………………………………………………………………… Category 2. Fatal if inhaled. Product may give off
vapor/fume/aerosol/mist that is very irritating or corrosive to the respiratory system. Exposure to decomposition products can cause
serious health hazard. Serious effects may be delayed following exposure.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1A. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis, redness and blistering.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data does not meet
classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction..
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data does not meet classification criteria.
MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data does not meet classification criteria.
CARCINOGENICITY: ……………………………………………………………….. Category 2. Suspected of causing cancer.
A component in this product, 4-Methyleimidazole, present at less than 1.0%, is suspected of causing cancer and is listed by IARC as a Group 2B
carcinogen. Under the conditions of 2-year NTP feed studies, there was no evidence of carcinogenic activity of 4-Methylimidazole in male rats
exposed to 625, 1,250 and 2,500 ppm. There was equivocal evidence of carcinogenic activity of 4-Methylimidazole in female rats based on
increased incidences of mononuclear cell leukemia. There was clear evidence of carcinogenic activity of 4-Methylimidazole in male and female
mice based on increased incidences of alveolar/bronchiolar neoplasms.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data does not meet classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Not classified. Based on available data does not meet classification criteria.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data does not meet classification criteria.
OTHER HEALTH HAZARD INFORMATON : ………………………………… This product is corrosive to skin and mucous membrane tissues. As a result
of this identified hazard, it is anticipated that excessive inhalation of vapors/fumes/mist/aerosol/dust may also corrosive to the respiratory tract.
12. ECOLOGICAL INFORMATION
PRO-SET
LAM-251-HT Hardener
Page 5 of 6 Last Revised: 03JAN22
ACUTE AQUATIC TOXICITY :……………………………………………………. No specific test data available for the mixture. Calculated
Estimate: Aquatic Acute Category 2. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the uncured state this product may be harmful to aquatic life
with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-ethyl-4-methylimidazole 931-36-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
4-Methylimidazole 822-36-6 Not classified
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFOR MATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 822-36-6 is on NDSL only. All other ingredients are DSL listed.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
PRO-SET
LAM-251-HT Hardener
Page 6 of 6 Last Revised: 03JAN22
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in section 2.
Subject to Section 313 ………………………………………………………. No data available.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
4-Methylimidazole
822-36-6
1
CA, PA, NJ
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:……………………………………………………………… Approval date change.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
SDS CONTACT: ……………………………………………………………………… safety@gougeon.com
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. January 3, 2022
SUPERSEDES DATE: ……………………………………………………………… January 15, 2019
SDS VERSION: ………………………………………………………………………. LAM-251-HT-2022a.
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 03JAN22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
LAM-251-HT Hardener
APPLICABLE PRODUCT CODES: ………………. LAM-251-HT, LAM-251-HT-2, LAM-251-HT-4
CHEMICAL FAMILY: ………………………………….. Polyamine-imidazole mixture.
INTENDED PRODUCT USES: ……………………… High-temperature curing agent for laminating epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. LAM-251-HT-2022a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity, Oral, Category 4
Acute toxicity, Dermal, Category 3
Acute toxicity, Inhalation, Category 2
Skin corrosion/irritation, Category 1A
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Carcinogenicity, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H311 Toxic in contact with skin
H330 Fatal if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H351 Suspected of causing cancer
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
PRO-SET
LAM-251-HT Hardener
Page 2 of 6 Last Revised: 03JAN22
P308 + P313 IF exposed or concerned: Get medical attention/advice
P310 Immediately call POISON CONTROL CENTER or doctor.
P313 + P333 If irritation or rash occurs: Get medical attention/advice
P362 + P364 Take of contaminated clothing and wash it before reuse
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HA ZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 80-100
Isophoronediamine 2855-13-2 10-30
2-ethyl-4-methylimidazole 931-36-2 1-10
4-Methylimidazole 822-36-6 0.1-1
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Toxic in contact with skin. Causes severe skin burns, redness
and irritation. May cause allergic skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a
POISON CONTROL CENTER or doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Fatal if inhaled. Can cause respiratory irritation, shortness of
breath or cough. Effects can be immediate or delayed. In the case of inhalation of thermal decomposition products, the exposed person may need
to be kept under medical surveillance for 48 hours. RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing.
Immediately call a POISON CONTROL CENTER or doctor.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. If vomiting occurs, the head should be kept low to prevent vomitus from entering lungs. RESPONSE:
Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway clear. Immediately call POISON CONTROL CENTER or
doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS : ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia. When mixed with sawdust, wood chips, or other cellulosic material,
spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly
enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary, untrained, and unprotected personnel from entering
area. Use appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand, limestone powder) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to
absorb the spill, as the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
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ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Store in
a well-ventilated area, away from incompatible materials listed in Section 10. Keep container tightly closed. Store in a secure location with
restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation or respiratory protection. Use PPE as
described in Section 8. Do not breathe vapors, aerosols or mists from material. Prevent all skin and eye contact. Wash thoroughly after handling.
