by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 03JAN22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ACE-166 Resin
APPLICABLE PRODUCT CODES: ………………. ACE-166, ACE-166-1, ACE-166-2, ACE-166-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin for composites.
PRODUCT RESTR ICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ACE-166-2022a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-80
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
PRO-SET
ACE-166 Resin
Page 2 of 6 Last Revised: 03JAN22
Benzyl alcohol 100-51-6 1-5
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-, ethyl ester 57834-33-0 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEA SE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
PRO-SET
ACE-166 Resin
Page 3 of 6 Last Revised: 03JAN22
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-,
ethyl ester
57834-33-0
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F. Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.7 lbs./gal. (1.17kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available.
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
Benzyl alcohol 100-51-6 1620 mg/kg No data >4.18 mg/l;
4h aerosol
Benzoic acid, 4[{(methylphenylamino)
methylene} amino]-, ethyl ester
57834-33-0
1000-2000 mg/kg
No data
No data
PRO-SET
ACE-166 Resin
Page 4 of 6 Last Revised: 03JAN22
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data does not meet acute oral
toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data does not meet acute
dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data does not meet acute inhalation
toxicity criteria. If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high
concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 2 – Causes skin irritation.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Category 2A – Causes serious eye irritation.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data does not meet criteria for
respiratory sensitizer. Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase
the chance of developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. Category 1 – May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data does not meet criteria for
reproductive toxicity.
Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth
defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data does not meet criteria for
mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data does not meet criteria for
carcinogenicity.
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or
IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Based on available data does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Based on available data does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Based on available data does not meet aspiration
toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
PRO-SET
ACE-166 Resin
Page 5 of 6 Last Revised: 03JAN22
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-
, ethyl ester
57834-33-0
Not Classified
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 57834-33-0 listed on NDSL only. All other ingredients listed or otherwise
compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ........................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): .............. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2.
Subject to Section 313 ................................................................ No data available.
PRO-SET
ACE-166 Resin
Page 6 of 6 Last Revised: 03JAN22
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
Benzyl alcohol
100-51-6 MA, PA, NJ
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Approval date change.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ January 3, 2022
SUPERSEDES DATE: ........................................................................ October 22, 2019
SDS VERSION: .................................................................................. ACE-166-2022a
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
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by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 03JAN22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ACE-166 Resin
APPLICABLE PRODUCT CODES: ………………. ACE-166, ACE-166-1, ACE-166-2, ACE-166-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin for composites.
PRODUCT RESTR ICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ACE-166-2022a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-80
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
PRO-SET
ACE-166 Resin
Page 2 of 6 Last Revised: 03JAN22
Benzyl alcohol 100-51-6 1-5
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-, ethyl ester 57834-33-0 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEA SE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
PRO-SET
ACE-166 Resin
Page 3 of 6 Last Revised: 03JAN22
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-,
ethyl ester
57834-33-0
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F. Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.7 lbs./gal. (1.17kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available.
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
Benzyl alcohol 100-51-6 1620 mg/kg No data >4.18 mg/l;
4h aerosol
Benzoic acid, 4[{(methylphenylamino)
methylene} amino]-, ethyl ester
57834-33-0
1000-2000 mg/kg
No data
No data
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ACE-166 Resin
Page 4 of 6 Last Revised: 03JAN22
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data does not meet acute oral
toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data does not meet acute
dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data does not meet acute inhalation
toxicity criteria. If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high
concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 2 – Causes skin irritation.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Category 2A – Causes serious eye irritation.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data does not meet criteria for
respiratory sensitizer. Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase
the chance of developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. Category 1 – May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data does not meet criteria for
reproductive toxicity.
Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth
defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data does not meet criteria for
mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data does not meet criteria for
carcinogenicity.
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or
IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Based on available data does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Based on available data does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Based on available data does not meet aspiration
toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
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Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-
, ethyl ester
57834-33-0
Not Classified
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 57834-33-0 listed on NDSL only. All other ingredients listed or otherwise
compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ........................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): .............. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2.
Subject to Section 313 ................................................................ No data available.
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STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
Benzyl alcohol
100-51-6 MA, PA, NJ
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Approval date change.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ January 3, 2022
SUPERSEDES DATE: ........................................................................ October 22, 2019
SDS VERSION: .................................................................................. ACE-166-2022a
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 03JAN22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ACE-166 Resin
APPLICABLE PRODUCT CODES: ………………. ACE-166, ACE-166-1, ACE-166-2, ACE-166-4
CHEMICAL FAMILY: ………………………………….. Epoxy resin mixture.
INTENDED PRODUCT USES: ……………………… Epoxy resin for composites.
PRODUCT RESTR ICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ACE-166-2022a
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: …………….. 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Skin corrosion/irritation, Category 2
Skin sensitizer, Category 1
Eye damage/irritation, Category 2A
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
WARNING
Hazard Statements:
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statements:
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P 280 Wear protective gloves/protective clothing/eye protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
P362 + P364 Take off contaminated clothing and wash it before re-use.
P391 Collect spillage.
Disposal
P501 Dispose of contents/container in accordance with local, regional and international regulations.
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers 25085-99-8 60-80
Phenol-Formaldehyde Polymer Glycidyl Ether 28064-14-4 10-30
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Benzyl alcohol 100-51-6 1-5
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-, ethyl ester 57834-33-0 1-5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes serious irritation and redness. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as precautionary measure.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin irritation. May cause allergic skin reaction and
sensitization. RESPONSE: Remove contaminated clothing. Wipe excess from skin. Apply waterless skin cleaner and then wash with soap and
water. Consult a physician if effects occur.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Not a likely route of exposure under normal conditions of use.
RESPONSE: Remove to fresh air if respiratory irritation occurs and keep comfortable for breathing.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to:
phenolics, carbon monoxide, and carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat.
6. ACCIDENTAL RELEA SE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Warm, soapy water or non-flammable, safe solvent may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 120 F (49 C)
STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in tightly sealed containers to prevent
moisture absorption and loss of volatiles. Excessive heat over long periods of time will degrade the resin.
