Safety Data Sheets | Revchem Composites

81EH-CCS-2_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
Last Revised: 30JAN20

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… CCS Hardener
APPLICABLE PRODUCT CODES: ………………. CCS, CCS-1, CCS-2, CCS-3, CCS-4, CCS-5, CCS-6, CCS-7, CCS-8, CCS-D, CCS-T.
CHEMICAL FAMILY: ………………………………….. Polyetheramine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. CCS-2020a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 310-882-2120 or 989-684-7286 Non-transportation
www.entropyresins.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Acute toxicity, Oral, Category 4
Skin corrosion/irritation, Category 1C
Eye damage/irritation, Category 1
Acute aquatic toxicity, Category 3
Chronic aquatic toxicity, Category 3

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P260 Do not breathe dust/fumes/mist/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call POISON CONTROL CENTER or doctor.
P363 Wash contaminated clothing before reuse.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

CCS Hardener
Page 2 of 6 Last Revised: 30JAN20
INGREDIENT NAME CAS # CONCENTRATION (%)
Polyoxypropylenediamine 9046-10-0 80-100
Polypropyleneglycol 25322-69-4 1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as a trade secret. Any ingredient not
disclosed may have been determined not to pose a health or environmental hazard, or may only be present in concentrations that do not require
disclosure. Refer to Section 15 for additional information regarding any CBI claim.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. RESPONSE:
Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or doctor.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: May be corrosive or irritating to the respiratory system.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately consult a physician if symptoms develop and
persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines. When mixed with sawdust, wood chips, or other cellulosic material, spontaneous
combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not dissipated quickly enough, it
can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand, diatomaceous earth) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials
to absorb the spill, as the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).

STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store away from incompatible materials listed in Section 10. Store in a secure location with restricted access or store
locked up.

HANDLING PRECAUTIONS: ……………………………………………………. Use with adequate ventilation. Do not breathe vapors or mists from heated
material. Avoid exposure to concentrated vapors. Avoid all skin and eye contact. Wash hands thoroughly after handling. When mixed with
epoxy resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding
materials and emit fumes and vapors that vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.

CCS Hardener
Page 3 of 6 Last Revised: 30JAN20
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber). Body protective clothing should be used as needed based on the task being performed and the potential for
exposure.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEAS URES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Polyoxypropylenediamine (Avg. MW 230) 9046-10-0 No data available.
Polyoxypropylenediamine (Avg. MW 400) 9046-10-0 No data available.
Polypropyleneglycol 25322-69-4 USA WEEL; 10 mg/m
3
TWA

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Clear
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.7
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C)
FLASH POINT: ……………………………………………………………………….. >200

F (93.3 C)
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… <1 mm/Hg @ 20 C. SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.95 (20 C). BULK DENSITY.................................................................................. 7.95 lbs./gal. (0.95 kg/L) VAPOR DENSITY (air = 1) ................................................................. No data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data. WATER SOLUBILITY (% BY WT.) ..................................................... Soluble. PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data. KINEMATIC VISCOSITY: ................................................................... 15.8 (mm 2 /s @ 25 C) DECOMPOSITION TEMPERATURE : ................................................. No data available % VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below. VOC Content Resin/Hardener (g/L) (lbs/gal) CCR / CCS ................................................................................. 8.0 0.07 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. REACTIVITY/HAZARDOUS REACTIONS: ......................................... Product will not react by itself. A mass of more than one pound of product mixed with an epoxy resin will cause irreversible polymerization with significant heat buildup. Strong acids can cause polymerization. INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat. DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to decomposition. Decomposition products may include, but not limited to: oxides of carbon, oxides of nitrogen, volatile amines. 11. TOXICOLOGICAL INFORMATION Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Polyoxypropylenediamine (Avg. MW 230) 9046-10-0 2885 mg/kg 2980 mg/kg >0.74 mg/l 8h
Polyoxypropylenediamine (Avg. MW 400) 9046-10-0 1100 mg/kg 1555 mg/kg >0.74 mg/l 8h

CCS Hardener
Page 4 of 6 Last Revised: 30JAN20
Polypropyleneglycol 25322-69-4 >2000 mg/kg >3000 mg/kg No data available
Note: Results in this table were derived using the appropriate rat and rabbit species unless otherwise noted.

ACUTE TOXICITY: …………………………………………………………… Acute toxicity data does not exist for this mixture.
Oral: ……………………………………………………………………….. Not classified. Based on available data product does not meet
acute oral toxicity classification criteria. Ingestion may result in gastrointestinal tract irritation, pain and possible burns. Can
cause burns to the mouth and throat.
Dermal: …………………………………………………………………… Not classified. Based on available data product does not meet
acute dermal toxicity classification criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data product does not meet
acute inhalation toxicity classification criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Category 1C. Causes severe skin burns. Effects may be
immediate.

SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious, irreversible eye damage. Effects
may be immediate.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data product does not meet
classification criteria.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Based on available data product does not meet
classification criteria.

REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data product does not meet classification
criteria.

MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data product does not meet classification
criteria.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data product does not meet classification
criteria. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a probable, possible or confirmed human
carcinogen by IARC, NTP, ACGIH or OSHA.

SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data product does not meet classification
criteria.

SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Not classified. Based on available data product does not meet classification
criteria.

ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data product does not meet classification
criteria.

OTHER HEALTH HAZARD INFORMATION : ……………………………….. No data available.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY :……………………………………………………. Category 3. Harmful to aquatic life.

CHRONIC AQUATIC TOXICITY : ……………………………………………….. Category 3. Harmful to aquatic life with long lasting effects.

PERSISTANCE AND BIODEGRADABILITY : ………………………………. Not biodegradable.

MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.

ADDITIONAL ECOTOXICITY INFORMATION: …………………………….. In the liquid, uncured state, this is harmful to aquatic life with
long lasting effects. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification Information
Polyoxypropylenediamine (Avg. MW 230) 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polyoxypropylenediamine (Avg. MW 400) 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polypropyleneglycol 25322-69-4 Not classified

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL ME THOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

CCS Hardener
Page 5 of 6 Last Revised: 30JAN20
US DOT
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

IMDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… No

ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.

US EPA TSCA Specific Requirements: …………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): ………….. No data available.

US EPA SARA TITTLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. Component RQ (propylene oxide) = 100 lbs. Calculated RQ not reasonably
attainable.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. No data available.

US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAME
/CAS NUMBER STATE CODE

Propylene oxide
75-56-9 < 0.05% 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both, and are regulated under Calif. Prop. 65. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Update to Section 1. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. CCS Hardener Page 6 of 6 Last Revised: 30JAN20 SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 30, 2020 SUPERSEDES DATE: ........................................................................ July 9, 2019 SDS VERSION: .................................................................................. CCS-2020a OTHER HAZARD INFORMATION AND RATING SYSTEMS: HMIS RATING NFPA 704 CODES HEALTH: 3 FLAMMABILITY: 1 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 3 0 1

81EH-CCF-4_SDS.pdf

by | Sep 27, 2025

SAFETY DATA SHEET
Last Revised: 30JAN20

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… CCF Hardener
APPLICABLE PRODUCT CODE S: ………………. CCF, CCF-1, CCF-2, CCF-3, CCF-4, CCF-5, CCF-6, CCF-7, CCF-8, CCF-D, CCF-T
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. CCF-2020a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 310-882-2120 or 989-684-7286 Non-transportation
www.entropyresins.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 1C
Eye damage/irritation, Category 1
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Reproductive toxicity, Category 2
Specific target organ toxicity, repeated exposure respiratory, Category 2
Acute aquatic toxicity, Category 3
Chronic aquatic toxicity, Category 3

Label Elements

Hazard Pictogram(s):

Signal Word:
DANGER

Hazard Statements:
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure if swallowed
H412 Harmful to aquatic life with long lasting effects

Precautionary Statements:
Prevention
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P331 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention/advice
P310 Immediately call a POISON CENTER or doctor
P313 + P333 If irritation or rash occurs: Get medical attention/advice
P314 Get medical attention/advice if you feel unwell
P342 + P 311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor

CCF Hardener
Page 2 of 6 Last Revised: 30JAN20
P362 + P364 Take off contaminated clothing and wash it before reuse
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and international regulations

Other Hazards
None known.

3. COMPOSITION/INFORMATION O N HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Polyoxypropylenediamine 9046-10-0 60-80
2,2′,2″-Nitrilotriethanol

102-71-6 10-30
Piperazine 110-85-0 1-5
1-Piperazineethanamine 140-31-8 1-5

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as a trade secret. Any ingredient not
disclosed may have been determined not to pose a hazard, or may only be present in concentrations that do not require disclosure. Refer to
Section 15 for any additional information regarding a CBI claim.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: May cause allergy or asthma symptoms or breathing
difficulties. Can cause respiratory irritation, shortness of breath or cough. Exposure to concentrated vapors, fumes or mist can cause damage to
lung tissue. RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call POISON CONTROL CENTER
or doctor if symptoms develop and persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes. When mixed with sawdust, wood chips, or other
cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If the heat is not
dissipated quickly enough, it can ignite the sawdust.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).

CCF Hardener
Page 3 of 6 Last Revised: 30JAN20

STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Avoid direct sunlight. Store in a secure location with restricted access or store locked up.

HANDLING PRECAUTIONS: ……………………………………………………. Use with adequate ventilation. Do not breathe vapors or mists from heated
material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy resin
this product causes an exothermic reaction, which in large masses, can produce enough heat to undergo thermal decomposition damage or ignite
surrounding materials. Fumes and vapors released as a result of thermal decomposition can vary widely in composition and toxicity.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.

SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Polyoxypropylenediamine (D230) 9046-10-0 No data available
Polyoxypropylenediamine (D400) 9046-10-0 No data available
2,2′,2″-Nitrilotriethanol 102-71-6 ACGIH TLV TWA: 5.0mg/m3
Piperazine 110-85-0 ACGIH TLV TWA: 0.03mg/m
3
(inhalable fraction and vapor)
1-Piperazineethanamine 140-31-8 No data available

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Clear.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 11.4
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. > 200

F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C estimated based on ingredient data. SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 0.97 BULK DENSITY.................................................................................. 8.15 lbs./gal. (0.97 kg/L) VAPOR DENSITY (air = 1) ................................................................. No data. EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data. WATER SOLUBILITY (% BY WT.) ..................................................... Appreciable. PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data. KINEMATIC VISCOSITY: ................................................................... 48.4 (mm 2 /s @ 20 C) DECOMPOSITION TEMPERATURE : ................................................. No data available. % VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below. VOC Content Resin/Hardener (g/L) (lb/gal) CCR / CCF ................................................................................. 9.2 0.08 10. STABILITY AND REACTIVITY STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures. CCF Hardener Page 4 of 6 Last Revised: 30JAN20 REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself under normal operating temperatures. A mass of more than one pound of product plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure. INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g., methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the drum could expand and rupture violently. CONDITIONS TO AVOID: .................................................................. Avoid excessive heat and direct sunlight. DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to thermal decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid. 11. TOXICOLOGICAL INFORMA TION Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation Polyoxypropylenediamine (D230) 9046-10-0 2885 mg/kg 2980 mg/kg >0.74 mg/L 8h mist
Polyoxypropylenediamine (D400) 9046-10-0 1100 mg/kg 1555 mg/kg >0.74 mg/L 8h mist
2,2′,2″-Nitrilotriethanol 102-71-6 No data available >22,000 mg/kg No data available
Piperazine 110-85-0 2600 mg/kg 8300 mg/kg No data available
1-Piperazineethanamine 140-31-8 2108 mg/kg 866 mg/kg No data available

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data the product does not
meet classification criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data the product does not
meet classification criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data the product does not
meet classification criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Category 1C. Causes severe skin burns. May cause persistent
irritation or dermatitis.

SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.

RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. May cause allergy or asthma symptoms or breathing
difficulties. Can cause respiratory irritation, shortness of breath or cough.

SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.

REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. Suspected of damaging fertility or the unborn child.

MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data the product does not meet
classification criteria.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data the product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data the product does not meet
classification criteria.

SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. Category 2. May cause damage to the respiratory system through
prolonged or repeated exposure if inhaled.

ASPIRATION HAZARD: …………………………………………………………… Not classified. Based on available data the product does not meet
classification criteria.

OTHER HEALTH HAZARD INFORMATON : ………………………………… This product is corrosive to skin and mucous membrane tissues. As a result
of this identified hazard, it is anticipated that excessive inhalation of vapors may also cause irritation to the respiratory tract.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY :……………………………………………………. Category 3. Harmful to aquatic life. Calculated Estimate. No
specific test data available for the mixture. Avoid release to the environment.

CHRONIC AQUATIC TOXICITY : ……………………………………………….. Category 3. Harmful to aquatic life with long lasting effects.
Calculated Estimate. No specific test data available for the mixture. Avoid release to the environment.

PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.

MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.

CCF Hardener
Page 5 of 6 Last Revised: 30JAN20

ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification Information
Polyoxypropylenediamine (D230) 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polyoxypropylenediamine (D400) 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2,2′,2″-Nitrilotriethanol 102-71-6 Not classified
Piperazine 110-85-0 Acute Aquatic Cat. 3
1-Piperazineethanamine 140-31-8 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL MET HOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

US DOT
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

IMDG
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… No

ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 2735
SHIPPING NAME: ……………………………………………………………………. Polyamines, liquid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.

US EPA TSCA Requirements: ………………………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): ………….. No data available.

US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… No data available.
Subject to Section 304 (RQ) ……………………………………………….. No data available.

CCF Hardener
Page 6 of 6 Last Revised: 30JAN20
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. No data available.

US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAME
/CAS NUMBER STATE CODE

Propylene oxide
75-56-9 < 0.065% 1 CA Piperazine 110-85-0 MA, PA, NJ 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Updates to Section 1. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 30, 2020 SUPERSEDES DATE: ........................................................................ July 9,2019 SDS VERSION: .................................................................................. CCF-2020a OTHER HAZARD INFORMATION AND RATING SYSTEMS: HMIS RATING NFPA 704 CODES HEALTH: 3 FLAMMABILITY: 1 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 3 0 1

81EH-CCF-3_SDS.pdf