When mixed with epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite
surrounding materials and emit fumes and vapors that vary widely in composition and toxicity. Do not breathe vapors or fumes from uncontrolled
exotherming masses.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, butyl
rubber or ethyl vinyl alcohol laminate EVAL) and full body protective clothing. Consider the parameters specified by the glove manufacturer and
check during use to ensure that gloves are still retaining their protective properties.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 No data available
Isophoronediamine 2855-13-2 No data available
2-ethyl-4-methylimidazole 931-36-2 No data available
4-Methylimidazole 822-36-6 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Amber
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.0 11.6 (estimated based on ingredient data).
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 300 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.94
BULK DENSITY.................................................................................. 7.83 lbs./gal. (0.94 kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... 42.5 (mm
2
/s @ 22
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
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Resin/Hardener (g/L) (lb/gal)
LAM-151-HT / LAM-251-HT ........................................................ 0.01 0.00
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY / HAZARDOUS REACTIONS: ....................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Strong exothermic reaction with acids. Avoid organic and mineral acids,
oxidizing materials, halogenated organic compounds (e.g., methylene chloride), nitrosating agents, sodium hyprochlorite, acid chlorides and acid
anhydrides. External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in
a drum, the drum could expand and rupture violently. Can have corrosive effects on some metals.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
2,2'-Dimethyl-4,4'-methylenebis(cyclohexylamine) 6864-37-5 320-460 mg/kg >200 mg/kg 0.42 mg/L; 4h
(aerosol/mist)
Isophoronediamine 2855-13-2 1030 mg/kg >2000 >5.01 mg/l 4h mist
2-ethyl-4-methylimidazole 931-36-2 731-1000 mg/kg >400 mg/kg No data
4-Methylimidazole 822-36-6 350-751 mg/kg 440 mg/kg No data
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed . May cause gastrointestinal
irritation or ulceration. May cause burns of the mouth and throat.
Dermal: …………………………………………………………………… Category 3. Toxic in contact with skin.
Inhalation:………………………………………………………………… Category 2. Fatal if inhaled. Product may give off
vapor/fume/aerosol/mist that is very irritating or corrosive to the respiratory system. Exposure to decomposition products can cause
serious health hazard. Serious effects may be delayed following exposure.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1A. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis, redness and blistering.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data does not meet
classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction..
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data does not meet classification criteria.
MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data does not meet classification criteria.
CARCINOGENICITY: ……………………………………………………………….. Category 2. Suspected of causing cancer.
A component in this product, 4-Methyleimidazole, present at less than 1.0%, is suspected of causing cancer and is listed by IARC as a Group 2B
carcinogen. Under the conditions of 2-year NTP feed studies, there was no evidence of carcinogenic activity of 4-Methylimidazole in male rats
exposed to 625, 1,250 and 2,500 ppm. There was equivocal evidence of carcinogenic activity of 4-Methylimidazole in female rats based on
increased incidences of mononuclear cell leukemia. There was clear evidence of carcinogenic activity of 4-Methylimidazole in male and female
mice based on increased incidences of alveolar/bronchiolar neoplasms.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data does not meet classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Not classified. Based on available data does not meet classification criteria.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data does not meet classification criteria.
OTHER HEALTH HAZARD INFORMATON : ………………………………… This product is corrosive to skin and mucous membrane tissues. As a result
of this identified hazard, it is anticipated that excessive inhalation of vapors/fumes/mist/aerosol/dust may also corrosive to the respiratory tract.
12. ECOLOGICAL INFORMATION
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ACUTE AQUATIC TOXICITY :……………………………………………………. No specific test data available for the mixture. Calculated
Estimate: Aquatic Acute Category 2. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the uncured state this product may be harmful to aquatic life
with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine) 6864-37-5 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-ethyl-4-methylimidazole 931-36-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
4-Methylimidazole 822-36-6 Not classified
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 2922
SHIPPING NAME: ……………………………………………………………………. Corrosive, liquids, toxic, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. 2,2′-Dimethyl-4,4′-methylenebis(cyclohexylamine)
HAZARD CLASS: …………………………………………………………………….. Class 8 (6.1)
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFOR MATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 822-36-6 is on NDSL only. All other ingredients are DSL listed.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
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US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in section 2.
Subject to Section 313 ………………………………………………………. No data available.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
4-Methylimidazole
822-36-6
1
CA, PA, NJ
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:……………………………………………………………… Approval date change.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
SDS CONTACT: ……………………………………………………………………… safety@gougeon.com
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. January 3, 2022
SUPERSEDES DATE: ……………………………………………………………… January 15, 2019
SDS VERSION: ………………………………………………………………………. LAM-251-HT-2022a.
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