HANDLING PRECAUTIONS: ……………………………………………………. Avoid skin and eye contact. Wash thoroughly after handling. Launder
contaminated clothing before reuse. Avoid inhalation of vapors from heated product. Precautionary steps should be taken when curing product in
large quantities. When mixed with epoxy curing agents this product causes an exothermic, which in large masses, can produce enough heat to
damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields or chemical splash goggles.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, or organic vapor cartridge + P100 particulate filter,
depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and
PRO-SET
ACE-166 Resin
Page 3 of 6 Last Revised: 03JAN22
cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Avoid skin contact when removing gloves and other protective equipment. Wash thoroughly after handling. Generally speaking, working
cleanly and following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use
conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
No data available
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 No data available
Benzyl alcohol 100-51-6 10 ppm (AIHA-WEEL)
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-,
ethyl ester
57834-33-0
No data available.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Liquid.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Mild.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F. Estimated based on ingredient data.
FLASH POINT: ……………………………………………………………………….. >200 F (93
C). Estimated based on ingredient data.
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 1.17
BULK DENSITY………………………………………………………………………. 9.7 lbs./gal. (1.17kg/L)
VAPOR DENSITY (air = 1) ……………………………………………………….. Heavier than air. Estimated based on ingredient data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. No data available
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available.
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. ASTM D 2369-07 was used to determine the Volatile Content of mixed
epoxy resin and hardener. Refer to the hardener SDS for information about the total volatile content of the resin/hardener system.
10. STABILITY AND REACTIVITY
STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself. A mass of more than one pound of product
plus an aliphatic amine will cause irreversible polymerization with significant heat buildup. Strong acids, bases, amines and mercaptans can cause
polymerization.
INCOMPATIBILITIES: ……………………………………………………………… Strong acids, bases, amines and mercaptans can cause polymerization.
External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a drum, the
drum could expand and rupture violently.
CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive heat.
DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide and phenolics may be produced during
uncontrolled exothermic reactions or when otherwise heated to decomposition.
11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION
Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-,
polymers
25085-99-8
>15,000 mg/kg
(rat)
>23,000 mg/kg
(rabbit)
No data
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 >2,000 mg/kg
(rat)
2,000 mg/kg
(rat)
No data
Benzyl alcohol 100-51-6 1620 mg/kg No data >4.18 mg/l;
4h aerosol
Benzoic acid, 4[{(methylphenylamino)
methylene} amino]-, ethyl ester
57834-33-0
1000-2000 mg/kg
No data
No data
PRO-SET
ACE-166 Resin
Page 4 of 6 Last Revised: 03JAN22
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Based on available data does not meet acute oral
toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Based on available data does not meet acute
dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Based on available data does not meet acute inhalation
toxicity criteria. If product is heated, vapors generated can cause headache, nausea, dizziness and possible respiratory irritation if inhaled in high
concentrations.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 2 – Causes skin irritation.
SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Category 2A – Causes serious eye irritation.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data does not meet criteria for
respiratory sensitizer. Repeated exposure to high vapor concentrations may cause irritation of pre-existing lung allergies and increase
the chance of developing allergy symptoms to this product.
SKIN SENSITIZATION:…………………………………………………………….. Category 1 – May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data does not meet criteria for
reproductive toxicity.
Diglycidyl ether bisphenol-A, in animal studies, has been shown not to interfere with reproduction. Diglycidyl ether bisphenol-A did not cause birth
defects or other adverse effects on the fetus when pregnant rabbits were exposed by skin contact, the most likely route of exposure, or when
pregnant rats or rabbits were exposed orally.
MUTAGENICITY: …………………………………………………………………….. Not classified. Based on available data does not meet criteria for
mutagenicity.
Diglycidyl ether bisphenol-A in animal mutagenicity studies were negative. In vitro mutagenicity tests were negative in some cases and positive in
others.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data does not meet criteria for
carcinogenicity.
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA, NTP or
IARC.
Many studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of bisphenol-A. Although some weak evidence of
carcinogenicity has been reported in animals, when all of the data are considered, the weight of evidence does not show that Diglycidyl ether
bisphenol-A is carcinogenic. Indeed, the most recent review of the available data by the International Agency for Research on Cancer (IARC) has
concluded that Diglycidyl ether bisphenol-A is not classified as a carcinogen.
Epichlorohydrin, an impurity in this product (<5 ppm) has been reported to produce cancer in laboratory animals and to produce mutagenic
changes in bacteria and cultured human cells. It has been established by the International Agency for Research on Cancer (IARC) as a probable
human carcinogen (Group 2A) based on the following conclusions: human evidence inadequate; animal evidence sufficient. It has been
classified as an anticipated human carcinogen by the National Toxicology Program (NTP). Note: It is unlikely that normal use of this product
would result in measurable exposure concentrations to this substance.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): .............. Not classified. Based on available data does not meet STOT SE criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): ........ Not classified. Based on available data does not meet STOT RE criteria.
ASPIRATION HAZARD : ..................................................................... Not classified. Based on available data does not meet aspiration
toxicity criteria.
OTHER HEALTH HAZARD INFORMATION : ...................................... None known.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated
Estimate: Not classified. Does not meet acute aquatic classification criteria.
CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated
Estimate: Aquatic Chronic Category 2.
PERSISTANCE AND BIODEGRADABILITY : ..................................... No specific test data available for the mixture.
MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : ................................... In the liquid, uncured state, this product may be harmful to
aquatic life long lasting effects. Prevent release to the environment, sewers and natural waters.
PRO-SET
ACE-166 Resin
Page 5 of 6 Last Revised: 03JAN22
Ingredient CAS# Ecotoxicity Classification Information
Propane, 2,2-bis[p-(2,3-epoxypropoxy)phenyl]-, polymers
25085-99-8
Aquatic Chronic Cat. 2
Phenol-formaldehyde polymer glycidyl ether 28064-14-4 Aquatic Chronic Cat. 2
Benzyl alcohol 100-51-6 Not Classified
Benzoic acid, 4[{(methylphenylamino) methylene} amino]-
, ethyl ester
57834-33-0
Not Classified
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
CANADA TDG
UN NUMBER: ..................................................................................... Not regulated.
SHIPPING NAME: ............................................................................... Not applicable.
TECHNICAL SHIPPING NAME: .......................................................... Not applicable.
HAZARD CLASS: ................................................................................ Not applicable.
PACKING GROUP: ............................................................................. Not applicable.
IMDG
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
EmS Number: .................................................................................... F-A, S-F
MARINE POLLUTANT ........................................................................ Yes
ICAO/IATA
UN NUMBER: ..................................................................................... UN3082.
SHIPPING NAME: ............................................................................... Environmentally hazardous substance, liquid, n.o.s.
TECHNICAL SHIPPING NAME: .......................................................... Epoxy Resin.
HAZARD CLASS: ................................................................................ Class 9.
PACKING GROUP: ............................................................................. PG III.
MARINE POLLUTANT: ....................................................................... Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) CAS# 57834-33-0 listed on NDSL only. All other ingredients listed or otherwise
compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ........................................................... No data available.
Canada WHMIS Confidential Business Information (CBI): .............. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ..................................................... No data available.
Subject to Section 304 (RQ) ........................................................ No data available.
Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2.
Subject to Section 313 ................................................................ No data available.
PRO-SET
ACE-166 Resin
Page 6 of 6 Last Revised: 03JAN22
STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER STATE CODE
Epichlorohydrin
106-89-8 < 5ppm
1
CA
Benzyl alcohol
100-51-6 MA, PA, NJ
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Approval date change.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
SDS CONTACT: ................................................................................. safety@gougeon.com
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ January 3, 2022
SUPERSEDES DATE: ........................................................................ October 22, 2019
SDS VERSION: .................................................................................. ACE-166-2022a
OTHER HAZARD INFORMATION AND RATING SYSTEMS :
HMIS RATING NFPA 704 CODES
HEALTH: 2
FLAMMABILITY: 1
PHYSICAL HAZARD: 1
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
2 1
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 24OCT23
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-277-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-277-QC, ADV-277-QC-0, ADV-277-QC-2, ADV-277-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-277-QC-2023A
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts, fumes, gas, mists, vapors or spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention/advice
PRO-SET
ADV-277-QC HARDENER
Page 2 of 7 Last Revised: 24OCT23
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGR EDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Trimethylolpropane polyoxpropylenetriamine 39423-51-3 10-30
Benzyl alcohol 100-51-6 10-30
Isophoronediamine 2855-13-2 10-30
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 7-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 5-10
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Hydroxybenzene 108-95-2 1-5
Triethyleneteteramine, reaction products with propylene oxide 26950-63-0 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE : Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
PRO-SET
ADV-277-QC HARDENER
Page 3 of 7 Last Revised: 24OCT23
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Trimethylolpropane polyoxpropylenetriamine 39423-51-3 No data available
Benzyl alcohol 100-51-6 10 ppm TWA (WEEL)
Isophoronediamine 2855-13-2 No data available
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2 No data available (reference IPD)
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Triethyleneteteramine, reaction products with
propylene oxide
26950-63-0
No data available
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
PRO-SET
ADV-277-QC HARDENER
Page 4 of 7 Last Revised: 24OCT23
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.02
BULK DENSITY.................................................................................. 8.56 lbs./gal. (1.02kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175-NC/ADV-277-NC ......................................................... 11.44 0.10
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes,
nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Trimethylolpropane polyoxpropylenetriamine 39423-51-3 550 mg/kg >1000 mg/kg No data available
Benzyl alcohol 100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2 No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h
Triethyleneteteramine, reaction products with
propylene oxide
26950-63-0 > 2000 mg/kg
(ATE)
> 2000 mg/kg
(ATE)
No data
Diethylenetriamine 111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.
PRO-SET
ADV-277-QC HARDENER
Page 5 of 7 Last Revised: 24OCT23
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION: ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Trimethylolpropane polyoxpropylenetriamine 39423-51-3 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 2
Benzyl alcohol 100-51-6 No data available
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2 No data available (reference IPD)
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Triethyleneteteramine, reaction products with propylene
oxide
26950-63-0
Aquatic Chronic Cat. 3
Diethylenetriamine 111-40-0 No data available
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
PRO-SET
ADV-277-QC HARDENER
Page 6 of 7 Last Revised: 24OCT23
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Trimethylolpropane polyoxpropylenetriamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Trimethylolpropane polyoxpropylenetriamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Trimethylolpropane polyoxpropylenetriamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Trimethylolpropane polyoxpropylenetriamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): …….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
16. OTHER INFORMATION
PRO-SET
ADV-277-QC HARDENER
Page 7 of 7 Last Revised: 24OCT23
REASON FOR ISSUE:……………………………………………………………… Change to Section 1.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. September 12, 2022
SUPERSEDES DATE: ……………………………………………………………… January 3, 2022
SDS VERSION: ………………………………………………………………………. ADV-277-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-276-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-276-QC, ADV-276-QC-0, ADV-276-QC-1, ADV-276-QC-2, ADV-276-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-276-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Reproductive toxicity, Category 2
Specific target organ toxicity single exposure, Category 3
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 1
Chronic aquatic toxicity, Category 1
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
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ADV-276-QC HARDENER
Page 2 of 8 Last Revised: 12SEP22
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention or advice
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIEN TS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 10-30
Polyoxypropylenediamine 9046-10-0 10-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-13
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products with 1-
piperazineethanamine
206565-89-1 5-10
Hydroxybenzene 108-95-2 3-7
Synthetic amorphous, pyrogenic silica 112945-52-5 3-7
Glass oxide 65997-17-3 3-7
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
4-tert-butylphenol 98-54-4 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system. May cause allergy, asthma symptoms or breathing
difficulties if inhaled. Serious effects may be delayed following exposure. RESPONSE: Remove to fresh air if effects occur and keep comfortable
for breathing. Immediately call a POISON CONTROL CENTER or doctor if symptoms develop and persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
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ADV-276-QC HARDENER
Page 3 of 8 Last Revised: 12SEP22
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PR OCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Do not handle until all safety precautions have been read and understood.
Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and
eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses,
can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing. Persons with a history of skin sensitization problems may need to avoid using this
product entirely.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard. Persons with a history of asthma, allergies or chronic or
recurrent respiratory disease should not be employed in any process in which this product is used.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2
No data available (reference Isophoronediamine)
Polyoxypropylenediamine 9046-10-0 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
Isophoronediamine 2855-13-2 No data available
Tall Oil Fatty Acids, C18-unsatd., dimers,
reaction products with 1-piperazineethanamine
206565-89-1 No data available
Hydroxybenzene
108-95-2
ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
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ADV-276-QC HARDENER
Page 4 of 8 Last Revised: 12SEP22
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Glass oxide 65997-17-3 Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available (reference Diethylenetriamine)
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
4-tert-butylphenol 98-54-4 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.65 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-176 / ADV-276 .................................................................... 7.69 0.06
ADV-175 / ADV-276 .................................................................... 4.34 0.04
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a
drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid heating or processing at temperatures greater than 120
F (48
C).
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines,
ammonia, nitric acid, aldehydes, nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2 No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
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Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction
products with 1-piperazineethanamine
206565-89-1 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Glass oxide 65997-17-3 No data available No data available No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
4-tert-butylphenol 98-54-4 > 2000 mg/kg No data available. No data available.
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough. May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. A component in this product is reported to cause
allergy, asthma symptoms or breathing difficulties if inhaled. Serious effects may be delayed following exposure.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. This product contains a substance that is suspected of
damaging fertility of the unborn child.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Category 3. This product contains a substance that may cause respiratory if
inhaled.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 1. Calculated Estimate. No specific test
data available for the mixture. Very toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY: ……………………………………………….. Aquatic Chronic Category 1. Calculated Estimate. No specific
test data available for the mixture. Very toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
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ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products
with 1-piperazineethanamine
206565-89-1 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1; M = 10
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Glass oxide 65997-17-3 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
Diethylenetriamine 111-40-0 No data available
4-tert-butylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 1
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS or
REACH
The substances in this product have been pre-registered and/or registered, or are
otherwise exempted from registration, according to EC No. 1907/2006 (REACH).
Canada CEPA (DSL/NDSL) CAS# 206565-89-1 is listed on NDSL; is not listed on DSL.
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Australia AICS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
South Korea KECI No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): …….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classification in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Paratertiarybutylphenol
98-54-4 PA, NJ
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0017%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-276-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
3 0
1
PRO-SET
ADV-276-QC HARDENER
Page 8 of 8 Last Revised: 12SEP22
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 11JUN24
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-276-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-276-QC, ADV-276-BK, ADV-276-QC-0, ADV-276-BK-0, ADV-276-QC-2, ADV-276-BK-2,
ADV-276-QC-4, ADV-276-BK-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-276-QC-2024B
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Reproductive toxicity, Category 2
Specific target organ toxicity single exposure, Category 3
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
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ADV-276-QC HARDENER
Page 2 of 8 Last Revised: 11JUN24
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention or advice
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 10-30
Polyoxypropylenediamine 9046-10-0 10-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-13
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products with 1-
piperazineethanamine
206565-89-1 5-10
Hydroxybenzene 108-95-2 3-7
Synthetic amorphous, pyrogenic silica 112945-52-5 3-7
Glass oxide 65997-17-3 3-7
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
4-tert-butylphenol 98-54-4 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system. May cause allergy, asthma symptoms or breathing
difficulties if inhaled. Serious effects may be delayed following exposure. RESPONSE: Remove to fresh air if effects occur and keep comfortable
for breathing. Immediately call a POISON CONTROL CENTER or doctor if symptoms develop and persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
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EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Do not handle until all safety precautions have been read and understood.
Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and
eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses,
can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing. Persons with a history of skin sensitization problems may need to avoid using this
product entirely.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard. Persons with a history of asthma, allergies or chronic or
recurrent respiratory disease should not be employed in any process in which this product is used.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2
No data available (reference Isophoronediamine)
Polyoxypropylenediamine 9046-10-0 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
Isophoronediamine 2855-13-2 No data available
Tall Oil Fatty Acids, C18-unsatd., dimers,
reaction products with 1-piperazineethanamine
206565-89-1 No data available
Hydroxybenzene
108-95-2
ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
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OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Glass oxide 65997-17-3 Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available (reference Diethylenetriamine)
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
4-tert-butylphenol 98-54-4 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.65 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-176 / ADV-276 .................................................................... 7.69 0.06
ADV-175 / ADV-276 .................................................................... 4.34 0.04
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a
drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid heating or processing at temperatures greater than 120
F (48
C).
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines,
ammonia, nitric acid, aldehydes, nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2 No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
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Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction
products with 1-piperazineethanamine
206565-89-1 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Glass oxide 65997-17-3 No data available No data available No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
4-tert-butylphenol 98-54-4 > 2000 mg/kg No data available. No data available.
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough. May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. A component in this product is reported to cause
allergy, asthma symptoms or breathing difficulties if inhaled. Serious effects may be delayed following exposure.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. This product contains a substance that is suspected of
damaging fertility of the unborn child.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Category 3. This product contains a substance that may cause respiratory if
inhaled.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Very toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY: ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Very toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
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ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products
with 1-piperazineethanamine
206565-89-1 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Glass oxide 65997-17-3 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
Diethylenetriamine 111-40-0 No data available
4-tert-butylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 1
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Contains Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Contains Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Contains Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Contains Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS or
REACH
The substances in this product have been pre-registered and/or registered, or are
otherwise exempted from registration, according to EC No. 1907/2006 (REACH).
Canada CEPA (DSL/NDSL) CAS# 206565-89-1 is not on DSL or NDSL. All other ingredients are listed or otherwise
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compliant.
Australia AICS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
South Korea KECI No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ………………………………………………….. Reference the SNUR in 40 CFR 721.10429 associated with the component
substance CAS# 206565-89-1.
Canada WHMIS Confidential Business Information (CBI): …….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classification in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Paratertiarybutylphenol
98-54-4 PA, NJ
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0017%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 14.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ 11JUN24
SUPERSEDES DA TE: ........................................................................ 3/18/2024
SDS VERSION: .................................................................................. ADV-276-QC-2024B
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
3 0
1
PRO-SET
ADV-276-QC HARDENER
Page 8 of 8 Last Revised: 11JUN24
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 12SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-276-NC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-276-NC, ADV-276-NC-0, ADV-276-NC-1, ADV-276-NC-2, ADV-276-NC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-276-NC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286 Non-transportation
www.prosetepoxy.com Poison Hotline: 800-222-1222
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Respiratory sensitizer, Category 1
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Reproductive toxicity, Category 2
Specific target organ toxicity single exposure, Category 3
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 1
Chronic aquatic toxicity, Category 1
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H361 Suspected of damaging fertility or the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts/fumes/gas/mists/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P284 In case of inadequate ventilation wear respiratory protection
Response
PRO-SET
ADV-276-NC HARDENER
Page 2 of 8 Last Revised: 12SEP22
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical attention or advice
P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 10-30
Polyoxypropylenediamine 9046-10-0 10-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-13
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products with 1-
piperazineethanamine
206565-89-1 5-10
Hydroxybenzene 108-95-2 3-7
Synthetic amorphous, pyrogenic silica 112945-52-5 3-7
Glass oxide 65997-17-3 3-7
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
4-tert-butylphenol 98-54-4 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system. May cause allergy, asthma symptoms or breathing
difficulties if inhaled. Serious effects may be delayed following exposure. RESPONSE: Remove to fresh air if effects occur and keep comfortable
for breathing. Immediately call a POISON CONTROL CENTER or doctor if symptoms develop and persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
PRO-SET
ADV-276-NC HARDENER
Page 3 of 8 Last Revised: 12SEP22
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, high-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Do not handle until all safety precautions have been read and understood.
Use only with adequate ventilation. Do not breathe vapors or mists from heated material. Avoid exposure to concentrated vapors. Avoid skin and
eye contact. Wash thoroughly after handling. When mixed with epoxy resin this product causes an exothermic reaction, which in large masses,
can produce enough heat to damage or ignite surrounding materials and emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS : ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing. Persons with a history of skin sensitization problems may need to avoid using this
product entirely.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard. Persons with a history of asthma, allergies or chronic or
recurrent respiratory disease should not be employed in any process in which this product is used.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2
No data available (reference Isophoronediamine)
Polyoxypropylenediamine 9046-10-0 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5
No data available
Isophoronediamine 2855-13-2 No data available
Tall Oil Fatty Acids, C18-unsatd., dimers,
reaction products with 1-piperazineethanamine
206565-89-1 No data available
Hydroxybenzene
108-95-2
ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
PRO-SET
ADV-276-NC HARDENER
Page 4 of 8 Last Revised: 12SEP22
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Glass oxide 65997-17-3 Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available (reference Diethylenetriamine)
Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
4-tert-butylphenol 98-54-4 No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Colorless.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.65 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-176 / ADV-276 .................................................................... 7.69 0.06
ADV-175 / ADV-276 .................................................................... 4.34 0.04
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating could result in rapid temperature increase and pressure build up. If such a condition were to occur in a
drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid heating or processing at temperatures greater than 120
F (48
C).
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, carbon monoxide, carbon dioxide, volatile amines,
ammonia, nitric acid, aldehydes, nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2 No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
PRO-SET
ADV-276-NC HARDENER
Page 5 of 8 Last Revised: 12SEP22
Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction
products with 1-piperazineethanamine
206565-89-1 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Glass oxide 65997-17-3 No data available No data available No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
4-tert-butylphenol 98-54-4 > 2000 mg/kg No data available. No data available.
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough. May give off gas, vapor or mist that is very irritating or corrosive to the respiratory system.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Category 1. A component in this product is reported to cause
allergy, asthma symptoms or breathing difficulties if inhaled. Serious effects may be delayed following exposure.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Category 2. This product contains a substance that is suspected of
damaging fertility of the unborn child.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Category 3. This product contains a substance that may cause respiratory if
inhaled.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 1. Calculated Estimate. No specific test
data available for the mixture. Very toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY: ……………………………………………….. Aquatic Chronic Category 1. Calculated Estimate. No specific
test data available for the mixture. Very toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
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ADV-276-NC HARDENER
Page 6 of 8 Last Revised: 12SEP22
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the liquid, uncured state, this product may be harmful to
aquatic life with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Tall Oil Fatty Acids, C18-unsatd., dimers, reaction products
with 1-piperazineethanamine
206565-89-1 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1; M = 10
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Glass oxide 65997-17-3 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
Diethylenetriamine 111-40-0 No data available
4-tert-butylphenol 98-54-4 Acute Aquatic Cat. 2; Chronic Aquatic Cat. 1
13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Polyoxypropylenediamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG III
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS or
REACH
The substances in this product have been pre-registered and/or registered, or are
otherwise exempted from registration, according to EC No. 1907/2006 (REACH).
Canada CEPA (DSL/NDSL) CAS# 206565-89-1 is listed on NDSL; is not listed on DSL.
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ADV-276-NC HARDENER
Page 7 of 8 Last Revised: 12SEP22
Australia AICS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
Japan ENCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
South Korea KECI No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS No data available for CAS# 206565-89-1. All other ingredients are listed or otherwise
compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the health and physical classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Paratertiarybutylphenol
98-54-4 PA, NJ
Propylene oxide
75-56-9 < 0.0017%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Change to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 12, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-276-NC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
3 0
1
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ADV-276-NC HARDENER
Page 8 of 8 Last Revised: 12SEP22
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
by | Sep 27, 2025
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-275-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-275-QC, ADV-275-QC-0, ADV-275-QC-1, ADV-275-QC-2, ADV-275-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-275-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts, fumes, gas, mists, vapors or spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention
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P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 7-30
Polyoxypropylenediamine 9046-10-0 10-30
Benzyl alcohol
100-51-6 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 5-10
Hydroxybenzene 108-95-2 5-10
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, hight-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCED URES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
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ADV-275-QC HARDENER
Page 3 of 7 Last Revised: 08SEP22
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 No data available
Benzyl alcohol
100-51-6 10 ppm TWA (WEEL)
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available
Isophoronediamine 2855-13-2 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
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Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.67 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175-QC/ADV-275-QC ......................................................... 9.43 0.08
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes,
nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2
No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
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Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the uncured state, this product may be harmful to aquatic life
with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2
No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Benzyl alcohol
100-51-6
No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Diethylenetriamine 111-40-0 No data available
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13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
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COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0018%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-275-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
by | Sep 27, 2025
SAFETY DATA SHEET
Last Revised: 08SEP22
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ……………………………………… PRO-SET
ADV-275-QC HARDENER
APPLICABLE PRODUCT CODE S: ………………. ADV-275-QC, ADV-275-QC-0, ADV-275-QC-1, ADV-275-QC-2, ADV-275-QC-4
CHEMICAL FAMILY: ………………………………….. Polyamine mixture.
INTENDED PRODUCT USES: ……………………… Curing agent for epoxy adhesive resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. ADV-275-QC-2022b
MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 888-377-6738 or 989-684-7286
www.prosetepoxy.com
2. HAZARDS IDENTIFICATION
Classification of Substance or Mixture
Acute toxicity Oral, Category 4
Acute toxicity Inhalation, Category 4
Skin corrosion/irritation, Category 1B
Skin sensitizer, Category 1
Eye damage/irritation, Category 1
Germ cell mutagenicity, Category 2
Specific target organ toxicity repeated exposure, Category 2
Acute aquatic toxicity, Category 2
Chronic aquatic toxicity, Category 2
Label Elements
Hazard Pictogram(s):
Signal Word:
DANGER
Hazard Statements:
H302 Harmful if swallowed
H332 Harmful if inhaled
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H341 Suspected of causing genetic defects
H373 May cause damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
Precautionary Statements:
Prevention
P201 Obtain special instruction before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dusts, fumes, gas, mists, vapors or spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well ventilated area
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
Response
P301 + P330 + 331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse or wash skin with soap and water (or
shower).
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention
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P310 Immediately call a POISON CONTROL CENTER or doctor
P333 + P313 If skin irritation or rash occurs: Get medical attention/advice
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents and container according to local, state, national and International regulations
Other Hazards
None known.
3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
INGREDIENT NAME CAS # CONCENTRATION (%)
Isophoronediamine, reaction products with phenol and formaldehyde 25265-17-2 7-30
Polyoxypropylenediamine 9046-10-0 10-30
Benzyl alcohol
100-51-6 10-30
Benzene-1,3-dimethanamine, reaction products with phenol and formaldehyde 57214-10-5 7-13
Isophoronediamine 2855-13-2 7-30
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 5-10
Hydroxybenzene 108-95-2 5-10
Synthetic amorphous, pyrogenic silica 112945-52-5 5-10
Benzene-1,3-dimethanamine 1477-55-0 1-5
Polymer of epichlorohydrin / bisphenol A and diethylenetriamine 31326-29-1 1-5
Diethylenetriamine 111-40-0 0.5-1.5
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.
4. FIRST AID MEASURES
FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Causes eye burns and eye damage. RESPONSE: Flush
immediately with water for at least 15 minutes. Remove contact lenses if present and easy to do. Immediately call a POISON CONTROL CENTER
or doctor.
FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: Causes skin burns, redness and irritation. May cause allergic
skin reaction and sensitization. RESPONSE: Immediately wash skin with soap and water. Immediately call a POISON CONTROL CENTER or
doctor.
FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Can cause respiratory irritation, shortness of breath or cough.
RESPONSE: Remove to fresh air if effects occur and keep comfortable for breathing. Immediately call a physician/doctor if symptoms develop and
persist.
FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: May cause gastrointestinal irritation or ulceration. May
cause burns of the mouth and throat. RESPONSE: Rinse mouth with water. DO NOT induce vomiting. If vomiting should occur, keep airway
clear. Immediately call POISON CONTROL CENTER or doctor.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), dry chemical. NON-SUITABLE:
Direct, hight-pressure water stream.
FIRE AND EXPLOSION HAZARDS: ………………………………………….. During a fire, smoke may contain the original materials in addition to
combustion products of varying composition which may be toxic and/or irritating. Combustion products may include, but are not limited to: oxides
of nitrogen, carbon monoxide, carbon dioxide, volatile amines, ammonia, nitric acid, aldehydes, nitrosamines. When mixed with sawdust, wood
chips, or other cellulosic material, spontaneous combustion can occur under certain conditions. Heat is generated as the air oxidizes the amine. If
the heat is not dissipated quickly enough, it can ignite the sawdust.
SPECIAL FIRE FIGHTING PROCED URES: ………………………………… Use full-body protective gear and a self-contained breathing apparatus.
Use of water may generate toxic aqueous solutions. Do not allow water run-off from fighting fire to enter drains or other water courses.
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Page 3 of 7 Last Revised: 08SEP22
6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.
MITIGATION AND CLEAN UP PROCEDURES: …………………………… Stop leak without additional risk. Isolate area. Dike and absorb with inert
material (e.g., sand) and collect in a suitable, closed container. Do not use sawdust, wood chips or other cellulosic materials to absorb the spill, as
the possibility for spontaneous combustion exists. Warm, soapy water may be used to clean residual.
ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Prevent from entering into soil, ditches, sewers, waterways and
groundwater. See Section 12 for environmental impact information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE (min./max.): …………………………………… 40 F (4 C) / 90 F (32 C).
STORAGE: …………………………………………………………………………….. Store in cool, dry place away from high temperatures and moisture. Keep
container tightly closed. Store in a secure location with restricted access or store locked up.
HANDLING PRECAUTIONS: ……………………………………………………. Use only with adequate ventilation. Do not breathe vapors or mists from
heated material. Avoid exposure to concentrated vapors. Avoid skin and eye contact. Wash thoroughly after handling. When mixed with epoxy
resin this product causes an exothermic reaction, which in large masses, can produce enough heat to damage or ignite surrounding materials and
emit fumes and vapors that vary widely in composition and toxicity.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.
EYE PROTECTION GUIDELINES: …………………………………………….. Chemical splash-proof goggles or face shield.
SKIN PROTECTION GUIDELINES: ……………………………………………. Wear liquid-proof, chemical resistant gloves (nitrile-butyl rubber, neoprene,
butyl rubber or natural rubber) and full body-covering clothing.
RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with an organic vapor cartridge, organic vapor cartridge + P100, or a multi-contaminant
cartridge, depending on specific workplace conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator
and cartridge based on ingredients listed in Section 3 and specific workplace conditions. Use and select a respirator according the guidelines
established in OSHA 1910.134 or other applicable respiratory protection standard.
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Use where there is immediate access to safety shower and emergency eye
wash. Wash thoroughly after use. Contact lens should not be worn when working with this material. Generally speaking, working cleanly and
following basic precautionary measures will greatly minimize the potential for harmful exposure to this product under normal use conditions.
OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.
Ingredient Name CAS# Exposure Limit Information
Isophoronediamine, reaction products with
phenol and formaldehyde
25265-17-2 No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 No data available
Benzyl alcohol
100-51-6 10 ppm TWA (WEEL)
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available
Isophoronediamine 2855-13-2 No data available
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 ACGIH TWA: 5 ppm; 19 mg/kg
NIOSH REL: 5 ppm; 19 mg/kg
OSHA PEL: 5 ppm; 19 mg/kg
NIOSH CEILING: 15.6 ppm; 60 mg/kg
Synthetic amorphous, pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3
Dust and PNOS: ACGIH 10mg/m
3
, TWA, Inhalable; 3
mg/m
3
, TWA, Respirable; OSHA PEL 15 mg/m
3
, TWA, total
dust; 5 mg/m
3
, TWA, Respirable
Benzene-1,3-dimethanamine 1477-55-0 NIOSH CEILING: 0.1 mg/m3; Remarks: Potential for dermal
absorption.
ACGIH TLV CEILING: 0.1 mg/m3; SKIN
OSHA CEILING: 0.1 mg/m3; Table Z 1A
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 No data available
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Diethylenetriamine 111-40-0 ACGIH TWA 1ppm; SKIN
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL FORM: ………………………………………………………………….. Gel.
COLOR: ………………………………………………………………………………… Blue.
ODOR: …………………………………………………………………………………… Ammonia-like
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data. Estimated to be between 10-12.5 based on ingredient data.
MELTING POINT / FREEZING POINT ………………………………………… No data.
BOILING POINT (760mm/Hg): ………………………………………………….. > 400 F (204 C) estimated based on similar product.
FLASH POINT: ……………………………………………………………………….. Estimated > 200
F (93 C) estimated based similar product.
AUTO IGNITION TEMPERATURE ……………………………………………… No data.
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data.
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data.
VAPOR PRESSURE ………………………………………………………………… < 1 mmHg @ 20 C (estimated based on ingredient data).
SPECIFIC GRAVITY/DENSITY (water = 1)......................................... 1.04
BULK DENSITY.................................................................................. 8.67 lbs./gal. (1.04kg/L)
VAPOR DENSITY (air = 1) ................................................................. No data.
EVAPORATIOIN RATE (Butyl Acetate = 1) ....................................... No data.
WATER SOLUBILITY (% BY WT.) ..................................................... No data.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ............ No data.
KINEMATIC VISCOSITY: ................................................................... Gel. (mm
2
/s @ 20
C)
DECOMPOSITION TEMPERATURE : ................................................. No data available.
% VOLATILE BY WEIGHT: ................................................................ ASTM 2369-07 was used to determine the Volatile Matter Content of mixed
epoxy resin and hardener. The combined VOC content for the resin and hardener system is listed below.
VOC Content
Resin/Hardener (g/L) (lb/gal)
ADV-175-QC/ADV-275-QC ......................................................... 9.43 0.08
10. STABILITY AND REACTIVITY
STABILITY: ........................................................................................ Product is stable at normal temperatures and pressures.
REACTIVITY/HAZARDOUS REACTIONS : ......................................... Product will not react by itself. A mass of more than one pound of product
plus an epoxy resin will cause irreversible polymerization with significant heat buildup and pressure.
INCOMPATIBILITIES: ........................................................................ Avoid acids, oxidizing materials, halogenated organic compounds (e.g.,
methylene chloride). External heating or self-heating could result in rapid temperature increase and pressure build up. If such a condition were to
occur in a drum, the drum could expand and rupture violently.
CONDITIONS TO AVOID: .................................................................. Avoid excessive heat.
DECOMPOSITION PRODUCTS: ........................................................ Very toxic fumes and gases when burned or otherwise heated to
decomposition. Decomposition products may include, but not limited to: oxides of nitrogen, volatile amines, ammonia, nitric acid, aldehydes,
nitrosamines.
11. TOXICOLOGICAL INFORMATION
Ingredient Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Isophoronediamine, reaction products with phenol
and formaldehyde
25265-17-2
No data available
(reference IPD)
No data available
(reference IPD)
No data available
(reference IPD)
Polyoxypropylenediamine 9046-10-0 2855 mg/kg 2980 mg/kg >0.74 mg/L 8h vapor
Benzyl alcohol
100-51-6
1620 mg/kg
No data available
>4.18 mg/l
4h aerosol
Benzene-1,3-dimethanamine, reaction products
with phenol and formaldehyde
57214-10-5 No data available No data available No data available
Isophoronediamine 2855-13-2 1030 mg/kg >2000 mg/kg >5.01 mg/l dust/mist
4h
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available No data available No data available
Hydroxybenzene 108-95-2 317 mg/kg 630 mg/kg (solid) 900 mg/m3; 8h (solid)
Synthetic amorphous, pyrogenic silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data available
Benzene-1,3-dimethanamine 1477-55-0 980 mg/kg 2000 mg/kg 1.34 mg/l 4h dust/mist
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1 1620 mg/kg No data available No data available
Diethylenetriamine
111-40-0
1080 mg/kg
1090 mg/kg
0.07-0.3 mg/l 4h
mist/aerosol
ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Category 4. Harmful if swallowed .
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Dermal: …………………………………………………………………… Not classified. Based on available data this product does not
meet classification criteria. However, product contains materials that are readily absorbed through the skin. Absorption of phenolic
solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas, spleen, and cause edema of the
lungs.
Inhalation:………………………………………………………………… Category 4. Harmful if inhaled. Can cause respiratory irritation,
shortness of breath or cough.
SKIN CORROSION / IRRITATION: …………………………………………….. Category 1B. Causes severe skin burns. Effects may be
immediate. May cause persistent irritation or dermatitis.
SERIOUS EYE DAMAGE / IRRITATION:…………………………………….. Category 1. Causes serious eye damage. May cause blurred
vision. May cause corneal damage resulting in vision impairment or even blindness.
RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Based on available data this product does not
meet classification criteria.
SKIN SENSITIZATION:…………………………………………………………….. Category 1. May cause allergic skin reaction.
REPRODUCTIVE TOXICITY: …………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
MUTAGENICITY: …………………………………………………………………….. Category 2. This product contains a substance (phenol, CAS# 108-95-2)
that is suspected of causing genetic defects.
CARCINOGENICITY: ……………………………………………………………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure): ………….. Not classified. Based on available data this product does not meet
classification criteria.
SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure): …….. STOT Category 2. Product contains materials that are readily absorbed
through the skin. Absorption of phenolic solutions through the skin may be very rapid and can cause damage to the kidneys, liver, pancreas,
spleen, and cause edema of the lungs.
ASPIRATION HAZARD : …………………………………………………………… Not classified. Based on available data this product does not meet
classification criteria.
OTHER HEALTH HAZARD INFORMATION : ……………………………….. This product contains a component (diethylenetriamine) that is highly toxic
by inhalation when aerosolized due to spraying or when a mist is formed due to heating. It is advised that exposure not occur to product that is
sprayed or heated. While this product does not meet the classification for a respiratory sensitizer, components of this product can cause
aggravation of existing respiratory conditions, such as asthma.
12. ECOLOGICAL INFORMATION
ACUTE AQUATIC TOXICITY :……………………………………………………. Aquatic Acute Category 2. Calculated Estimate. No specific test
data available for the mixture. Toxic to aquatic life. Avoid release to the environment.
CHRONIC AQUATIC TOXICITY : ……………………………………………….. Aquatic Chronic Category 2. Calculated Estimate. No specific
test data available for the mixture. Toxic to aquatic life with long lasting effects. Avoid release to the environment.
PERSISTANCE AND BIODEGRADABILITY : ………………………………. No specific test data available for the mixture.
MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.
ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. In the uncured state, this product may be harmful to aquatic life
with long lasting effects. Prevent release to the environment, sewers and natural waters.
Ingredient CAS# Ecotoxicity Classification Information
Isophoronediamine, reaction products with phenol and
formaldehyde
25265-17-2
No data available (reference IPD)
Polyoxypropylenediamine 9046-10-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Benzyl alcohol
100-51-6
No data available
Benzene-1,3-dimethanamine, reaction products with phenol
and formaldehyde
57214-10-5 Acute Aquatic Cat. 1; Chronic Aquatic Cat. 1
Isophoronediamine 2855-13-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
2-Propenenitrile polymer with 1,3-butadiene 68683-29-4 No data available
Hydroxybenzene 108-95-2 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 2
Synthetic amorphous, pyrogenic silica 112945-52-5 No data available
Benzene-1,3-dimethanamine 1477-55-0 Acute Aquatic Cat. 3; Chronic Aquatic Cat. 3
Polymer of epichlorohydrin / bisphenol A and
diethylenetriamine
31326-29-1
No data available
Diethylenetriamine 111-40-0 No data available
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13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.
Incinerate, recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
US DOT
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
CANADA TDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. No
IMDG
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
EmS Number: ………………………………………………………………………… F-A, S-B
MARINE POLLUTANT ……………………………………………………………… Yes
ICAO/IATA
UN NUMBER: …………………………………………………………………………. UN 3259
SHIPPING NAME: ……………………………………………………………………. Polyamines, solid, corrosive, n.o.s.
TECHNICAL SHIPPING NAME: …………………………………………………. Benzene-1,3-dimethanamine
HAZARD CLASS: …………………………………………………………………….. Class 8
PACKING GROUP: ………………………………………………………………….. PG II
MARINE POLLUTANT: …………………………………………………………….. Yes
15. REGULATORY INFORMATION
COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI No data on CAS# 25265-17-2. All other ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
US EPA TSCA Requirements: ………………………………………………….. No data available.
Canada WHMIS Confidential Business Information (CBI): ………….. No data available.
US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) ……………………………………………… Phenol = 500/1000 (lbs.). TPQ = 500 lbs. if phenol is in powder form and
has a particle size of less than 100 microns or is handled in solution or molten form, or meets the criteria for a NFPA reactivity rating of 2, 3,
or 4.
Subject to Section 304 (RQ) ……………………………………………….. Phenol RQ = 1000 lbs.
Subject to Section 311 or 312 …………………………………………….. Refer to the Health and Physical Classifications in Section 2.
Subject to Section 313 ………………………………………………………. This product contains hydroxybenzene (phenol) and is subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
US STATE REGULATORY INFORMATION:
The following chemicals may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.
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COMPONENT NAME
/CAS NUMBER CONCENTRATION STATE CODE
Benzene-1,3-dimethanamine
1477-55-0 MA, PA, NJ
Hydroxybenzene
108-95-2 PA, MA, NJ, IL, RI
Diethylenetriamine
111-40-0 PA
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA
Propylene oxide
75-56-9 < 0.0018%
1
CA
1.
These substances are known to the state of California to cause cancer or reproductive harm, or both.
16. OTHER INFORMATION
REASON FOR ISSUE:........................................................................ Update to Section 1.
PREPARED BY: ................................................................................. Gougeon Brothers, Inc.
TITLE: ................................................................................................ Health, Safety & Environmental Manager
APPROVAL DATE: ............................................................................ September 8, 2022
SUPERSEDES DATE: ........................................................................ January 3, 2022
SDS VERSION: .................................................................................. ADV-275-QC-2022b
OTHER HAZARD INFORMATION AND RATING SYSTEMS:
HMIS RATING NFPA 704 CODES
HEALTH: 3
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:
Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe
Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
3 0
1
